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    • 1. 发明申请
    • PESTICIDAL MIXTURES
    • 农药混合物
    • WO2007082841A3
    • 2008-01-10
    • PCT/EP2007050280
    • 2007-01-12
    • BASF AGGEWEHR MARKUSPUHL MICHAELDICKHAUT JOACHIMBASTIAANS HENRICUS MARIA MARTIANSPAUGH DOUGLAS DKUHN DAVID GOLOUMI-SADEGHI HASSANARMES NIGEL
    • GEWEHR MARKUSPUHL MICHAELDICKHAUT JOACHIMBASTIAANS HENRICUS MARIA MARTIANSPAUGH DOUGLAS DKUHN DAVID GOLOUMI-SADEGHI HASSANARMES NIGEL
    • A01N43/56
    • A01N43/56A01N2300/00
    • Pesticidal mixtures comprising, as active components, 1 ) an anthranilamid compound of the formula I wherein Q is H, Cl, Cr, I, CN or methyl; B 1 is halogen, alkyl, haloalkyl, or haloalkoxy; B 2 is halogen, haloalkyl, alkoxy, haloalkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, alkyl- S(=O) x -O- or haloalkyl S(O) x -O-, wherein x is 1 or 2 and the alkoxy radical may be substituted, or C(R i )=N-OR j , C(R i )=N(R j R k ), wherein R i , R j and R k are hydrogen or alkyl; R is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, alkylene-cycloalkyl, wherein these groups are optionally substituted; R 1 is F, CI, Br, methyl or trifluoromethyl; or the enantiomers or salts or N-oxides thereof, n is 1 , 2 or 3; and 2) one or more compounds II selected from group A consisting of organo(thio)- phosphates, carbamates, pyrethroids, growth regulators, nicotinic receptor agonists/antagonists compounds, GABA antagonist compounds, macrocyclic lactone insecticides, METI I acaricides, METI II and III compounds, uncoupler compounds, oxidative phosphorylation inhibitor compounds, mixed function oxidase inhibitor compounds, sodium channel blocker compounds and others, all as defined in the description, in synergistically effective amounts, use of these mixture for combating insects, arachnids or nematodes in and on plants and for the protection of seeds, and for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation or infection by parasites.
    • 作为活性成分的农药混合物,1)式I的氨基甲酰胺化合物,其中Q是H,Cl,Cr,I,CN或甲基; B 1是卤素,烷基,卤代烷基或卤代烷氧基; B 2是卤素,卤代烷基,烷氧基,卤代烷氧基,烯氧基,炔氧基,烷硫基,卤代烷硫基,烷基亚磺酰基,卤代烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基,烷基-S(= O) O-或卤代烷基S(O)x -O-,其中x为1或2,烷氧基可以被取代,或C(R i)= N- C(R i)i = N(R i,R k)),其中R 0, R i,R j和R k都是氢或烷基; R是氢,烷基,烯基,炔基,环烷基,亚烷基 - 环烷基,其中这些基团是任选取代的; R 1是F,Cl,Br,甲基或三氟甲基; 或其对映异构体或其盐或N-氧化物,n为1,2或3; 和2)选自有机(硫代) - 磷酸酯,氨基甲酸酯,拟除虫菊酯,生长调节剂,烟碱受体激动剂/拮抗剂化合物,GABA拮抗剂化合物,大环内酯杀虫剂,METI I杀螨剂,METI II和 III化合物,解偶联剂化合物,氧化磷酸化抑制剂化合物,混合功能氧化酶抑制剂化合物,钠通道阻断剂化合物和其它,如描述中所定义的,协同有效量的这些混合物用于对抗昆虫,蜘蛛或线虫 植物和保护种子,以及用于治疗,控制,预防或保护温血动物或鱼类免受寄生虫感染或感染。
    • 2. 发明申请
    • PESTICIDAL MIXTURES
    • 农药混合物
    • WO2007017433A2
    • 2007-02-15
    • PCT/EP2006064950
    • 2006-08-02
    • BASF AGGEWEHR MARKUSPUHL MICHAELDICKHAUT JOACHIMBASTIAANS HENRICUS MARIA MARTIZELLER ALISSAANSPAUGH DOUGLAS DKUHN DAVID GOLOUMI-SADEGHI HASSANARMES NIGEL
    • GEWEHR MARKUSPUHL MICHAELDICKHAUT JOACHIMBASTIAANS HENRICUS MARIA MARTIZELLER ALISSAANSPAUGH DOUGLAS DKUHN DAVID GOLOUMI-SADEGHI HASSANARMES NIGEL
    • A01N43/56A01N51/00A01P5/00A01P7/00
    • A01N43/56A01N51/00A01N2300/00
    • Pesticidal mixtures comprising, as active components, 1 ) an anthranilamid compound of the formula I ,2 (I) Y wherein B1 is halogen, alkyl, haloalkyl, or haloalkoxy; B2 is halogen, haloalkyl, alkoxy, haloalkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, alkyl- S(=O)?-O- or haloalkyl S(O)x-O-, wherein x is 1 or 2 and the alkoxy radical may be substituted; R is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, wherein these groups are optionally substituted; X is halogen; Y is H or halogen; or the enantiomers or salts or N-oxides thereof, and 2) one or more compounds Il selected from group A consisting of organo(thio)- phosphates, carbamates, pyrethroids, growth regulators, nicotinic receptor agonists/antagonists compounds, GABA antagonist compounds, macrocyclic lactone insecticides, METI I acaricides, METI Il and III compounds, uncoupler compounds, oxidative phosphorylation inhibitor compounds, mixed function oxidase inhibitor compounds, sodium channel blocker compounds and others, all as defined in the description, in synergistically effective amounts, use of these mixture for combating insects, arachnids or nematodes in and on plants and for the protection of seeds, and for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation or infection by parasites.
