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1. 发明授权

US08816135B2 Trisphenol compound 有权
标题翻译：三酚化合物
公开(公告)号：US08816135B2
公开(公告)日：2014-08-26
申请号：US13395062
申请日：2010-09-09
申请人： Akira Yoshitomo , Shihoko Nakano
发明人： Akira Yoshitomo , Shihoko Nakano
IPC分类号： C07C39/14 , C07C39/15 , C07C37/20
CPC分类号： C07C39/15 , C07C37/20
摘要： A trisphenol compound is expressed by formula (1), wherein R represents an alkyl group or alkoxyl group with 1 to 8 carbon atoms, phenyl group or hydroxyl group; R1 represents an alkyl group or alkoxyl group with 1 to 8 carbon atoms, or phenyl group; R2 represents an alkyl group or alkoxyl group with 1 to 8 carbon atoms; R3 represents a hydrogen atom or alkyl group with 1 to 8 carbon atoms; a represents 0, 1, 2, or 3; b represents 1 or 2; and c and d represent 0, 1, 2, 3, or 4; where the sum of b and c is 5 or less; R's may be either the same or different when a is 2 or more; R1's may be either the same or different when c is 2 or more; and R2's may be either the same or different when d is 2 or more.
摘要翻译：三酚化合物由式（1）表示，其中R表示烷基或具有1至8个碳原子的烷氧基，苯基或羟基; R1表示碳原子数为1〜8的烷基或烷氧基，或苯基。 R2表示碳原子数为1〜8的烷基或烷氧基， R3表示氢原子或碳原子数为1〜8的烷基; a表示0,1,2或3; b表示1或2; 和c和d代表0，1，2，3或4; 其中b和c之和为5或更小; 当a为2以上时，R可以相同或不同; 当c为2以上时，R1可以相同或不同; 当d为2或更多时，R2的可能相同或不同。

2. 发明申请

US20090182175A1 METHOD FOR PRODUCING NEW POLYNUCLEAR POLY(FORMYLPHENOL) 有权
标题翻译：生产新型多核聚烯烃（甲基酚）的方法
公开(公告)号：US20090182175A1
公开(公告)日：2009-07-16
申请号：US12299902
申请日：2007-05-31
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C47/56
CPC分类号： C07C47/57 , C07C45/565
摘要： Produce the target substance, or a polynuclear poly(formylphenol) expressed by General Formula (2), in an industrial setting with ease and at high purity by causing a polynuclear poly(hydroxymethylphenol) or polynuclear poly(alkoxymethylphenol) to react with hexamethylene tetramine in the presence of an acid and then hydrolyzing the obtained reaction product.
摘要翻译：通过使多核聚（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺进行反应，在工业设置中通过使多元醇（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺反应生成目标物质或由通式（2）表示的多核聚（甲酰基苯酚）酸的存在，然后水解所得反应产物。

3. 发明申请

US20090076310A1 NOVEL BIS-(HYDROXYBENZALDEHYDE) COMPOUND AND NOVEL POLYNUCLEAR POLYPHENOL COMPOUND DERIVED THEREFROM AND METHOD FOR PRODUCTION THEREOF 有权
标题翻译：新型双 - （羟基苄二醛）化合物和衍生自其的新型多核多环戊二烯化合物及其生产方法
公开(公告)号：US20090076310A1
公开(公告)日：2009-03-19
申请号：US11817113
申请日：2006-02-23
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C47/57 , C07C39/15 , C07C45/00
CPC分类号： C07C39/15 , C07C39/17 , C07C45/71 , C07C47/57
摘要： Provide a new bis-(hydroxybenzaldehyde) compound, as well as a new polynuclear polyphenol compound derived therefrom, suitable for use as component materials for photosensitive resist compositions, component materials and hardeners for epoxy resins, developers and anti-fading agents used in thermosensitive recording materials, bactericides, fungicides, antioxidants and other functional chemical products or component materials thereof, wherein such bis-(hydroxybenzaldehyde) compound is produced by reacting in the presence of trihalogenated acetic acid catalyst or phosphoric acid catalyst a 2,6-di(hydroxymethyl)-4-alkylphenol with a hydroxybenzaldehyde expressed by general formula (14).
摘要翻译：提供一种新的双（羟基苯甲醛）化合物，以及衍生自其的新的多核多酚化合物，适用于光敏抗蚀剂组合物，组分材料和环氧树脂用硬化剂，显影剂和用于热敏记录的抗褪色剂的组分材料材料，杀菌剂，杀真菌剂，抗氧化剂等功能性化学产品或其组分材料，其中通过在三卤化乙酸催化剂或磷酸催化剂存在下，将2,6-二（羟基甲基） -4-烷基酚与通式（14）表示的羟基苯甲醛反应。

