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    • 4. 发明授权
    • Method for the preparation of .beta.-ketothioamide compound
    • β-酮硫代酰胺化合物的制备方法
    • US5677444A
    • 1997-10-14
    • US530402
    • 1995-09-15
    • Tohru TsuchiyaIsao ShibuyaYoichi TaguchiAkihiro OishiKazumasa Honda
    • Tohru TsuchiyaIsao ShibuyaYoichi TaguchiAkihiro OishiKazumasa Honda
    • C07D223/08C07C327/42C07C327/44C07D223/02C07D223/06C07D225/02
    • C07C327/44C07C327/42C07D223/06C07D225/02
    • A novel and simple method is proposed for the synthetic preparation of an N,N-disubstituted .beta.-ketothioamide compound represented by the general formula R.sup.1 R.sup.2 N--CS--CH.sub.2 --CO--R.sup.3, in which R.sup.1 and R.sup.2 are each a monovalent hydrocarbon group or each a divalent hydrocarbon group jointly forming a cyclic structure together with the nitrogen atom and R.sup.3 is a hydrogen atom, a monovalent hydrocarbon group or a divalent hydrocarbon group forming a cyclic structure jointly with R.sup.1, R.sup.1 being a divalent hydrocarbon group and R.sup.2 being a monovalent hydrocarbon group. The method comprises:(a) mixing an N,N-disubstituted amide compound represented by the general formula R.sup.1 R.sup.2 N--CO--R.sup.3, and a bis(trialkylsilyl)thioketene compound represented by the general formula (R.sub.3 Si).sub.2 C.dbd.C.dbd.S, in which each R is an alkyl group, to effect an addition reaction therebetween forming an intermediate compound; and (b) dissolving the intermediate compound obtained in step (a) in an alcohol.
    • 提出了一种简单的方法,用于合成制备由通式R 1 R 2 N-CS-CH 2 -CO-R 3表示的N,N-二取代的β-酮硫代酰胺化合物,其中R 1和R 2各自是一价烃基, 二价烃基与氮原子一起形成环状结构,R 3为氢原子,一价烃基或二价烃基,与R 1一起形成环状结构,R 1为二价烃基,R 2为一价烃基 。 该方法包括:(a)将由通式R 1 R 2 N -CO-R 3表示的N,N-二取代酰胺化合物和由通式(R3Si)2C = C = S表示的双(三烷基甲硅烷基)硫代烯酮化合物混合,其中 每个R是烷基,以形成中间体化合物之间的加成反应; 和(b)将步骤(a)中获得的中间体化合物溶解在醇中。
    • 9. 发明授权
    • Image coding apparatus and image coding method
    • 图像编码装置和图像编码方法
    • US09066100B2
    • 2015-06-23
    • US13602561
    • 2012-09-04
    • Akihiro Oishi
    • Akihiro Oishi
    • H04N11/04H04N19/136H04N19/103H04N19/107
    • H04N19/136H04N19/103H04N19/107
    • At least one exemplary embodiment is directed to an image coding apparatus configured to encode moving image data including: a coding unit configured to encode each picture in the moving image data in a unit of a first block; a luminance change detection unit configured to divide the moving image data into a plurality of second blocks and to detect a luminance change block in which a luminance change occurred from the plurality of the second blocks in one picture; and a code amount adjustment unit configured to increase an amount of code allocated to the first block if the first block corresponds to the luminance change block detected by the luminance change detection unit.
    • 至少一个示例性实施例涉及被配置为对运动图像数据进行编码的图像编码装置,包括:编码单元,被配置为以第一块为单位对运动图像数据中的每个图像进行编码; 亮度变化检测单元,被配置为将运动图像数据划分成多个第二块,并且检测在一个图像中从多个第二块发生亮度变化的亮度变化块; 以及代码量调整单元,被配置为如果第一块对应于由亮度变化检测单元检测的亮度变化块,则增加分配给第一块的代码量。