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1. 发明申请

WO0222262A2 CATALYSTS FIXED ON A CARRIER AND USED FOR THE METATHESIS OF OLEFINS 审中-公开
标题翻译：固载催化剂用于烯烃复分解反应
公开(公告)号：WO0222262A2
公开(公告)日：2002-03-21
申请号：PCT/EP0110675
申请日：2001-09-14
申请人： BASF AG , BASSET JEAN MARIE , CHABANAS MATHIEU , COPERET CHRISTOPHE
发明人： BASSET JEAN-MARIE , CHABANAS MATHIEU , COPERET CHRISTOPHE
IPC分类号： B01J31/26 , B01J31/12 , B01J31/16 , B01J31/22 , C07B61/00 , C07C2/34 , C07C6/04 , C07C11/02 , C07C11/08 , C07C11/107 , C07C13/12 , C07C67/475 , B01J37/02 , C07F13/00
CPC分类号： B01J31/1625 , B01J31/2265 , B01J2231/543 , B01J2231/74 , C07C6/04 , C07C67/475 , C07C2531/12 , C07C69/593
摘要： The invention relates to a novel, heterogeneous catalyst which is especially suitable for the metathesis of olefins. Said catalyst is fixed on an inorganic carrier and contains at least one active rhenium compound having at least one carbene group and optionally other functional groups. The rhenium compound is bonded to the material used as the carrier by a chemical bond.
摘要翻译：本发明涉及一种新的，特别是用于所谓的烯烃复分解合适的非均相催化剂。该催化剂被固定在无机载体上，并至少含有具有至少一个碳烯基和任选进一步的官能团的活性铼化合物。铼化合物通过化学键与用作载体材料相连。

2. 发明申请

WO2004089541A2 METALLIC COMPOUND FIXED TO A SUPPORT, METHOD FOR PRODUCTION AND USE OF SAID COMPOUND IN HYDROCARBON METATHESIS REACTIONS 审中-公开
标题翻译：金属化合物固定到支持物上，生产方法和使用所述化合物在烃类反应中的反应
公开(公告)号：WO2004089541A2
公开(公告)日：2004-10-21
申请号：PCT/FR2004000730
申请日：2004-03-24
申请人： CPE LYON FCR , BASSET JEAN-MARIE , COPERET CHRISTOPHE , SOULIVONG DARAVONG , TAOUFIK MOSTAFA , THIVOLLE-CAZAT JEAN
发明人： BASSET JEAN-MARIE , COPERET CHRISTOPHE , SOULIVONG DARAVONG , TAOUFIK MOSTAFA , THIVOLLE-CAZAT JEAN
IPC分类号： B01J31/12 , B01J37/02 , B01J37/18 , C07C6/10 , C08L61/06 , B01J31/00
CPC分类号： C07C6/10 , B01J31/121 , B01J37/0209 , B01J37/18 , C07C2521/04 , C07C2531/12 , C08L61/06
摘要： The invention relates to a supported metal compound, comprising a support made from aluminium oxide to which a tungsten hydride is grafted. The support may be selected from the homogeneous supports with a composition based on aluminum oxide and from heterogeneous supports made from aluminium oxide with aluminum oxide essentially on the surface of said support. The support may in particular comprise aluminium oxide, mixed aluminium oxides and modified aluminium oxides particularly comprising one or more elements of groups 15 to 17 of the periodic table of the elements, such as phosphorus, sulphur, fluorine or chlorine. A support made from porous, non-porous or mesoporous aluminas is preferred. The degree of oxidation of the tungsten may have a value of from 2 to 6. The tungsten atom is generally bonded to one or several hydrogen atoms and optionally to one or several hydrocarbon groups. According to the invention, the compound may be prepared by a dispersion step and grafting of a tungsten organometallic precursor to the support made from aluminium oxide then hydrogenation of the resulting product. The product may be used as catalyst in reactions of cleavage and recombination of hydrocarbons, particularly in hydrocarbon metathesis reactions most particularly of alkanes. The product has a surprising, extremely high catalytic activity in this type of reaction and in particular, a high selectivity for the formation of n-alkanes with relation to iso-alkanes.
摘要翻译：本发明涉及一种负载型金属化合物，其包含由氢氧化铝接枝到其上的氧化铝制成的载体。载体可以选自具有基于氧化铝的组合物的均质载体和基本上来自氧化铝和氧化铝的不均匀载体，基本上在所述载体的表面上。载体尤其可以包含氧化铝，混合氧化铝和改性氧化铝，其特别包含元素周期表第15至17族的一个或多个元素，例如磷，硫，氟或氯。由多孔，无孔或中孔氧化铝制成的载体是优选的。钨的氧化度可以为2至6的值。钨原子通常与一个或多个氢原子以及任选地与一个或多个烃基键合。根据本发明，该化合物可以通过分散步骤制备并将钨有机金属前体接枝到由氧化铝制成的载体上，然后氢化所得产物。该产物可用作烃裂解和重组反应的催化剂，特别是在烃类复分解反应中，最特别是在烷烃中。该产物在这种类型的反应中具有令人惊讶的极高的催化活性，特别是对于与异构烷烃相关的正构烷烃的形成具有高选择性。

