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1. 发明授权

US08034219B2 System and method for the production of hydrogen 有权
标题翻译：用于生产氢气的系统和方法
公开(公告)号：US08034219B2
公开(公告)日：2011-10-11
申请号：US12367369
申请日：2009-02-06
申请人： Andrew Maxwell Peter , Stephane Renou , James Anthony Ruud , Leah Diane Crider , Kenneth Walter Browall , Chellappa Balan
发明人： Andrew Maxwell Peter , Stephane Renou , James Anthony Ruud , Leah Diane Crider , Kenneth Walter Browall , Chellappa Balan
IPC分类号： C25B9/06 , C25B1/02 , C25B1/04 , C25B1/10
CPC分类号： C25B1/02 , C25B15/08 , F22B31/00
摘要： Disclosed herein are a system and a method for the production of hydrogen. The system advantageously combines an independent high temperature heat source with a solid oxide electrolyzer cell and a heat exchanger located between the cathode inlet and the cathode outlet. The heat exchanger is used to extract heat from the molecular components such as hydrogen derived from the electrolysis. A portion of the hydrogen generated in the solid oxide electrolyzer cell is recombined with steam and recycled to the solid oxide electrolyzer cell. The oxygen generated on the anode side is swept with compressed air and used to drive a gas turbine that is in operative communication with a generator. Electricity generated by the generator is used to drive the electrolysis in the solid oxide electrolyzer cell.
摘要翻译：本文公开了用于生产氢气的系统和方法。该系统有利地将独立的高温热源与固体氧化物电解池单元和位于阴极入口和阴极出口之间的热交换器组合。热交换器用于从分子成分（例如从电解产生的氢）中提取热量。在固体氧化物电解池中产生的氢的一部分与蒸汽重新组合并再循环到固体氧化物电解池中。在阳极侧产生的氧气被压缩空气扫过，用于驱动与发电机操作性连通的燃气轮机。由发电机产生的电力用于驱动固体氧化物电解槽中的电解。

2. 发明申请

US20090139874A1 SYSTEM AND METHOD FOR THE PRODUCTION OF HYDROGEN 有权
标题翻译：用于生产氢的系统和方法
公开(公告)号：US20090139874A1
公开(公告)日：2009-06-04
申请号：US12367369
申请日：2009-02-06
申请人： Andrew Maxwell Peter , Stephane Renou , James Anthony Ruud , Leah Diane Crider , Kenneth Walter Browall , Chellappa Balan
发明人： Andrew Maxwell Peter , Stephane Renou , James Anthony Ruud , Leah Diane Crider , Kenneth Walter Browall , Chellappa Balan
IPC分类号： C25B15/08 , C25B9/00 , C25B1/02
CPC分类号： C25B1/02 , C25B15/08 , F22B31/00
摘要： Disclosed herein are a system and a method for the production of hydrogen. The system advantageously combines an independent high temperature heat source with a solid oxide electrolyzer cell and a heat exchanger located between the cathode inlet and the cathode outlet. The heat exchanger is used to extract heat from the molecular components such as hydrogen derived from the electrolysis. A portion of the hydrogen generated in the solid oxide electrolyzer cell is recombined with steam and recycled to the solid oxide electrolyzer cell. The oxygen generated on the anode side is swept with compressed air and used to drive a gas turbine that is in operative communication with a generator. Electricity generated by the generator is used to drive the electrolysis in the solid oxide electrolyzer cell.
摘要翻译：本文公开了用于生产氢气的系统和方法。该系统有利地将独立的高温热源与固体氧化物电解池单元和位于阴极入口和阴极出口之间的热交换器组合。热交换器用于从分子成分（例如从电解产生的氢）中提取热量。在固体氧化物电解池中产生的氢的一部分与蒸汽重新组合并再循环到固体氧化物电解池中。在阳极侧产生的氧气被压缩空气扫过，用于驱动与发电机操作性连通的燃气轮机。由发电机产生的电力用于驱动固体氧化物电解槽中的电解。

