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    • 4. 发明申请
    • PROCESS FOR PREPARING POROUS METAL ORGANIC FRAMEWORKS
    • 用于生产多孔金属有机骨架
    • WO2007131948A3
    • 2008-02-07
    • PCT/EP2007054554
    • 2007-05-11
    • BASF AGPUETTER HERMANNSCHUBERT MARKUSRICHTER INGOMUELLER ULRICHTRUKHAN NATALIA
    • PUETTER HERMANNSCHUBERT MARKUSRICHTER INGOMUELLER ULRICHTRUKHAN NATALIA
    • C25B3/12
    • C25B3/12
    • The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
    • 本发明涉及一种用于制备包含配位的至少两个的至少一种金属有机化合物,包括(a)氧化中的至少一种的存在下相应的含有金属的阳极中的反应介质中的至少一种金属离子的至少之一中的步骤的多孔金属有机骨架 第一有机化合物,其中所述第一有机化合物和任选取代的单 - ,双 - 或多环饱和或未饱和烃基,其中至少两个环碳原子被选自下组的杂原子取代由选自N,O和S的取代, 形成所述至少一个金属离子和第一含有机化合物的中间体反应产物; 和(b)反应,该反应与至少其协调结合到所述至少一种金属离子,其中,二,三或四羧酸的第二有机化合物导出的第二有机化合物中间体在设定温度。
    • 8. 发明申请
    • SILICATE PRODUCING METHOD
    • 用于生产硅酸盐
    • WO2007042531A2
    • 2007-04-19
    • PCT/EP2006067269
    • 2006-10-11
    • BASF AGRUBITEC GESELLSCHAFT FUER INNOVATION & TECHNOLOGIE RUHR UNIV BOCHUM MBHMUELLER ULRICHRUETZ ROGERGIES HERMANN
    • MUELLER ULRICHRUETZ ROGERGIES HERMANN
    • C01B37/02Y02P20/582
    • The invention relates to producing a silicate containing at least one type of silicium and oxygen consisting (1) in mixing silicium dioxide and/or silicium dioxide precursors with an aqueous solution, which comprises at least one type of R 1 R 2 R 3 R 4 N + compound containing a tetra-acryl ammonium compound and at least one type of base, wherein R 1 and R 2 represent methyl and, at the same time, R 3 and R 4 represent n-propyl; (2) in heating the colloidal solution thus obtained with a temperature greater than a boiling temperature at a selected colloidal solution pressure up to 180 °C at a normal pressure in such a way that at least one type of silicate-containing suspension is obtained. Said invention is characterised in that the silicium and oxygen-containing silicate is added in the form of a crystallisation-assisting agent.
    • 本发明涉及一种方法,用于至少硅和硅酸盐,包括:(1)将二氧化硅和/或与水溶液含有至少一个R二氧化硅前体含氧 1 - [R 2 - [R 3 - [R 4 ñ + 全面四烷基铵化合物和至少一个基极,其中R 1 且R 2 是甲基且R 3 和R 4 是相同的正丙基; (2)在(1)胶体溶液,以所选择的压力在常压下沸腾的胶体溶液,以180℃的温度,以获得至少一种含硅酸盐的悬浮液下范围从大于本的温度下加热所得到的,其特征在于,作为结晶助剂 至少含有硅和含氧硅酸盐(1)中的溶液。
    • 10. 发明申请
    • METHOD FOR PRODUCING PROPENE FROM PROPANE
    • 用于生产丙烯丙烷
    • WO2007113085A3
    • 2008-03-13
    • PCT/EP2007052354
    • 2007-03-13
    • BASF AGSCHUBERT MARKUSMUELLER ULRICHKIENER CHRISTOPHTEICH FRIEDHELMCRONE SVENSIMON FALKPASTRE JOERG
    • SCHUBERT MARKUSMUELLER ULRICHKIENER CHRISTOPHTEICH FRIEDHELMCRONE SVENSIMON FALKPASTRE JOERG
    • C07C7/12C07C7/13
    • C07C5/333C07C7/12C07C7/13C07C11/06
    • The invention relates to a method for producing propene from propane. Said method comprises the following steps: A) a feed gas stream (a) containing propane is prepared; B) the feed gas stream (a) containing propane, is introduced with optionally water vapour and optionally, an oxygen-containing gas stream into a dehydrogenation zone and then the propane is dehydrogenated to form propene, and a product gas stream (b) containing propane, propene, methane, ethane, ethene, hydrogen, optionally carbon monoxide, carbon dioxide, water vapour and oxygen, is obtained; C) the product gas stream (b) is cooled, optionally compressed and then water vapour is separated by condensation and a product gas stream (c) depleted in water vapour is obtained; D) the product gas stream (c) is brought into contact with a selectively active adsorber which selectively adsorbs propene in the selected adsorption conditions, and an adsorber charged with propene and a gas stream (d2) depleted in propene and containing propane, methane, ethane, ethene and hydrogen, carbon monoxide and carbon dioxide are obtained; E) a gas stream (e1) containing propene is released from the adsorber charged with propene by reducing the pressure and/or heat of the adsorber.
    • 本发明涉及用于由丙烷制备丙烯的方法,包括步骤:A)(a)中,提供了一种含丙烷的原料气流; B)包含(a),任选的蒸汽和任选的含氧气体流中的丙烷进料气流被送入脱氢区和丙烷经受脱氢成丙烯,得到产物气流b包括丙烷,丙烯,甲烷,乙烷,乙烯,氢气,任选的一氧化碳 ,二氧化碳,获得水蒸汽和氧气; C)的产物气流(B)被冷却,冷凝,任选地,这将允许水蒸气通过冷凝分离,得到一个蒸汽贫化产物气流(获得的C); D)的产物气流(c)的具有选择性作用的吸附剂选择性吸附所选择的吸附条件下丙烯,与一个装有丙烯吸附剂和贫丙烯气流(D2)的包含丙烷,甲烷,乙烷,乙烯接触接触 和氢,得到一氧化碳和二氧化碳; E)从载有丙烯吸附剂通过减压和/或吸附剂的加热,气体流包含丙烯(E1)释放。