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1. 发明授权

US3476669A Apparatus for photochemical reactions 失效
标题翻译：光化学反应装置
公开(公告)号：US3476669A
公开(公告)日：1969-11-04
申请号：US3476669D
申请日：1966-04-06
申请人： BASF AG
发明人： BECKMANN WILHELM , KENGELBACH WERNER LUDWIG , PAPE MARTIN
IPC分类号： B01F15/06 , B01J19/12 , B28C7/08 , B01K1/00 , C07C3/24
CPC分类号： B28C7/0841 , B01F15/066 , B01J19/123

2. 发明授权

US3567609A Photolytic production of n-substituted n-nitrosohydroxylamines 失效
标题翻译： N-取代的N-硝基甲硅烷基胺的光致产生
公开(公告)号：US3567609A
公开(公告)日：1971-03-02
申请号：US3567609D
申请日：1967-10-20
申请人： BASF AG
发明人： PAPE MARTIN , RAFF PAUL
IPC分类号： B01J1/10
CPC分类号： Y10S204/903 , Y10S204/904
摘要： A PROCESS FOR THE PRODUCTION OF N-SUBSTITUTED N-NITROSOHYDROXYLAMINES HAVING THE FORMULA:

R-N(-N=O)-OH

IN WHICH R DENOTES AN ALKYL, CYCLOLKYL OR ARALKYL RADICAL, BY REACTING A HYDROCARBON R-H (IN WHICH R HAS THE SAID MEANING) WITH NO AND HC1 IN THE PRESENCE OF LIGHT AT TEMPERATURE OF FROM-100*C. TO+100*C. AT A PRESSURE OF UP TO 2 ATMOSPHERES ABSOLUTE.

3. 发明专利

GB1136116A Carrying out photochemical reactions 未知
公开(公告)号：GB1136116A
公开(公告)日：1968-12-11
申请号：GB1549866
申请日：1966-04-07
申请人： BASF AG
发明人： BECKMANN WILHELM , KENGELBACH WERNER LUDWIG , METZGER HORST , PAPE MARTIN
IPC分类号： B01F15/06 , B01J19/12 , B28C7/08
摘要： 1,136,116. Photochemical reactors. BADISCHE ANILIN-& SODA-FABRIK A.G. 7 April, 1966 [9 April, 1965], No. 15498/66. Heading B1X. A photochemical liquid phase reactor, which is especially suitable for use in the production of oximes from cycloalkanes in the presence of a solvent, has a central stirrer around which is a plurality of lamps, the diameter of a lamp being D, the inter-lamp separation is 0.3-2D, the lamp-stirrer separation is 0.05-0.5D, and the separation between the lamps and the wall is at least 0.5D. The reactor may be cylindrical with the stirrer at the axis and the lamps disposed on a circle about the axis. The stirrer may be rectangular (7 in Fig. 1, not shown), or anchor shaped (Fig. 3, not shown), and generally operates at 40-200 rpm. The cell may be cooled by elements 8, coils 10, or a cooling jacket 9 (Fig. 4, not shown). In Figs. 5 and 6 (not shown) are shown arrangements having a plurality of cells in series. In the reactor of Fig. 5, liquid flows in the direction of the arrows through cells 11 having perforate partitions 14 and stirrers 12. In the arrangement of Fig. 6, liquid flows to reactors 15, 17, 19, 21, 23, and 25 through coolers 16, 18, 20, 22, 24, and 26.

4. 发明专利

CA754175A PRODUCTION OF .epsilon.-CYANOCAPROIC ACID 未知
公开(公告)号：CA754175A
公开(公告)日：1967-03-07
申请号：CA754175D
申请人： BASF AG
发明人： METZGER HORST , PAPE MARTIN

5. 发明专利

FR1432108A 未知
公开(公告)号：FR1432108A
公开(公告)日：1966-03-18
申请号：FR13807
申请日：1965-04-20
申请人： BASF AG
发明人： PAPE MARTIN , BECKMANN WILHELM , METZGER HORST
IPC分类号： B01J19/12

6. 发明专利

CA813318A PRODUCTION OF N-SUBSTITUTED N-NITROSOHYDROXYLAMINES 未知
公开(公告)号：CA813318A
公开(公告)日：1969-05-20
申请号：CA813318D
申请人： BASF AG
发明人： RAFF PAUL , PAPE MARTIN

7. 发明专利

CA799957A CARRYING OUT PHOTOCHEMICAL REACTIONS 未知
公开(公告)号：CA799957A
公开(公告)日：1968-11-26
申请号：CA799957D
申请人： BASF AG
发明人： KENGELBACH WERNER L , BECKMANN WILHELM , PAPE MARTIN , METZGER HORST

8. 发明专利

FR1440775A 未知
公开(公告)号：FR1440775A
公开(公告)日：1966-06-03
申请号：FR13984
申请日：1965-04-21
申请人： BASF AG
发明人： BEER LUDWIG , PAPE MARTIN , METZGER HORST
IPC分类号： B01J19/12

9. 发明专利

GB1136747A Continuous photooximation of cyclododecane 未知
公开(公告)号：GB1136747A
公开(公告)日：1968-12-18
申请号：GB1722566
申请日：1966-04-20
申请人： BASF AG
发明人： BEER LUDWIG , PAPE MARTIN , METZGER HORST
IPC分类号： B01J19/12
摘要： 1,136,747. Cyclododecane oxime. BADISCHE ANILIN- & SODA-FABRIK A.G. 20 April, 1966 [21 April, 1965], No. 17225/66. Heading C2C. Cyclododecane is converted to its oxime by treating a solution of cyclododecane in chlorobenzene with a nitrosating agent and with light having a wavelength of 360-600 millimicrons while mixing the reaction mixture with turbulence, the cyclododecane oxime being removed from the reaction mixture outside the reaction zone by extraction with strong sulphuric acid. Suitable nitrosating agents are, for example, nitrosyl chloride or compounds which form nitrosyl chloride in the reaction medium. If desired, the process may be carried out in the presence of hydrogen chloride.

10. 发明专利

GB1095916A Continuous photochemical reactions 未知
公开(公告)号：GB1095916A
公开(公告)日：1967-12-20
申请号：GB1618865
申请日：1965-04-15
申请人： BASF AG
发明人： PAPE MARTIN , BECKMANN WILHELM , METZEGER HORST
IPC分类号： B01J19/12
摘要： In a continuous process for the photonitrosation of cycloalkanes, a concentration gradient in respect of the photo-sensitive substance is produced in the solution to be irradiated, the concentration gradient being such that the concentration of the photosensitive substance in the reaction medium adjacent to the light transmitting surface is at most half the concentration in the rest of the reaction medium. The cycloalkanes may have 5 to 12 carbon atoms, and may be reacted in the temperature range - 30 DEG to + 30 DEG C. with for example nitrosyl chloride in amount to give from 0.3% to 0.5% by weight in the reaction mixture of nitrous oxide and chlorine under the influence of light having a wave-length of 360 to 600 millimicrons, advantageously in the presence of hydrogen chloride. If a solvent is needed it may be benzene, chloroform, ethylene chloride or glacial acetic acid. The example relates to the nitrosation of cyclohexane, in which a solution of nitrosyl chloride in cyclohexane saturated with hydrogen chloride is exposed at 18 DEG to 20 DEG C. to a mercury vapour lamp to give cyclohexanone oxime hydrochloride.

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