3. 发明授权

US07491309B2 System and method for the production of hydrogen 有权
标题翻译：用于生产氢气的系统和方法
公开(公告)号：US07491309B2
公开(公告)日：2009-02-17
申请号：US11314137
申请日：2005-12-21
申请人： Andrew Maxwell Peter , Chellappa Balan , James Anthony Ruud , Stephane Renou , Kenneth Walter Browall
发明人： Andrew Maxwell Peter , Chellappa Balan , James Anthony Ruud , Stephane Renou , Kenneth Walter Browall
IPC分类号： C25C7/06
CPC分类号： C25B1/02 , Y02P20/13
摘要： Disclosed herein are a system and a method for the production of hydrogen. The system advantageously combines an independent high temperature heat source with a solid oxide electrolyzer cell and a heat exchanger. The heat exchanger is used to extract heat from the molecular components such as hydrogen derived from the electrolysis. A portion of the hydrogen generated in the solid oxide electrolyzer cell is recombined with steam and recycled to the solid oxide electrolyzer cell. The oxygen generated on the anode side is swept with compressed air and used to drive a gas turbine that is in operative communication with a generator. Electricity generated by the generator is used to drive the electrolysis in the solid oxide electrolyzer cell.
摘要翻译：本文公开了用于生产氢气的系统和方法。该系统有利地将独立的高温热源与固体氧化物电解槽和热交换器组合。热交换器用于从分子成分（例如从电解产生的氢）中提取热量。在固体氧化物电解池中产生的氢的一部分与蒸汽重新组合并再循环到固体氧化物电解池中。在阳极侧产生的氧气被压缩空气扫过，用于驱动与发电机操作性连通的燃气轮机。由发电机产生的电力用于驱动固体氧化物电解槽中的电解。

4. 发明授权

US07691770B2 Electrode structure and methods of making same 有权
标题翻译：电极结构及制作方法
公开(公告)号：US07691770B2
公开(公告)日：2010-04-06
申请号：US11218651
申请日：2005-09-02
申请人： James Anthony Ruud , Kenneth Walter Browall , Timothy Joseph Rehg , Stephane Renou , Todd-Michael Striker
发明人： James Anthony Ruud , Kenneth Walter Browall , Timothy Joseph Rehg , Stephane Renou , Todd-Michael Striker
IPC分类号： H01M4/88 , H01M4/00
CPC分类号： C25B11/00 , H01M4/8853 , H01M4/9058 , H01M4/92 , H01M8/1246 , H01M8/1253 , H01M2300/0077 , Y02E60/525 , Y02P70/56
摘要： A method of making an electrode structure is provided. The method includes disposing an electrocatalytic material on an electrode, applying heat to the electrocatalytic material to form a volatile oxide of the electrocatalytic material, and applying a voltage to the electrode to reduce the volatile oxide to provide a number of nano-sized electrocatalytic particles on or proximate to a triple phase boundary, where the number of nano-sized electrocatalytic particles is greater on or proximate to the triple phase boundary than in an area that is not on or proximate to the triple phase boundary, and where the triple phase boundary is disposed on the electrode.
摘要翻译：提供了制作电极结构的方法。该方法包括在电极上设置电催化材料，向电催化材料施加热量以形成电催化材料的挥发性氧化物，并向电极施加电压以减少挥发性氧化物以在多个纳米尺寸的电催化颗粒上提供或接近三相边界，其中纳米尺寸的电催化颗粒的数量在三相边界上或接近三相边界时比在不在或接近三相边界的区域中更大，并且其中三相边界为设置在电极上。

