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1. 发明申请

US20100135353A1 TTI INDICATOR WITH BALANCED PHOTOCHEMICAL PROCESSES 失效
标题翻译：具有平衡光化学过程的TTI指示剂
公开(公告)号：US20100135353A1
公开(公告)日：2010-06-03
申请号：US12520613
申请日：2007-12-17
申请人： Andre Fuchs , Anne Veronica Carrigan
发明人： Andre Fuchs , Anne Veronica Carrigan
IPC分类号： G01K3/00 , G01N31/22
CPC分类号： C09K9/02 , C08K5/3417 , G01D7/005 , Y10T428/24901 , Y10T428/2495 , Y10T428/31507 , Y10T428/31551 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31801 , Y10T428/31855
摘要： The invention relates to a time temperature indicator comprising a) at least one photo-chromic colorant introduced into and/or atop a matrix substrate and charged by exposure to UV light; b) at least a transparent colorless or a transparent colored light absorbing protecting layer adhered to the underlying layer a) which contains the photo-chromic colorant; characterized in that the light absorbing protecting layer comprises 1-50 wt % of an UV light absorber or an UV light absorber mixture and 0.1-10 wt % of an optical brightener wherein the weight ratio of the UV light absorber and optical brightener is 0.1-10.
摘要翻译：本发明涉及一种时间温度指示器，其包括：a）至少一种引入到基质基质中和/或顶部的光铬着色剂并通过暴露于紫外光而被充电; b）至少一个透明的无色或透明着色的光吸收保护层，粘附到包含光致色着色剂的下层a）; 其特征在于，所述光吸收保护层包含1-50重量％的UV光吸收剂或UV光吸收剂混合物和0.1-10重量％的荧光增白剂，其中所述UV光吸收剂和荧光增白剂的重量比为0.1- 10。

2. 发明申请

US20050004249A1 Novel disfunctional photoinitiators 有权
标题翻译：新型失活光引发剂
公开(公告)号：US20050004249A1
公开(公告)日：2005-01-06
申请号：US10494593
申请日：2002-10-31
申请人： Andre Fuchs , Rinaldo Husler , Christian Schregenberger , Martin Kunz
发明人： Andre Fuchs , Rinaldo Husler , Christian Schregenberger , Martin Kunz
IPC分类号： C07B61/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/66 , C07C45/81 , C07C49/83 , C08F2/50 , C09D7/12 , C09D11/00 , C09D201/00 , G03F7/031 , C08F2/46 , C07C45/00 , C07C49/213 , C07C49/225 , C07C49/563 , C07C49/76 , C08J3/28
CPC分类号： G03F7/031 , B33Y70/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/81 , C07C49/83 , C08F2/50 , C07C49/784 , C07C49/813
摘要： The invention relates to α-hydroxy ketones of formula I or IIa; or mixtures of compounds of formula I and II; or mixtures of compounds of formulae Ia and IIa
摘要翻译：本发明涉及式I或IIa的α-羟基酮; 或式I和II化合物的混合物; 或式Ia和IIa化合物的混合物

3. 发明申请

US20070060667A1 Process for preparing pigment concentrates for use in radiation-curable coatings 审中-公开
标题翻译：用于制备用于可辐射固化涂料的颜料浓缩物的方法
公开(公告)号：US20070060667A1
公开(公告)日：2007-03-15
申请号：US10557227
申请日：2004-05-24
申请人： Tunja Jung , Thomas Healy , Andre Fuchs , Thomas Bolle
发明人： Tunja Jung , Thomas Healy , Andre Fuchs , Thomas Bolle
IPC分类号： C08K5/00 , C09D11/00
CPC分类号： C09D11/101 , B41M7/0045 , B41M7/0081 , C08F290/061 , C09B67/006
摘要： A process for preparing pigment concentrates is provided which comprises dispersing a dry pigment in a radiation polymerizable (curable) ethylenically-unsaturated compound. The concentrates to which optionally photoinitiators are added can be used for preparing radiation, preferably ultraviolet radiation, curable printing inks, paints or other coating compositions which in turn are applied in printing processes or in the painting or coating of substrates. The performance enhancement of the cured pigmented inks/paints/coatings include e.g. good tinctorial strength and gloss, as well as surface hardness, good adhesion to substrate and chemical and corrosion resistance.
摘要翻译：提供了一种制备颜料浓缩物的方法，其包括将干颜料分散在可辐射聚合的（可固化的）烯属不饱和化合物中。添加任选的光引发剂的浓缩物可以用于制备辐射，优选紫外线辐射，可固化的印刷油墨，油漆或其它涂料组合物，这些涂料组合物又被应用于印刷方法或涂料或涂料中。固化的着色油墨/油漆/涂料的性能提高包括例如。良好的着色强度和光泽度，以及表面硬度，对基材的良好粘合性以及耐化学腐蚀性。

