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1. 发明授权

US08071819B2 Industrial process for production of high-purity diol 有权
标题翻译：工业生产高纯度二醇的工艺
公开(公告)号：US08071819B2
公开(公告)日：2011-12-06
申请号：US11991292
申请日：2006-12-28
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C31/18 , B01J19/00 , B01D3/00
CPC分类号： C07C29/80 , B01D3/008 , B01D3/009 , B01D3/20 , B01D3/22 , B01D3/32 , C07C29/128 , C07C68/065 , Y02P20/127 , C07C69/96 , C07C31/202
摘要： The invention provides an apparatus and process for producing high-purity diol by taking cyclic carbonate and aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into column A, carrying out reactive distillation in column A, continuously withdrawing a low boiling point reaction mixture containing a produced dialkyl carbonate and the aliphatic monohydric alcohol from an upper portion of column A, continuously withdrawing a high boiling point reaction mixture containing a produced diol from a lower portion of column A, continuously feeding the high boiling point reaction mixture into distillation column C, distilling off material having a lower boiling point than that of the diol contained in the high boiling point reaction mixture AB as a column top component and/or a side cut component so as to obtain a column bottom component, continuously feeding the column bottom component into distillation column E, and obtaining the diol.
摘要翻译：本发明提供一种以环状碳酸酯和脂肪族一元醇为原料制备高纯度二醇的装置和方法，将原料连续供给到塔A中，在塔A中进行反应性蒸馏，连续取出低沸点反应混合物从塔A的上部含有生成的碳酸二烷基酯和脂肪族一元醇，从塔A的下部连续取出含有生成的二醇的高沸点反应混合物，将高沸点反应混合物连续供给到蒸馏塔C 将沸点低于高沸点反应混合物AB中所含的二醇作为塔顶成分和/或侧馏分成分的材料蒸馏出来，从而得到塔底成分，将塔底成分加入蒸馏塔E中，得到二醇。

2. 发明授权

US07884251B2 Industrial process for separating out by-produced alcohols 有权
标题翻译：用于分离副产物醇的工业过程
公开(公告)号：US07884251B2
公开(公告)日：2011-02-08
申请号：US11660900
申请日：2005-09-12
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C27/10
CPC分类号： B01D3/009 , B01D3/143 , B01D3/16 , C07C29/80 , C07C68/06 , C07C68/08 , Y02P20/127 , Y02P20/582 , C07C69/96 , C07C31/04
摘要： It is an object of the present invention to provide a specific industrial separation process that enables an alcohol to be separated out efficiently and stably for a prolonged period of time from a large amount of a low boiling point reaction mixture containing a by-produced alcohol when mass-producing aromatic carbonates on an industrial scale by subjecting a dialkyl carbonate and an aromatic monohydroxy compound to transesterification reaction in a reactive distillation column in which a catalyst is present. Although there have been various proposals regarding processes for the production of aromatic carbonates by means of a reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures whatsoever on a specific process or apparatus enabling mass production on an industrial scale to be carried out stably for a prolonged period of time. Moreover, there have been no disclosures on a specific process or apparatus enabling the alcohol by-produced when producing aromatic carbonates the an industrial scale using a reactive distillation system to be separated out efficiently and stably for a prolonged period of time on an industrial scale of not less than 200 kg/hr. According to the present invention, there is proposed a specific process using a continuous multi-stage distillation column having a specified structure enabling the above object to be attained.
摘要翻译：本发明的目的是提供一种具体的工业分离方法，其使得能够从大量含有副产物醇的低沸点反应混合物中有效地和稳定地分离出较长时间的醇，通过在其中存在催化剂的反应蒸馏塔中使碳酸二烷基酯和芳族单羟基化合物进行酯交换反应，大量生产芳族碳酸酯。尽管通过反应性蒸馏法已经有关于生产芳族碳酸酯的方法的各种建议，但这些方法都已经在小规模和操作时间短的实验室水平上，并且在具体方法或装置上没有公开任何内容使工业规模的大规模生产能够长期稳定进行。此外，在制造芳香族碳酸酯时能够使副产物醇化的具体方法或装置没有公开，使用反应蒸馏系统的工业规模能够在工业规模上有效且稳定地分离出来不小于200公斤/小时。根据本发明，提出了使用具有能够实现上述目的的特定结构的连续多级蒸馏塔的具体方法。

