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1. 发明授权

US5858944A Polycarboxylates for automatic dishwashing detergents 失效
标题翻译：用于自动洗碗洗涤剂的多羧酸盐
公开(公告)号：US5858944A
公开(公告)日：1999-01-12
申请号：US729885
申请日：1996-10-11
申请人： Andrea Claudette Keenan , Thomas Cleveland Kirk , Thomas Francis McCallum, III , Jan Edward Shulman , Richard James Tallent , Barry Weinstein
发明人： Andrea Claudette Keenan , Thomas Cleveland Kirk , Thomas Francis McCallum, III , Jan Edward Shulman , Richard James Tallent , Barry Weinstein
IPC分类号： C08F220/04 , C08F222/00 , C08F222/02 , C11D3/37 , C11D3/10
CPC分类号： C11D3/3757
摘要： Polycarboxylate additives suitable for use in automatic dishwasher detergent compositions are prepared by polymerizing three or more monomers including monoethylenically unsaturated C.sub.3 to C.sub.6 monocarboxylic acids such as acrylic acid, monoethylenically unsaturated C.sub.4 to C.sub.6 dicarboxylic acids such as maleic acid, and monoethylenically unsaturated esters of acrylic or methacrylic acid. Automatic dishwasher detergents prepared from these additives produce low filming and spotting on washed glassware.
摘要翻译：适用于自动洗碗机洗涤剂组合物的多羧酸盐添加剂通过聚合三种或更多种单体来制备，所述单体包括单烯属不饱和C3至C6单羧酸，例如丙烯酸，单烯属不饱和C 4 -C 6二羧酸如马来酸，和丙烯酸单烯属不饱和酯或甲基丙烯酸。由这些添加剂制备的自动洗碗机洗涤剂在洗涤的玻璃器皿上产生低成膜和斑点。

2. 发明授权

US5854197A Cleaning compositions containing lime-soap dispersant and method of preparation 失效
标题翻译：含有钙皂分散剂的清洁剂及其制备方法
公开(公告)号：US5854197A
公开(公告)日：1998-12-29
申请号：US720497
申请日：1996-09-30
申请人： Yves Duccini , Andrea Claudette Keenan , Jan Edward Shulman
发明人： Yves Duccini , Andrea Claudette Keenan , Jan Edward Shulman
IPC分类号： C11D3/18 , C11D3/37 , C11D10/04 , C11D11/00 , C11D3/12
CPC分类号： C11D11/0094 , C11D10/04 , C11D3/18 , C11D3/3765
摘要： Cleaning compositions containing a lime-soap dispersant and a method of preparing liquid cleaning compositions containing lime-soap dispersants are disclosed. More specifically, cleaning compositions containing lime-soap dispersant polymers derived from maleic acid, maleic anhydride, or salts thereof, copolymerized with a hydrophobic monomer containing from 4 to 20 carbon atoms are disclosed. Cleaning compositions containing a lime-soap dispersant based on maleic acid/diisobutylene polymers are particulary effective in producing stable liquid cleaning compositions with good lime-soap dispersancy properties.
摘要翻译：公开了含有钙皂分散剂的清洁组合物和制备含有钙皂分散剂的液体清洗组合物的方法。更具体地，公开了含有与含有4至20个碳原子的疏水单体共聚的由马来酸，马来酸酐或其盐衍生的钙皂分散剂聚合物的清洗组合物。含有基于马来酸/二异丁烯聚合物的钙皂分散剂的清洗组合物在生产具有良好的钙皂分散性能的稳定的液体清洗组合物中特别有效。

3. 发明授权

US06451756B2 Method of promoting soil release from fabrics 有权
标题翻译：促进织物去污的方法
公开(公告)号：US06451756B2
公开(公告)日：2002-09-17
申请号：US09878445
申请日：2001-06-11
申请人： Jan Edward Shulman , Thomas Cleveland Kirk , Graham Swift , Curtis Schwartz , Marianne Patricia Creamer , Beth Ann Falcone
发明人： Jan Edward Shulman , Thomas Cleveland Kirk , Graham Swift , Curtis Schwartz , Marianne Patricia Creamer , Beth Ann Falcone
IPC分类号： C11D337
CPC分类号： C11D3/3757 , C11D3/0015
摘要： Hydrophobically modified polycarboxylate polymers of Formula 1: are useful for promoting soil release from fabrics, particularly cotton and cotton-containing fabrics, by contacting the fabrics with compositions comprising said polymers.
摘要翻译：式1的疏水改性的聚羧酸酯聚合物可用于通过使织物与包含所述聚合物的组合物接触来促进织物，特别是棉和含棉织物的污垢释放。

