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    • 5. 发明授权
    • Method for the growth of silicon carbide single crystals
    • 碳化硅单晶生长方法
    • US5279701A
    • 1994-01-18
    • US933964
    • 1992-08-24
    • Mitsuhiro ShigetaAkira SuzukiKatsuki FurukawaYoshihisa Fujii
    • Mitsuhiro ShigetaAkira SuzukiKatsuki FurukawaYoshihisa Fujii
    • C30B25/02C30B25/18C30B23/02
    • C30B25/18C30B25/02C30B29/36Y10S148/148Y10S438/931Y10S438/973
    • A method for the growth of silicon carbide single crystals is disclosed which includes the step of growing silicon carbide single crystals on a silicon single-crystal substrate. The silicon single-crystal substrate has growth areas with a crystal orientation inclined by an angle .theta. from the [100] direction toward at least one of the [011] and [011] directions and with a lateral dimension d taken along the direction of such inclination toward the [011] or [011] direction. The angle .theta. is set to be in the range of zero to tan.sup.-1 (.sqroot.2/8) degrees (with the proviso that the angle .theta. is not equal to tan.sup.-1 (.sqroot.2/2) degrees). The lateral dimension d is set to be in the range of 0.1 to 100 .mu.m. In this method, the silicon carbide single crystals are grown to a thickness t approximately equal to or greater than (.sqroot.2+tan.theta.)d/.vertline.1-.sqroot.2tan.theta..vertline., so that these silicon carbide single crystals are substantially free of defects such as stacking faults.
    • 公开了一种用于生长碳化硅单晶的方法,其包括在硅单晶衬底上生长碳化硅单晶的步骤。 硅单晶衬底具有晶体取向从(100)方向朝向(011)和(011)方向中的至少一个方向倾斜角度(θ)的生长区域,并且沿着方向 朝向(011)或(011)方向倾斜。 角度(θ)设定为零到tan-1((平方根)2/8)度的范围(条件是角度(θ)不等于tan-1((平方根) 2/2)度)。 横向尺寸d设定在0.1到100(my)m的范围内。 在该方法中,碳化硅单晶生长至大致等于或大于((平方根)2 + tan(θ))d // 1-(平方根)2tan(θ)/的厚度t,使得 这些碳化硅单晶基本上没有诸如堆垛层错的缺陷。
    • 9. 发明授权
    • Method of producing silicon-carbide single crystals by sublimation
recrystallization process using a seed crystal
    • 使用晶种的升华重结晶法生产碳化硅单晶的方法
    • US5433167A
    • 1995-07-18
    • US156472
    • 1993-11-23
    • Katsuki FurukawaYoshimitsu TajimaAkira Suzuki
    • Katsuki FurukawaYoshimitsu TajimaAkira Suzuki
    • C30B23/02C30B29/36
    • C30B23/02C30B23/002C30B29/36
    • There is provided a method of producing a high-quality n-type, 6H silicon carbide single crystal with good reproducibility. A silicon carbide single crystal substrate having a growth orientation of , as a seed crystal, is mounted to an inner surface of a cover of a graphite crucible. A source material includes a high-purity silicon carbide powder having an impurity proportion of not more than 1 ppm and an aluminum powder of 50 ppm relative to the silicon carbide powder. The source material is loaded into the graphite crucible. The graphite crucible is closed with a seed crystal-mounted cover placed in a double quartz tube. Ar gas and N.sub.2 gas are caused to flow in the double quartz tube. Temperature of the silicon carbide powder and aluminum powder is controlled to 2300.degree. C., and temperature of the silicon carbide single crystal substrate to 2200.degree. C.; and interior of the double quartz tube is controlled to 30 torr. Silicon carbide single crystal growth is effected on the seed crystal under these conditions. A high-quality n-type, 6H silicon carbide single crystal is thus obtained which has a uniform crystal structure with little defect, if any, throughout its structure, from the substrate surface to the outermost grown surface, and has a specific resistance of 0.5 .OMEGA.cm.
    • 提供了一种制造高品质的n型,6H碳化硅单晶,具有良好的再现性的方法。 具有生长方向<0001>的碳化硅单晶衬底作为晶种安装在石墨坩埚的盖的内表面上。 源材料包括杂质比例不大于1ppm的高纯度碳化硅粉末和相对于碳化硅粉末为50ppm的铝粉末。 将原料装入石墨坩埚中。 石墨坩埚用放置在双重石英管中的晶种安装的盖封闭。 使Ar气和N2气在双重石英管中流动。 将碳化硅粉末和铝粉末的温度控制在2300℃,将碳化硅单晶基板的温度控制在2200℃。 并将双重石英管的内部控制在30乇。 在这些条件下,对晶种进行碳化硅单晶生长。 因此获得了高质量的n型6H碳化硅单晶,其具有从基材表面到最外面的生长表面的整个结构中几乎没有缺陷(如果有的话)的均匀晶体结构,并且具有0.5的电阻率 欧米茄厘米