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1. 发明授权

US07750190B2 Method for producing new polynuclear poly(formylphenol) 有权
标题翻译：生产新型多核聚（甲酰苯酚）的方法
公开(公告)号：US07750190B2
公开(公告)日：2010-07-06
申请号：US12299902
申请日：2007-05-31
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C45/00
CPC分类号： C07C47/57 , C07C45/565
摘要： Produce the target substance, or a polynuclear poly(formylphenol) expressed by General Formula (2), in an industrial setting with ease and at high purity by causing a polynuclear poly(hydroxymethylphenol) or polynuclear poly(alkoxymethylphenol) to react with hexamethylene tetramine in the presence of an acid and then hydrolyzing the obtained reaction product.
摘要翻译：通过使多核聚（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺进行反应，在工业设置中通过使多元醇（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺反应生成目标物质或由通式（2）表示的多核聚（甲酰苯酚）酸的存在，然后水解所得反应产物。

2. 发明授权

US07456323B2 1,3-bis(3-formyl-4-hydroxyphenyl)adamantanes and polynuclear polyphenols derived therefrom 有权
标题翻译： 1,3-双（3-甲酰基-4-羟基苯基）金刚烷和由其衍生的多核多酚
公开(公告)号：US07456323B2
公开(公告)日：2008-11-25
申请号：US11915829
申请日：2006-06-13
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C45/00 , C07C47/00 , C07C39/00
CPC分类号： C07C37/20 , C07C39/17 , C07C45/565 , C07C47/57 , C07C2601/14 , C07C2603/74
摘要： A new 1,3-bis(3-formyl-4-hydroxyphenyl)adamantane, which provides a material offering excellent properties such as heat resistance and mechanical strength for use as an intermediate material for adamantanebisphenol derivatives or use in photosensitive resist materials, epoxy resins and other synthetic resins, thermosensitive recording materials, and the like, can be obtained through an industrial process in an easy manner at a good yield and high purity by producing a Schiff base from a 1,3-bis(4-hydroxyphenyl)adamantane by causing it to react with a hexamethylenetetramine or other substance in the presence of an acid, and then hydrolyzing the obtained Schiff base using an acid. A new polynuclear polyphenol is also provided that may be derived from the same.
摘要翻译：一种新的1,3-双（3-甲酰基-4-羟基苯基）金刚烷，其提供提供优异性能的材料，例如用作金刚烷二苯酚衍生物的中间体材料或用于光敏抗蚀剂材料的耐热性和机械强度，环氧树脂和其它合成树脂，热敏记录材料等可以通过工业方法以容易的方式以良好的产率和高纯度通过从1,3-双（4-羟基苯基）金刚烷生成席夫碱得到，由使其在酸存在下与六亚甲基四胺或其他物质反应，然后使用酸水解所得的席夫碱。还提供了可以衍生自其的新的多核多酚。

3. 发明申请

US20090182175A1 METHOD FOR PRODUCING NEW POLYNUCLEAR POLY(FORMYLPHENOL) 有权
标题翻译：生产新型多核聚烯烃（甲基酚）的方法
公开(公告)号：US20090182175A1
公开(公告)日：2009-07-16
申请号：US12299902
申请日：2007-05-31
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C47/56
CPC分类号： C07C47/57 , C07C45/565
摘要： Produce the target substance, or a polynuclear poly(formylphenol) expressed by General Formula (2), in an industrial setting with ease and at high purity by causing a polynuclear poly(hydroxymethylphenol) or polynuclear poly(alkoxymethylphenol) to react with hexamethylene tetramine in the presence of an acid and then hydrolyzing the obtained reaction product.
摘要翻译：通过使多核聚（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺进行反应，在工业设置中通过使多元醇（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺反应生成目标物质或由通式（2）表示的多核聚（甲酰基苯酚）酸的存在，然后水解所得反应产物。

