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1. 发明申请

WO02053520A2 METHOD FOR PRODUCING HYDROCARBONS HAVING A MODIFIED CARBON SKELETON 审中-公开
标题翻译：用改变的碳框架生产碳氢化合物的方法
公开(公告)号：WO02053520A2
公开(公告)日：2002-07-11
申请号：PCT/EP0200054
申请日：2002-01-05
申请人： BASF AG , VANOPPEN DOMINIC , SCHWAB EKKEHARD , BASSET JEAN-MARIE , THIVOLLE-CAZAT JEAN , TAOUFIK MOSTAPHA , SCHULZ MICHAEL , HOEHN ARTHUR
发明人： VANOPPEN DOMINIC , SCHWAB EKKEHARD , BASSET JEAN-MARIE , THIVOLLE-CAZAT JEAN , TAOUFIK MOSTAPHA , SCHULZ MICHAEL , HOEHN ARTHUR
IPC分类号： C07C6/08 , C07C6/10
CPC分类号： C07C6/10 , C07C6/08 , C07C2531/12
摘要： The invention relates to a method for producing hydrocarbons having a modified carbon skeleton by reacting aliphatic hydrocarbons a) with themselves, b) with another aliphatic hydrocarbon or c) with aromatic alkyl substituted hydrocarbons, in the presence of a metal organic catalyst or the hybrid thereof, at a temperature of between 20 - 400 DEG C and a pressure of between 0.2 - 100 bars, wherein the reaction takes place in the presence of hydrogen.
摘要翻译：通过脂族烃反应制备具有改性碳骨架的烃的方法：a）与其本身; b）与另一种脂族烃或c）与芳族烷基取代的烃在有机金属催化剂或其杂化物存在下，在20-400℃的温度和0.2-100巴的压力下，通过在氢存在下执行。

2. 发明申请

WO0166614A3 POLYMERIC ALDEHYDE/POLY(THF)-AMINO NETWORKS 审中-公开
标题翻译：聚合物醛/聚（THF） - 胺NETWORKS
公开(公告)号：WO0166614A3
公开(公告)日：2002-03-07
申请号：PCT/EP0102519
申请日：2001-03-06
申请人： BASF AG , EVSIOUKOV SERGUEI , SCHORNICK GUNNAR , NOUWEN JAN , HOEHN ARTHUR
发明人： EVSIOUKOV SERGUEI , SCHORNICK GUNNAR , NOUWEN JAN , HOEHN ARTHUR
IPC分类号： C08G12/00 , C08G12/02 , C08G12/06 , C08G12/10 , C08G73/06
CPC分类号： C08G73/065 , C08G12/00 , C08G12/02 , C08G12/06 , C08G12/10 , C08G73/0644
摘要： The aim of the invention is to produce polymeric networks. An aldehyde or a mixture of aldehydes or precursors thereof are condensed with a component (A) that contains amines, optionally in the presence of a solvent (S). The component (A) contains at least one amine (I) which can be obtained by means of amination of polymeric ethers of the 1.4 butanediol and is provided with at least two free amino groups. Said component (A) also and optionally contains at least one amine of the formula (II): Y (-NH2)n and optionally contains at least one amine of the formula (III): (Z-)(q-r)Y (-NH2)r, wherein Y means n-valued organic radicals, Y means q-valued organic radicals, Z means functional single-valued radicals, n means an integral value of 1 to 20, q means an integral value of 2 to 20 and r means an integral value of 1 to 19 with the proviso that 1
摘要翻译：聚合物网络可获得该任选地稠合的醛或其前体与含组分A在溶剂S的存在，其中组分A包含由1聚合醚的胺化制得的至少一种胺（I）的胺的醛或混合物 1,4-丁二醇是可用的并且具有至少两个游离氨基，任选地，式中的至少一种胺（II）Y <1>（ - NH 2）N（II）和任选地式中的至少一种胺（III）（Z - ）（ QR）Y <2>（ - NH 2）R（III）其中：Y <1> n价有机残基，Y <2> q价的有机残基，Z官能单价基团，n为1的整数至20，q为从2到20的整数，并且r为1的整数值至19，条件是1