    • 作为活性成分的农药混合物,1)式I,2(I)Y的氨脒类化合物,其中B1为卤素,烷基,卤代烷基或卤代烷氧基; B是卤素,卤代烷基,烷氧基,卤代烷氧基,烯氧基,炔氧基,烷硫基,卤代烷硫基,烷基亚磺酰基,卤代烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基,烷基-S(= O)2 -O-或卤代烷基S(O)x O-,其中x是1 或2,并且烷氧基可以被取代; R是氢,烷基,烯基,炔基,环烷基,其中这些基团是任选取代的; X是卤素; Y是H或卤素; 或其对映异构体或其盐或N-氧化物,以及2)选自有机(硫代) - 磷酸酯,氨基甲酸酯,拟除虫菊酯,生长调节剂,烟碱型受体激动剂/拮抗剂化合物,GABA拮抗剂化合物, 大环内酯杀虫剂,METI I杀螨剂,METI II和III化合物,解偶联剂化合物,氧化磷酸化抑制剂化合物,混合功能氧化酶抑制剂化合物,钠通道阻断剂化合物等,均在协同有效量中,协同有效量使用 用于防治昆虫,蜘蛛或线虫在植物内和植物中的混合物,并用于保护种子,以及治疗,控制,预防或保护温血动物或鱼类免受寄生虫感染或感染。
    • 6. 发明申请
    • RESORCINE DERIVATIVES AND THEIR USE AS PESTICIDES
    • RESORCINE衍生物及其作为杀虫剂的用途
    • WO2007054558A2
    • 2007-05-18
    • PCT/EP2006068329
    • 2006-11-10
    • BASF AGPUHL MICHAELKORDES MARKUSPOHLMAN MATTHIASGOETZ NORBERTRACK MICHAELLANGEWALD JUERGENSCHNEIDER FELIXANSPAUGH DOUGLAS DCULBERTSON DEBORAH LOLOUMI-SADEGHI HASSANKUHN DAVID G
    • PUHL MICHAELKORDES MARKUSPOHLMAN MATTHIASGOETZ NORBERTRACK MICHAELLANGEWALD JUERGENSCHNEIDER FELIXANSPAUGH DOUGLAS DCULBERTSON DEBORAH LOLOUMI-SADEGHI HASSANKUHN DAVID G
    • C07D213/64C07D277/34C07D307/80
    • This invention relates to resorcine derivatives of formula (I) wherein R 1 is phenyl or a 5- to 6-membered heteroaromatic ring which may contain 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur, wherein phenyl or the heteroaromatic ring may be fused to a ring selected from phenyl and a 5- to 6-membered saturated, partially unsaturated or aromatic heterocyclic ring which may contain 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur, wherein phenyl or the 5- to 6-membered heteroaromatic ring or the respective fused ring systems may be unsubstituted or substituted by any combination of 1 to 6 optionally substituted groups R 3 , wherein R 3 is halogen, cyano, nitro, hydroxy, mercapto, amino, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, haloalkyl, haloalkenyl, haloalkynyl, halocycloalkyl, halocycloalkenyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, haloalkenyloxy, haloalkynyloxy, alkylthio, alkenylthio, alkynylthio, haloalkylthio, haloalkenylthio, haloalkynylthio, alkylamino, alkenylamino, alkynylamino, dialkylamino, dialkenylamino, dialkynylamino, alkyl-alkenylamino, alkyl-alkynylamino, alkenyl- alkynylamino, trialkylsilyl, or phenyl or a 5-to 7-membered saturated or partially unsaturated heterocyclic ring which may contain 1 to 3 heteroatoms selected from oxygen, sulfur and nitrogen or a 5- to 6-membered heteraromatic ring system which may contain 1 to 4 heteroatoms selected from oxygen, nitrogen and sulfur, which phenyl and which heteroaromatic ring may be bonded via an oxygen or a sulfur atom, or -C(=G)Ra, -C(=G)ORa, -C(=G)NRa2, -C(=G)[N=SRa2], -C(=NORa)Ra, -C(=NORa)NRa2, -C(=NNRa2)Ra , -OC(=G)-OC(=G)ORa, N=SRa2, -NRaC(=G)Ra, -N[C(=G)Ra]2, - NRaC(=G)ORa, -C(=G)NRa-NRa2, -C(=G)NRa-NRa [C(=G)Ra], -NRa-C(=G)NRa2, -NRa-NRaC(=G)Ra, -NRa-N[C(=G)Ra]2, -N[(C=G)Ra]-NRa2, -NRa-NRa[(C=G)GRa], -NRa[(C=G)NRa2, -NRa[C=NRa]Ra, -NRa(C=NRa)NRa2, -O-NRa2, -O-NRa(C=G)Ra, - SO2NRa2, -NRaSO2Ra, -S(=O)Ra, -S(=O)2Ra, -SO2ORa, or -OSO2Ra, wherein G is oxygen or sulfur and Ra is as defined in the description, R 2 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, alkoxy, or haloalkoxy, x is 2, 3, 4, 5, 6, or 7, or the diastereomers, enantiomers, salts or N-oxides thereof, with the proviso that R 1 is not 5-chloro-2,2,-dimethyl-2,3-dihydrobenzo[b]furan-7-yl when R 2 is hydrogen and x is 3 or 4, processes and intermediates for the preparation of compounds I, use of compounds I for combating insects, acarids, or nematodes, and a method for treating, controlling, preventing or protecting animals against infestation or infection by parasites using compounds I.
    • 本发明涉及其中R 1为苯基或可含有1-3个选自氧,氮和硫的杂原子的5至6元杂芳环的式(I)的间苯二酚衍生物,其中苯基 或杂芳环可以与选自苯基和5-至6-元饱和,部分不饱和或芳族杂环的环稠合,所述杂环可以含有1-3个选自氧,氮和硫的杂原子,其中苯基或5- 至6元杂芳环或相应的稠环体系可以是未取代的或被1至6个任选取代的基团R 3 3的任何组合取代,其中R 3是卤素, 氰基,硝基,羟基,巯基,氨基,烷基,烯基,炔基,环烷基,环烯基,卤代烷基,卤代烯基,卤代炔基,卤代环烷基,卤代环烯基,烷氧基,烯氧基,炔氧基,卤代烷氧基,卤代烯氧基,卤代炔氧基,烷硫基,烯硫基,炔硫基,卤代烷硫基, H 烯基氨基,炔基氨基,二烷基氨基,二链烷基氨基,二炔基氨基,烷基 - 链烯基氨基,烷基 - 炔基氨基,烯基 - 炔基氨基,三烷基甲硅烷基或苯基或5至7元饱和或部分不饱和的杂环, 至3个选自氧,硫和氮的杂原子或5至6元杂芳环体系,其可以含有1至4个选自氧,氮和硫的杂原子,该苯基和杂芳环可以通过氧或 硫原子或-C(= G)R a,-C(= G)OR a,-C(= G)NR a 2,-C(= G)[N = SR a 2] (= NORa)NRa2,-C(= NNRa2)Ra,-OC(= G)-OC(= G)ORa,N = SRa2,-NRaC(= G)Ra,-N [C(= G)Ra] 2,-NR a C(= G)OR a,-C(= G)NR a -NR a 2,-C(= G)NR a -NR a [C(= G)R a] -NRaC(= G)Ra,-NRa-N [C(= G)Ra] 2,-N [(C = G)Ra] -NRa2,-NRa-NRa [(C = G) [(C = G)NRa2,-NRa [C = NRa] Ra,-NRa(C = NRa)NRa2,-O-NRa2,-O-NRa(C = G)Ra,-SO2NRa2,-NRaSO2Ra,-S (= O)R a,-S(= O)2 R a,-SO 2 OR a或-O SO 2 R a,其中G是氧或硫,Ra如说明书中所定义,R 2是氢,卤素,氰基,烷基,卤代烷基,烯基,卤代烯基,炔基,卤代炔基,烷氧基或卤代烷氧基, x是2,3,4,5,6或7,或其非对映异构体,对映异构体,盐或N-氧化物,条件是R 1不是5-氯-2,2 ,当R 2是氢并且x是3或4时,制备化合物I的方法和中间体,使用化合物I,其中R 1,R 2,R 3, 用于防治昆虫,螨虫或线虫,以及用化合物I治疗,控制,预防或保护动物免受寄生虫侵袭或感染的方法。
    • 10. 发明申请
    • SULFONAMIDE COMPOUNDS
    • 磺酰胺化合物
    • WO2009153285A2
    • 2009-12-23
    • PCT/EP2009057531
    • 2009-06-17
    • BASF SEDEYN WOLFGANG VONPUHL MICHAELPOHLMAN MATTHIASRACK MICHAELPARRA RAPADO LILIANALANGEWALD JUERGENANSPAUGH DOUGLAS DOLOUMI-SADEGHI HASSANCULBERTSON DEBORAH LRANKL NANCY BKAMP HENNICKEVAN RAVENZWAAY BENNARD
    • VON DEYN WOLFGANGPUHL MICHAELPOHLMAN MATTHIASRACK MICHAELPARRA RAPADO LILIANALANGEWALD JUERGENANSPAUGH DOUGLAS DOLOUMI-SADEGHI HASSANCULBERTSON DEBORAH LRANKL NANCY BKAMP HENNICKEVAN RAVENZWAAY BENNARD
    • C07D417/06A01N43/80C07D417/14
