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1. 发明申请

US20050159518A1 Moldings of flame-retardant aromatic polycarbonate resin compositions 有权
标题翻译：阻燃芳香族聚碳酸酯树脂组合物的成型品
公开(公告)号：US20050159518A1
公开(公告)日：2005-07-21
申请号：US10507903
申请日：2003-03-18
申请人： Akira Miyamoto , Toshiharu Sakuma , Kazuhiro Shibuya , Hiroshi Hachiya , Hiroshi Hachiya
发明人： Akira Miyamoto , Toshiharu Sakuma , Kazuhiro Shibuya , Hiroshi Hachiya , Hiroshi Hachiya
IPC分类号： C08K5/42 , C08K7/00 , C08L69/00 , B29C45/26 , B29C45/00 , B29C45/76 , C08K3/18 , C08K3/34 , C08K5/41
CPC分类号： C08L69/00 , B29K2027/12 , B29K2069/00 , B29K2105/0026 , B29K2105/16 , B29K2995/0016 , B29K2995/0088 , C08K5/42 , C08K7/00 , C08L2666/04
摘要： A molded article produced by injection-molding a molten form of a flame-retardant aromatic polycarbonate resin composition comprising: 100 parts by weight of an aromatic polycarbonate (A) (Mw: 17,000 to 35,000), 0.01 to 3 parts by weight of inorganic compound particles (B) (average diameter: 10 nm to 10 μm), 0.001 to 0.5 part by weight of an alkali metal salt (C) of an organic sulfonic acid, and 0.01 to 0.5 part by weight of a fluoropolymer (D), wherein the largest FL/t ratio of the molded article is 50 or more, wherein FL is a flow length of the composition in a mold and t is a thickness of the molded article, the FL/t ratios being obtained by measuring the thicknesses of the molded article at portions corresponding to flow paths (L) (from a gate to points at which the flow of the composition stops) of the composition in the mold during the molding, and calculating an integral of (dL/T′) along each (L) (dL: length of a segment of (L), t′: thickness of the molded article at a portion corresponding to the segment), wherein the calculated integrals are defined as the FL/t ratios.
摘要翻译：通过注塑成型熔融形式的阻燃性芳香族聚碳酸酯树脂组合物而制造的成型体，其包含：100重量份芳香族聚碳酸酯（A）（Mw：17,000〜35,000），0.01〜3重量份的无机化合物颗粒（B）（平均直径：10nm至10μm），0.001至0.5重量份的有机磺酸的碱金属盐（C）和0.01至0.5重量份的含氟聚合物（D），其中成型体的最大FL / t比为50以上，其中，FL为成型体的成型体的流动长度，t为成型品的厚度，FL / t比是通过测定模制品在成形期间对应于流动路径（L）（从浇口到组合物流动的点停止的部分），并计算每个（dL / T'）的积分（dL / T'） L）（dL：（L）的段的长度，t'：成形品的一部分的厚度对应于该段），其中所计算的积分被定义为FL / t比。

