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1. 发明申请

WO2006114429A2 PLASTIC OBJECTS FOR METAL-PLATING WITH IMPROVED SHAPING PROPERTIES 审中-公开
标题翻译： FOR金属化塑料物品具有改进的成型性
公开(公告)号：WO2006114429A2
公开(公告)日：2006-11-02
申请号：PCT/EP2006061844
申请日：2006-04-26
申请人： BASF AG , SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT , NIESSNER NORBERT , SCHEIBITZ MATTHIAS , DAHLKE MICHAEL , WARZELHAN VOLKER
发明人： SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT , NIESSNER NORBERT , SCHEIBITZ MATTHIAS , DAHLKE MICHAEL , WARZELHAN VOLKER
CPC分类号： C08L51/003 , B29C47/0004 , B29C47/0011 , B29C47/0021 , B29C47/06 , B29C47/14 , B29C51/00 , B29K2105/0008 , B29K2105/0032 , B29K2105/0044 , B29K2105/005 , B29K2105/256 , B32B5/16 , B32B27/08 , B32B27/14 , B32B2255/10 , B32B2255/205 , B32B2260/025 , B32B2260/046 , B32B2264/105 , B32B2274/00 , B32B2307/202 , B32B2307/416 , B32B2307/546 , B32B2307/558 , B32B2307/7242 , B32B2419/00 , B32B2509/00 , B32B2605/00 , C08J5/18 , C08K3/08 , C08K2201/008 , C08L23/02 , C08L53/02 , C08L55/02 , C08L71/02 , C08L2205/16 , C23C18/54 , C25D5/56 , H01Q15/141 , H01Q17/008 , H05K9/0083 , Y10T156/10 , Y10T428/25 , Y10T428/256 , C08L2666/04 , C08L2666/02
摘要： Films or plates made of a plastic mixture and capable of being metal-plated are disclosed, comprising, in relation to the total weight of components A, B, C and D, which add up to 100 % by weight: (a) 5-50 % by weight of a thermoplastic polymer as component A; (b) 50-95 % by weight of a metal powder having an average particle diameter ranging from 0.01-100 µm (determined by the method defined in the description), the metal having a more negative normal potential in an acid solution than silver, as component B; (c) 0-10 % by weight of a dispersant as component C; and (d) 0-40 % by weight fibrous or particulate fillers or their mixtures as component D. The elongation at tear of component A (determined by the method defined in the description) is 1.1-100 times higher than the elongation at tear of the plastic mixture comprising components A, B and optionally C and D (determined by the method defined in the description). The tensile strength of component A (determined by the method defined in the description) is 0.5-4 times higher than the tensile strength of the plastic mixture comprising components A, B and optionally C and D (determined by the method defined in the description). Also disclosed are thermoplastic moulding compounds for producing these films or plates that can be metal-plated, a granulate comprising these thermoplastic moulding compounds, stratified composite films or plates and mouldings comprising these films or plates, metal-plated polymer bodies comprising these films or plates, stratified composite films or plates and mouldings, processes for producing these objects, the use of these objects as EMI shieldings and absorbers, dampers or reflectors for electromagnetic radiation, oxygen scavengers, electroconducting components, gas barriers, and decorative elements comprising these objects.
摘要翻译：本发明涉及由包含一塑料混合物的金属化薄膜或片材，基于组分A，B，C和D，其给出了一个总的100重量％，A）5〜50重量的热塑性聚合物作为组分％的总重量 A，b）50至95重量具有0.01至100微米的平均颗粒直径（根据说明书中所定义的方法测定），与具有比银的酸性溶液具有更负的标准电极电位的金属的金属粉末的％，作为组分 B，C）0至10重量的分散剂作为C成分的％，和d）0至40重量的纤维状或颗粒状填料或其混合物作为组分D的％，其中所述组分的断裂伸长率（根据中在塑料混合物的断裂由1.1至100比伸长大的因子定义的方法）的描述，其包括组分A，B和，如果存在的话，C和D（如根据在说明书中确定的定义的方法），并且其中，所述组分A的拉伸强度（根据由0.5至4倍于说明书中的定义）来确定是比塑料混合物的拉伸强度，包括更大的组分A，B和，如果存在的话，C和D（根据在描述中所定义的）来确定。此外，本发明涉及热塑性模塑组合物用于制造这种金属化的薄膜或片材，颗粒涉及包括这种热塑性模塑材料，复合膜或片，和模制品包括这样的薄膜或片材，金属化聚合物，其包括板，这些膜或片材，复合膜或与模制部件，用于使方法这些物品中，使用这些对象以及EMI屏蔽，作为吸收体，阻尼器，或用于电磁辐射，氧清除剂，导电部件，阻气性和包含这些对象装饰部件的反射器。

