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    • 3. 发明申请
    • PROCESS FOR PREPARING POROUS METAL ORGANIC FRAMEWORKS
    • 用于生产多孔金属有机骨架
    • WO2007131948A3
    • 2008-02-07
    • PCT/EP2007054554
    • 2007-05-11
    • BASF AGPUETTER HERMANNSCHUBERT MARKUSRICHTER INGOMUELLER ULRICHTRUKHAN NATALIA
    • PUETTER HERMANNSCHUBERT MARKUSRICHTER INGOMUELLER ULRICHTRUKHAN NATALIA
    • C25B3/12
    • C25B3/12
    • The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
    • 本发明涉及一种用于制备包含配位的至少两个的至少一种金属有机化合物,包括(a)氧化中的至少一种的存在下相应的含有金属的阳极中的反应介质中的至少一种金属离子的至少之一中的步骤的多孔金属有机骨架 第一有机化合物,其中所述第一有机化合物和任选取代的单 - ,双 - 或多环饱和或未饱和烃基,其中至少两个环碳原子被选自下组的杂原子取代由选自N,O和S的取代, 形成所述至少一个金属离子和第一含有机化合物的中间体反应产物; 和(b)反应,该反应与至少其协调结合到所述至少一种金属离子,其中,二,三或四羧酸的第二有机化合物导出的第二有机化合物中间体在设定温度。
    • 9. 发明申请
    • METHOD FOR PRODUCING ALCOXYLATED CARBONYL COMPOUNDS BY AN ANODIC OXIDATION METHOD USING A CATHODIC COUPLED REACTION FOR ORGANIC SYNTHESIS
    • PROCESS FOR烷氧基化由阳极氧化法UNDER阴极KOPPEL反应在有机合成中使用的制备羰基
    • WO0242524A2
    • 2002-05-30
    • PCT/EP0113587
    • 2001-11-22
    • BASF AGPUETTER HERMANNFISCHER ANDREAS
    • PUETTER HERMANNFISCHER ANDREAS
    • C25B3/02C25B3/00
    • C25B3/00
    • A method for producing alcoxylated carbonyl compounds of general formula (I) (compounds I): R aR C(OR )b wherein R , R represent hydrogen or C1- C6-alkyl, R independently means C1- C6-alkyl, a is 0 or 1, b 2 or 3 with the proviso that the sum of a and b is 3, by means of anodic oxidation of germinal dialcoxy compounds of general formula (II) (compounds II) wherein R , R , R , R represent hydrogen or C1- C6-alkyl, R , R represent C1- C6-alkyl or C1- C6-alcoxy, in the presence of a C1-C6-alkyl alcohol (compounds III).A usual compound (compound IV) is used as a cathodic depolarizer suitable for electrochemical oxidation. The anodic oxidation and cathodic reduction is carried out in an undivided electrolyte cell in the presence of C1-C6-alkyl alcohols.
    • 一种生产通式(I)的烷氧基​​化的羰基化合物的方法(I化合物):R <1> AR <2> C(OR <3>)b式中[R <1>,R <2>是氢或C 1 -C -C 6 - 烷基,R <3>彼此独立地C1-C6烷基,a是0或1,b 2或3,条件是a和b的总和为3,由通式的偕二烷氧基化合物的阳极氧化 (II)(化合物II),其中R <4>,R <5> - [R <6> - [R <7>是氢或C1-C6烷基,R <5> - [R <6>的C1至C6 在C1的存在下C6烷基醇或烷基C1至C6烷氧基(化合物III),被用作消偏振镜一个常规有机化合物(化合物IV)阴极,其适合用于电化学氧化和得到 阳极氧化和在未分割的电解槽的阴极还原在C1-C6烷基醇执行的存在。