2. 发明授权

US07060780B2 Moldings of flame-retardant aromatic polycarbonate resin compositions 有权
标题翻译：阻燃芳香族聚碳酸酯树脂组合物的成型品
公开(公告)号：US07060780B2
公开(公告)日：2006-06-13
申请号：US10507903
申请日：2003-03-18
申请人： Akira Miyamoto , Toshiharu Sakuma , Kazuhiro Shibuya , Hiroshi Hachiya
发明人： Akira Miyamoto , Toshiharu Sakuma , Kazuhiro Shibuya , Hiroshi Hachiya
IPC分类号： C08G64/00
CPC分类号： C08L69/00 , B29K2027/12 , B29K2069/00 , B29K2105/0026 , B29K2105/16 , B29K2995/0016 , B29K2995/0088 , C08K5/42 , C08K7/00 , C08L2666/04
摘要： A molded article produced by injection-molding a molten form of a flame-retardant aromatic polycarbonate resin composition comprising: 100 parts by weight of an aromatic polycarbonate (A) (Mw: 17,000 to 35,000), 0.01 to 3 parts by weight of inorganic compound particles (B) (average diameter: 10 nm to 10 μm), 0.001 to 0.5 part by weight of an alkali metal salt (C) of an organic sulfonic acid, and 0.01 to 0.5 part by weight of a fluoropolymer (D), wherein the largest FL/t ratio of the molded article is 50 or more, wherein FL is a flow length of the composition in a mold and t is a thickness of the molded article, the FL/t ratios being obtained by measuring the thicknesses of the molded article at portions corresponding to flow paths (L) (from a gate to points at which the flow of the composition stops) of the composition in the mold during the molding, and calculating an integral of (dL/T′) along each (L) (dL: length of a segment of (L), t′: thickness of the molded article at a portion corresponding to the segment), wherein the calculated integrals are defined as the FL/t ratios.
摘要翻译：通过注塑成型熔融形式的阻燃性芳香族聚碳酸酯树脂组合物而制造的成型体，其包含：100重量份芳香族聚碳酸酯（A）（Mw：17,000〜35,000），0.01〜3重量份的无机化合物颗粒（B）（平均直径：10nm至10μm），0.001至0.5重量份的有机磺酸的碱金属盐（C）和0.01至0.5重量份的含氟聚合物（D），其中成型体的最大FL / t比为50以上，其中，FL为成型体的成型体的流动长度，t为成型品的厚度，FL / t比是通过测定模制品在成形期间对应于流动路径（L）（从浇口到组合物流动的点停止的部分），并计算每个（dL / T'）的积分（dL / T'） L）（dL：（L）的段的长度，t'：成形品的一部分的厚度对应于该段），其中所计算的积分被定义为FL / t比。

3. 发明授权

US06833397B2 Method for producing a flame retardant polycarbonate resin composition 有权
标题翻译：阻燃聚碳酸酯树脂组合物的制造方法
公开(公告)号：US06833397B2
公开(公告)日：2004-12-21
申请号：US09947368
申请日：2001-09-07
申请人： Akira Miyamoto , Kazuhiro Shibuya , Hiroshi Hachiya , Chung Neng Wu , Wen-Yi Su
发明人： Akira Miyamoto , Kazuhiro Shibuya , Hiroshi Hachiya , Chung Neng Wu , Wen-Yi Su
IPC分类号： C08K549
CPC分类号： B29C47/402 , B29C47/0009 , B29C47/38 , B29K2069/00 , B29K2105/0026
摘要： Disclosed is a method for producing a flame retardant polycarbonate resin composition by using a screw extruder, which comprises extruding a resin component (mainly comprising a polycarbonate) and an organic phosphorus compound having an acid value of not more than 0.1 mg KOH/g while kneading, wherein the temperature of the resin component in the extruder is not higher than 300° C., and the residence time of the resin component in the extruder is not more than 40 seconds.
摘要翻译：公开了使用螺杆挤出机制造阻燃聚碳酸酯树脂组合物的方法，该方法包括挤出树脂组分（主要包含聚碳酸酯）和酸值不超过0.1mg KOH / g的有机磷化合物，同时捏合其中，挤出机中树脂成分的温度不高于300℃，树脂成分在挤出机中的停留时间不超过40秒。