3. 发明申请

US20090253939A1 Process for industrially producing dialkyl carbonate and diol 审中-公开
标题翻译：工业生产碳酸二烷基酯和二醇的方法
公开(公告)号：US20090253939A1
公开(公告)日：2009-10-08
申请号：US11991075
申请日：2006-11-17
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C45/00
CPC分类号： C07C68/065 , B01D3/22 , B01D3/32 , Y02P20/127 , C07C69/96
摘要： It is an object of the present invention to provide a specific process that enables a dialkyl carbonate and a diol to be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively with high selectivity and high productivity stably for a prolonged period of time through a reactive distillation system of taking a cyclic carbonate and an aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into a continuous multi-stage distillation column in which a catalyst is present, and carrying out reaction and distillation simultaneously in the column. Although there have been many proposals regarding processes for the production of the dialkyl carbonate and the diol through the reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures whatsoever on a specific process or apparatus enabling mass production on an industrial scale. According to the present invention, there is provided a specific continuous multi-stage distillation column having a specified structure, and a production process using this continuous multi-stage distillation column, according to which the dialkyl carbonate and the diol can be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively each with a selectivity of not less than 95%, preferably not less than 97%, more preferably not less than 99%, stably for not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours.
摘要翻译：本发明的目的是提供一种能够以不低于2吨/小时并且不低于1.3吨/小时的工业规模生产碳酸二烷基酯和二醇的具有高选择性和高的特定方法通过以环状碳酸酯和脂肪族一元醇为起始原料的反应蒸馏系统，稳定地长时间稳定生产，将原料连续供给到存在催化剂的连续多级蒸馏塔中，并进行在柱中同时进行反应和蒸馏。虽然通过反应蒸馏法生产碳酸二烷基酯和二醇的方法有许多提案，但这些都是在规模小，操作时间短的实验室水平上，并没有公开任何关于具体方法或能够在工业规模上批量生产的设备。根据本发明，提供了具有特定结构的特定连续多级蒸馏塔和使用该连续多级蒸馏塔的制备方法，根据该方法可以在工业上生产碳酸二烷基酯和二醇不小于2吨/小时，不小于1.3吨/小时，选择性不低于95％，优选不低于97％，更优选不低于99％，选择性不低于1000 小时，优选不小于3000小时，更优选不小于5000小时。

4. 发明申请

US20090163734A1 Process for producing high-purity diphenyl carbonate on industrial scale 审中-公开
标题翻译：工业规模生产高纯度碳酸二苯酯的工艺
公开(公告)号：US20090163734A1
公开(公告)日：2009-06-25
申请号：US11991382
申请日：2006-12-12
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C69/96
CPC分类号： C07C68/065 , C07C68/06 , C07C68/08 , C08G64/307 , Y02P20/127 , C07C69/96
摘要： It is an object of the present invention to provide a specific process that enables a high-purity diphenyl carbonate required for producing a high-quality high-performance aromatic polycarbonate to be produced industrially in a large amount (e.g. not less than 1 ton/hr) stably for a prolonged period of time (e.g. not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours) from a cyclic carbonate and a phenol. When producing, from a cyclic carbonate and a phenol, a high-purity diphenyl carbonate required for producing a high-quality high-performance aromatic polycarbonate, the above object can be attained by carrying out a process according to the present invention which comprises steps of: (I) producing a dialkyl carbonate and a diol using a reactive distillation column having a specified structure; (II) producing a diphenyl carbonate using two reactive distillation columns each having a specified structure, and (III) obtaining a high-purity diphenyl carbonate from the diphenyl carbonate using a high boiling point material separating column A and a diphenyl carbonate purifying column B.
摘要翻译：本发明的目的是提供一种具体方法，其能够大量生产高品质高性能芳族聚碳酸酯所需的高纯度碳酸二苯酯（例如不小于1吨/小时））从环状碳酸酯和苯酚稳定延长的时间（例如不小于1000小时，优选不小于3000小时，更优选不小于5000小时）。当从环状碳酸酯和苯酚生产高品质高性能芳族聚碳酸酯所需的高纯度碳酸二苯酯时，可以通过进行本发明的方法来实现上述目的，其中包括以下步骤：：（I）使用具有特定结构的反应性蒸馏塔生产碳酸二烷基酯和二醇; （II）使用两个具有特定结构的反应性蒸馏塔制备碳酸二苯酯，（III）使用高沸点材料分离塔A和碳酸二苯酯精制塔B从碳酸二苯酯得到高纯度碳酸二苯酯。