4. 发明授权

US08680033B2 Scale-reducing additive for automatic dishwashing systems 有权
标题翻译：自动洗碗系统的减垢添加剂
公开(公告)号：US08680033B2
公开(公告)日：2014-03-25
申请号：US12720330
申请日：2010-03-09
申请人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
发明人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
IPC分类号： C11D3/08 , C11D3/10 , C11D3/37 , C11D7/12 , C11D7/14 , C11D17/00 , C11D17/06 , C11D3/395
CPC分类号： C11D3/08 , C11D3/10 , C11D3/3757 , C11D3/3953 , C11D7/12 , C11D7/14 , C11D17/0091 , C11D17/06
摘要： A phosphorus-free automatic dishwashing detergent composition containing a polymer of acrylic acid, maleic acid and methacrylic acid; a carbonate; and a silicate. The composition contains carbonate and silicate in a weight ratio from 4:1 to 1:3, respectively; from 10 to 90 wt % total carbonate and silicate.
摘要翻译：含有丙烯酸，马来酸和甲基丙烯酸的聚合物的无磷自动餐具洗涤剂组合物; 碳酸盐和硅酸盐。该组合物分别含有重量比为4:1至1:3的碳酸盐和硅酸盐; 总碳酸盐和硅酸盐为10至90重量％。

5. 发明申请

US20110224118A1 Scale-reducing additive for automatic dishwashing systems 有权
标题翻译：自动洗碗系统的减垢添加剂
公开(公告)号：US20110224118A1
公开(公告)日：2011-09-15
申请号：US12932834
申请日：2011-03-08
申请人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
发明人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
IPC分类号： C11D3/60
CPC分类号： C11D3/33 , C11D3/3757
摘要： An automatic dishwashing detergent composition having at least two components. The first component is a polymer containing polymerized residues of at least one C3-C6 carboxylic acid monomer and a hydroxy end group. The second component is a biodegradable builder selected from among nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, glycine-N,N-diacetic acid, methylglycine-N,N-diacetic acid, 2-hydroxyethyliminodiacetic acid, glutamic acid-N,N-diacetic acid, 3-hydroxy-2,2′-iminodisuccinate, S,S-ethylenediaminedisuccinate aspartic acid-diacetic acid, N,N′-ethylenediamine disuccinic acid, iminodisuccinic acid, aspartic acid, aspartic acid-N,N-diacetate, beta-alaninediacetic acid, polyaspartic acid, salts thereof and combinations thereof.
摘要翻译：一种具有至少两种组分的自动餐具洗涤剂组合物。第一组分是含有至少一个C 3 -C 6羧酸单体和羟基端基的聚合残基的聚合物。第二组分是选自次氮基三乙酸，乙二胺四乙酸，二亚乙基三胺五乙酸，甘氨酸-N，N-二乙酸，甲基甘氨酸-N，N-二乙酸，2-羟乙基亚氨基二乙酸，谷氨酸-N，N-二乙酸酸，3-羟基-2,2'-亚氨基二琥珀酸盐，S，S-乙二胺二丁二酸天冬氨酸 - 二乙酸，N，N'-乙二胺二琥珀酸，亚氨基二琥珀酸，天冬氨酸，天冬氨酸-N，N-二乙酸酯，丙氨酸二乙酸，聚天冬氨酸，其盐及其组合。