5. 发明授权

US07713642B2 System and method for fuel cell operation with in-situ reformer regeneration 有权
标题翻译：用原位重整器再生的燃料电池运行系统和方法
公开(公告)号：US07713642B2
公开(公告)日：2010-05-11
申请号：US11241133
申请日：2005-09-30
申请人： Gregory Lee Warner , Kenneth Walter Browall , Stephane Renou
发明人： Gregory Lee Warner , Kenneth Walter Browall , Stephane Renou
IPC分类号： H01M8/04 , H01M8/06
CPC分类号： H01M8/04089 , H01M8/04014 , H01M8/0612
摘要： A system and method for operating a fuel cell, including reacting a fuel with an oxidant within the fuel cell to produce electricity and reaction products comprising steam. The fuel is fed through the fuel cell, wherein a concentration of the steam increases in the first direction through the fuel cell. The direction of fuel-flow through the fuel cell is altered or reversed upon satisfying a condition, thereby altering the concentration gradient of steam in the fuel cell and providing for removal of carbon deposition with the fuel cell. Such reversal of fuel flow may also provide an exhaust from the fuel cell that can regenerate an external or adjacent hydrocarbon reformer.
摘要翻译：一种用于操作燃料电池的系统和方法，包括使燃料与燃料电池内的氧化剂反应以产生电，以及包括蒸汽的反应产物。燃料通过燃料电池进料，其中蒸汽的浓度在第一方向上通过燃料电池增加。通过燃料电池的燃料流动的方向在满足条件时改变或反转，从而改变燃料电池中的蒸汽的浓度梯度并提供用于去除与燃料电池的碳沉积。燃料流的这种反转也可以提供来自燃料电池的废气，其能够再生外部或相邻的烃重整器。

6. 发明申请

US20070138022A1 System and method for the production of hydrogen 有权
标题翻译：用于生产氢气的系统和方法
公开(公告)号：US20070138022A1
公开(公告)日：2007-06-21
申请号：US11314137
申请日：2005-12-21
申请人： Andrew Peter , Chellappa Balan , James Ruud , Stephane Renou , Kenneth Browall
发明人： Andrew Peter , Chellappa Balan , James Ruud , Stephane Renou , Kenneth Browall
IPC分类号： C25D17/00 , G01N27/26 , C25C1/02
CPC分类号： C25B1/02 , Y02P20/13
摘要： Disclosed herein are a system and a method for the production of hydrogen. The system advantageously combines an independent high temperature heat source with a solid oxide electrolyzer cell and a heat exchanger. The heat exchanger is used to extract heat from the molecular components such as hydrogen derived from the electrolysis. A portion of the hydrogen generated in the solid oxide electrolyzer cell is recombined with steam and recycled to the solid oxide electrolyzer cell. The oxygen generated on the anode side is swept with compressed air and used to drive a gas turbine that is in operative communication with a generator. Electricity generated by the generator is used to drive the electrolysis in the solid oxide electrolyzer cell.
摘要翻译：本文公开了用于生产氢气的系统和方法。该系统有利地将独立的高温热源与固体氧化物电解槽和热交换器组合。热交换器用于从分子成分（例如从电解产生的氢）中提取热量。在固体氧化物电解池中产生的氢的一部分与蒸汽重新组合并再循环到固体氧化物电解池中。在阳极侧产生的氧气被压缩空气扫过，用于驱动与发电机操作性连通的燃气轮机。由发电机产生的电力用于驱动固体氧化物电解槽中的电解。