5. 发明申请

US20090137833A1 Process for industrially producing dialkyl carbonate and diol 有权
公开(公告)号：US20090137833A1
公开(公告)日：2009-05-28
申请号：US11991076
申请日：2006-11-17
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C69/96 , B01D3/04
CPC分类号： C07C68/065 , B01D3/32 , C07C29/128 , Y02P20/127 , Y02P20/52 , C07C69/96 , C07C31/202
摘要： It is an object of the present invention to provide a specific process that enables a dialkyl carbonate and a diol to be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively with high selectivity and high productivity stably for a prolonged period of time through a reactive distillation system of taking a cyclic carbonate and an aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into a continuous multi-stage distillation column in which a catalyst is present, and carrying out reaction and distillation simultaneously in the column. Although there have been many proposals regarding processes for the production of the dialkyl carbonate and the diol through the reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures whatsoever on a specific process or apparatus enabling mass production on an industrial scale. According to the present invention, there is provided a specific continuous multi-stage distillation column having a specified structure, and a production process using this continuous multi-stage distillation column, according to which the dialkyl carbonate and the diol can be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively each with a selectivity of not less than 95%, preferably not less than 97%, more preferably not less than 99%, stably for not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours.

6. 发明申请

US20090118530A1 Industrial Process for Production of Aromatic Carbonate 审中-公开
标题翻译：工业生产芳香族碳酸酯的工艺
公开(公告)号：US20090118530A1
公开(公告)日：2009-05-07
申请号：US11991473
申请日：2006-12-07
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C69/96 , C07C68/06
CPC分类号： C07C68/065 , C07C68/06 , Y02P20/127 , C07C69/96
摘要： It is an object of the present invention to provide a specific process that enables an aromatic carbonate required for producing a high-quality high-performance aromatic polycarbonate to be produced industrially in a large amount (e.g. not less than 1 ton/hr) stably for a prolonged period of time (e.g. not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours) from a cyclic carbonate and an aromatic monohydroxy compound. When producing an aromatic carbonate from a cyclic carbonate and an aromatic monohydroxy compound, the above object can be attained by carrying out a step of: (I) producing a dialkyl carbonate and a diol using a reactive distillation column having a specified structure, and (II) producing the an aromatic carbonate using a first reactive distillation column having a specified structure.
摘要翻译：本发明的一个目的是提供一种特别的方法，其能够使制造高品质高性能芳族聚碳酸酯所需的芳族碳酸酯在工业上大量（例如不小于1吨/小时）稳定地生产来自环状碳酸酯和芳族单羟基化合物的长时间（例如不小于1000小时，优选不小于3000小时，更优选不小于5000小时）。当从环状碳酸酯和芳族单羟基化合物制备芳族碳酸酯时，可以通过以下步骤来实现上述目的：（I）使用具有特定结构的反应性蒸馏塔制备碳酸二烷基酯和二醇，和（ II）使用具有特定结构的第一反应蒸馏塔生产芳族碳酸酯。

7. 发明申请

US20090030223A1 PROCESS FOR INDUSTRIALLY PRODUCING DIALKYL CARBONATE AND DIOL WITH HIGH YIELD 审中-公开
标题翻译：工业生产碳酸二乙酯和高铝合金的工艺
公开(公告)号：US20090030223A1
公开(公告)日：2009-01-29
申请号：US11991248
申请日：2006-12-06
申请人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hironori Miyaji , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： C07C69/96 , C07C31/20 , B01D3/14
CPC分类号： B01D3/009 , B01D3/32 , C07C68/065 , Y02P20/127 , C07C69/96
摘要： It is an object of the present invention to provide a solution by providing a specific process that enables a dialkyl carbonate and a diol to be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively with high selectivity and high productivity stably for a prolonged period of time through a reactive distillation system of taking a cyclic carbonate and an aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into a continuous multi-stage distillation column in which a catalyst is present, and carrying out reaction and distillation simultaneously in the column. Although there have been many proposals regarding processes for the production of the dialkyl carbonate and the diol through the reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures whatsoever on a specific process or apparatus enabling mass production on an industrial scale. According to the present invention, there are provided a specific continuous multi-stage distillation column having a specified structure, and a production process using this continuous multi-stage distillation column, in which the dialkyl carbonate and the diol can be produced on an industrial scale of not less than 2 ton/hr and not less than 1.3 ton/hr respectively each with a selectivity of not less than 95%, preferably not less than 97%, more preferably not less than 99%, stably for not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours.
摘要翻译：本发明的目的是通过提供一种能够以不低于2吨/小时并且不低于1.3吨/小时的工业规模生产碳酸二烷基酯和二醇的具体方法来提供溶液，通过以环状碳酸酯和脂肪族一元醇为起始原料的反应蒸馏系统，稳定地选择性高，生产稳定，连续地将原料进料到其中存在催化剂的连续多级蒸馏塔中并在柱中同时进行反应和蒸馏。虽然通过反应蒸馏法生产碳酸二烷基酯和二醇的方法有许多提案，但这些都是在规模小，操作时间短的实验室水平上，并没有公开任何关于具体方法或能够在工业规模上批量生产的设备。根据本发明，提供了具有特定结构的特定连续多级蒸馏塔和使用该连续多级蒸馏塔的生产方法，其中可以以工业规模生产碳酸二烷基酯和二醇不小于2吨/小时，不低于1.3吨/小时，选择性不低于1000小时，选择性不低于95％，优选不低于97％，更优选不低于99％优选为3000小时以上，更优选为5000小时以上。