4. 发明申请

US20060160915A1 Photocurable compositions 审中-公开
标题翻译：可光固化组合物
公开(公告)号：US20060160915A1
公开(公告)日：2006-07-20
申请号：US10544509
申请日：2004-02-09
申请人： Andre Fuchs , Rinaldo Husler , Thomas Bolle
发明人： Andre Fuchs , Rinaldo Husler , Thomas Bolle
IPC分类号： C08F2/50
CPC分类号： C08F2/50 , C08K5/07 , G03F7/031
摘要： Benzophenone derivatives of formula I R1, R2 and R3 are each independently of the others hydrogen or C1-C4alkyl, cyclopentyl or cyclohexyl; R4, R5 and R6 are each independently of the others hydrogen, C1-C4alkyl, cyclopentyl or cyclohexyl; R7 and R8 are each independently of the other hydrogen, C1-C4alkyl, cyclopentyl or cyclohexyl; with the provisos that (i) at least one radical R1, R2, R3, R4, R5, R6, R7, R8 is other than hydrogen; (ii) when all radicals R4, R5 , R6, R7 and R8 are hydrogen and only one radical R1, R2, R3 is C1-C4alkyl, that radical must be in the meta-position of the phenyl ring; and (iii) when all radicals R1, R2, R3, R7 and R8 are hydrogen and two of the radicals R4, R5 and R6 are hydrogen and the remaining radical R4, R5 or R6 is C1-C4alkyl, that alkyl radical is not bonded in the para-position on the phenyl ring; are found to be especially suitable in photocurable compositions in respect of solubility, reactivity and a low level of yellowing.
摘要翻译：式IR 1 R 2，R 2和R 3的二苯甲酮衍生物各自独立地为氢或C 1〜 -C 4烷基，环戊基或环己基; R 4，R 5和R 6各自独立地为氢，C 1 -C 3 烷基，环戊基或环己基; R 7和R 8分别独立地为氢，C 1 -C 4烷基，环戊基或环己基条件是（i）至少一个基团R 1，R 2，R 3，R 4， R 5，R 6，R 7，R 8不同于氢; R 5，R 7，R 7，（ii）当所有基团R 4，R 5，R 6，R 7和R 7， 8是氢，只有一个基团R 1，R 2，R 3是C 1 H 2， -C 4 - 烷基，该基团必须在苯环的间位; 和（iii）当所有基团R 1，R 2，R 3，R 7和R SUB > 8 是氢，基团R 4，R 5和R 6中的两个是氢，剩余的基团R' R 4，R 5或R 6是C 1 -C 4烷基，该C 1 -C 4烷基，烷基在苯环的对位不结合; 在溶解性，反应性和黄化程度方面都被认为特别适用于光固化组合物。

5. 发明申请

US20050239971A1 New difunctional photoinitators 有权
标题翻译：新型双功能光电二极管
公开(公告)号：US20050239971A1
公开(公告)日：2005-10-27
申请号：US10521650
申请日：2003-07-10
申请人： Rinaldo Husler , Andre Fuchs
发明人： Rinaldo Husler , Andre Fuchs
IPC分类号： B05D3/02 , B05D3/06 , B05D5/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/68 , C07C49/83 , C07C49/84 , C08F2/46 , C08F2/50 , C08F20/34 , C09D4/00 , C09D4/02 , C09D5/00 , C09D5/03 , C09D7/12 , C09D11/02 , G03F7/031 , C08F265/00
CPC分类号： G03F7/031 , B33Y70/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/68 , C07C49/83 , C07C49/84 , C08F2/50 , Y10S522/909 , C07C49/784 , C07C49/813
摘要： The invention relates to novel photoinitiators of formula (I) wherein A is —O—, —CH2−, CH(CH3)— or —C(CH3)2−, and R is methyl or trimethylsilyl, and R may in addition be hydrogen when A is simultaneously the group —C(CH3)2−. The invention relates also to compositions comprising (A) at least one ethylenically unsaturated compound, (B) a photoinitiator of formula (I), (C) optionally further binders or additives, (D) optionally further photoinitiators or co-initiators. Compositions comprising (A) an ethylenically unsaturated compound that contains at least one aminoacrylate, (B) a photoinitiator of formula (II) or (III), (C) optionally further binders or additives, (D) optionally further photoinitiators or co-initiators.
摘要翻译：本发明涉及式（I）的新型光引发剂，其中A是-O-，-CH 2 - ，CH（CH 3） - 或-C（CH _{3）2 - ，且R是甲基或三甲基甲硅烷基，当A同时为基团-C（CH 3）3）时，R另外可以是氢。 2 - 。本发明还涉及包含（A）至少一种烯键式不饱和化合物，（B）式（I）的光引发剂，（C）任选的其它粘合剂或添加剂的组合物，（D）任选的其它光引发剂或共引发剂。包含（A）含有至少一个氨基丙烯酸酯的烯属不饱和化合物，（B）式（II）或（III）的光引发剂，（C）任选的其它粘合剂或添加剂的组合物，（D）任选的其它光引发剂或共引发剂。}