7. 发明申请

US20080299436A1 COMPOSITE CERAMIC ELECTROLYTE STRUCTURE AND METHOD OF FORMING; AND RELATED ARTICLES 审中-公开
标题翻译：复合陶瓷电解质结构及其形成方法; 和相关文章
公开(公告)号：US20080299436A1
公开(公告)日：2008-12-04
申请号：US11755044
申请日：2007-05-30
申请人： Todd-Michael Striker , James Anthony Ruud , Stephane Renou
发明人： Todd-Michael Striker , James Anthony Ruud , Stephane Renou
IPC分类号： H01M8/10 , H01M6/18
CPC分类号： H01M8/1246 , H01M2300/0074 , H01M2300/0091 , Y02E60/525 , Y02P70/56
摘要： A composite ceramic electrolyte is provided. The composite ceramic electrolyte has a microstructure, which comprises a first ceramic composition comprising a plurality of nano-dimensional microcracks, and a second ceramic composition substantially embedded within at least a portion of the plurality of nano-dimensional microcracks. The first and the second compositions are different. A solid oxide fuel cell comprising a composite ceramic electrolyte having such a microstructure is provided. A method of making a composite ceramic electrolyte is also described. The method includes the steps of: providing a first ceramic composition comprising a plurality of nano-dimensional microcracks; and closing a number of the nano-dimensional microcracks with a second ceramic composition, wherein the first and the second compositions are different, so as to form a composite ceramic electrolyte having a microstructure which comprises a first ceramic composition comprising a plurality of nano-dimensional microcracks and a second ceramic composition substantially embedded within at least a portion of the plurality of nano-dimensional microcracks.
摘要翻译：提供复合陶瓷电解质。复合陶瓷电解质具有微观结构，其包括包含多个纳米尺寸微裂纹的第一陶瓷组合物，以及基本嵌入在所述多个纳米尺寸微裂纹的至少一部分中的第二陶瓷组合物。第一和第二组合物是不同的。提供一种包括具有这种微结构的复合陶瓷电解质的固体氧化物燃料电池。还描述了制备复合陶瓷电解质的方法。该方法包括以下步骤：提供包含多个纳米尺寸微裂纹的第一陶瓷组合物; 以及用第二陶瓷组合物封闭许多纳米尺寸微裂纹，其中所述第一和第二组合物是不同的，以便形成具有微结构的复合陶瓷电解质，所述复合陶瓷电解质包含第一陶瓷组合物，所述第一陶瓷组合物包含多个纳米尺寸微裂纹和基本上嵌入在所述多个纳米尺寸微裂纹的至少一部分中的第二陶瓷组合物。

8. 发明申请

US20080176113A1 Systems and method for solid oxide fuel cell cathode processing and testing 审中-公开
标题翻译：固体氧化物燃料电池阴极处理和测试的系统和方法
公开(公告)号：US20080176113A1
公开(公告)日：2008-07-24
申请号：US11656078
申请日：2007-01-22
申请人： Jian Wu , Simon William Gaunt , James Anthony Ruud , Stephane Renou , Todd Michael Striker
发明人： Jian Wu , Simon William Gaunt , James Anthony Ruud , Stephane Renou , Todd Michael Striker
IPC分类号： H01M8/10 , B32B37/00
CPC分类号： H01M8/00 , H01M4/8621 , H01M4/8885 , H01M8/0204 , H01M8/1231 , H01M8/2404 , H01M8/2425 , H01M8/2432 , Y10T156/10
摘要： Systems and methods for high performing in-situ SOFC cathodes, demonstrating self-improved performance over time. Exemplary embodiments include a SOFC including an electrolyte layer, an anode coupled to the electrolyte layer and a cathode coupled to the electrolyte layer, wherein the anode is prepared by applying an anode contact layer to the anode layer and applying anode bond paste to the anode contact layer, wherein the cathode is prepared by screen printing a cathode layer on the electrolyte with or without a barrier layer, and applying cathode bond paste to the dried cathode layer and drying the cathode bond paste in an oven.
摘要翻译：用于高性能原位SOFC阴极的系统和方法，证明自我改进的性能随着时间的推移。示例性实施例包括包括电解质层的SOFC，耦合到电解质层的阳极和耦合到电解质层的阴极，其中通过向阳极层施加阳极接触层并将阳极粘合膏施加到阳极接触层来制备阳极层，其中通过在具有或不具有阻挡层的电解质上丝网印刷阴极层来制备阴极，并且将阴极粘合浆料施加到干燥的阴极层上并在烘箱中干燥阴极粘合膏。