3. 发明申请

WO02053520A2 METHOD FOR PRODUCING HYDROCARBONS HAVING A MODIFIED CARBON SKELETON 审中-公开
标题翻译：用改变的碳框架生产碳氢化合物的方法
公开(公告)号：WO02053520A2
公开(公告)日：2002-07-11
申请号：PCT/EP0200054
申请日：2002-01-05
申请人： BASF AG , VANOPPEN DOMINIC , SCHWAB EKKEHARD , BASSET JEAN-MARIE , THIVOLLE-CAZAT JEAN , TAOUFIK MOSTAPHA , SCHULZ MICHAEL , HOEHN ARTHUR
发明人： VANOPPEN DOMINIC , SCHWAB EKKEHARD , BASSET JEAN-MARIE , THIVOLLE-CAZAT JEAN , TAOUFIK MOSTAPHA , SCHULZ MICHAEL , HOEHN ARTHUR
IPC分类号： C07C6/08 , C07C6/10
CPC分类号： C07C6/10 , C07C6/08 , C07C2531/12
摘要： The invention relates to a method for producing hydrocarbons having a modified carbon skeleton by reacting aliphatic hydrocarbons a) with themselves, b) with another aliphatic hydrocarbon or c) with aromatic alkyl substituted hydrocarbons, in the presence of a metal organic catalyst or the hybrid thereof, at a temperature of between 20 - 400 DEG C and a pressure of between 0.2 - 100 bars, wherein the reaction takes place in the presence of hydrogen.
摘要翻译：通过脂族烃反应制备具有改性碳骨架的烃的方法：a）与其本身; b）与另一种脂族烃或c）与芳族烷基取代的烃在有机金属催化剂或其杂化物存在下，在20-400℃的温度和0.2-100巴的压力下，通过在氢存在下执行。

4. 发明申请

WO2013111015A8 HYDROGEN GENERATION 审中-公开
标题翻译：氢生成
公开(公告)号：WO2013111015A8
公开(公告)日：2014-09-04
申请号：PCT/IB2013000472
申请日：2013-01-22
申请人： UNIV KING ABDULLAH SCI & TECH , BASSET JEAN-MARIE
发明人： BASSET JEAN-MARIE , POLSHETTIWAR VIVEK , BOUHRARA MOHAMED , SAIH YOUSSEF
IPC分类号： C01B3/26 , C01B3/38 , C07C2/76
CPC分类号： C01B3/26 , C01B2203/0277 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C07C2/76 , C07C2521/08 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C9/06
摘要： A process for the decomposition of methane can be controlled to form ethane or hydrogen with a solid carbon product.
摘要翻译：可以控制甲烷分解的方法以与固体碳产物形成乙烷或氢气。

5. 发明申请

WO2004018367A3 REMOVAL OF METAL IONS FROM AQUEOUS EFFLUENTS 审中-公开
标题翻译：从水溶液中去除金属离子
公开(公告)号：WO2004018367A3
公开(公告)日：2004-04-08
申请号：PCT/FR0302550
申请日：2003-08-19
申请人： CENTRE NAT RECH SCIENT , BASSET JEAN-MARIE , GODARD GREGORY , CANDY JEAN-PIERRE
发明人： BASSET JEAN-MARIE , GODARD GREGORY , CANDY JEAN-PIERRE
IPC分类号： B01J20/02 , C02F1/28 , C02F1/70
CPC分类号： C02F1/281 , B01J20/02 , C02F1/705 , C02F2101/103 , C02F2101/20
摘要： The invention relates to a method of reducing the ionic metal content of aqueous effluents. The inventive method consists in bringing an aqueous effluent loaded with metal ions into contact with at least one hydrogen-covered metal.
摘要翻译：本发明涉及一种降低含水废水的离子金属含量的方法。本发明的方法包括使负载有金属离子的含水流出物与至少一个氢覆盖的金属接触。