4. 发明申请

US20080242896A1 1,3-Bis(3-Formyl-4-Hydroxyphenyl)Adamantanes and Polynuclear Polyphenols Derived Therefrom 有权
标题翻译：金刚烷衍生的1,3-二（3-甲酰基-4-羟基苯基）金刚烷和多核多酚
公开(公告)号：US20080242896A1
公开(公告)日：2008-10-02
申请号：US11915829
申请日：2006-06-13
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C47/56 , C07C39/15 , C07C45/42
CPC分类号： C07C37/20 , C07C39/17 , C07C45/565 , C07C47/57 , C07C2601/14 , C07C2603/74
摘要： A new 1,3-bis(3-formyl-4-hydroxyphenyl)adamantane, which provides a material offering excellent properties such as heat resistance and mechanical strength for use as an intermediate material for adamantanebisphenol derivatives or use in photosensitive resist materials, epoxy resins and other synthetic resins, thermosensitive recording materials, and the like, can be obtained through an industrial process in an easy manner at a good yield and high purity by producing a Schiff base from a 1,3-bis(4-hydroxyphenyl)adamantane by causing it to react with a hexamethylenetetramine or other substance in the presence of an acid, and then hydrolyzing the obtained Schiff base using an acid. A new polynuclear polyphenol is also provided that may be derived from the same.
摘要翻译：一种新的1,3-双（3-甲酰基-4-羟基苯基）金刚烷，其提供提供优异性能的材料，例如用作金刚烷二苯酚衍生物的中间体材料或用于光敏抗蚀剂材料的耐热性和机械强度，环氧树脂和其它合成树脂，热敏记录材料等可以通过工业方法以容易的方式以良好的产率和高纯度通过从1,3-双（4-羟基苯基）金刚烷生成席夫碱得到，由使其在酸存在下与六亚甲基四胺或其他物质反应，然后使用酸水解所得的席夫碱。还提供了可以衍生自其的新的多核多酚。

5. 发明申请

US20110028752A1 NOVEL BIS(FORMYLPHENYL) COMPOUND AND NOVEL POLYNUCLEAR POLYPHENOL COMPOUND DERIVED FROM THE SAME 审中-公开
标题翻译：新型双（对甲苯基）化合物和衍生自其的新型多核多环戊二烯化合物
公开(公告)号：US20110028752A1
公开(公告)日：2011-02-03
申请号：US12745367
申请日：2008-11-07
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C69/734 , C07C59/68 , C07C51/29 , C07C67/40
CPC分类号： C07C69/712 , C07C51/29 , C07C59/68 , C07C69/738 , C07C2601/14
摘要： A bis(formylphenyl) compound expressed by general formula (1) is manufactured by, for example, using a corresponding bis(hydroxy-formylphenyl) compound as the direct material and causing it to react with a halogenated alkoxycarbonyl hydrocarbon in the presence of a base according to a known phenylether manufacturing method.
摘要翻译：由通式（1）表示的双（甲酰基苯基）化合物通过例如使用相应的双（羟基甲酰基苯基）化合物作为直接材料并使其与卤代烷氧基羰基烃在碱的存在下反应根据已知的苯醚制造方法。

6. 发明授权

US07858819B2 Tris(formylphenyl) and novel polynuclear phenol derived therefrom 有权
标题翻译：三（甲酰基苯基）和由其衍生的新型多核苯酚
公开(公告)号：US07858819B2
公开(公告)日：2010-12-28
申请号：US12304085
申请日：2007-06-11
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C47/57 , C07C59/74 , C07C69/66 , C07C69/76
CPC分类号： C07C47/57 , C07C39/15 , C07C59/74 , C07C69/712
摘要： A new tris(formylphenyl) of the following general formula and polynuclear phenol derived therefrom:
摘要翻译：一种新的三（甲酰基苯基）下列通式和由其衍生的多核苯酚：

7. 发明申请

US20070232839A1 NOVEL POLYNUCLEAR POLYPHENOL COMPOUND 审中-公开
标题翻译：新型聚环氧乙烷化合物
公开(公告)号：US20070232839A1
公开(公告)日：2007-10-04
申请号：US11692854
申请日：2007-03-28
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C39/12
CPC分类号： C07C39/12
摘要： A polynuclear polyphenol compound is constituted by, as a main skeleton, a 4,4′-methylene bis phenol structure where tris phenol skeletons of tris phenyl methane type are mutually bonded by methylene groups, wherein the reactivity of two hydroxyl groups bonded to the central skeleton of 4,4′-methylene bis phenol is significantly different from the reactivity of hydroxyl groups respectively bonded to the four phenyl groups of the two diphenyl methyl substituted groups.
摘要翻译：作为主要骨架的多核多酚化合物以三苯基甲烷型三苯酚骨架通过亚甲基相互结合的4,4'-亚甲基双酚结构体构成，其中与中心键合的两个羟基的反应性 4,4'-亚甲基双酚的骨架与分别与两个二苯基甲基取代基的四个苯基键合的羟基的反应性显着不同。

