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1. 发明授权

US07300983B2 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：US07300983B2
公开(公告)日：2007-11-27
申请号：US10920485
申请日：2004-08-17
申请人： Alexander W. Degroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund M. Carnahan , David Gillespie , Daniel D. Vanderlende
发明人： Alexander W. Degroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund M. Carnahan , David Gillespie , Daniel D. Vanderlende
IPC分类号： C08L23/08 , C08L23/16
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition that has a backbone chain; and a plurality of long chain branches connected to the backbone is described. The polymer composition also has a value of 2g′LCB-1g′LCB that is less than about 0.22, where 1g′LCB is the long chain branching index for a fraction of the composition having a Mw of 100,000 and 2g′LCB is the long chain branching index for a fraction of the composition having a Mw of 500,000.
摘要翻译：具有主链的聚合物组合物; 并且描述了连接到主干的多个长链分支。该聚合物组合物还具有小于约2％的值的小于等于2的LCB <！ - SIPO - > 0.22，其中，对于具有100,000和50ppm的组合物的一部分的长链支化指数，其中L LCB 是具有50,000的M组成的一部分的长链支化指数。

2. 再颁专利

USRE42276E1 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：USRE42276E1
公开(公告)日：2011-04-05
申请号：US12604905
申请日：2009-10-23
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
IPC分类号： C08L23/00 , C08F4/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要翻译：聚合物组合物包含：（a）高分子量的支化组分; 和（b）低分子量支化组分。一些聚合物组合物的特征在于基本上不存在戊基或甲基支链和满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约12.5，y大于或等于一些聚合物的特征在于满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约3，y大于或等于约4.5，以及分子量分布大于3.还公开了制备聚合物的方法。

3. 再颁专利

USRE43004E1 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：USRE43004E1
公开(公告)日：2011-12-06
申请号：US12604940
申请日：2009-10-23
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
IPC分类号： C08L23/08 , C08L23/10
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition that has a backbone chain; and a plurality of long chain branches connected to the backbone is described. The polymer composition also has a value of 2g′LCB-1g′LCB g′2LCB-g′1LCB that is less than about 0.22, where 1g′LCB g′2LCB is the long chain branching index for a fraction of the composition having a Mw of 100,000 and 2g′LCB g′1LCB is the long chain branching index for a fraction of the composition having a Mw of 500,000.
摘要翻译：具有主链的聚合物组合物; 并且描述了连接到主干的多个长链分支。聚合物组合物还具有小于约0.22的2g'LCB-1g'LCB g'2LCB-g'1LCB的值，其中1g'LCB g'2LCB是组分的一部分的长链支化指数，其具有 Mw为100,000和2g'LCB g'1LCB是Mw为500,000的组合物的一部分的长链支化指数。

4. 发明授权

US07999039B2 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：US07999039B2
公开(公告)日：2011-08-16
申请号：US10918906
申请日：2004-08-16
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
IPC分类号： C08L9/00 , C08L23/00 , C08L47/00 , C08F297/02 , C08F4/06
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A process of making a polymer is described. The process includes contacting one or more olefinic monomers in the presence of at least a high molecular weight (HMW) catalyst and at least a low molecular weight (LMW) catalyst in a polymerization reactor system; and effectuating the polymerization of the one or more olefinic monomers in the polymerization reactor system to obtain an olefin polymer, wherein the LMW catalyst has an RvL, defined as R v L = [ vinyl ] [ vinyl ] + [ vinylidene ] + [ cis ] + [ trans ] wherein [vinyl] is the concentration of vinyl groups in the olefin polymer produced by the low molecular weight catalyst expressed in vinyls/1,000 carbon atoms; [vinylidene], [cis] and [trans] are the concentration of vinylidene, cis and trans groups in the olefin polymer expressed in the number of the respective groups per 1,000 carbon atoms, of greater than 0.12, and wherein the HMW catalyst has a reactivity ratio, r1 of about 5 or less.
摘要翻译：描述制备聚合物的方法。该方法包括在聚合反应器系统中在至少一种高分子量（HMW）催化剂和至少一种低分子量（LMW））催化剂的存在下使一种或多种烯属单体接触; 并且在聚合反应器体系中实现一种或多种烯烃单体的聚合以获得烯烃聚合物，其中LMW催化剂具有RvL，定义为R v L = [乙烯基] [乙烯基] + [亚乙烯基] + [顺式] + [反式]其中[乙烯基]是由以乙烯基/ 1,000个碳原子表示的低分子量催化剂制备的烯烃聚合物中乙烯基的浓度; [亚乙烯基]，[顺式]和[反式]是烯烃聚合物中每1000个碳原子数目表示的亚乙烯基，顺式和反式基团的浓度大于0.12，并且其中HMW催化剂具有反应性比例r1约为5或更小。

5. 发明授权

US06875816B2 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：US06875816B2
公开(公告)日：2005-04-05
申请号：US10100687
申请日：2002-03-15
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
IPC分类号： C08F2/00 , C08F4/02 , C08F4/64 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F290/04 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/02 , C08F4/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要翻译：聚合物组合物包含：（a）高分子量的支化组分; 和（b）低分子量支化组分。一些聚合物组合物的特征在于基本上不存在戊基或甲基支链和满足以下关系的熔体强度（MS）：其中x大于或等于约12.5，y大于或等于约3.一些聚合物其特征在于熔体强度（MS）满足以下关系：其中x大于或等于约3，y大于或等于约4.5，分子量分布大于3.一种制备聚合物的方法也被披露。