6. 发明申请

US20070240609A1 Photoinitiators 有权
公开(公告)号：US20070240609A1
公开(公告)日：2007-10-18
申请号：US11578595
申请日：2005-04-11
申请人： Rinaldo Husler , Thomas Horni , Andre Fuchs , Tunja Jung , Reinhard Sommerlade
发明人： Rinaldo Husler , Thomas Horni , Andre Fuchs , Tunja Jung , Reinhard Sommerlade
IPC分类号： D21H17/07 , C08F2/48 , C08J3/28
CPC分类号： C07C45/46 , B33Y70/00 , C07C45/58 , C07C45/63 , C07C45/64 , C07C45/71 , C07C45/74 , C07C49/792 , C07C49/82 , C07C49/83 , C07C49/84 , C07C69/96 , C07C271/12 , C07C317/24 , C07D295/108 , C07D295/112 , C07D493/08 , C08F2/50 , C07C49/76 , C07C49/80 , C07C49/813
摘要： The invention relates to novel photoinitators of formulae (V), (II), (III), (IV), (V) and (VI) wherein R1 and R2 are each independently of the other C1-C8alkyl; C1-C4alkyl substituted by OH, C1-C4alkoxy, —COO(C1-C8alkyl), (C1-C4alkyl)-COO—, —CN, benzyl, phenyl or by —N(R15)(R16); C3-C6alkerlyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; or R1 and R2 together are unbranched or branched C2-C9alkylene or C3-C6-oxa- or -azaalkylene; R3, R4, R5 and R6 are each independently of the others hydrogen, C1-C8alkyl, C3-C6alkenyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; R3 and R4 together and/or R5 and R6 together are unbranched or branched C2-C9alkylene; A is Cl, Br, —O—R9, —N(R11)(R12) or —S—R18, A′ is —O—, —NH— or —NR11—; A″ is Cl, Br, —O—R9, —N(R11)(R12) or —S—R18 or hydrogen, X is —O—R10 or —N(R13)(R14), n is an integer from 1 to 10, preferably an integer from 1 to 4, especially 1, 2 or 3; R7 is a linker; R8 is a bivalent C2-C3alkylele radical.

7. 发明申请

US20060209098A1 Radiation curable ink-jet ink containing an alpha hydroxy ketone as photoinitiator 审中-公开
标题翻译：含有α羟基酮作为光引发剂的可辐射固化喷墨油墨
公开(公告)号：US20060209098A1
公开(公告)日：2006-09-21
申请号：US10553068
申请日：2004-04-06
申请人： Andre Fuchs , Sebastien Villeneuve , Michelle Richert
发明人： Andre Fuchs , Sebastien Villeneuve , Michelle Richert
IPC分类号： B41J2/01
CPC分类号： C09D11/101
摘要： A process for preparing an inkjet printed matter, which comprises the steps of applying an ultraviolet curable inkjet ink composition comprising a photopolymerizable monomer, oligomer or prepolymer; a colorant and a compound of the formula (I) or (II) or (Ia) or (IIa) or mixtures thereof, and optionally a reactive diluent to a recording medium and curing the ink composition on the recording medium by irradiating with ultraviolet ray.
摘要翻译：一种制备喷墨印刷品的方法，其包括以下步骤：施加包含可光聚合单体，低聚物或预聚物的紫外线固化型喷墨油墨组合物; 着色剂和式（I）或（II）或（Ia）或（IIa）或其混合物的化合物，以及任选的反应性稀释剂加入到记录介质中，并通过照射紫外线固化记录介质上的油墨组合物。