6. 发明申请

WO2011126829A3 OLEFIN METATHESIS REACTANT RATIOS USED WITH TUNGSTEN HYDRIDE CATALYSTS 审中-公开
标题翻译：用金属氢化物催化剂使用的OLEFIN METATHESIS REACTANT RATIOS
公开(公告)号：WO2011126829A3
公开(公告)日：2012-02-09
申请号：PCT/US2011030287
申请日：2011-03-29
申请人： UOP LLC , TAOUFIK MOSTAFA , MAZOYER ETIENNE , NICHOLAS CHRISTOPHER P , BASSET JEAN-MARIE
发明人： TAOUFIK MOSTAFA , MAZOYER ETIENNE , NICHOLAS CHRISTOPHER P , BASSET JEAN-MARIE
IPC分类号： C07C6/04 , B01J31/02 , C07C11/06 , C07C11/08
CPC分类号： C07C6/04 , C07C2521/04 , C07C2531/12 , Y02P20/52 , Y02P20/582 , Y02P30/42 , C07C11/06
摘要： Processes for olefin metathesis, for example for the production of propylene, utilize a catalyst comprising a solid support and a tungsten hydride bonded to alumina present in the support. Conversion, selectivity, and/or catalyst stability advantages may be realized when a first olefin reactant (e.g., ethylene) is present in the hydrocarbon feedstock at a stoichiometric deficit relative to a second, higher carbon number olefin reactant (e.g., butylene).
摘要翻译：用于烯烃复分解的方法，例如用于生产丙烯的方法，使用包含固体载体和与载体中存在的氧化铝结合的氢化钨的催化剂。当相对于第二较高碳数的烯烃反应物（例如丁烯）以化学计量的缺陷存在于烃原料中时，第一烯烃反应物（例如乙烯）可以实现转化率，选择性和/或催化剂稳定性优点。

7. 发明申请

WO03087173A2 METHOD FOR TRANSFORMATION AND/OR RECYCLING OF POLYMERS OR COPOLYMERS 审中-公开
标题翻译：聚合物或共聚物的转化和/或回收方法
公开(公告)号：WO03087173A2
公开(公告)日：2003-10-23
申请号：PCT/FR0301227
申请日：2003-04-16
申请人： CENTRE NAT RECH SCIENT , GOBLEY OLIVIER , DA CRUZ FERNANDE , BASSET JEAN-MARIE , MARANGELLI CATHERINE , NICCOLAI VERONIQUE , LUCAS CHRISTINE
发明人： GOBLEY OLIVIER , DA CRUZ FERNANDE , BASSET JEAN-MARIE , MARANGELLI CATHERINE , NICCOLAI VERONIQUE , LUCAS CHRISTINE
IPC分类号： C08F8/50 , C08J11/16
CPC分类号： C08J11/16 , Y02W30/705
摘要： The invention relates to a method for transformation of polymers or copolymers in particular branched polyolefins, in the presence of a solid catalyst, comprising a metal hydride supported on a mineral support or an organometallic complex supported on a mineral support, preferably in the presence of hydrogen. In said method the reaction conditions are controlled such as to preferentially arrive at a cleavage of the branching of the polymer(s) or copolymer(s) with the formation of polymers and/or copolymers with properties and chemical structures different from the starting materials. The invention can be applied to polyethylenes, polypropylenes, polystyrenes and copolymers.
摘要翻译：本发明涉及一种在固体催化剂存在下转化聚合物或共聚物，特别是支链聚烯烃的方法，其包含负载在矿物载体上的金属氢化物或负载在矿物载体上的有机金属络合物，优选在氢气存在下。在所述方法中，控制反应条件，以便与形成具有不同于起始原料的性质和化学结构的聚合物和/或共聚物优先地得到聚合物或共聚物的支化物的裂解。本发明可应用于聚乙烯，聚丙烯，聚苯乙烯和共聚物。

8. 发明申请

WO2011126798A3 CONVERSION OF BUTYLENE TO PROPYLENE UNDER OLEFIN METATHESIS CONDITIONS 审中-公开
标题翻译：丁烯转化为丙烯在特殊条件下的丙烯
公开(公告)号：WO2011126798A3
公开(公告)日：2012-03-29
申请号：PCT/US2011030161
申请日：2011-03-28
申请人： UOP LLC , NICHOLAS CHRISTOPHER P , MAZOYER ETIENNE , TAOUFIK MOSTAFA , BASSET JEAN-MARIE , BARGER PAUL T , REKOSKE JAMES E
发明人： NICHOLAS CHRISTOPHER P , MAZOYER ETIENNE , TAOUFIK MOSTAFA , BASSET JEAN-MARIE , BARGER PAUL T , REKOSKE JAMES E
IPC分类号： C07C6/04 , B01J23/30 , C07C4/10 , C07C11/06
CPC分类号： C07C6/04 , C07C2521/04 , C07C2531/12 , Y02P20/52 , C07C11/06 , C07C11/10
摘要： Processes for the conversion, under conditions and with a catalyst system effective for olefin metathesis, of hydrocarbon feedstocks comprising butylene, for example all or a large proportion of a single C4 olefin isomer such as butene-1, are described. Olefin products, and particularly propylene, are formed in the presence of a catalyst comprising a solid support and a tungsten hydride bonded to alumina present in the support. This occurs despite the expectation that the olefin metathesis reaction mechanism leads to the formation of olefin products having other carbon numbers.
摘要翻译：描述了在烯烃复分解的条件下和用于烯烃复分解的催化剂体系的转化方法中包含丁烯的烃原料，例如全部或大部分单一C 4烯烃异构体如丁烯-1的方法。烯烃产物，特别是丙烯，在催化剂的存在下形成，所述催化剂包含固体载体和与载体中存在的氧化铝结合的氢化钨。尽管期望烯烃复分解反应机制导致形成具有其它碳数的烯烃产物，但是这种情况发生。

