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    • 1. 发明授权
    • Solid catalyst component for olefin polymerization catalysts
    • 烯烃聚合催化剂的固体催化剂组分
    • US4847227A
    • 1989-07-11
    • US105586
    • 1987-10-08
    • Atsushi MuraiMinoru TeranoKohei KimuraMasuo InoueKatsuyoshi Miyoshi
    • Atsushi MuraiMinoru TeranoKohei KimuraMasuo InoueKatsuyoshi Miyoshi
    • C08F4/60C08F4/64C08F4/658C08F10/00
    • C08F10/00
    • A solid catalyst component for olefin polymerization catalysts prepared by suspending diethoxymagnesium (a) in an aromatic hydrocarbon (b) which is liquid at normal temperature and bringing the suspension into a first contact with titanium tetrachloride (c) to form a product and bringing it into a second contact with tianium tetrachloride (c) in such manner that a diester (d) of an aromatic dicarboxylic acid and calcium chloride (e) are allowed to coexist at any stage of the above suspending and/or contacts, the calcium chloride (e) being used in an amount of 1-2 grams per gram of the diethoxymagnesium (a). This solid catalyst component exhibits, when applied to the polymerization of olefins, a surprisingly enhanced polymerization activity per titanium atom and a high stereospecific performance and scarcely necessitates any deashing treatment, thus affording a great economical advantage.
    • 一种用于烯烃聚合催化剂的固体催化剂组分,其通过将二乙氧基镁(a)悬浮在常温下为液体的芳族烃(b)中并使悬浮液与四氯化钛(c)首次接触形成产物并使其进入 与四氯化钛(c)的第二次接触,使得芳族二羧酸和氯化钙(e)的二酯(d)在上述悬浮和/或接触的任何阶段共存,氯化钙(e )的用量为每克二乙氧基镁(a)1-2克。 当用于烯烃聚合时,该固体催化剂组分表现出惊人的增加的每个钛原子的聚合活性和高立体特异性性能,并且几乎不需要任何脱屑处理,从而提供了巨大的经济优势。
    • 2. 发明授权
    • Solid catalyst component for olefin polymerization catalysts
    • 用于烯烃聚合催化剂的固体催化剂组分
    • US4839321A
    • 1989-06-13
    • US141523
    • 1988-01-07
    • Atsushi MuraiMinoru TeranoKohei KimuraMasuo Inoue
    • Atsushi MuraiMinoru TeranoKohei KimuraMasuo Inoue
    • C08F4/60C08F4/64C08F4/658C08F10/00
    • C08F10/00
    • A solid catalyst component for olefin polymerization catalysts prepared by subjecting diethoxymagnesium (a), calcium chloride (b) and a silicon compound (c) of the general formula: Si(OR).sub.4 (wherein R is an alkyl or aryl group) together to a contact treatment in the presence of an organic solvent (d), suspending the treated composition in an aromatic hydrocarbon (e) which is liquid at normal temperature and bringing the suspension into a first contact with titanium tetrachloride (f) to form a product and bringing it to a second contact with titanium tetrachloride (f) in such manner that a diester (g) of an aromatic dicarboxylic acid is allowed to coexist at any stage of the above suspending and/or contacts with the exception of the contact treatment, the calcium chloride (b) being used in an amount of 1-2 g per gram of the diethoxymagnesium (a). This solid catalyst component exhibits, when applied to the polymerization of olefins, a surprisingly enhanced polymerization activity per titanium atom and a high stereospecific performance and scarcely necessitates any deashing treatment, thus affording a great economical advantage.
