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1. 发明申请

WO2006042675A2 EXTRACTION OF NICKEL(0) COMPLEXES FROM NITRILE MIXTURES WITH REDUCED POWDER FORMATION 审中-公开
标题翻译：含腈OFF WITH REDUCED抹布形成镍的提取（0）配合物
公开(公告)号：WO2006042675A2
公开(公告)日：2006-04-27
申请号：PCT/EP2005010956
申请日：2005-10-12
申请人： BASF AG , DECKERT PETRA , BASSLER PETER , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS , PFAB PETER , AECHTNER TOBIAS , SIEGEL WOLFGANG
发明人： DECKERT PETRA , BASSLER PETER , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS , PFAB PETER , AECHTNER TOBIAS , SIEGEL WOLFGANG
CPC分类号： B01J31/4053 , B01D11/0434 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/403 , B01J2231/323 , B01J2531/847 , C07C253/10 , C07C253/32 , Y02P20/584 , C07C255/04
摘要： The invention relates to a method for the extractive separation of homogeneously dissolved catalysts from a reaction product from a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction with a carbon material (K), characterised in that a) a non-polar aprotic liquid (F) is added to the reaction product to give a stream (I) and b) the stream (I) is extracted with a carbon material (K) at a temperature (T), to give a stream (II), containing the carbon material (K), enriched with the catalyst and a stream (III), stripped of catalyst.
摘要翻译：通过烃的装置（K），其特征在于用于由不饱和单腈向二腈，通过萃取的氢氰化反应流出物均匀溶解的催化剂的提取分离方法，包括：a）向所述反应在非极性非质子液体（F），由此电流在温度（T）（与烃K（I）获得，以及b）的电流（I））被提取，其特征在于，一个流（II）含有富含与催化剂烃（K）和催化剂贫流（ III）。

2. 发明申请

WO2007115936A3 METHOD FOR THE SEPARATION OF NICKEL(0) COMPLEXES AND PHOSPHOROUS-CONTAINING LIGANDS FROM NITRILE MIXTURES 审中-公开
标题翻译： PROCESS FOR分离镍（0）络合物和含腈OFF磷配体
公开(公告)号：WO2007115936A3
公开(公告)日：2007-11-29
申请号：PCT/EP2007052955
申请日：2007-03-28
申请人： BASF AG , HADERLEIN GERD , AECHTNER TOBIAS , BARTSCH MICHAEL , LUYKEN HERMANN , PFAB PETER , SCHEIDEL JENS , LEITNER ANDREAS
发明人： HADERLEIN GERD , AECHTNER TOBIAS , BARTSCH MICHAEL , LUYKEN HERMANN , PFAB PETER , SCHEIDEL JENS , LEITNER ANDREAS
IPC分类号： B01D11/04 , B01J31/18 , B01J31/24 , B01J31/40 , C07C253/10 , C07C253/32
CPC分类号： B01J31/403 , B01D11/0426 , B01D11/0457 , B01J31/1845 , B01J31/185 , B01J31/1865 , B01J31/24 , B01J31/4053 , C07C253/34 , C07D333/48 , Y02P20/584 , C07C255/09
摘要： The invention relates to a method for extractive separation of nickel (0) complexes with phosphorous ligands, from a reaction product of a hydrocyanation of unsaturated mononitriles to give dinitriles, by means of extraction with a hydrocarbon, wherein a phase separation of the hydrocarbon and the nitrile-containing solution into two phases occurs, by addition of a polar additive to the reaction product (feed stream) and/or the extraction stage.
摘要翻译：一种用于提取处理中除去镍处理（0）通过烃的装置具有由不饱和单腈向二腈，通过萃取的氢氰化反应流出物的磷配位体配合物，所述烃和含腈溶液的相分离成两相是由氢氰化进行放电（进料流）和/或提取阶段被提供至少一种极性添加剂。

3. 发明申请

WO2005042157A3 METHOD FOR THE PRODUCTION OF NICKEL(0)-PHOSPHOROUS LIGAND COMPLEXES 审中-公开
标题翻译：制备镍（0）磷杂草配合物的方法
公开(公告)号：WO2005042157A3
公开(公告)日：2005-07-21
申请号：PCT/EP2004012180
申请日：2004-10-28
申请人： BASF AG , HADERLEIN GERD , BAUMANN ROBERT , BARTSCH MICHAEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG
发明人： HADERLEIN GERD , BAUMANN ROBERT , BARTSCH MICHAEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG
IPC分类号： B01J31/18 , B01J31/24 , C07C253/10 , C07C255/04 , C07F15/04 , B01J37/16 , B01J31/30
CPC分类号： C07F15/045 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/24 , B01J2231/323 , B01J2231/52 , B01J2531/847 , C07C253/10 , C07F15/04 , C07C255/04
摘要： The invention relates to a method for the production of nickel(0)-phosphorous ligand complexes from nickel(II)-ether adducts.
摘要翻译：本发明是从镍（II）醚加合物开始制备镍（0）磷配体配合物的方法。