3. 发明授权

US6271430B2 Preparation of propene 失效
标题翻译：丙烯的制备
公开(公告)号：US6271430B2
公开(公告)日：2001-08-07
申请号：US28320199
申请日：1999-04-01
申请人： BASF AG
发明人： SCHWAB PETER , HOEHN ARTHUR
IPC分类号： C07C6/04 , C07C11/06 , C07C6/02
CPC分类号： B01D3/141 , C07C6/04 , C07C11/06 , C07C2521/04 , C07C2523/36 , Y02P20/52
摘要： The present invention relates to a process for preparing propene by metathesis of olefins. The process comprises preparing propene bya) in a first reactor (R1), reacting 1-butene and 2-butene to give propene and 2-pentene in the presence of a metathesis catalyst comprising at least one compound of a metal of transition group VIb, VIIb, or VIII of the Periodic Table of elements,b) subsequently separating the propene, unreacted raffinate II, and 2-pentene formed in a) in a distillation column (D1),c) subsequently reacting the 2-pentene of b) with ethene to give propene and 1-butene in a reactor (R2) in the presence of a metathesis catalyst comprising at least one compound of a metal of transition group VIb, VIIb, or VIII of the Periodic Table of Elements,d) subsequently separating the propene and 1-butene formed in c),e) subsequently returning the 1-butene formed in d) to step a) andf) wherein unreacted raffinate II is taken off at the middle off take of column D1 in b) and partly returned to step a).
摘要翻译：本发明涉及通过烯烃复分解制备丙烯的方法。该方法包括通过在第一反应器（R1）中制备丙烯，使1-丁烯和2-丁烯反应得到丙烯和2-戊烯，在复分解催化剂存在下，该复分解催化剂包含至少一种转移基团VIb的金属化合物， Ⅶb或Ⅷ元素，b）随后将a）中形成的丙烯，未反应的残液II和2-戊烯分离在蒸馏塔（D1）中，c）随后使b）的2-戊烯与乙烯在反应器（R2）中在复分解催化剂存在下给出丙烯和1-丁烯，所述复分解催化剂包含至少一种元素周期表的VIb，VIIb或VIII族过渡金属的化合物，d）随后将丙烯和1-丁烯，e）随后将d）中形成的1-丁烯返回到步骤a）和f），其中未反应的残液II在b）中的中间馏分D1取出，并部分还原为步骤a）。

4. 发明授权

US6111100C1 Preparation of bis(2-morpholinoethyl) ether 有权
标题翻译：双（2-吗啉代乙基）醚的制备
公开(公告)号：US6111100C1
公开(公告)日：2002-04-02
申请号：US47490699
申请日：1999-12-30
申请人： BASF AG
发明人： RIECHERS HARTMUT , SIMON JOACHIM , HENNE ANDREAS , HOEHN ARTHUR
IPC分类号： C07D295/08 , B01J23/72 , C07D295/088 , C07D413/12
CPC分类号： C07D295/088

5. 发明专利

JP2003137845A METHOD FOR PRODUCING AMINE 审中-公开
公开(公告)号：JP2003137845A
公开(公告)日：2003-05-14
申请号：JP2002265909
申请日：2002-09-11
申请人： BASF AG
发明人： SCHAFER MARTIN , BOETTCHER ARND , KRAMER ANDREAS , HOEHN ARTHUR , LIANG SHELUE , FUNKE FRANK DR
IPC分类号： C07C209/22 , C07B61/00 , C07C209/26 , C07C211/07
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an amine, comprising the reductive amination of the corresponding carbonyl or alcohol containing a considerable amount (at least 50 ppm, especially organically bound) of a halogen, by which the amine can simply be produced at a low cost in reduced catalyst consumption rate and in a high yield. SOLUTION: This method for producing the amine of formula (I): R R CH- NR R (I) (R , R , R and R are each, for example, a 1 to 12C alkyl), comprising the catalytic reductive amination of a mixture of a carbonyl compound of formula (II): R -C(=O)-R and/or an alcohol of formula (III): R -CH(OH)-R with at least 50 ppm (based on the mixture) of a halogen in the presence of a Co- and/or Ni-containing catalyst with a nitrogen compound of formula (IV): HNR R , is characterized in that the reductive animation is carried out in the additive presence of a solid acidic cocatalyst.