4. 发明授权

US06417319B1 Flame-retardant polycarbonate resin composition with excellent melt flowability 有权
标题翻译：具有优异熔体流动性的阻燃聚碳酸酯树脂组合物
公开(公告)号：US06417319B1
公开(公告)日：2002-07-09
申请号：US09830832
申请日：2001-05-01
申请人： Kazuhiro Shibuya , Hiroshi Hachiya , Nobutsugu Nanba
发明人： Kazuhiro Shibuya , Hiroshi Hachiya , Nobutsugu Nanba
IPC分类号： C08G6400
CPC分类号： C08K5/523 , C08L25/08 , C08L27/18 , C08L51/04 , C08L51/08 , C08L51/085 , C08L69/00 , Y10T428/31507 , C08L2666/02
摘要： Disclosed is a flame retardant polycarbonate resin composition having an improved melt fluidity, which comprises (A) an aromatic polycarbonate having a weight average molecular weight of from 12,000 to 25,000, (B) a styrene-acrylonitrile-butyl acrylate copolymer having a butyl acrylate unit content of from 1 to 30% by weight, (C) a complex rubber graft copolymer obtained by a process comprising graft-polymerizing at least one graft-polymerizable monomer onto a complex rubber comprising a polyorganosiloxane and a polyalkyl (meth)acrylate, (D) a phosphoric ester, and (E) a tetrafluoroethylene polymer. The resin composition of the present invention not only has excellent melt fluidity, but is also excellent in flame retardancy, impact resistance and modulus of elasticity. The resin composition of the present invention can be advantageously used for producing various types of shaped articles (including those for use in office automation machines and in electric and electronic equipment), and is especially advantageous for producing small-thickness shaped articles.
摘要翻译：公开了具有改进的熔体流动性的阻燃聚碳酸酯树脂组合物，其包含（A）重均分子量为12,000至25,000的芳族聚碳酸酯，（B）具有丙烯酸丁酯单元的苯乙烯 - 丙烯腈 - 丙烯酸丁酯共聚物（C）通过将至少一种可接枝聚合单体接枝聚合到包含聚有机硅氧烷和（甲基）丙烯酸烷基酯的复合橡胶上的方法得到的复合橡胶接枝共聚物（C））磷酸酯，和（E）四氟乙烯聚合物。本发明的树脂组合物不仅具有优异的熔体流动性，而且阻燃性，耐冲击性和弹性模量也优异。本发明的树脂组合物可以有利地用于生产各种类型的成型制品（包括用于办公自动化机器和电气和电子设备的成型制品），并且特别有利于制造小型成形制品。

5. 发明授权

US06512077B1 Polycarbonate-base flame-retardant resin composition 有权
标题翻译：聚碳酸酯基阻燃树脂组合物
公开(公告)号：US06512077B1
公开(公告)日：2003-01-28
申请号：US09889044
申请日：2001-07-11
申请人： Akira Miyamoto , Hiroshi Hachiya , Nobutsugu Nanba
发明人： Akira Miyamoto , Hiroshi Hachiya , Nobutsugu Nanba
IPC分类号： C08G6400
CPC分类号： C08K5/523 , C08F6/001 , C08L25/12 , C08L27/12 , C08L27/18 , C08L51/04 , C08L55/02 , C08L69/00 , C08L85/02 , C08L2666/02
摘要： Disclosed is a flame retardant polycarbonate resin composition, which comprises 50 to 98 parts by weight of an aromatic polycarbonate (A), 0.1 to 49 parts by weight of a copolymer (B) comprising an aromatic vinyl monomer unit (b-1) and a vinyl cyanide monomer unit (b-2), 0.5 to 30 parts by weight of a cyanide-containing, graft copolymer (C) obtained by copolymerizing an aromatic vinyl compound (c-1) and a vinyl cyanide compound (c-2) in the presence of a rubbery polymer (c-3), 0.5 to 30 parts by weight of a (meth)acrylate-containing, graft copolymer (D) obtained by copolymerizing an aromatic vinyl compound (d-1) and an alkyl (meth)acrylate (d-2) in the presence of a rubbery butadiene polymer (d-3), and 0.1 to 30 parts by weight of at least one organic phosphorus compound oligomer (E), wherein the total amount of the components (A), (B), (C) and (D) is 100 parts by weight.
摘要翻译：公开了一种阻燃聚碳酸酯树脂组合物，其包含50至98重量份的芳族聚碳酸酯（A），0.1至49重量份的包含芳族乙烯基单体单元（b-1）的共聚物（B）和乙烯基氰单体单元（b-2），0.5〜30重量份通过使芳香族乙烯基化合物（c-1）与乙烯基氰化合物（c-2）共聚而得到的含氰化物的接枝共聚物（C）橡胶质聚合物（c-3）的存在，通过使芳族乙烯基化合物（d-1）与（甲基）丙烯酸烷基酯共聚而得到的含（甲基）丙烯酸酯的接枝共聚物（D），0.5〜30重量份丙烯酸酯（d-2）在橡胶状丁二烯聚合物（d-3）的存在下，和0.1〜30重量份的至少一种有机磷化合物低聚物（E），其中组分（A），（B），（C）和（D）为100重量份。