4. 发明申请

WO2006106123A3 IMPROVED METHOD FOR PRODUCING BIPHENOLS FROM MONOPHENOLS 审中-公开
标题翻译：改进工艺用于生产双酚关单酚
公开(公告)号：WO2006106123A3
公开(公告)日：2007-01-18
申请号：PCT/EP2006061352
申请日：2006-04-05
申请人： BASF AG , BARTSCH MICHAEL , HADERLEIN GERD , AECHTNER TOBIAS , SCHEIDEL JENS , DIENES CHRISTIAN , TEMPEL ALEXANDER , HOFRICHTER THORSTEN , WEINLE WERNER
发明人： BARTSCH MICHAEL , HADERLEIN GERD , AECHTNER TOBIAS , SCHEIDEL JENS , DIENES CHRISTIAN , TEMPEL ALEXANDER , HOFRICHTER THORSTEN , WEINLE WERNER
IPC分类号： C07C37/11 , C07C39/15 , C07F9/02
CPC分类号： C07C37/11 , C07C39/15
摘要： The invention relates to a method for producing biphenols of general formula (I) by reacting monophenols of general formula (II), wherein the radicals R1, R2 and R3 independently represent hydrogen, alkyl, aryl or arylalkyl, with 1 - 10 C-atoms, in the presence of an oxidation agent in a reactor. Said method is characterised in that a) the reactor does not contain any stationary integrated components which act as a current agitator, b) a maximum of 0,6 mol of oxidation agents are used per mol of monophenol, and c) the oxidation agent is added in a continuous or discontinuous manner in a plurality of portions within a time span of between 10 min - 24 hours, whereby the amount of oxidation agent which is added per time unit is not constant over the entire tine span, but is varied.
摘要翻译：一种用于在一个存在下，通过式（II）其中基团R1，R2和R3独立地是氢，烷基，芳基或芳烷基的碳原子数1〜10中的一元酚的反应由通式（I）制备双酚过程氧化剂在反应器中，其特征在于：a）反应器含有不作为挡板作用固定设备，b）中的最大0.6摩尔的氧化剂是每单酚的一倍摩尔使用的，和c）在一段10分钟至24氧化剂小时或者连续，或间歇地在几个部分中，加入，引入氧化剂的每单位量不随时间恒定的整个期间而被改变。

5. 发明申请

WO2005073166A2 METHOD FOR THE PRODUCTION OF PENTENE NITRILES FROM N-BUTANE 审中-公开
标题翻译：用于生产戊烯腈由正丁烷
公开(公告)号：WO2005073166A2
公开(公告)日：2005-08-11
申请号：PCT/EP2005000773
申请日：2005-01-27
申请人： BASF AG , BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , SCHINDLER GOETZ-PETER , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , BRODHAGEN ANDREAS
发明人： BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , SCHINDLER GOETZ-PETER , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , BRODHAGEN ANDREAS
IPC分类号： C07C253/10 , C07C255/07 , C07C253/00
CPC分类号： C07C253/10 , C07C255/07
摘要： The invention relates to a method for hydrocyanation of 1,3-butadiene on at least one nickel(o) complex with phosphor-containing ligands as a catalyst, wherein 1,3-butadiene is used in a mixture with n-butane and the mixture contains 60 - 90 vol. % 1,3-butadiene and 40 -10 vol. % n-butane.
摘要翻译：公开了一种用于1,3-丁二烯的在至少一个镍（O）氢氰化过程复杂具有磷配体作为催化剂，其中，所述1,3-丁二烯以与正丁烷的混合物和60至90体积混合物中使用 .-％含有1,3-丁二烯和40至10％（体积）正丁烷。

6. 发明申请

WO2005073178A3 METHOD FOR HYDROCYANATION 审中-公开
标题翻译：方法氰化
公开(公告)号：WO2005073178A3
公开(公告)日：2005-09-22
申请号：PCT/EP2005000724
申请日：2005-01-26
申请人： BASF AG , JUNGKAMP TIM , POLKA HANS-MARTIN , BAUMANN ROBERT , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS
发明人： JUNGKAMP TIM , POLKA HANS-MARTIN , BAUMANN ROBERT , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS
IPC分类号： C07C253/34 , C07C255/04 , C07C255/07
CPC分类号： C07C253/34 , C07C255/07 , C07C255/04
摘要： The invention relates to a method for separating hydrogen cyanide from mixtures containing pentenenitrile, by means of the azeotropic distillation of hydrogen cyanide with 1,3-butadiene.
摘要翻译：公开了一种用于氰化氢的从含有其中通过与1,3-丁二烯氰化氢的共沸蒸馏分离进行戊烯腈混合物中分离的方法。