8. 发明申请

US20080041712A1 Industrial Process For Production Of High-Purity Diphenyl Carbonate 有权
标题翻译：高纯度碳酸二苯酯生产工艺
公开(公告)号：US20080041712A1
公开(公告)日：2008-02-21
申请号：US11660362
申请日：2005-08-24
申请人： Shinsuke Fukuoka , Hiroshi Hachiya , Kazuhiko Matsuzaki , Hironori Miyaji
发明人： Shinsuke Fukuoka , Hiroshi Hachiya , Kazuhiko Matsuzaki , Hironori Miyaji
IPC分类号： B01D3/14 , C07C33/00
CPC分类号： B01D3/143 , B01D3/009 , C07C68/06 , C07C68/08 , Y02P20/127 , C07C69/96
摘要： It is an object of the present invention to provide a specific process that enables a high-purity diphenyl carbonate that can be used as a raw material of a high-quality and high-performance polycarbonate to be produced stably for a prolonged period of time on an industrial scale of not less than 1 ton/hr from a reaction mixture containing a catalyst and reaction by-products that has been obtained through transesterification reaction and the like using a dialkyl carbonate and a phenol as a starting material. Although there have been various proposals regarding processes for the production of reaction mixtures containing aromatic carbonates by means of a reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures on a specific process or apparatus enabling mass production on an industrial scale from such a reaction mixture to a high-purity diphenyl carbonate that can be used as a raw material of a high-quality and high-performance polycarbonate. According to the present invention, there are provided a high boiling point material separating column A and a diphenyl carbonate purifying column B each comprising a continuous multi-stage distillation column having specified structures, and there is provided a specific process that enables a high-purity diphenyl carbonate which is important as a raw material of a high-quality and high-performance polycarbonate to be produced stably for a prolonged period of time on an industrial scale of not less than 1 ton/hr from a reaction mixture containing the diphenyl carbonate using an apparatus in which these two continuous multi-stage distillation columns are connected together.
摘要翻译：本发明的目的是提供一种具体方法，其能够将高纯度碳酸二苯酯用作高质量和高性能聚碳酸酯的原料，以在较长时间内稳定地制备，从含有催化剂的反应混合物和通过酯交换反应等获得的反应副产物使用碳酸二烷基酯和苯酚作为起始原料的工业规模不低于1吨/小时。虽然已经有关于通过反应蒸馏法生产含有芳族碳酸酯的反应混合物的方法的各种建议，但是这些方法都已经在小规模和操作时间短的实验室水平上，并且没有公开具体方法或能够从这种反应混合物到能够用作高质量和高性能聚碳酸酯的原料的高纯度碳酸二苯酯在工业规模上批量生产的装置。根据本发明，提供了一种分离塔A和碳酸二苯酯精制塔B的高沸点物质，它们均包含具有特定结构的连续多级蒸馏塔，并且提供了能够获得高纯度碳酸二苯酯作为高质量，高性能的聚碳酸酯的原料，以不低于1吨/小时的工业规模从含有碳酸二苯酯的反应混合物中长时间稳定地制备而成，其使用这两个连续多级蒸馏塔连接在一起的装置。