6. 发明申请

US20120263642A1 METHOD FOR IMPROVING COERCIVE FORCE OF EPSILON-TYPE IRON OXIDE, AND EPSILON-TYPE IRON OXIDE 有权
标题翻译：改善EPSILON型氧化铁和EPSILON型氧化铁的强化力的方法
公开(公告)号：US20120263642A1
公开(公告)日：2012-10-18
申请号：US13499172
申请日：2010-09-30
申请人： Shin-ichi Ohkoshi , Shunsuke Sakurai , Asuka Namai , Sayaka Umeda , Hiroshi Hachiya , Kazuyuki Matsumoto , Takashi Gotoh
发明人： Shin-ichi Ohkoshi , Shunsuke Sakurai , Asuka Namai , Sayaka Umeda , Hiroshi Hachiya , Kazuyuki Matsumoto , Takashi Gotoh
IPC分类号： C01G55/00
CPC分类号： H01F1/047 , C01G49/0018 , C01G49/06 , C01P2002/50 , C01P2002/52 , C01P2006/42 , C04B35/26 , C04B35/62826 , C04B2235/3217 , C04B2235/3286 , C04B2235/3289 , C04B2235/3418 , C04B2235/761 , H01F1/10
摘要： To provide a method for improving a coercive force of epsilon-type iron oxide particles, and an epsilon-type iron oxide. Specifically, to provide a method for improving the coercive force of an epsilon-type iron oxide comprising: substituting Fe-site of the epsilon-type iron oxide with other element, while not substituting Fe of D-site in the epsilon-type iron oxide with other element, and the epsilon type iron oxide.
摘要翻译：提供一种改善ε型氧化铁颗粒和ε型氧化铁的矫顽力的方法。具体地，提供一种改进ε型氧化铁的矫顽力的方法，包括：用其它元素代替ε型氧化铁的Fe部位，而不是在ε型氧化铁中代替D位的Fe 与其他元素，和epsilon型氧化铁。

7. 发明授权

US08071819B2 Industrial process for production of high-purity diol 有权
标题翻译：工业生产高纯度二醇的工艺
公开(公告)号：US08071819B2
公开(公告)日：2011-12-06
申请号：US11991292
申请日：2006-12-28
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C31/18 , B01J19/00 , B01D3/00
CPC分类号： C07C29/80 , B01D3/008 , B01D3/009 , B01D3/20 , B01D3/22 , B01D3/32 , C07C29/128 , C07C68/065 , Y02P20/127 , C07C69/96 , C07C31/202
摘要： The invention provides an apparatus and process for producing high-purity diol by taking cyclic carbonate and aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into column A, carrying out reactive distillation in column A, continuously withdrawing a low boiling point reaction mixture containing a produced dialkyl carbonate and the aliphatic monohydric alcohol from an upper portion of column A, continuously withdrawing a high boiling point reaction mixture containing a produced diol from a lower portion of column A, continuously feeding the high boiling point reaction mixture into distillation column C, distilling off material having a lower boiling point than that of the diol contained in the high boiling point reaction mixture AB as a column top component and/or a side cut component so as to obtain a column bottom component, continuously feeding the column bottom component into distillation column E, and obtaining the diol.
摘要翻译：本发明提供一种以环状碳酸酯和脂肪族一元醇为原料制备高纯度二醇的装置和方法，将原料连续供给到塔A中，在塔A中进行反应性蒸馏，连续取出低沸点反应混合物从塔A的上部含有生成的碳酸二烷基酯和脂肪族一元醇，从塔A的下部连续取出含有生成的二醇的高沸点反应混合物，将高沸点反应混合物连续供给到蒸馏塔C 将沸点低于高沸点反应混合物AB中所含的二醇作为塔顶成分和/或侧馏分成分的材料蒸馏出来，从而得到塔底成分，将塔底成分加入蒸馏塔E中，得到二醇。