6. 发明申请

US20120015861A1 POLYMERS FOR LAUNDRY DETERGENTS 有权
标题翻译：聚合物洗涤剂洗涤剂
公开(公告)号：US20120015861A1
公开(公告)日：2012-01-19
申请号：US13178592
申请日：2011-07-08
申请人： Joseph Manna , Roy Roberts , Jan Edward Shulman
发明人： Joseph Manna , Roy Roberts , Jan Edward Shulman
IPC分类号： C11D3/60
CPC分类号： C11D3/3765 , C11D3/0036
摘要： A detergent composition having at least two components. The first component is from 8 to 50 wt % surfactants. The second component is from 0.05 to 4 wt % of a polymer which has polymerized residues of 40 to 80 wt % C1-C4 alkyl acrylates, 20 to 52 wt % C3-C6 carboxylic acid monomers, and 0 to 10 wt % of monomers having an alkyl group having at least ten carbon atoms.
摘要翻译：一种具有至少两种组分的洗涤剂组合物。第一组分是8至50重量％的表面活性剂。第二组分是0.05至4重量％的聚合物，该聚合物具有40至80重量％的丙烯酸C 1 -C 4烷基酯，20至52重量％的C 3 -C 6羧酸单体和0至10重量％的具有具有至少10个碳原子的烷基。

7. 发明申请

US20100234266A1 SCALE-REDUCING ADDITIVE FOR AUTOMATIC DISHWASHING SYSTEMS 有权
标题翻译：自动洗碗系统的缩减添加剂
公开(公告)号：US20100234266A1
公开(公告)日：2010-09-16
申请号：US12720330
申请日：2010-03-09
申请人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
发明人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
IPC分类号： C11D3/37
CPC分类号： C11D3/08 , C11D3/10 , C11D3/3757 , C11D3/3953 , C11D7/12 , C11D7/14 , C11D17/0091 , C11D17/06
摘要： A phosphorus-free automatic dishwashing detergent composition containing a polymer of acrylic acid, maleic acid and methacrylic acid; a carbonate; and a silicate. The composition contains carbonate and silicate in a weight ratio from 4:1 to 1:3, respectively; from 10 to 90 wt % total carbonate and silicate.
摘要翻译：含有丙烯酸，马来酸和甲基丙烯酸的聚合物的无磷自动餐具洗涤剂组合物; 碳酸盐和硅酸盐。该组合物分别含有重量比为4:1至1:3的碳酸盐和硅酸盐; 总碳酸盐和硅酸盐为10至90重量％。

8. 发明授权

US08722606B2 Scale-reducing additive for automatic dishwashing systems 有权
标题翻译：自动洗碗系统的减垢添加剂
公开(公告)号：US08722606B2
公开(公告)日：2014-05-13
申请号：US12932834
申请日：2011-03-08
申请人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
发明人： Marianne Patricia Creamer , Joseph Manna , Jan Edward Shulman
IPC分类号： C11D3/60
CPC分类号： C11D3/33 , C11D3/3757
摘要： An automatic dishwashing detergent composition having at least two components. The first component is a polymer containing polymerized residues of at least one C3-C6 carboxylic acid monomer and a hydroxy end group. The second component is a biodegradable builder selected from among nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, glycine-N,N-diacetic acid, methylglycine-N,N-diacetic acid, 2-hydroxyethyliminodiacetic acid, glutamic acid-N,N-diacetic acid, 3-hydroxy-2,2′-iminodisuccinate, S,S-ethylenediaminedisuccinate aspartic acid-diacetic acid, N,N′-ethylenediamine disuccinic acid, iminodisuccinic acid, aspartic acid, aspartic acid-N,N-diacetate, beta-alaninediacetic acid, polyaspartic acid, salts thereof and combinations thereof.
摘要翻译：一种具有至少两种组分的自动餐具洗涤剂组合物。第一组分是含有至少一个C 3 -C 6羧酸单体和羟基端基的聚合残基的聚合物。第二组分是选自次氮基三乙酸，乙二胺四乙酸，二亚乙基三胺五乙酸，甘氨酸-N，N-二乙酸，甲基甘氨酸-N，N-二乙酸，2-羟乙基亚氨基二乙酸，谷氨酸-N，N-二乙酸酸，3-羟基-2,2'-亚氨基二琥珀酸盐，S，S-乙二胺二丁二酸天冬氨酸 - 二乙酸，N，N'-乙二胺二琥珀酸，亚氨基二琥珀酸，天冬氨酸，天冬氨酸-N，N-二乙酸酯，丙氨酸二乙酸，聚天冬氨酸，其盐及其组合。