4. 发明申请

US20080242896A1 1,3-Bis(3-Formyl-4-Hydroxyphenyl)Adamantanes and Polynuclear Polyphenols Derived Therefrom 有权
标题翻译：金刚烷衍生的1,3-二（3-甲酰基-4-羟基苯基）金刚烷和多核多酚
公开(公告)号：US20080242896A1
公开(公告)日：2008-10-02
申请号：US11915829
申请日：2006-06-13
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C47/56 , C07C39/15 , C07C45/42
CPC分类号： C07C37/20 , C07C39/17 , C07C45/565 , C07C47/57 , C07C2601/14 , C07C2603/74
摘要： A new 1,3-bis(3-formyl-4-hydroxyphenyl)adamantane, which provides a material offering excellent properties such as heat resistance and mechanical strength for use as an intermediate material for adamantanebisphenol derivatives or use in photosensitive resist materials, epoxy resins and other synthetic resins, thermosensitive recording materials, and the like, can be obtained through an industrial process in an easy manner at a good yield and high purity by producing a Schiff base from a 1,3-bis(4-hydroxyphenyl)adamantane by causing it to react with a hexamethylenetetramine or other substance in the presence of an acid, and then hydrolyzing the obtained Schiff base using an acid. A new polynuclear polyphenol is also provided that may be derived from the same.
摘要翻译：一种新的1,3-双（3-甲酰基-4-羟基苯基）金刚烷，其提供提供优异性能的材料，例如用作金刚烷二苯酚衍生物的中间体材料或用于光敏抗蚀剂材料的耐热性和机械强度，环氧树脂和其它合成树脂，热敏记录材料等可以通过工业方法以容易的方式以良好的产率和高纯度通过从1,3-双（4-羟基苯基）金刚烷生成席夫碱得到，由使其在酸存在下与六亚甲基四胺或其他物质反应，然后使用酸水解所得的席夫碱。还提供了可以衍生自其的新的多核多酚。

5. 再颁专利

USRE43067E1 Method for producing new polynuclear poly(formylphenol) 有权
标题翻译：生产新型多核聚（甲酰苯酚）的方法
公开(公告)号：USRE43067E1
公开(公告)日：2012-01-03
申请号：US12984215
申请日：2007-05-31
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C45/00
CPC分类号： C07C47/57 , C07C45/565
摘要： Produce the target substance, or a polynuclear poly(formylphenol) expressed by General Formula (2), in an industrial setting with ease and at high purity by causing a polynuclear poly(hydroxymethylphenol) or polynuclear poly(alkoxymethylphenol) to react with hexamethylene tetramine in the presence of an acid and then hydrolyzing the obtained reaction product.
摘要翻译：通过使多核聚（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺进行反应，在工业设置中通过使多元醇（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺反应生成目标物质或由通式（2）表示的多核聚（甲酰苯酚）酸的存在，然后水解所得反应产物。

6. 发明申请

US20110028752A1 NOVEL BIS(FORMYLPHENYL) COMPOUND AND NOVEL POLYNUCLEAR POLYPHENOL COMPOUND DERIVED FROM THE SAME 审中-公开
标题翻译：新型双（对甲苯基）化合物和衍生自其的新型多核多环戊二烯化合物
公开(公告)号：US20110028752A1
公开(公告)日：2011-02-03
申请号：US12745367
申请日：2008-11-07
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C69/734 , C07C59/68 , C07C51/29 , C07C67/40
CPC分类号： C07C69/712 , C07C51/29 , C07C59/68 , C07C69/738 , C07C2601/14
摘要： A bis(formylphenyl) compound expressed by general formula (1) is manufactured by, for example, using a corresponding bis(hydroxy-formylphenyl) compound as the direct material and causing it to react with a halogenated alkoxycarbonyl hydrocarbon in the presence of a base according to a known phenylether manufacturing method.
摘要翻译：由通式（1）表示的双（甲酰基苯基）化合物通过例如使用相应的双（羟基甲酰基苯基）化合物作为直接材料并使其与卤代烷氧基羰基烃在碱的存在下反应根据已知的苯醚制造方法。

7. 发明授权

US07858819B2 Tris(formylphenyl) and novel polynuclear phenol derived therefrom 有权
标题翻译：三（甲酰基苯基）和由其衍生的新型多核苯酚
公开(公告)号：US07858819B2
公开(公告)日：2010-12-28
申请号：US12304085
申请日：2007-06-11
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C47/57 , C07C59/74 , C07C69/66 , C07C69/76
CPC分类号： C07C47/57 , C07C39/15 , C07C59/74 , C07C69/712
摘要： A new tris(formylphenyl) of the following general formula and polynuclear phenol derived therefrom:
摘要翻译：一种新的三（甲酰基苯基）下列通式和由其衍生的多核苯酚：