8. 发明授权

US07884251B2 Industrial process for separating out by-produced alcohols 有权
标题翻译：用于分离副产物醇的工业过程
公开(公告)号：US07884251B2
公开(公告)日：2011-02-08
申请号：US11660900
申请日：2005-09-12
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C27/10
CPC分类号： B01D3/009 , B01D3/143 , B01D3/16 , C07C29/80 , C07C68/06 , C07C68/08 , Y02P20/127 , Y02P20/582 , C07C69/96 , C07C31/04
摘要： It is an object of the present invention to provide a specific industrial separation process that enables an alcohol to be separated out efficiently and stably for a prolonged period of time from a large amount of a low boiling point reaction mixture containing a by-produced alcohol when mass-producing aromatic carbonates on an industrial scale by subjecting a dialkyl carbonate and an aromatic monohydroxy compound to transesterification reaction in a reactive distillation column in which a catalyst is present. Although there have been various proposals regarding processes for the production of aromatic carbonates by means of a reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures whatsoever on a specific process or apparatus enabling mass production on an industrial scale to be carried out stably for a prolonged period of time. Moreover, there have been no disclosures on a specific process or apparatus enabling the alcohol by-produced when producing aromatic carbonates the an industrial scale using a reactive distillation system to be separated out efficiently and stably for a prolonged period of time on an industrial scale of not less than 200 kg/hr. According to the present invention, there is proposed a specific process using a continuous multi-stage distillation column having a specified structure enabling the above object to be attained.
摘要翻译：本发明的目的是提供一种具体的工业分离方法，其使得能够从大量含有副产物醇的低沸点反应混合物中有效地和稳定地分离出较长时间的醇，通过在其中存在催化剂的反应蒸馏塔中使碳酸二烷基酯和芳族单羟基化合物进行酯交换反应，大量生产芳族碳酸酯。尽管通过反应性蒸馏法已经有关于生产芳族碳酸酯的方法的各种建议，但这些方法都已经在小规模和操作时间短的实验室水平上，并且在具体方法或装置上没有公开任何内容使工业规模的大规模生产能够长期稳定进行。此外，在制造芳香族碳酸酯时能够使副产物醇化的具体方法或装置没有公开，使用反应蒸馏系统的工业规模能够在工业规模上有效且稳定地分离出来不小于200公斤/小时。根据本发明，提出了使用具有能够实现上述目的的特定结构的连续多级蒸馏塔的具体方法。