2. 发明申请

WO2007028762A3 DISPERSION CONTAINING TWO DIFFERENT METALS FOR APPLYING A METAL LAYER 审中-公开
标题翻译：分散液中两种不同的金属用于将金属层
公开(公告)号：WO2007028762A3
公开(公告)日：2007-06-28
申请号：PCT/EP2006065875
申请日：2006-08-31
申请人： BASF AG , SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT
发明人： SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT
IPC分类号： H01B1/22 , C08K3/08 , C08K7/06
CPC分类号： H01B1/22 , C09D5/24 , H05K1/095 , H05K3/246 , H05K2201/0245 , H05K2201/0248 , H05K2201/0272 , H05K2201/0347 , Y10T428/25 , Y10T428/256 , Y10T428/258
摘要： The invention relates to a dispersion for applying a metal layer to an electrically non-conductive substrate containing an organic binder component, a metal component with different metals and/or metal particle shapes, and a solvent component. The invention further relates to methods for producing said dispersion, methods for creating an optionally structured metal layer with the aid of the dispersion, the obtained substrate surfaces, and the use thereof.
摘要翻译：本发明涉及一种分散体含有有机粘合剂成分，用不同的金属和/或Metallteilchenformen和溶剂成分的金属成分的非导电衬底上施加金属层。此外，本发明提供了制备分散体中，过程用于制备任选结构的金属层的与所述分散体的助剂，并且获得的基板表面和其用途的方法。

3. 发明专利

CA2625013A1 DISPERSION CONTAINING TWO DIFFERENT METALS FOR APPLYING A METAL LAYER 未知
公开(公告)号：CA2625013A1
公开(公告)日：2007-03-15
申请号：CA2625013
申请日：2006-08-31
申请人： BASF AG
发明人： SOBOTKA BETTINA , WAGNER NORBERT , SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN
IPC分类号： H01B1/22 , C08K3/08 , C08K7/06 , C09K23/00
摘要： Dispersion for applying a metal layer on an electrically non-conductive substrate comprises an organic binder component (0.01-30 wt.%); a metal component (30-89.99 wt.%) containing a first metal with a first metal particle (0.01-99.99 wt.%) and a second metal with a second metal particle (99.99-0.01 wt.%); and a solvent component (10-69.99 wt.%); where the first metal and -particle and second metal and -particle are different from each other. Independent claims are included for: (1) a method for preparing the dispersion comprising mixing an organic binder component, a metal component containing a first metal with a first metal particle and a second metal with a second metal particle, a solvent component, dispersing agent, filler components and further components, and dispersing the obtained mixture; (2) preparation of metal layer on at least a part of an electrically non-conductive substrate comprising applying the dispersion on the substrate, drying the dispersion applied layer on the substrate and optionally de-energizing and/or galvanically separating the metal on the dried dispersion layer; and (3) a substrate surface comprising at least a partially electrical conductive metal layer.