9. 发明申请

US20110224119A1 Scale-reducing additive for automatic dishwashing systems 有权
标题翻译：自动洗碗系统的减垢添加剂
公开(公告)号：US20110224119A1
公开(公告)日：2011-09-15
申请号：US12932860
申请日：2011-03-08
申请人： Joseph Manna , Jan Edward Shulman
发明人： Joseph Manna , Jan Edward Shulman
IPC分类号： C11D3/60
CPC分类号： C11D3/3776 , C08F2/38 , C08F8/16 , C08F2810/40 , C11D3/33 , C11D3/3757 , C11D11/0023 , C08F20/06 , C08F22/02
摘要： An automatic dishwashing detergent composition having at least two components. The first component is a polymer containing polymerized residues of at least one C3-C6 carboxylic acid monomer and a lactone end group. The second component is a biodegradable builder selected from among nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, glycine-N,N-diacetic acid, methylglycine-N,N-diacetic acid, 2-hydroxyethyliminodiacetic acid, glutamic acid-N,N-diacetic acid, 3-hydroxy-2,2′-iminodisuccinate, S,S-ethylenediaminedisuccinate aspartic acid-diacetic acid, N,N′-ethylenediamine disuccinic acid, iminodisuccinic acid, aspartic acid, aspartic acid-N,N-diacetate, beta-alaninediacetic acid, polyaspartic acid, salts thereof and combinations thereof.
摘要翻译：一种具有至少两种组分的自动餐具洗涤剂组合物。第一组分是含有至少一个C 3 -C 6羧酸单体和内酯端基的聚合残基的聚合物。第二组分是选自次氮基三乙酸，乙二胺四乙酸，二亚乙基三胺五乙酸，甘氨酸-N，N-二乙酸，甲基甘氨酸-N，N-二乙酸，2-羟乙基亚氨基二乙酸，谷氨酸-N，N-二乙酸酸，3-羟基-2,2'-亚氨基二琥珀酸盐，S，S-乙二胺二丁二酸天冬氨酸 - 二乙酸，N，N'-乙二胺二琥珀酸，亚氨基二琥珀酸，天冬氨酸，天冬氨酸-N，N-二乙酸酯，丙氨酸二乙酸，聚天冬氨酸，其盐及其组合。

10. 发明申请

US20090305934A1 Polymers and their use for inhibition of scale build-up in automatic dishwashing applications 审中-公开
标题翻译：聚合物及其在自动洗碗应用中抑制结垢的用途
公开(公告)号：US20090305934A1
公开(公告)日：2009-12-10
申请号：US12387909
申请日：2009-05-08
申请人： Marianne P. Creamer , Joseph Manna , Jan Edward Shulman
发明人： Marianne P. Creamer , Joseph Manna , Jan Edward Shulman
IPC分类号： C11D3/37 , C02F5/08
CPC分类号： C11D3/378
摘要： The present invention provides a method of controlling scale in aqueous dishwashing systems which involves adding at least one high molecular weight terpolymer made from one or more monoethylenically unsaturated C3 to C6 monocarboxylic acids, one or more monomers having a sulfonic acid group, and one or more monoethylenically unsaturated monomers polymerizable with (I) and (II). In another embodiment, a high molecular weight copolymer made from one or more monoethylenically unsaturated C3 to C6 monocarboxylic acids and one or more monomers having a sulfonic acid group is added to the aqueous dishwashing system. Additionally, the present invention provides a machine dishwashing formulation comprising: a builder, which comprises not more than 2% by weight of one or more phosphate groups, based on the total weight of the dishwashing formulation; and the aforesaid terpolymer or copolymer.
摘要翻译：本发明提供了一种控制水性餐具洗涤系统中的垢的方法，其包括加入至少一种由一种或多种单烯属不饱和C3至C6一元羧酸，一种或多种具有磺酸基的单体和一种或多种单烯属不饱和三元共聚物制成的高分子量三元共聚物（I）和（II）可聚合的单烯属不饱和单体。在另一个实施方案中，将由一种或多种单烯键式不饱和C3至C6一元羧酸和一种或多种具有磺酸基团的单体制成的高分子量共聚物加入到含水洗碗碟清洗系统中。另外，本发明提供了一种机器洗碟剂制剂，其包括：助洗剂，其包含不超过2重量％的一种或多种磷酸酯基，基于餐具洗涤剂的总重量; 和上述三元共聚物或共聚物。

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