6. 发明专利

JP2002226437A METHOD FOR RACEMIZING OPTICALLY ACTIVE AMINE 审中-公开
公开(公告)号：JP2002226437A
公开(公告)日：2002-08-14
申请号：JP2001383504
申请日：2001-12-17
申请人： BASF AG
发明人： FUNKE FRANK DR , LIANG SHELUE , KRAMER ANDREAS DR , STUERMER RAINER DR , HOEHN ARTHUR
IPC分类号： C07C209/00 , C07B55/00 , C07B61/00 , C07C209/68 , C07C209/88 , C07C211/03 , C07C213/00 , C07C213/02 , C07C217/08
摘要： PROBLEM TO BE SOLVED: To provide an improved profitable method for racemizing an optically active amine, by which the objective product having a high racemization degree can simultaneously be obtained in a high racemization yield (racemate yield). SOLUTION: This method for racemizing the optically active amine, comprising reacting an optically active amine represented by formula I (R1 and R2 are different from each other; R1, R2, and R3 are each an alkyl, a cycloalkyl, an arylalkyl, an aryl, a heteroaryl or a heterocyclic group; R3 may additionally be H; provided that the above-described groups each may have one or more substituents selected from alkyl groups, cycloalkyl groups, alkoxy groups, aryloxy groups, amino groups, alkylamino groups and dialkylamino groups) in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at an enhanced temperature, is characterized in that the catalyst contains copper and zinc oxide as active catalyst components and a carrying material.

7. 发明专利

JP2003055319A Method for producing secondary amine 有权
标题翻译：生产二级胺的方法
公开(公告)号：JP2003055319A
公开(公告)日：2003-02-26
申请号：JP2002179034
申请日：2002-06-19
申请人： Basf Ag , ビーエーエスエフアクチェンゲゼルシャフト
发明人： NEUMANN PETER , MELDER JOHANN-PETER DR , BENISCH CHRISTOPH , HOEHN ARTHUR , PFEFFINGER JOACHIM
IPC分类号： C07C209/60 , C07B61/00 , C07C209/64 , C07C211/13 , C07C211/14
CPC分类号： C07C209/64 , C07C211/13
摘要： PROBLEM TO BE SOLVED: To provide a preferable method for producing a secondary amine by which a high yield and a high selectivity are achieved.
SOLUTION: The secondary amine of formula (I) (R
1 , R
2 and A are each shown in the specification) is obtained by reacting a primary amine of formula (II): R
1 R
2 N-A-NH
2 [R
1 , R
2 and A are each as previously defined] in the presence of a catalyst containing hydrogen and at least one compound of an atom or an element of groups VIII or IB in the periodic table.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：提供一种制备可以实现高产率和高选择性的仲胺的优选方法。解决方案：式（I）的仲胺（R 1，R 2和A各自在说明书中示出）通过使式（II）的伯胺：R 1 R 2 在含有氢和至少一种元素周期表中VIII或VIII族元素的化合物的催化剂存在下，将NA-NH 2 [R 1，R 2和A各自如前所定义]。