9. 发明申请

WO2011126796A3 CONVERSION OF ACYCLIC SYMMETRICAL OLEFINS TO HIGHER AND LOWER CARBON NUMBER OLEFIN PRODUCTS 审中-公开
标题翻译：交联对称烯烃转化成更高碳和更低碳的烯烃产品
公开(公告)号：WO2011126796A3
公开(公告)日：2012-02-23
申请号：PCT/US2011030155
申请日：2011-03-28
申请人： UOP LLC , NICHOLAS CHRISTOPHER P , MAZOYER ETIENNE , TAOUFIK MOSTAFA , BASSET JEAN-MARIE , BARGER PAUL T , REKOSKE JAMES E
发明人： NICHOLAS CHRISTOPHER P , MAZOYER ETIENNE , TAOUFIK MOSTAFA , BASSET JEAN-MARIE , BARGER PAUL T , REKOSKE JAMES E
IPC分类号： C07C6/04 , B01J31/02 , C07C11/06 , C07C11/10
CPC分类号： C07C6/04 , C07C2521/04 , C07C2531/12 , Y02P20/52 , Y02P30/42 , C07C11/10 , C07C11/06
摘要： Processes for the conversion, under conditions and with a catalyst system effective for olefin metathesis, of hydrocarbon feedstocks comprising an acyclic symmetrical olefin (e.g., butene-2) are described. Olefin products of lower and higher carbon numbers (e.g., propylene and pentene) are formed in the presence of a catalyst comprising a solid support and a tungsten hydride bonded to alumina present in the support. This occurs despite the olefin metathesis reaction mechanism leading to a degenerative result, without any expected production of different carbon number products from acyclic symmetrical olefins.
摘要翻译：描述了在包含无环对称的烯烃（例如丁烯-2）的烃原料的转化条件和对烯烃复分解有效的催化剂体系的转化方法。在包含固体载体和与载体中存在的氧化铝结合的氢化钨的催化剂存在下形成具有较低和较高碳数的烯烃产物（例如丙烯和戊烯）。尽管烯烃复分解反应机理导致退化结果，但是从无环对称的烯烃预期不会产生不同的碳数产物，这种情况发生。

10. 发明申请

WO2012092014A2 OLEFIN METATHESIS PROCESS AND CATALYST CONTAINING TUNGSTEN FLUORINE BONDS 审中-公开
标题翻译：含烯烃的金属催化过程和催化剂
公开(公告)号：WO2012092014A2
公开(公告)日：2012-07-05
申请号：PCT/US2011066065
申请日：2011-12-20
申请人： UOP LLC , TAOUFIK MOSTAFA , MAZOYER ETIENNE , NICHOLAS CHRISTOPHER P , BASSET JEAN-MARIE
发明人： TAOUFIK MOSTAFA , MAZOYER ETIENNE , NICHOLAS CHRISTOPHER P , BASSET JEAN-MARIE
IPC分类号： B01J23/30 , C07C2/08 , C07C11/04 , C07C11/06 , C07C11/08
CPC分类号： C07C6/04 , B01J21/08 , B01J31/122 , B01J35/1014 , B01J35/1019 , B01J37/031 , B01J37/035 , B01J2231/54 , B01J2531/66 , C07C2531/22 , Y02P20/52 , Y02P30/42 , C07C11/06
摘要： A process and catalyst for the metathesis of olefins in general and specifically for the production of propylene from ethylene and butylene has been developed. The catalyst comprises a tungsten metal compound, which contains at least one tungsten-fluoro bond, dispersed or grafted onto a support. A specific example of the catalyst is the compound WOF(CH2CMe3)3 grafted onto a silica support.
摘要翻译：已经开发了用于烯烃复分解的方法和催化剂，特别是用于从乙烯和丁烯生产丙烯。催化剂包含分散或接枝到载体上的至少一种钨 - 氟键的钨金属化合物。催化剂的具体实例是接枝到二氧化硅载体上的化合物WOF（CH 2 CMe 3）3。

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