    • C07D417/06A01N43/80C02F1/001C02F2209/03C02F2303/16C07D417/14
    • The present invention relates to sulfonamide compounds of formula (I) wherein R1 is H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; R2 and R3 are H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; or R2 together with R3 form a fused 5 or 6-membered carbocycle or heterocycle; R4 is halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-haloalkoxy, C1-C6-haloalkylthio, C1-C6-haloalkylsulfinyl or C1-C6-haloalksulfonyl; n is 0, 1, 2 or 3; R5 is phenyl or a 5- or 6-membered heterocycle; X is O or NRx, wherein Rx is H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; Y is N or C(Ry), wherein Ry is H, halogen, CN, C1-C6-alkyl,C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-7-cycloalkyl- C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl and C1-C6-haloalkoxy; and Z is a chemical bond, O or N(Rz), wherein Rz is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; as well as to the N-oxides and salts thereof. These compounds are useful for combating animal pests. The invention also relates to a process for the preparation of these compounds and to intermediate compounds used in said process. The invention further relates to a method for controlling animal pests by using the compounds of formula (I), the N-oxides or the salts thereof, to plant propagation material and to an agricultural and veterinary composition comprising said compounds, the N-oxides or the salts thereof.
    • 本发明涉及式(I)的磺酰胺化合物,其中R1是H,卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C3-C7-环烷基 C 1 -C 4 - 烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6 - 炔硫基,C 1 -C 6 - 卤代烷基或C 1 1 -C 6 - 卤代烷氧基; R2和R3是H,卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C3-C7-环烷基-C1-C4-烷基,C1-C6- 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6炔硫基,C 1 -C 6卤代烷基或C 1 -C 6卤代烷氧基; 或R 2与R 3一起形成稠合的5或6元碳环或杂环; R4是卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C1-C6-烷氧基,C1-C6-烷硫基,C1-C6-烷基亚磺酰基,C1-C6-烷基磺酰基,C1- C 1 -C 6卤代烷基,C 1 -C 6卤代烷硫基,C 1 -C 6卤代烷基亚磺酰基或C 1 -C 6卤代磺酰基; n为0,1,2或3; R5是苯基或5-或6-元杂环; X是O或NR x,其中Rx是H,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6 - 炔基,C 3 -C 7 - 环烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔基氧基,C 1 -C 6 - 烷基羰基或C 1 -C 6烷基羰基氧基; Y是N或C(Ry),其中R y是H,卤素,CN,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 7 - 环烷基,C 3-7 - C 1 -C 6烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6 - 炔硫基, 卤代烷氧基; Z为化学键,O或N(Rz),其中Rz为C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C1-C6-烷氧基,C2-C6 - 烯氧基,C1-C6-烷基羰基或C1-C6-烷基羰基氧基; 以及N-氧化物及其盐。 这些化合物可用于对抗动物害虫。 本发明还涉及制备这些化合物的方法和用于所述方法的中间体化合物。 本发明还涉及通过使用式(I)化合物,其N-氧化物或其盐来植物繁殖材料以及包含所述化合物,N-氧化物或其盐的农业和兽医组合物来控制动物害虫的方法 其盐。