8. 发明申请

US20060100298A1 Storage stability of photoinitiators 有权
标题翻译：光引发剂的储存稳定性
公开(公告)号：US20060100298A1
公开(公告)日：2006-05-11
申请号：US10531482
申请日：2003-10-17
申请人： Thomas Ulrich , Thomas Bolle , Kurt Dietliker , Jean-Pierre Wolf , Andre Fuchs
发明人： Thomas Ulrich , Thomas Bolle , Kurt Dietliker , Jean-Pierre Wolf , Andre Fuchs
IPC分类号： C08F2/50
CPC分类号： C07D295/096 , B33Y70/00 , C07D295/112 , C08F2/50 , C09D11/101 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/031
摘要： Compounds of formula (I), wherein R1 is hydrogen or alkyl; R2 is C1-C4alkoxy or a morpholino radical; and R3 is hydrogen or C1-C4alkoxy, are suitable for improving the solubility of specific photoinitiators in formulations and accordingly enhance the storage stability of formulations comprising a photoinitiator and compounds of formula (I).
摘要翻译：式（I）化合物，其中R 1是氢或烷基; R 2是C 1 -C 4烷氧基或吗啉代基; R 3和R 3是氢或C 1 -C 4烷氧基，适用于提高特定光引发剂在制剂中的溶解度并因此增强储存包含光引发剂和式（I）化合物的制剂的稳定性。

9. 发明申请

US20070225397A1 In-Can Stabilizers 审中-公开
标题翻译：罐内稳定剂
公开(公告)号：US20070225397A1
公开(公告)日：2007-09-27
申请号：US11661351
申请日：2005-08-24
申请人： Peter Nasvadba , Andre Fuchs , Stephan Ilg , Edith Pighetti
发明人： Peter Nasvadba , Andre Fuchs , Stephan Ilg , Edith Pighetti
IPC分类号： C08K5/1535
CPC分类号： C08K5/3435
摘要： The invention relates to the use of highly sterically hindered nitroxyl radicals as in-can stabilizers for UV-curable resins. The present invention further relates to the use of quinone methides as in-can stabilizers for UV-curable resins.
摘要翻译：本发明涉及高空间位阻硝酰自由基作为UV固化树脂的罐内稳定剂。本发明还涉及使用醌甲基化物作为UV可固化树脂的罐内稳定剂。

10. 发明申请

US20060270748A1 Novel trifunctional photoinitiators 有权
公开(公告)号：US20060270748A1
公开(公告)日：2006-11-30
申请号：US10552952
申请日：2004-05-04
申请人： Reinhard Sommerlade , Rinaldo Husler , Stephen Ilg , Andre Fuchs , Souad Boulmaaz , Jean-Luc Birbaum
发明人： Reinhard Sommerlade , Rinaldo Husler , Stephen Ilg , Andre Fuchs , Souad Boulmaaz , Jean-Luc Birbaum
IPC分类号： C08F2/50
CPC分类号： G03F7/0295 , B33Y70/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/71 , C07C49/784 , C07C49/813 , C07C49/83 , C07C49/84 , C07C225/22 , C07C271/20 , C07C2601/14 , C08F2/50 , G03F7/029 , G03F7/031
摘要： The Invention relates to novel ketones of formulae (I) and (II) wherein R1, R2, R3 and R4 are, for example, C1-C8alkyl, R5 is, for example, hydrogen, A is CI, Br, -0-R7, —NR8R9 or —S—R16, A′ is —O—, —NH— or —NR8—, X and Y are each independently of the other —O—R10 or —N(R11)(R12), n is an integer from 1 to 10, R6 is, for example, an n-valent radical of linear or branched C2-C20alkyl the carbon chain of which may be interrupted by cyclohexanediyl, phenylene, —CH(OH)—, —C(C2H5)(CH2—CH2—OH)—, —C(CH3)(CH2—CH2—OH)—, —C(CH2—CH2—OH)2—, —N(CH3)—, —N(C2H5)—, —N(CH2—CH2—OH)—, —CO—O—, —O—CO—, —P(CH2—CH2—OH)—, —P(O)(CH2—CH2—OH)—, -0-P(O—CH2—CH2—OH)—O—, -0-P(O)(0-CH2—CH2—OH)—O—, —O-cyclohexanediyl-C(CH3)2-Cyclohexanediyl-O—, —O-phenylene-C(CH3)2-phenylene-O—, —O-phenylene-CH2-phenylene-O—, —Si(CH3)2—, -0-Si(CH3)2—O—, —O—Si(CH3)(0-CH3)—O—, —Si(CH3)(R17)—O—Si(CH3)(R18)—, 5-(2-hydroxyethyl)-[1,3,5]triazinane-2,4,6-trione-1,3-diyl and/or by from one to nine oxygen atoms.

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