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    • 7. 发明授权
    • Thin-film forming method
    • 薄膜成型方法
    • US5783260A
    • 1998-07-21
    • US686366
    • 1996-07-25
    • Yoshifumi KatoYoshifumi FujitaAtsushi HozumiAkiteru Nishio
    • Yoshifumi KatoYoshifumi FujitaAtsushi HozumiAkiteru Nishio
    • C08J3/24C08J7/04B05D3/02B05D3/06
    • C08J7/04C08J3/243C08J7/047C08J2333/12C08J2369/00
    • A thin-film forming method comprising an uncured-layer forming step in which a mixed composition containing an organic polymerizing agent curable composition and a silicone polymerizing curable composition is prepared to form an uncured layer consisting of this mixed composition on a resin substrate; a solvent removing step in which the solvent in the uncured layer is removed; a first polymerization curing step in which the organic polymerizing curable composition in the uncured layer is polymerized; and a second polymerization curing step in which the silicone polymerizing curable composition in the uncured layer is polymerized. The thin-film forming method can comprise formation of the uncured layer on a resin substrate through the intermediation of a primer layer or formation of an uncured underlayer and uncured top layer followed by separate underlayer polymerization and top layer polymerization curing steps. The methods are applicable to the production of abrasion-resistant and water-repellant resin glass for automobiles.
    • 一种包含未固化层形成步骤的薄膜形成方法,其中制备含有有机聚合剂固化性组合物和硅氧烷聚合性固化性组合物的混合组合物,以在树脂基材上形成由该混合组合物构成的未固化层; 除去未固化层中的溶剂的溶剂除去步骤; 将未固化层中的有机聚合性固化性组合物聚合的第一聚合固化步骤; 和第二聚合固化步骤,其中未固化层中的硅氧烷聚合可固化组合物聚合。 薄膜形成方法可以包括通过底漆层或未固化的底层和未固化的顶层的形成,然后分开的下层聚合和顶层聚合固化步骤在树脂基材上形成未固化的层。 该方法适用于生产用于汽车的耐磨和防水树脂玻璃。
    • 8. 发明授权
    • Thin-film forming method
    • 薄膜成型方法
    • US5571569A
    • 1996-11-05
    • US420209
    • 1995-04-11
    • Yoshifumi KatoYoshifumi FujitaAtsushi HozumiAkiteru Nishio
    • Yoshifumi KatoYoshifumi FujitaAtsushi HozumiAkiteru Nishio
    • C08J3/24C08J7/04B05D3/02B05D3/06
    • C08J7/04C08J3/243C08J7/047C08J2333/12C08J2369/00
    • A thin-film forming method comprising an uncured-layer forming step in which a mixed composition containing an organic polymerizing agent curable composition and a silicone polymerizing curable composition is prepared to form an uncured layer consisting of this mixed composition on a resin substrate; a solvent removing step in which the solvent in the uncured layer is removed; a first polymerization curing step in which the organic polymerizing curable composition in the uncured layer is polymerized; and a second polymerization curing step in which the silicone polymerizing curable composition in the uncured layer is polymerized. The thin-film forming method can comprise formation of the uncured layer on a resin substrate through the intermediation of a primer layer or formation of an uncured underlayer and uncured top layer followed by separate underlayer polymerization and top layer polymerization curing steps. The methods are applicable to the production of abrasion-resistant and water-repellent resin glass for automobiles.