8. 发明申请

US20070232839A1 NOVEL POLYNUCLEAR POLYPHENOL COMPOUND 审中-公开
标题翻译：新型聚环氧乙烷化合物
公开(公告)号：US20070232839A1
公开(公告)日：2007-10-04
申请号：US11692854
申请日：2007-03-28
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C39/12
CPC分类号： C07C39/12
摘要： A polynuclear polyphenol compound is constituted by, as a main skeleton, a 4,4′-methylene bis phenol structure where tris phenol skeletons of tris phenyl methane type are mutually bonded by methylene groups, wherein the reactivity of two hydroxyl groups bonded to the central skeleton of 4,4′-methylene bis phenol is significantly different from the reactivity of hydroxyl groups respectively bonded to the four phenyl groups of the two diphenyl methyl substituted groups.
摘要翻译：作为主要骨架的多核多酚化合物以三苯基甲烷型三苯酚骨架通过亚甲基相互结合的4,4'-亚甲基双酚结构体构成，其中与中心键合的两个羟基的反应性 4,4'-亚甲基双酚的骨架与分别与两个二苯基甲基取代基的四个苯基键合的羟基的反应性显着不同。

9. 发明授权

US08563770B2 Bis(formylphenyl) compound and novel polynuclear polyphenol compound derived from the same 有权
标题翻译：双（甲酰基苯基）化合物和衍生自其的新型多核多酚化合物
公开(公告)号：US08563770B2
公开(公告)日：2013-10-22
申请号：US13555023
申请日：2012-07-20
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C59/40 , C07C62/30 , C07C63/33
CPC分类号： C07C69/712 , C07C51/29 , C07C59/68 , C07C69/738 , C07C2601/14
摘要： A bis(formylphenyl) compound expressed by general formula (2) is useful as a photo-sensitive resist material:
摘要翻译：由通式（2）表示的双（甲酰基苯基）化合物可用作光敏抗蚀剂材料：

10. 发明申请

US20100099908A1 TRIS(FORMYLPHENYL) AND NEW POLYNUCLEAR POLYPHENOL DERIVED THEREFROM 有权
标题翻译： TRIS（甲基苯酚）和衍生自其的新型多核聚苯乙烯
公开(公告)号：US20100099908A1
公开(公告)日：2010-04-22
申请号：US12304085
申请日：2007-06-11
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C47/57 , C07C69/66 , C07C69/76 , C07C59/74 , C07C39/15
CPC分类号： C07C47/57 , C07C39/15 , C07C59/74 , C07C69/712
摘要： A novel tris(formylphenyl) according to the following general formula and polynuclear phenol derived therefrom, which are useful as a material for heat resistant materials, material for photosensitive resist compositions, epoxy resin material or hardener, developer or anti-fade agent for thermosensitive recording materials, or sterilizer, fungicide, antioxidant, etc: In the formula, Y represents a hydrogen atom or —R2COOR3 group, R2 represents a monocyclic or condensed cyclic aromatic hydrocarbon group with a carbon atom number of 6 to 15 or an aliphatic hydrocarbon group with a carbon atom number of 1 to 8 that may have in its main chain a monocyclic or condensed cyclic aromatic hydrocarbon group with a carbon atom number of 6 to 15, and R3 represents a hydrogen atom or alkyl group with a carbon atom number of 1 to 6. R1s may be the same or different and respectively represent a hydrogen atom, alkyl group with a carbon atom number of 1 to 8 or alkoxyl group with a carbon atom number of 1 to 8. RB and RC may be the same or different, where RA, RB and RC respectively represent a hydrogen atom or alkyl group with a carbon atom number of 1 to 6 and n and m are respectively an integer of 0 or 1 to 3.
摘要翻译：根据以下通式的新型三（甲酰基苯基）和由其衍生的多核苯酚，其可用作耐热材料的材料，用于光敏抗蚀剂组合物的材料，环氧树脂材料或硬化剂，用于热敏记录的显影剂或抗褪色剂材料或杀菌剂，杀菌剂，抗氧化剂等：式中，Y表示氢原子或-R2COOR3基，R2表示碳原子数为6〜15的单环或稠环状芳香族烃基，碳原子数1〜8的碳原子数为6〜15的单环或稠环状芳香族烃基，其主链中可以具有碳原子数为1〜8的氢原子或烷基 R6可以相同或不同，分别表示氢原子，碳原子数为1〜8的烷基或碳原子数的烷氧基 R 1和R 2可以相同或不同，其中RA，RB和RC分别表示氢原子或碳原子数为1至6的烷基，n和m分别为0或1的整数到3。

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