7. 发明申请

WO2008012249A3 PROCESS FOR THE LONG-TERM OPERATION OF A CONTINUOUSLY OPERATED HETEROGENEOUSLY CATALYZED PARTIAL DEHYDROGENATION OF A HYDROCARBON TO BE DEHYDROGENATED 审中-公开
标题翻译：对于长期运行的方法连续操作的非均相催化部分脱氢的烃与氢
公开(公告)号：WO2008012249A3
公开(公告)日：2008-04-17
申请号：PCT/EP2007057407
申请日：2007-07-18
申请人： BASF AG , DIETERLE MARTIN , KLANNER CATHARINA , SCHINDLER GOETZ-PETER , MUELLER-ENGEL KLAUS JOACHIM , SCHEIDEL JENS , ADAMI CHRISTOPH
发明人： DIETERLE MARTIN , KLANNER CATHARINA , SCHINDLER GOETZ-PETER , MUELLER-ENGEL KLAUS JOACHIM , SCHEIDEL JENS , ADAMI CHRISTOPH
IPC分类号： B01J8/04 , B01J8/06 , B01J19/00 , C07C5/333 , C07C45/35 , C07C51/25
CPC分类号： B01J8/0453 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J19/0033 , B01J2208/00221 , B01J2208/00407 , B01J2208/00415 , B01J2208/00522 , B01J2208/025 , C07C5/3337 , C07C45/33 , C07C45/35 , C07C67/08 , C07C2523/42 , Y02P20/52 , C07C11/02 , C07C11/06 , C07C47/22 , C07C69/54
摘要： A process for the long-term operation of a continuously operated heterogeneous catalyzed partial dehydrogenation of a hydrocarbon to be dehydrogenated, in which a stream of reaction gas mixture containing the hydrocarbon to be dehydrogenated in a molar starting amount HC is passed through a total catalyst bed containing the total amount M of dehydrogenation catalyst and deactivation of the total catalyst bed is counteracted by, as the period of operation increases, the conversion contribution of the first third in the flow direction of the total amount M of dehydrogenation catalyst decreasing, the conversion contribution of the last third in the flow direction of the total amount M of dehydrogenation catalyst increasing and the conversion contribution of the second third in the flow direction of the total amount M of dehydrogenation catalyst going through a maximum.
摘要翻译：待脱氢一种用于在烃的一项所述的烃与氢的连续多相催化部分脱氢的长期操作方法中含有氢时的摩尔起始量KW反应气体混合物流经含有脱氢催化剂总床和整体催化剂床的失活，从而抵消，一个总量M 在总量脱氢催化剂的男，以在脱氢催化剂m增加总量的流动方向，第三销售最后的贡献的流动方向，第三越来越大的贡献的工作时间，以销售所述第一的降低，并在脱氢催化剂的总量M的流动方向第三销售第二的贡献经过最大值。