    • 将通式为Si(OR)4(其中R为烷基或芳基)的二乙氧基镁(a),氯化钙(b)和硅化合物(c))(其中R为烷基或芳基)一起制备的烯烃聚合催化剂固体催化剂组分 在有机溶剂(d)的存在下进行接触处理,将经处理的组合物悬浮在常温下为液态的芳烃(e)中,并使悬浮液与四氯化钛(f)进行第一次接触以形成产物, 使其与四氯化钛(f)进行第二次接触,使得除了接触处理之外,在上述悬浮和/或接触的任何阶段允许芳族二羧酸的二酯(g)共存, 氯化钙(b)的用量为每克二乙氧基镁(a)1-2克。 当用于烯烃聚合时,该固体催化剂组分表现出惊人的增加的每个钛原子的聚合活性和高立体特异性性能,并且几乎不需要任何脱屑处理,从而提供了巨大的经济优势。
    • 4. 发明授权
    • Process for the preparation of catalyst component for the polymerization
of olefins
    • 制备烯烃聚合催化剂组分的方法
    • US4460701A
    • 1984-07-17
    • US482059
    • 1983-04-05
    • Minoru TeranoKouhei KimuraAtsushi MuraiMasuo InoueKatsuyoshi Miyoshi
    • Minoru TeranoKouhei KimuraAtsushi MuraiMasuo InoueKatsuyoshi Miyoshi
    • C08F4/00C08F4/10C08F4/16C08F4/60C08F4/64C08F4/65C08F10/00C08F4/02
    • C08F10/00
    • A process for the preparation of the former catalyst component of a catalyst for the polymerization of olefins composed of a titanium-based catalyst component and an organo aluminium compound is disclosed, which process comprises suspending (a) a fatty acid salt of magnesium and (b) dialkoxymagnesium into (c) a liquid halogenated hydrocarbon to form a first suspension, and adding said first suspension to (d) a titanium halide of the general formula: TiX.sub.4, wherein X represents a halogen atom, to be contacted for reaction to form a first reaction mixture, (e) an electron donor compound being present in at least one of the first suspension, the titanium halide and the first reaction mixture; or suspending the dialkoxymagnesium into the liquid halogenated hydrocarbon to form a second suspension, and adding said second suspension to a mixture of the titanium halide and the fatty acid salt of magnesium to be contacted for reaction to form a second reaction mixture, the electron donor compound being present in at least one of the second suspension, the mixture of the titanium halide and the fatty acid salt of magnesium, and the second reaction mixture.In the polymerization of olefins by use of the former catalyst component, both the amount of catalyst residues in the produced polymer and halogen content therein are greatly reduced with high polymerization activity per unit weight of the former catalyst component and with high yield of stereoregular polymer.
    • 公开了制备由钛基催化剂组分和有机铝化合物组成的烯烃聚合催化剂的前催化剂组分的方法,该方法包括将(a)镁的脂肪酸盐和(b )二烷氧基镁转化为(c)液体卤代烃以形成第一悬浮液,并将所述第一悬浮液加入到(d)通式TiX 4的卤化钛,其中X表示卤素原子,以进行反应以形成 第一反应混合物,(e)电子给体化合物存在于第一悬浮液,卤化钛和第一反应混合物中的至少一种中; 或将二烷氧基镁悬浮到液体卤代烃中以形成第二悬浮液,并将所述第二悬浮液加入到待接触的卤化钛和镁的脂肪酸盐的混合物中以形成第二反应混合物,电子给体化合物 存在于第二悬浮液,卤化钛和镁的脂肪酸盐的混合物中的至少一种和第二反应混合物中。 在通过使用前述催化剂组分的烯烃聚合中,所制备的聚合物中的催化剂残余物的量和其中的卤素含量都大大降低,而单一重量的前一种催化剂组分具有高的聚合活性,并且立体有规聚合物的产率高。
    • 9. 发明授权
    • Absorbent article
    • 吸收制品
    • US07048726B2
    • 2006-05-23
    • US10056485
    • 2002-01-28
    • Tetsuya KusagawaAtsushi MuraiMitsugu HamajimaJinko Noguchi
    • Tetsuya KusagawaAtsushi MuraiMitsugu HamajimaJinko Noguchi
    • A61F13/15A61F13/20
    • A61F13/4753
    • An absorbent article (1) having a liquid-retentive absorbing layer (2), a liquid-impermeable leakproof layer (3), and standing gathers (4) on each side. The gathers have an elastically extensible portion (40) coming into planar contact with the wearer's skin while worn. The elastically extensible portion (40) is made of a sheet (44) and at least one elastic member (45), the elastic member (45) being fixed to the sheet (44) discretely in the longitudinal direction in its stretched state, and the parts of the sheet where the elastic member (45) is not fixed are raised by contraction of the elastic member (45) to form a plurality of hollow ridges (43) on the side of the elastically extensible portion (40) to be brought into contact with the wearer's skin.
    • 一种具有液体保持性吸收层(2)的吸收性物品(1),不透液性的防漏层(3)和每侧的立体褶皱(4)。 所述褶皱具有在穿着时与穿着者皮肤平面接触的弹性可延伸部分(40)。 弹性伸缩部分(40)由薄片(44)和至少一个弹性构件(45)制成,弹性构件(45)在拉伸状态下沿纵向离散地固定在薄片(44)上,以及 弹性构件(45)未固定的片材的部分通过弹性构件(45)的收缩而升高,以在弹性伸缩部分(40)的侧面上形成多个中空脊(43) 与穿着者的皮肤接触。