9. 发明申请

US20090317705A1 FUEL CELL INTERCONNECT STRUCTURES, AND RELATED DEVICES AND PROCESSES 审中-公开
标题翻译：燃料电池互连结构及相关设备和工艺
公开(公告)号：US20090317705A1
公开(公告)日：2009-12-24
申请号：US12143188
申请日：2008-06-20
申请人： Matthew Joseph Alinger , Frederic Joseph Klug , James Anthony Ruud , Stephane Renou , Reza Sarrafi-Nour
发明人： Matthew Joseph Alinger , Frederic Joseph Klug , James Anthony Ruud , Stephane Renou , Reza Sarrafi-Nour
IPC分类号： H01M2/20 , H01M2/00 , H01M4/50 , H01M4/52 , H01M4/38 , H01M8/10
CPC分类号： H01M8/021 , H01M8/0228 , H01M2008/1293
摘要： A method for the formation of a diffusion barrier layer on a surface of at least one fuel cell interconnect structure is described. The interconnect structure is usually formed from ferritic stainless steel, and includes chromium. The method includes the step of coating an austenite phase-stabilizer on the interconnect surface, and then heating the coated surface. The heat treatment transforms the microstructure of the surface region of the interconnect, from a substantially ferritic body-centered cubic (BCC) phase to a substantially austenitic face-centered cubic (FCC) phase. The diffusion rate of chromium through the FCC phase is relatively low. Thus, the formation of a thick layer of chromium oxide can be minimized, leading to better fuel cell performance. Related fuel cells and fuel cell stacks are also disclosed.
摘要翻译：描述了在至少一个燃料电池互连结构的表面上形成扩散阻挡层的方法。互连结构通常由铁素体不锈钢形成，并且包括铬。该方法包括在互连表面上涂覆奥氏体相稳定剂，然后加热涂覆表面的步骤。热处理将互连表面区域的微观结构从基本上是铁素体体心立方（BCC）相变换为基本上奥氏体的面心立方（FCC）相。铬通过FCC相的扩散速率相对较低。因此，可以最小化形成厚的氧化铬层，从而导致更好的燃料电池性能。还公开了相关的燃料电池和燃料电池堆。

10. 发明申请

US20080131750A1 CERAMIC ELECTROLYTE STRUCTURE AND METHOD OF FORMING; AND RELATED ARTICLES 审中-公开
标题翻译：陶瓷电解质结构及其形成方法和相关文章
公开(公告)号：US20080131750A1
公开(公告)日：2008-06-05
申请号：US11565236
申请日：2006-11-30
申请人： Todd-Michael Striker , James Anthony Ruud , Stephane Renou
发明人： Todd-Michael Striker , James Anthony Ruud , Stephane Renou
IPC分类号： B05D5/12 , H01M8/10
CPC分类号： H01M8/1246 , Y02E60/525 , Y02P70/56
摘要： A ceramic electrolyte is provided. The ceramic electrolyte has a microstructure, which comprises at least a first region comprising a plurality of microcracks having a first average microcrack length and a first average microcrack width, and a second region comprising a second average microcrack length and a second average microcrack width. The microstructure satisfies the criteria of (a) the first average microcrack length being different from the second average microcrack length; or (b) the first average microcrack width being different from the second average microcrack width. A solid oxide fuel cell comprising a ceramic electrolyte having such a microstructure is provided. A method of making a ceramic electrolyte is also described. The method includes the steps of: providing a ceramic electrolyte comprising a plurality of nano-dimensional microcracks; and closing a number of the nano-dimensional microcracks preferentially from one surface of the ceramic electrolyte, such that the ceramic electrolyte has at least one hermetic region and one compliant region.
摘要翻译：提供陶瓷电解质。所述陶瓷电解质具有至少包括具有第一平均微裂纹长度和第一平均微裂纹宽度的多个微裂纹的第一区域和包含第二平均微裂纹长度和第二平均微裂纹宽度的第二区域的微结构。微结构满足（a）第一平均微裂纹长度不同于第二平均微裂纹长度的标准; 或（b）第一平均微裂纹宽度不同于第二平均微裂纹宽度。提供一种包含具有这种微结构的陶瓷电解质的固体氧化物燃料电池。还描述了制备陶瓷电解质的方法。该方法包括以下步骤：提供包含多个纳米尺寸微裂纹的陶瓷电解质; 并且优选地从陶瓷电解质的一个表面封闭多个纳米尺寸微裂纹，使得陶瓷电解质具有至少一个密封区域和一个柔顺区域。

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