9. 发明申请

US20080017325A1 Industrial Evaporation Apparatus 审中-公开
标题翻译：工业蒸发仪
公开(公告)号：US20080017325A1
公开(公告)日：2008-01-24
申请号：US11667624
申请日：2005-12-12
申请人： Shinsuke Fukuoka , Hiroshi Hachiya , Kazuhiko Matsuzaki
发明人： Shinsuke Fukuoka , Hiroshi Hachiya , Kazuhiko Matsuzaki
IPC分类号： B01D1/00
CPC分类号： C08G63/90 , B01D1/22 , C08G64/406
摘要： It is an object of the present invention, in the case of an apparatus in which a liquid containing material having a lower boiling point than that of the liquid is made to flow down along external surfaces of guides, during which time the low boiling point material is evaporated, to provide a specific apparatus that can be operated stably for a prolonged period of time on an industrial scale such that not less than 1 ton/hr of the liquid is produced through the evaporation, and furthermore to provide a specific industrial evaporation apparatus in which there are no problems due to degeneration caused by some of the liquid residing in the apparatus for a prolonged period of time. The present inventors have reached to the present invention upon discovering that the above object can be attained, and a high-quality and high-purity concentrated liquid or condensation polymer or thermoplastic polymer can easily be obtained, by using an industrial evaporation apparatus having a specified structure in which there are guides that do not themselves have a heat source, a flow path controlling member having a function of making the liquid fed onto a perforated plate from a liquid receiving port flow mainly from a peripheral portion toward a middle portion of the perforated plate is installed in a liquid feeding zone, the distance K (cm) between an internal wall of a side-wall casing of an evaporation zone and the guide closest to the internal wall is in a specified range, and formulae (1) to (5), preferably formulae (1) to (11), more preferably formulae (1) to (14), are satisfied.
摘要翻译：本发明的目的在于，使具有比液体沸点低的液体的液体的材料沿引导件的外表面向下流动的装置的情况下，在该时间内，低沸点材料蒸发，提供可以在工业规模下稳定运行的特定装置，使得通过蒸发产生不少于1吨/小时的液体，并且还提供特定的工业蒸发装置其中由于长时间在该设备中滞留的一些液体引起的退化，不存在问题。本发明人在发现可以实现上述目的的本发明已达到本发明，通过使用具有规定的工业蒸发装置，可以容易地获得高质量和高纯度的浓缩液体或缩聚物或热塑性聚合物具有本身不具有热源的导向件的结构，具有使从液体接收口供给到多孔板上的液体主要从周边部朝向穿孔的中间部分流动的功能的流路控制构件板被安装在供液区域中，蒸发区域的侧壁壳体的内壁与最靠近内壁的导轨之间的距离K（cm）在规定范围内，式（1）至（ 5），优选式（1）〜（11），更优选式（1）〜（14）。

10. 发明授权

US07304292B2 Displacement sensor having a phase variation of an impedance 失效
标题翻译：具有阻抗相位变化的位移传感器
公开(公告)号：US07304292B2
公开(公告)日：2007-12-04
申请号：US11188602
申请日：2005-07-25
申请人： Tsuyoshi Nakamoto , Norihisa Shibayama , Masakazu Matsui , Kazuhiko Matsuzaki
发明人： Tsuyoshi Nakamoto , Norihisa Shibayama , Masakazu Matsui , Kazuhiko Matsuzaki
IPC分类号： H01J40/14
CPC分类号： G01D3/036 , G01D5/2013
摘要： A displacement sensor comprising: a detecting portion including a coil arranged in such manner that a relative position to a magnetic response substance varies in correspondence to a displacement of an object to be measured; an oscillating circuit to supply an alternating-current signal with a prescribed frequency to the detecting portion; an externally attached circuit connected to the detecting portion; and a displacement detecting means to detect the displacement of the object to be measured based on an amount of phase variation of an impedance in the detecting portion and the externally attached circuit, wherein parameters of the externally attached circuit are set in such manner that the amount of the phase variation by the displacement becomes larger than the amount of the phase variation by temperature variation.
摘要翻译： 1.一种位移传感器，包括：检测部，其包括线圈，所述线圈以使得与磁性响应物质的相对位置对应于待测量物体的位移而变化的方式布置; 振荡电路，用于向所述检测部分提供具有规定频率的交流信号; 连接到检测部分的外部附接电路; 以及位移检测装置，用于基于检测部分和外部附接电路中的阻抗的相位变化量来检测被测量物体的位移，其中外部附加电路的参数被设定为使得量通过位移的相位变化大于通过温度变化的相位变化量。

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