4. 发明专利

CA2631180A1 METHOD FOR PRODUCING PLANAR METALLISED TEXTILE STRUCTURES, PLANAR METALLISED TEXTILE STRUCTURE AND USE OF THE THUS PRODUCED PLANAR METALLISED TEXTILE STRUCTURE 未知
公开(公告)号：CA2631180A1
公开(公告)日：2007-07-05
申请号：CA2631180
申请日：2006-12-18
申请人： BASF AG
发明人： DURIS TIBOR , LOCHTMAN RENE , SOBOTKA BETTINA , PFISTER JUERGEN , NOERENBERG RALF , WAGNER NORBERT , SCHNEIDER NORBERT , RAFFAELE ADDAMO ANTONINO
IPC分类号： D06M11/83 , C09D5/24 , D06M23/16 , H05B3/34
摘要： A method for the production of metallised textile sheet (I) involves (A) printing the textile with a formulation containing at least one metal powder (a) with a greater negative standard potential than hydrogen in the electrochemical displacement series, (B) subjecting the fabric to thermal treatment in one or more stages and (C) depositing another metal on the fabric. Independent claims are included for (1) metallised textile sheet (I) obtained by this method (2) heatable textiles, textiles which convert electricity into heat, textiles which can screen electric fields, textile-integrated electronics and RFID textiles made from (I) (3) printing formulations containing metal powder (a), binder(s) (b), emulsifier(s) (c) and optionally rheology modifier(s) (d) (4) a method for the production of such formulations by mixing the components .

5. 发明专利

DE102005059324A1 The film or plate, which can be metalized as an electromagnetic radiation shield, comprises a plastics mixture of thermoplastics and metal powder together with dispersant and filling materials 未知
公开(公告)号：DE102005059324A1
公开(公告)日：2007-06-21
申请号：DE102005059324
申请日：2005-12-09
申请人： BASF AG
发明人： SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT , NIESNER NORBERT , SCHEIBITZ MATTHIAS , DAHLKE MICHAEL , WARZELHAN VOLKER
IPC分类号： C08J5/18 , B29C47/06 , B29C69/00 , B32B15/08 , C08J5/04 , C08J5/12 , C08J7/04 , C08K3/08 , C09D5/24 , H05K9/00
摘要： The film or plate, which can be metalized, is a plastics mixture of four components. The tensile stretch of the thermoplastic polymer component is greater than the mixture including the metal powder, dispersant and filling components by a factor of 1.1-100.0. The tensile strength of the thermoplastic polymer component is stronger than the mixture by a factor of 0.5-4.0. The film or board is metalised by deposition in one or more layers. The plastics mixture (based on 100 weight%) comprises: (a) 5-50 weight% of a thermoplastics polymer; (b) 50-95 weight% of a metal powder with an average particle diameter of 0.01-100 microns and has a negative potential in acidic solution present a silver; (c) 0-10 weight% of a dispersant; and (d) 0-40 weight% of a fibre or particulate filler or mixture. INDEPENDENTLY CLAIMED are: (1) thermoplastic moulding formed from the film or plate; (2) granulate formed from the thermoplastics moulding; (3) bonded layered film or plate formed comprising the film or plate as covering layer and a substrate layer formed from one or more thermoplastic polymers; (4) Moulding comprising the film or plate or a bonded layered film or plate and a back sprayed, foamed, charged or compressed plastics carrier layer; (5) metallised moulding of the (bonded layered) film or plate and (component (b) containing layer, preferably of copper, chromium, nickel, silver and/or gold; (6) production of the film or plate and bonded layered film or plate by melt mixing and extrusion of the plastics mixture; (7) production of the metallised mouldings involving galvanisation or direct metallisation through vacuum deposition, irradiation/spraying or sputtering.

6. 发明专利

DE102005043242A1 未知
公开(公告)号：DE102005043242A1
公开(公告)日：2007-03-15
申请号：DE102005043242
申请日：2005-09-09
申请人： BASF AG
发明人： SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT
IPC分类号： C08J7/04 , C09D5/38 , C09D5/23 , C09D5/32 , C09K23/00
摘要： Dispersion for applying a metal layer on an electrically non-conductive substrate comprises an organic binder component (0.01-30 wt.%); a metal component (30-89.99 wt.%) containing a first metal with a first metal particle (0.01-99.99 wt.%) and a second metal with a second metal particle (99.99-0.01 wt.%); and a solvent component (10-69.99 wt.%); where the first metal and -particle and second metal and -particle are different from each other. Independent claims are included for: (1) a method for preparing the dispersion comprising mixing an organic binder component, a metal component containing a first metal with a first metal particle and a second metal with a second metal particle, a solvent component, dispersing agent, filler components and further components, and dispersing the obtained mixture; (2) preparation of metal layer on at least a part of an electrically non-conductive substrate comprising applying the dispersion on the substrate, drying the dispersion applied layer on the substrate and optionally de-energizing and/or galvanically separating the metal on the dried dispersion layer; and (3) a substrate surface comprising at least a partially electrical conductive metal layer.