    • 一种包含未固化层形成步骤的薄膜形成方法,其中制备含有有机聚合剂固化性组合物和硅氧烷聚合性固化性组合物的混合组合物,以在树脂基材上形成由该混合组合物构成的未固化层; 除去未固化层中的溶剂的溶剂除去步骤; 将未固化层中的有机聚合性固化性组合物聚合的第一聚合固化步骤; 和第二聚合固化步骤,其中未固化层中的硅氧烷聚合可固化组合物聚合。 薄膜形成方法可以包括通过底漆层或未固化的底层和未固化的顶层的形成,然后分开的下层聚合和顶层聚合固化步骤在树脂基材上形成未固化的层。 该方法适用于生产用于汽车的耐磨和防水树脂玻璃。
    • 9. 发明授权
    • Process for producing ceramic porous bodies having hollow structures at low temperatures
    • 在低温下制造具有中空结构的陶瓷多孔体的方法
    • US06645571B1
    • 2003-11-11
    • US09657398
    • 2000-09-08
    • Osamu TakaiHiroyuki SugimuraAtsushi Hozumi
    • Osamu TakaiHiroyuki SugimuraAtsushi Hozumi
    • B05D306
    • C04B41/009C04B38/0022C04B38/062C04B41/4582C04B35/01C04B35/62218C04B38/0054C04B40/0017C04B40/0089C04B38/009C04B41/0045C04B41/4515C04B41/4554C04B41/5027
    • A process for producing the ceramic porous body comprising the steps of (1) forming micelles in liquid by mixing {circle around (1)} surfactant molecules, {circle around (2)} surfactant molecules and given organic molecules, or {circle around (3)} different kinds of surfactant molecules, (2) forming a precursor of a ceramic porous body having an organic-inorganic structure is formed through mixing a ceramic material or a precursor of the ceramic material into the liquid containing the micelles, the precursor of the ceramic porous body comprising a template having the micelles arranged in a hexagonal, cubic or lamella form and the ceramic material or the ceramic material precursor adsorbed around the micelles, (3) removing the surfactant molecules or the surfactant molecules and the given organic molecules in the precursor of the ceramic porous body by photo-oxidation through irradiating vacuum ultraviolet light upon the precursor to leave an inorganic skeleton alone, and (4) thereby forming the ceramic porous body having nanometer-scale pores at a low temperature.
    • 一种制造陶瓷多孔体的方法,包括以下步骤:(1)通过混合(圆周(1个表面活性剂分子,2个表面活性剂分子和给定的有机分子,或3个不同的 表面活性剂分子,(2)通过将陶瓷材料或陶瓷材料的前体混合到含有胶束的液体中形成具有有机 - 无机结构的陶瓷多孔体的前体,陶瓷多孔体的前体包含 具有以六边形,立方体或薄片形式布置的胶束和陶瓷材料或陶瓷材料前体吸附在胶束周围的模板,(3)去除表面活性剂分子或表面活性剂分子和陶瓷多孔的前体中的给定有机分子 通过对前体照射真空紫外光进行光氧化,单独留下无机骨架,(4)由此形成 该陶瓷多孔体在低温下具有纳米尺度的孔。
    • 10. 发明授权
    • Process for forming a film with photocatalytic function
    • 用光催化功能形成薄膜的方法
    • US06465388B1
    • 2002-10-15
    • US09626658
    • 2000-07-27
    • Atsushi HozumiHitotoshi Murase
    • Atsushi HozumiHitotoshi Murase
    • B01J3100
    • B05D7/586B05D5/00
    • A photocatalytic film is formed by: a step for forming an uncured underlayer from an organic composition on the surface of a resinous base and polymerizing the organic composition to convert the uncured underlayer into an underlayer having a hardness higher than that of the resinous base; a step for forming an uncured intermediate layer from a polymerizable and curable silicone composition on the uncured underlayer or on the underlayer to yield an uncured intermediate layer, and polymerizing the polymerizable and curable silicone composition to convert the uncured intermediate layer to an intermediate layer, the polymerizable and curable silicone composition being prepared mainly from a hydrolyzable tetrafunctional silane derivative; and a step for forming a photocatalytic layer on the intermediate layer. This process can form an intermediate layer having a very high hardness without cracking and can easily yield a photocatalytic film having a satisfactory abrasion resistance.
    • 通过以下步骤形成光催化膜:通过在树脂基材的表面上形成有机组合物的未固化底层的步骤,并使有机组合物聚合,将未固化的底层转化为硬度高于树脂基材的硬度的底层; 从未固化的底层或底层上的可聚合和可固化的硅氧烷组合物形成未固化的中间层以产生未固化的中间层,并聚合可聚合和可固化的硅氧烷组合物以将未固化的中间层转化为中间层的步骤, 可聚合和可固化的有机硅组合物主要由可水解的四官能硅烷衍生物制备; 以及在中间层上形成光催化层的步骤。 该方法可以形成具有非常高的硬度而不破裂的中间层,并且可以容易地产生具有令人满意的耐磨性的光催化膜。