8. 再颁专利

USRE43067E1 Method for producing new polynuclear poly(formylphenol) 有权
标题翻译：生产新型多核聚（甲酰苯酚）的方法
公开(公告)号：USRE43067E1
公开(公告)日：2012-01-03
申请号：US12984215
申请日：2007-05-31
申请人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
发明人： Akira Yoshitomo , Tatsuya Iwai , Kentaro Watanabe
IPC分类号： C07C45/00
CPC分类号： C07C47/57 , C07C45/565
摘要： Produce the target substance, or a polynuclear poly(formylphenol) expressed by General Formula (2), in an industrial setting with ease and at high purity by causing a polynuclear poly(hydroxymethylphenol) or polynuclear poly(alkoxymethylphenol) to react with hexamethylene tetramine in the presence of an acid and then hydrolyzing the obtained reaction product.
摘要翻译：通过使多核聚（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺进行反应，在工业设置中通过使多元醇（羟基甲基苯酚）或多核聚（烷氧基甲基苯酚）与六亚甲基四胺反应生成目标物质或由通式（2）表示的多核聚（甲酰苯酚）酸的存在，然后水解所得反应产物。

9. 发明申请

US20110172457A1 TETRAKIS(ETHER-SUBSTITUTED FORMYLPHENYL) AND NEW POLYNUCLEAR POLYPHENOL DERIVED FROM THE SAME 审中-公开
标题翻译：四氯乙烯（取代甲基苯酚）和从其衍生的新的多核聚苯乙烯
公开(公告)号：US20110172457A1
公开(公告)日：2011-07-14
申请号：US13000191
申请日：2009-06-22
申请人： Akira Yoshitomo , Tatsuya Iwai
发明人： Akira Yoshitomo , Tatsuya Iwai
IPC分类号： C07C69/95 , C07C59/31
CPC分类号： C07C69/738 , C07C39/17 , C07C47/57 , C07C59/70 , C07C69/712 , C07C2601/14 , C07C2603/74 , C09B11/02 , C09B11/06
摘要： Disclosed are tetrakis(ether-substituted formylphenyl) expressed by General Formula (1), as well as polynuclear polyphenol derived from such tetrakis(ether-substituted formylphenyl): (In the formula, R1 represents an alkyl group with 1 to 8 carbon atoms or alkoxyl group with 1 to 8 carbon atoms, or aromatic hydrocarbon group or saturated hydrocarbon group with 1 to 8 carbon atoms having an aromatic hydrocarbon group, n represents 0 or an integer of 1 to 3, R2 represents a divalent monocyclic or fused-ring aromatic hydrocarbon group with 6 to 15 carbon atoms or divalent aliphatic hydrocarbon group with 1 to 8 carbon atoms that may have a monocyclic or fused-ring aromatic hydrocarbon group with 6 to 15 carbon atoms, R3 represents a hydrogen atom or alkyl group with 1 to 6 carbon atoms, A represents a tetravalent carbon atom group or tetravalent saturated hydrocarbon group with 2 or more carbon atoms, where, if A is a tetravalent saturated hydrocarbon group with 2 or more carbon atoms, the two carbon atoms in the A group are bonded with two phenyl groups, respectively.)
摘要翻译：公开了由通式（1）表示的四（醚取代的甲酰基苯基），以及由这种四（醚取代的甲酰基苯基）衍生的多核多酚：（式中，R1表示碳原子数为1〜8的烷基或具有1至8个碳原子的烷氧基或具有芳族烃基的具有1至8个碳原子的芳族烃基或饱和烃基，n表示0或1至3的整数，R 2表示二价单环或稠环芳族具有6至15个碳原子的烃基或具有1至8个碳原子的二价脂族烃基，其可具有6至15个碳原子的单环或稠环芳族烃基，R 3表示氢原子或具有1至6个碳原子的烷基碳原子，A表示碳原子数为2以上的四价碳原子数或四价饱和烃基，其中，如果A是具有2个以上碳原子的四价饱和烃基，则th A组中的两个碳原子分别与两个苯基键合。）

10. 发明授权

US07875743B2 Bis(formylphenyl)alkane and novel polynuclear phenol derived from the same 有权
标题翻译：双（甲酰苯基）烷烃和衍生自其的新型多核苯酚
公开(公告)号：US07875743B2
公开(公告)日：2011-01-25
申请号：US12445259
申请日：2007-10-03
申请人： Akira Yoshitomo
发明人： Akira Yoshitomo
IPC分类号： C07C59/40
CPC分类号： C07C69/76 , C07C65/24
摘要： Manufacture a novel bis(formylphenyl)alkane according to General Formula (1), as well as a novel polynuclear phenol derived therefrom, by causing a bis(hydroxymethyl-hydroxyphenyl)alkane to react with hexamethylene tetramine in the presence of an acid and hydrolyzing the reaction product, and then using the obtained bis(hydroxy-formylphenyl)alkane as a direct material and causing this material to react with halogenated alkoxycarbonyl hydrocarbon in the presence of a base.
摘要翻译：通过在酸存在下使双（羟甲基 - 羟基苯基）烷烃与六亚甲基四胺反应，制备根据通式（1）的新型双（甲酰基苯基）烷烃，以及由其衍生的新型多核苯酚，反应产物，然后使用所得到的双（羟基甲酰基苯基）烷烃作为直接材料，并使该物质与卤代烷氧基羰基烃在碱存在下反应。

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