8. 发明申请

WO2012041859A3 PROCESS FOR WORKING UP AN EXHAUST GAS FROM A SYSTEM FOR PRODUCING HYDROXYLAMINE OR HYDROXYLAMMONIUM SALTS 审中-公开
标题翻译：一种用于处理中产生的废气所涉及的工厂为生产或HYDROXYLAMINE羟铵盐
公开(公告)号：WO2012041859A3
公开(公告)日：2012-05-24
申请号：PCT/EP2011066781
申请日：2011-09-27
申请人： BASF SE , GARSUCH ARND , PANCHENKO ALEXANDER , BRAEUNINGER SIGMAR , SCHEIDEL JENS , THOME ALFRED
发明人： GARSUCH ARND , PANCHENKO ALEXANDER , BRAEUNINGER SIGMAR , SCHEIDEL JENS , THOME ALFRED
IPC分类号： C01B21/14 , B01D53/22 , C01B3/50 , C01B5/00 , H01M8/06
CPC分类号： B01D53/46 , B01D53/229 , B01D53/326 , B01D69/148 , B01D71/024 , B01D71/32 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2257/108 , B01D2313/345 , C01B3/501 , C01B3/503 , C01B21/1418 , C01B2203/0405 , C01B2203/041 , C01B2203/0465 , H01M8/086 , H01M8/1023 , H01M8/1025 , H01M8/106 , H01M8/1246 , Y02E60/525 , Y02P70/56
摘要： A process for working up an exhaust gas (A) from a system for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen, wherein the exhaust gas (A) comprises nitrogen monoxide, hydrogen, dinitrogen monoxide, nitrogen and ammonia, and at least some of the hydrogen present in the exhaust gas (A) is separated off from the exhaust gas (A) by means of a gas-tight membrane-electrode assembly which comprises at least one selectively proton-conducting membrane, a retentate side, a permeate side, and, on each side of the membrane, at least one electrode catalyst, wherein, on the retentate side of the membrane, at least some of the hydrogen is oxidized to protons at the anode catalyst and the protons, after crossing the membrane, are, on the permeate side, at the cathode catalyst according to (I) reduced to hydrogen and/or (II) reacted with oxygen to form water, wherein the oxygen originates from an oxygen-comprising stream (O) which is contacted with the permeate side.
摘要翻译：一种用于从植物后处理的排气（A）用于制备羟胺或通过催化还原用氢气一氧化氮的羟铵盐的方法，其中所述废气（A）一氧化氮，氢气，一氧化二氮，氮和氨和废气中的至少一部分（A）包含在废气的（a）中的氢被具有至少一个选择性质子传导膜，截留侧，渗透物侧的气密膜电极组件分离，并且在膜的每一侧上的至少一个电极催化剂，其特征在于，上的渗余物侧膜被氧化至少在阳极催化剂成质子和质子的氢的一部分以根据所述阴极催化剂的渗透侧穿过膜; 被减少到氢（I）和/或（II）与氧反应以形成水，其中从氧（O）的含氧料流衍生的，其被带入与渗透侧接触。

9. 发明专利

BRPI0506587B1 未知
公开(公告)号：BRPI0506587B1
公开(公告)日：2014-10-29
申请号：BRPI0506587
申请日：2005-01-27
申请人： BASF AG
发明人： SCHEIDEL JENS , HADERLEIN GERD , LUYKEN HERMANN , JUNGKAMP TIM , BARTSCH MICHAEL , BAUMANN ROBERT
IPC分类号： C07C253/10 , C07C253/34 , C07C255/07
摘要： A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) reacting 1,3-butadiene with hydrogen cyanide over at least one catalyst to obtain a stream 1 which comprises 3-pentenenitrile, 2-methyl-3-butenenitrile, the at least one catalyst and 1,3-butadiene, (b) distilling stream 1 in a column to obtain a high-1,3-butadiene stream 2 as the top product and a low-1,3-butadiene stream 3 as the bottom product which comprises 3-pentenenitrile, the at least one catalyst and 2-methyl-3-butenenitrile, (c) distilling stream 3 in a column to obtain a stream 4 as the top product which comprises 1,3-butadiene, a stream 5 which comprises 3-pentenenitrile and 2-methyl-3-butenenitrile at a side draw of the column, and a stream 6 as the bottom product which comprises the at least one catalyst, (d) distilling stream 5 to obtain a stream 7 as the top product which comprises 2-methyl-3-butenenitrile, and a stream 8 as the bottom product which comprises 3-pentenenitrile.

10. 发明专利

BRPI0506581B1 未知
公开(公告)号：BRPI0506581B1
公开(公告)日：2014-10-29
申请号：BRPI0506581
申请日：2005-01-27
申请人： BASF AG
发明人： LUYKEN HERMANN , SCHEIDEL JENS , JUNGKAMP TIM , BAUMANN ROBERT , BARTSCH MICHAEL , HADERLEIN GERD
IPC分类号： C07C253/10 , C07C255/04
摘要： An adiponitrile/methylglutaronitrile preparation process includes distilling a reaction stream to obtain stream 3 depleted in pentenenitriles (bottom product) and stream 4 enriched in pentenenitriles (top product); extracting stream 3 obtaining stream 6 enriched with extractant (top product) and stream 7 depleted in extractant (bottom product); distilling stream 6 obtaining stream 8 comprising the catalyst (bottom product) and stream 9 comprising the extractant (top product); distilling stream 7 obtaining stream 10 (bottom product) and stream 11 comprising the extractant (top product); distilling stream 10 obtaining stream 12 comprising catalyst degradation products, at least one promotor, adiponitrile and methylglutaronitrile (bottom product) and stream 13 comprising pentenenitriles (top product); distilling stream 12 obtaining stream 14 comprising catalyst degradation products and the promotor(s) (bottom product) and stream 15 comprising adiponitrile and methylglutaronitrile (top product); distilling stream 15 obtaining stream 16 comprising adiponitrile (bottom product) and stream 17 comprising methylglutaronitrile (top product).

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