9. 发明授权

US07799939B2 Process for production of dialkyl carbonate and diol 有权
标题翻译：二烷基碳酸酯和二醇的制备方法
公开(公告)号：US07799939B2
公开(公告)日：2010-09-21
申请号：US11990913
申请日：2006-09-05
申请人： Hironori Miyaji , Shinsuke Fukuoka , Hiroshi Hachiya
发明人： Hironori Miyaji , Shinsuke Fukuoka , Hiroshi Hachiya
IPC分类号： C07C68/06
CPC分类号： C07C68/065 , C07C69/96
摘要： It is an object of the present invention to provide, for a case of producing a dialkyl carbonate and a diol from a cyclic carbonate and an aliphatic monohydric alcohol, a process that simultaneously satisfies the cyclic carbonate conversion being high, the selectivities for the dialkyl carbonate and diol to be produced being high, and a high-purity diol having a high UV transmittance and a low aldehyde content being obtained without carrying out complicated treatment such as feeding water into a diol distillation purification step. The present invention discloses a process for the production of the dialkyl carbonate and the diol in which, when producing the dialkyl carbonate and the diol by reacting the cyclic carbonate and the aliphatic monohydric alcohol together in the presence of a catalyst in a transesterification reactor comprising a tray type continuous multi-stage distillation column, reaction conditions (residence times, temperatures) in the distillation column are controlled to be specific conditions.
摘要翻译：本发明的目的是提供一种从环状碳酸酯和脂肪族一元醇制造碳酸二烷基酯和二醇的情况，同时满足环状碳酸酯转化率高的方法，碳酸二烷基酯的选择性所生产的二醇的高纯度，并且在不进行复杂处理的情况下获得具有高的紫外线透射率和低醛含量的高纯度二醇，而不需要进行二醇蒸馏精制步骤中的水。本发明公开了一种制备碳酸二烷基酯和二醇的方法，其中当在含酯交换反应器的酯交换反应器中，在催化剂存在下，使环状碳酸酯与脂肪族一元醇反应生成碳酸二烷基酯和二醇时，托盘式连续多级蒸馏塔，将蒸馏塔中的反应条件（停留时间，温度）控制为特定条件。

10. 发明申请

US20090253939A1 Process for industrially producing dialkyl carbonate and diol 审中-公开
标题翻译：工业生产碳酸二烷基酯和二醇的方法
公开(公告)号：US20090253939A1
公开(公告)日：2009-10-08
申请号：US11991075
申请日：2006-11-17
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C45/00
CPC分类号： C07C68/065 , B01D3/22 , B01D3/32 , Y02P20/127 , C07C69/96
摘要： It is an object of the present invention to provide a specific process that enables a dialkyl carbonate and a diol to be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively with high selectivity and high productivity stably for a prolonged period of time through a reactive distillation system of taking a cyclic carbonate and an aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into a continuous multi-stage distillation column in which a catalyst is present, and carrying out reaction and distillation simultaneously in the column. Although there have been many proposals regarding processes for the production of the dialkyl carbonate and the diol through the reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures whatsoever on a specific process or apparatus enabling mass production on an industrial scale. According to the present invention, there is provided a specific continuous multi-stage distillation column having a specified structure, and a production process using this continuous multi-stage distillation column, according to which the dialkyl carbonate and the diol can be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively each with a selectivity of not less than 95%, preferably not less than 97%, more preferably not less than 99%, stably for not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours.
摘要翻译：本发明的目的是提供一种能够以不低于2吨/小时并且不低于1.3吨/小时的工业规模生产碳酸二烷基酯和二醇的具有高选择性和高的特定方法通过以环状碳酸酯和脂肪族一元醇为起始原料的反应蒸馏系统，稳定地长时间稳定生产，将原料连续供给到存在催化剂的连续多级蒸馏塔中，并进行在柱中同时进行反应和蒸馏。虽然通过反应蒸馏法生产碳酸二烷基酯和二醇的方法有许多提案，但这些都是在规模小，操作时间短的实验室水平上，并没有公开任何关于具体方法或能够在工业规模上批量生产的设备。根据本发明，提供了具有特定结构的特定连续多级蒸馏塔和使用该连续多级蒸馏塔的制备方法，根据该方法可以在工业上生产碳酸二烷基酯和二醇不小于2吨/小时，不小于1.3吨/小时，选择性不低于95％，优选不低于97％，更优选不低于99％，选择性不低于1000 小时，优选不小于3000小时，更优选不小于5000小时。

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