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1. 发明授权

US3476669A Apparatus for photochemical reactions 失效
标题翻译：光化学反应装置
公开(公告)号：US3476669A
公开(公告)日：1969-11-04
申请号：US3476669D
申请日：1966-04-06
申请人： BASF AG
发明人： BECKMANN WILHELM , KENGELBACH WERNER LUDWIG , PAPE MARTIN
IPC分类号： B01F15/06 , B01J19/12 , B28C7/08 , B01K1/00 , C07C3/24
CPC分类号： B28C7/0841 , B01F15/066 , B01J19/123

2. 发明授权

US3458467A Continuous emulsion polymerization 失效
标题翻译：连续乳化聚合
公开(公告)号：US3458467A
公开(公告)日：1969-07-29
申请号：US3458467D
申请日：1965-12-27
申请人： BASF AG
发明人： HERRLE KARL , BAUMANN KARL HEINZ , BECKMANN WILHELM , HEIL EDUARD
IPC分类号： B01J10/00 , B01J19/24 , C08F2/00 , C08F2/22 , C08F1/06 , C08F1/13
CPC分类号： C08F2/22 , B01J19/2435 , B01J2219/00094

3. 发明授权

US3458418A Process for carrying out photochemical reactions and apparatus therefor 失效
标题翻译：执行光化学反应的方法及其装置
公开(公告)号：US3458418A
公开(公告)日：1969-07-29
申请号：US3458418D
申请日：1966-03-15
申请人： BASF AG
发明人： BECKMANN WILHELM
IPC分类号： B01J19/12 , B01J1/10
CPC分类号： B01J19/123

4. 发明专利

GB1095916A Continuous photochemical reactions 未知
公开(公告)号：GB1095916A
公开(公告)日：1967-12-20
申请号：GB1618865
申请日：1965-04-15
申请人： BASF AG
发明人： PAPE MARTIN , BECKMANN WILHELM , METZEGER HORST
IPC分类号： B01J19/12
摘要： In a continuous process for the photonitrosation of cycloalkanes, a concentration gradient in respect of the photo-sensitive substance is produced in the solution to be irradiated, the concentration gradient being such that the concentration of the photosensitive substance in the reaction medium adjacent to the light transmitting surface is at most half the concentration in the rest of the reaction medium. The cycloalkanes may have 5 to 12 carbon atoms, and may be reacted in the temperature range - 30 DEG to + 30 DEG C. with for example nitrosyl chloride in amount to give from 0.3% to 0.5% by weight in the reaction mixture of nitrous oxide and chlorine under the influence of light having a wave-length of 360 to 600 millimicrons, advantageously in the presence of hydrogen chloride. If a solvent is needed it may be benzene, chloroform, ethylene chloride or glacial acetic acid. The example relates to the nitrosation of cyclohexane, in which a solution of nitrosyl chloride in cyclohexane saturated with hydrogen chloride is exposed at 18 DEG to 20 DEG C. to a mercury vapour lamp to give cyclohexanone oxime hydrochloride.

5. 发明专利

FR1471708A 未知
公开(公告)号：FR1471708A
公开(公告)日：1967-03-03
申请号：FR53978
申请日：1966-03-18
申请人： BASF AG
发明人： BECKMANN WILHELM
IPC分类号： B01J19/12

6. 发明专利

GB1136116A Carrying out photochemical reactions 未知
公开(公告)号：GB1136116A
公开(公告)日：1968-12-11
申请号：GB1549866
申请日：1966-04-07
申请人： BASF AG
发明人： BECKMANN WILHELM , KENGELBACH WERNER LUDWIG , METZGER HORST , PAPE MARTIN
IPC分类号： B01F15/06 , B01J19/12 , B28C7/08
摘要： 1,136,116. Photochemical reactors. BADISCHE ANILIN-& SODA-FABRIK A.G. 7 April, 1966 [9 April, 1965], No. 15498/66. Heading B1X. A photochemical liquid phase reactor, which is especially suitable for use in the production of oximes from cycloalkanes in the presence of a solvent, has a central stirrer around which is a plurality of lamps, the diameter of a lamp being D, the inter-lamp separation is 0.3-2D, the lamp-stirrer separation is 0.05-0.5D, and the separation between the lamps and the wall is at least 0.5D. The reactor may be cylindrical with the stirrer at the axis and the lamps disposed on a circle about the axis. The stirrer may be rectangular (7 in Fig. 1, not shown), or anchor shaped (Fig. 3, not shown), and generally operates at 40-200 rpm. The cell may be cooled by elements 8, coils 10, or a cooling jacket 9 (Fig. 4, not shown). In Figs. 5 and 6 (not shown) are shown arrangements having a plurality of cells in series. In the reactor of Fig. 5, liquid flows in the direction of the arrows through cells 11 having perforate partitions 14 and stirrers 12. In the arrangement of Fig. 6, liquid flows to reactors 15, 17, 19, 21, 23, and 25 through coolers 16, 18, 20, 22, 24, and 26.

7. 发明专利

GB1139822A Carrying out photochemical reactions 未知
公开(公告)号：GB1139822A
公开(公告)日：1969-01-15
申请号：GB1191966
申请日：1966-03-18
申请人： BASF AG
发明人： BECKMANN WILHELM
IPC分类号： B01J19/12
摘要： 1,139,822. Lamps. BADISCHE ANILIN- & SODA-FABRIK A.G. 18 March, 1966 [19 March, 1965], No. 11919/66. Heading F4R. [Also in Division B1] A lamp 1 for use in photochemical reactors (see Division B1) is surrounded by an inner cooling tube 4 which is in turn surrounded by a central cooling tube 5 which is in turn surrounded by an insulating tube 9. Cooling liquid is continuously passed into the chamber between said inner and central tubes, and the outer chamber 10 contains a gas at atmospheric or sub-atmospheric pressure.