7. 发明专利

DE102005019982A1 Extruded films or plates, useful as decorative or functional parts, comprises metal- or mineral- haptic and optics from a plastic mixture comprising thermoplastic polymer, particulate or fibrous inorganic filler, dispersant, and additives 未知
公开(公告)号：DE102005019982A1
公开(公告)日：2006-11-02
申请号：DE102005019982
申请日：2005-04-27
申请人： BASF AG
发明人： NIESNER NORBERT , SOBOTKA BETTINA , PFISTER JUERGEN , SCHEIBITZ MATTHIAS , WAGNER NORBERT , LOCHTMAN RENE , SCHNEIDER NORBERT , WARZELHAN VOLKER , LIPPERT GERALD
IPC分类号： C08J5/18 , C08K5/56 , C08L23/00 , C08L23/10 , C08L25/04 , C08L27/06 , C08L51/00 , C08L53/00 , C08L53/02 , C08L55/02 , C08L69/00 , C08L75/04
摘要： Extruded film or plates comprises a metal- or mineral- haptic and optics obtained from a plastic mixture comprising (wt.%) thermoplastic polymer (5-50); particulate or fibrous inorganic filler (50-95); dispersant (0-10); and additives (0-40), where the tear elongation and the tensile strength of the polymer is 1.1-100 and 0.5-4 times, respectively, larger than the tear elongation of the mixture. Independent claims are included for: (1) a thermoplastic molding material for preparing (A); (2) granulates for the thermoplastic molding material; (3) a foil layer or plate comprising (A), surface layer and at least one substrate layer obtained from thermoplastic polymers; (4) a molded part comprising (A), foil layer, plate, rear spray, rear foam or rear pressed carrier layer of plastic; (5) a method for preparing (A); (6) a method for the preparation of foil layer or plate comprising melting the layer foils or plates with one another by a coextrusion process; (7) a method for the preparation of the molded part comprising inserting rear tool, rear spray, rear mold or rear press of thermoplastic mold; or rear layer or rear press of duroplastic molding material in (A) and layer foil or plate by hot molding process; and (8) a decorative or functional parts comprising (A), foil layers or plates, and molded parts.

8. 发明专利

DE102005019923A1 The film or plate, which can be metalized as an electromagnetic radiation shield, comprises a plastics mixture of thermoplastics and metal powder together with dispersant and filling materials 未知
公开(公告)号：DE102005019923A1
公开(公告)日：2006-11-02
申请号：DE102005019923
申请日：2005-04-27
申请人： BASF AG
发明人： NIESNER NORBERT , SOBOTKA BETTINA , PFISTER JUERGEN , SCHEIBITZ MATTHIAS , WAGNER NORBERT , LOCHTMAN RENE , SCHNEIDER NORBERT , WARZELHAN VOLKER , LIPPERT GERALD
IPC分类号： C08J5/18 , B29D7/01 , B32B15/08 , B32B27/08 , C08J3/12 , C08K3/08 , C08K7/02 , C08K7/16 , C08L101/12 , H01Q17/00
摘要： The film or plate, which can be metalized, is a plastics mixture of four components. The tensile stretch of the thermoplastic polymer component is greater than the mixture including the metal powder, dispersant and filling components by a factor of 1.1-100.0. The tensile strength of the thermoplastic polymer component is stronger than the mixture by a factor of 0.5-4.0. The film or board is metalised by deposition in one or more layers. The plastics mixture (based on 100 weight%) comprises: (a) 5-50 weight% of a thermoplastics polymer; (b) 50-95 weight% of a metal powder with an average particle diameter of 0.01-100 microns and has a negative potential in acidic solution present a silver; (c) 0-10 weight% of a dispersant; and (d) 0-40 weight% of a fibre or particulate filler or mixture. INDEPENDENTLY CLAIMED are: (1) thermoplastic moulding formed from the film or plate; (2) granulate formed from the thermoplastics moulding; (3) bonded layered film or plate formed comprising the film or plate as covering layer and a substrate layer formed from one or more thermoplastic polymers; (4) Moulding comprising the film or plate or a bonded layered film or plate and a back sprayed, foamed, charged or compressed plastics carrier layer; (5) metallised moulding of the (bonded layered) film or plate and (component (b) containing layer, preferably of copper, chromium, nickel, silver and/or gold; (6) production of the film or plate and bonded layered film or plate by melt mixing and extrusion of the plastics mixture; (7) production of the metallised mouldings involving galvanisation or direct metallisation through vacuum deposition, irradiation/spraying or sputtering.