6. 发明申请

US20110124818A1 Catalyst Composition Comprising Shuttling Agent for Ethylene Multi-Block Copolymer Formation 有权
公开(公告)号：US20110124818A1
公开(公告)日：2011-05-26
申请号：US12962822
申请日：2010-12-08
申请人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
IPC分类号： C08F210/16 , C08F4/30 , C08F216/04
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

7. 发明授权

US08785551B2 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation 有权
公开(公告)号：US08785551B2
公开(公告)日：2014-07-22
申请号：US12962800
申请日：2010-12-08
申请人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
IPC分类号： C08F255/02 , C08F255/00 , C08F293/00
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

8. 发明授权

US08710143B2 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation 有权
标题翻译：催化剂组合物包含用于乙烯多嵌段共聚物形成的穿梭剂
公开(公告)号：US08710143B2
公开(公告)日：2014-04-29
申请号：US13562600
申请日：2012-07-31
申请人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
IPC分类号： C08L53/00 , C08L23/08
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
摘要翻译：一种用于形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，使用该多嵌段共聚物的聚合方法和所得聚合物，其中组合物包含混合物或反应产物由（A）第一金属络合物烯烃聚合催化剂，（B）能够在等效聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二金属络合物烯烃聚合催化剂，以及（C）链式穿梭剂。

9. 发明授权

US07858706B2 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation 有权
标题翻译：催化剂组合物包含用于乙烯多嵌段共聚物形成的穿梭剂
公开(公告)号：US07858706B2
公开(公告)日：2010-12-28
申请号：US10589377
申请日：2005-03-17
申请人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , Yunwa Wilson Cheung , David D. Devore , David D. Graf , Phillip D. Hustad , Roger L. Kuhlman , Colin Li Pi Shan , Benjamin C. Poon , Gordon R. Roof , James C. Stevens , Pamela J. Stirn , Timothy T. Wenzel
IPC分类号： C08F255/00 , C08F255/02 , C08F293/00
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
摘要翻译：一种用于形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，使用该多嵌段共聚物的聚合方法和所得聚合物，其中组合物包含混合物或反应产物由（A）第一金属络合物烯烃聚合催化剂，（B）能够在等效聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二金属络合物烯烃聚合催化剂，以及（C）链式穿梭剂。

10. 发明授权

US06696379B1 Supported modified alumoxane catalyst activator 失效
标题翻译：负载改性铝氧烷催化剂活化剂
公开(公告)号：US06696379B1
公开(公告)日：2004-02-24
申请号：US09502502
申请日：2000-02-11
申请人： Edmund M. Carnahan , Grant B. Jacobsen , Eugene Y. Chen , James C. Stevens
发明人： Edmund M. Carnahan , Grant B. Jacobsen , Eugene Y. Chen , James C. Stevens
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C07F5/068 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F210/16 , C08F4/65912 , C08F4/642 , C08F4/6428 , C08F2/34 , C08F210/08 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： A supported catalyst composition comprising: A1) a mixture of aluminum containing Lewis acids of the formulas: [(—AlQ1—O—)z(—AlArf—O—)z′] and (Arfz″Al2Q16−z″) where; Q1 independently each occurrence is C1-20 alkyl; Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; z is a number from 1 to 50; z′ is a number from 1 to 50; and z″ is an number from 0 to 6; or A2) a fluorohydrocarbyl-substituted alumoxane compound corresponding to the formula: R1—(AlR3O)m—R2, wherein: R1 and R2 independently each occurrence is a C1-40 aliphatic or aromatic group or a fluorinated derivative thereof or R1 and R2 together form a covalent bond; R3 independently each occurrence is a monovalent, fluorinated organic group containing from 1 to 100 carbon atoms or R1, with the proviso that in at least one occurrence per molecule, R3 is a monovalent, fluorinated organic group containing from 1 to 100 carbon atoms, and m is a number from 1 to 1000; B) a Group 3, 4, or Lanthanide metal complex containing from 1 to 3 &pgr;-bonded anionic or neutral ligand groups; and C) a support.
摘要翻译：一种载体催化剂组合物，其包含：A1）含有下式的含铝路易斯酸的混合物：其中; Q 1各自独立地为C 1-20烷基; Ar f为6至30碳的氟化芳族烃基部分原子; z是1至50的数; z'是1至50的数; andz“是从0到6的数字; 或A2）对应于下式的氟代烃基取代的铝氧烷化合物：其中：R 1和R 2各自独立地为C 1-4脂族或芳族基团或其氟化衍生物或R 1和R 2 >共同形成共价键; R 3各自独立地为含有1至100个碳原子或R 1的单价含氟有机基团，条件是在每分子至少一次出现时，R 3，是含有1至100个碳原子的单价氟化有机基团，并且m为1至1000的数; B）含有1至3个π键合的阴离子或中性配体基团的第3,4族或镧系元素金属络合物; 和C）支持。

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