8. 发明专利

JP2001064281A PRODUCTION OF PURE TRIETHYLENEDIAMINE SOLUTION 失效
公开(公告)号：JP2001064281A
公开(公告)日：2001-03-13
申请号：JP2000221322
申请日：2000-07-21
申请人： BASF AG
发明人： RIECHERS HARTMUT , HOEHN ARTHUR , SIMON JOACHIM , LANG ORTMUND , SCHOENMAKERS HARTMUT , RAULS MATTHIAS DR , CLAERBOUT KOEN
IPC分类号： C07D471/08 , C07D487/08
摘要： PROBLEM TO BE SOLVED: To provide an effective and economical method for producing pure triethylenediamine(TEDA) and its solution. SOLUTION: This method for producing pure triethylenediamine solution comprises evaporating triethylenediamine and introducing the gas state triethylenediamine into a liquid solvent. The gaseous triethylendiamine is obtained from the top of a column or its side discharging port. Further, the pure triethylenediamine solution is produced by following the above method and then crystallizing the triethylenediamine from the solution. The liquid solvent is selected from the group consisting of cyclic or non-cyclic hydrocarbons, chlorinated aliphatic hydrocarbons, aromatic hydrocarbons, alcohols, ketones, aliphatic carboxylic acid esters, aliphatic nitriles and ethers.

9. 发明专利

JP2002179626A METHOD FOR PRODUCING AMINE 审中-公开
公开(公告)号：JP2002179626A
公开(公告)日：2002-06-26
申请号：JP2001327394
申请日：2001-10-25
申请人： BASF AG
发明人： LIANG SHELUE DR , FUNKE FRANK , HOEHN ARTHUR
IPC分类号： C07B61/00 , C07C209/14 , C07C209/26 , C07C211/29
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an amine from a ketone or an alkyl. SOLUTION: This method for producing an amine of the formula (I): R1R2CH- NR3R4 [R1 to R4 are each independently hydrogen, a straight-chain or branched 1-12C alkyl, a 3-12C cycloalkyl, a 6-10C aryl or a 7-11C aralkyl; one or more groups of R1 and R2 are each an aryl or an aralkyl in which an aromatic unit is substituted with one or more halogens] comprises carrying out catalytic and reductive amination of a carbonyl compound of the formula (II): R1-C(=O)-R2 or an alcohol of the formula (III): R1-CH(OH)-R2 with a nitrogen compound of the formula (IV) HNR3R4 [R1 to R4 are each the same as described above] in the presence of Co- and/or Ni-containing catalyst and a solid acid cocatalyst in the absence of an organic sulfur compound.

10. 发明专利

JP2001199939A METHOD OF PRODUCING MONOISOPRORYLAMINE 失效
公开(公告)号：JP2001199939A
公开(公告)日：2001-07-24
申请号：JP2000371847
申请日：2000-12-06
申请人： BASF AG
发明人： NOUWEN JAN , KAESHAMMER STEFAN , HOEHN ARTHUR , FUNKE FRANK DR , MELDER JOHANN-PETER DR , GUTSCHOVEN FRANK , BUSKENS PHILIPP DR
IPC分类号： B01J35/02 , B01J23/755 , C07B61/00 , C07C209/26 , C07C211/06
摘要： PROBLEM TO BE SOLVED: To provide a method of producing monoisopropylamine(MIPA), capable of overcoming disadvantages of conventional methods and therefore capable of economically improving the methods, when the MIPA is produced by aminating acetone with ammonia and simultaneously hydrogenating with hydrogen. SOLUTION: This method of producing the MIPA comprises reacting the acetone with the ammonia and the hydrogen in the presence of a catalyst at a high temperature under an increased pressure, wherein the catalyst has a main body for catalytic activity which contains aluminum dioxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2) in an amount of 20-90 wt.%, an oxygen-containing copper compound in an amount of 1-70 wt.% (calculated as CuO), an oxygen-containing nickel compound in an amount of 1-70 wt.% (calculated as NiO) and an oxygen-containing cobalt compound in an amount of 1-70 wt.% (calculated as CoO), when measured at a time after the catalyst is produced but before the catalyst is subjected to hydrogenation treatment.

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