8. 发明专利

CA799957A CARRYING OUT PHOTOCHEMICAL REACTIONS 未知
公开(公告)号：CA799957A
公开(公告)日：1968-11-26
申请号：CA799957D
申请人： BASF AG
发明人： KENGELBACH WERNER L , BECKMANN WILHELM , PAPE MARTIN , METZGER HORST

9. 发明专利

GB1124610A Continuous emulsion polymerization 未知
公开(公告)号：GB1124610A
公开(公告)日：1968-08-21
申请号：GB5536365
申请日：1965-12-31
申请人： BASF AG
发明人： HERRLE KARL , BAUMAN KARL HEINZ , BECKMANN WILHELM , HEIL EDUARD
IPC分类号： B01J10/00 , B01J19/24 , C08F2/00 , C08F2/22
摘要： A process for the continuous emulsion polymerization of conventional olefinically unsaturated monomers which are practically insoluble or at most partly soluble in water, in aqueous medium in the presence of conventional polymerization catalysts, comprises continuous supplying monomers exclusively in the form of a preformed aqueous emulsion through a tube in an upward flow at a flow velocity of 5 to 100 cm. per sec. to the lower part of a vertically arranged circulation system, blending with an excess of polymer dispersion which has already formed, and polymerizing in the circulation system without the use of mechanical stirrers to a mean conversion of more than 75%, the polymer dispersion being withdrawn at a point not higher than the point of entry of the monomer emulsion into the circulation system and at the same rate as the monomer emulsion is supplied. Optional process features include preblending of monomer with polymer, a temperature difference between ascending and descending parts, bubbling inert gas through the ascending part, boiling the ascending dispersion with the aid of reduced pressure, and complex circulation systems. In examples, monomers polymerized are: (1) butyl acrylate-acrylic acid, (2) and (3) methyl methacrylate in the presence of dispersed polymethyl methacrylate, (4) and (5) butyl acrylate-vinyl acetate-acrylic acid, (6) and (7) vinyl propionate-sodium vinyl sulphonate, (8) styrene-acrylic acid-acrylonitrile, (9) vinylidene chloride-acrylonitrile-methacrylamide and (10) butyl acrylate-vinyl acetate-sodium vinyl sulphonate-acrylic acid; the catalyst being potassium persulphate or azodiisobutyronitrile and the emulsifier being selected from dodecylbenzene sulphonate, C10-C16-alkyl sulphonate, polyethoxylated octadecyl alcohol, turkey red oil and sodium salt of sulphochlorinated paraffins. The process can also be applied using other monomers such as ethyl acrylate, vinyl pivalate, vinyl chloride, methacrylic acid, acrylamide and N-methylolmethacrylamide; and with other catalysts, e.g. hydrogen peroxide, ammonium persulphate, benzoyl peroxide and dialkyl percarbonates.

10. 发明专利

FR1466640A 未知
公开(公告)号：FR1466640A
公开(公告)日：1967-01-20
申请号：FR44468
申请日：1965-12-31
申请人： BASF AG
发明人： HERRLE KARL , BAUMANN KARL HEINZ , BECKMANN WILHELM , HEIL EDUARD
IPC分类号： B01J10/00 , B01J19/24 , C08F2/00 , C08F2/22
摘要： A process for the continuous emulsion polymerization of conventional olefinically unsaturated monomers which are practically insoluble or at most partly soluble in water, in aqueous medium in the presence of conventional polymerization catalysts, comprises continuous supplying monomers exclusively in the form of a preformed aqueous emulsion through a tube in an upward flow at a flow velocity of 5 to 100 cm. per sec. to the lower part of a vertically arranged circulation system, blending with an excess of polymer dispersion which has already formed, and polymerizing in the circulation system without the use of mechanical stirrers to a mean conversion of more than 75%, the polymer dispersion being withdrawn at a point not higher than the point of entry of the monomer emulsion into the circulation system and at the same rate as the monomer emulsion is supplied. Optional process features include preblending of monomer with polymer, a temperature difference between ascending and descending parts, bubbling inert gas through the ascending part, boiling the ascending dispersion with the aid of reduced pressure, and complex circulation systems. In examples, monomers polymerized are: (1) butyl acrylate-acrylic acid, (2) and (3) methyl methacrylate in the presence of dispersed polymethyl methacrylate, (4) and (5) butyl acrylate-vinyl acetate-acrylic acid, (6) and (7) vinyl propionate-sodium vinyl sulphonate, (8) styrene-acrylic acid-acrylonitrile, (9) vinylidene chloride-acrylonitrile-methacrylamide and (10) butyl acrylate-vinyl acetate-sodium vinyl sulphonate-acrylic acid; the catalyst being potassium persulphate or azodiisobutyronitrile and the emulsifier being selected from dodecylbenzene sulphonate, C10-C16-alkyl sulphonate, polyethoxylated octadecyl alcohol, turkey red oil and sodium salt of sulphochlorinated paraffins. The process can also be applied using other monomers such as ethyl acrylate, vinyl pivalate, vinyl chloride, methacrylic acid, acrylamide and N-methylolmethacrylamide; and with other catalysts, e.g. hydrogen peroxide, ammonium persulphate, benzoyl peroxide and dialkyl percarbonates.

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