9. 发明专利

DE102005062028A1 Production of metallised textile sheet, e.g. for use in heatable car seats, involves printing with printing paste containing iron pentacarbonyl, heating the printed fabric and depositing another metal, e.g. copper 未知
公开(公告)号：DE102005062028A1
公开(公告)日：2007-06-28
申请号：DE102005062028
申请日：2005-12-22
申请人： BASF AG
发明人： RAFFAELE ADDAMO ANTONINO , NOERENBERG RALF , SOBOTKA BETTINA , DURIS TIBOR , LOCHTMAN RENE , WAGNER NORBERT , SCHNEIDER NORBERT , PFISTER JUERGEN
IPC分类号： D06Q1/12 , A41D1/00 , B60N2/56 , C23C18/31 , C23C18/54 , D03D15/00 , D04H1/42 , D06M11/83 , H05B3/54 , H05K3/30 , H05K9/00
摘要： A method for the production of metallised textile sheet (I) involves (A) printing the textile with a formulation containing at least one metal powder (a) with a greater negative standard potential than hydrogen in the electrochemical displacement series, (B) subjecting the fabric to thermal treatment in one or more stages and (C) depositing another metal on the fabric. Independent claims are included for (1) metallised textile sheet (I) obtained by this method (2) heatable textiles, textiles which convert electricity into heat, textiles which can screen electric fields, textile-integrated electronics and RFID textiles made from (I) (3) printing formulations containing metal powder (a), binder(s) (b), emulsifier(s) (c) and optionally rheology modifier(s) (d) (4) a method for the production of such formulations by mixing the components .

10. 发明专利

DE102005059323A1 Preparing metal-plated, extruded plastic, useful as e.g. decorative particle, comprises melt blending and extrusion of plastic mixture and contacting mixture with acid, neutral or basic metal salt solution by electrolessly/glavanically 未知
公开(公告)号：DE102005059323A1
公开(公告)日：2007-06-14
申请号：DE102005059323
申请日：2005-12-09
申请人： BASF AG
发明人： SCHNEIDER NORBERT , LIPPERT GERALD , LOCHTMAN RENE , MAAS HEIKO , PFISTER JUERGEN , SOBOTKA BETTINA , WAGNER NORBERT , NIESNER NORBERT , SCHEIBITZ MATTHIAS , DAHLKE MICHAEL , WARZELHAN VOLKER
IPC分类号： B29C55/00 , B29C59/00 , C23C18/18
摘要： Preparation of metal-plated, extruded plastic comprises: melt blending and extrusion of a plastic mixture (comprising: thermoplastic polymer (A); metal powder (B) having an average particle diameter of 0.1-100 mu m and more negative normal potential in acid solution than silver; dispersant (C); and fibrous/particulate fillers or their mixture (D)); and contacting the extruded plastic object with an acid, neutral or basic metal salt solution through electrolessly or galvanically. Preparation of metal-plated, extruded plastic comprises: melt blending and extrusion of a plastic mixture (comprising 100 wt.% of the components related to the total weight: 5-50 wt.% of thermoplastic polymer (A); 50-95 wt.% of metal powder (B) having an average particle diameter of 0.1-100 mu m and more negative normal potential in acid solution than silver; 0-10 wt.% of dispersant (C); and 0-40 wt.% of fibrous/particulate fillers or their mixture (D)); and contacting extruded plastic object with an acid, neutral or basic metal salt solution through electrolessly or galvanically brought into contact , that metal having a more positive normal potential in a correspondingly acid, neutral or basic solution than component (B), where the plastic object is surface-activated in the non-molten state after the melt blending and extrusion step and before the contacting step. An independent claim is included for a metal-plated, extruded plastic object obtained by the process.

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