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    • 3. 发明申请
    • Inorganically Coated Synthetic Body, Method for Producing the Same and Its Use
    • 无机涂层合成体,其生产方法及其用途
    • US20080032124A1
    • 2008-02-07
    • US11572716
    • 2005-07-09
    • Patrick BeckerRolf NeebGhirmay Seyoum
    • Patrick BeckerRolf NeebGhirmay Seyoum
    • C08J5/00B29C37/00C08J7/06C09D1/00
    • B29C37/0032C08J5/00C09D1/00C09D5/24Y10T428/265Y10T428/31667
    • The invention relates to a method for producing a synthetic body from a synthetic material obtained by radical polymerization, which is coated on one or several sides with an Si-containing or inorganic substance. According to the inventive method, a substrate is coated with a lacquer composition which contains inorganic particles dissolved in a solvent which may optionally also contain a flow-control agent. One or more substrates that are coated in this manner can be used to construct a polymerization chamber, the coated sides facing the interior of the chamber. After radical polymerization of a monomer mixture in the presence of a polymerization initiator and a separating agent mixture the inward inorganic coating is transferred from the substrate to or onto the surfaces of the radically polymerized synthetic material or the corresponding synthetic body. The invention also relates to the corresponding synthetic bodies and their uses and to the use of the separating agent mixture in the polymerization casting method.
    • 本发明涉及一种通过自由基聚合得到的合成材料的制造方法,该合成材料用含Si或无机物质涂覆在一面或几面上。 根据本发明的方法,用含有溶解在可任选还含有流动控制剂的溶剂中的无机颗粒的漆组合物涂覆基材。 以这种方式涂覆的一个或多个基材可用于构建聚合室,涂覆的侧面朝向室的内部。 在聚合引发剂和分离剂混合物存在下,单体混合物自由基聚合后,向内的无机涂层从基材转移到基体聚合的合成材料或相应合成物的表面上或表面上。 本发明还涉及相应的合成物及其用途以及在聚合浇铸法中使用分离剂混合物。
    • 5. 发明申请
    • Coating agents and plastic body with an antigraffiti effect and method for the production thereof
    • 涂布剂和具有防刮擦效果的塑料体及其制造方法
    • US20070172673A1
    • 2007-07-26
    • US10555772
    • 2004-03-25
    • Patrick BeckerThomas HasskerlRolf NeebGhirmay SeyoumReiner Lingelbach
    • Patrick BeckerThomas HasskerlRolf NeebGhirmay SeyoumReiner Lingelbach
    • B32B9/04C09D5/00
    • C08G77/24C08J7/047C08J2483/00Y10T428/31663
    • The invention relates to coating agents having an antigraffiti effect. Said coating agents can be obtained according to a method consisting in condensing the organic silicon compounds of general formula (I): R1nSIX4-n, wherein R1 represents a group comprising 1-20 carbon atoms, X represents an alkoxy radical having 1-20 carbon atoms or halogen and n represents an even number between 0-3. The different radicals X or R1 can be identical or different and/or the precondensates can be obtained from said components. At least 50 wt. % of the silicon compounds, in relation to the total weight of the used silicon compounds, is represented by the formula R1SiX3, wherein R1 and X have the above-cited meaning, in order to form polysiloxanes until the ratio of signals R1SiO(OH) and signals R1SiO1,5 measured by NMR-spectroscopy ranges from 0.6-4, and by adding compounds of formula (II) (R″)uSi(R′)t(OR)(4-t-u) to said polysiloxane mixture, wherein R represents a group comprising 1-20 carbon atoms having at least 3 fluoro atoms. U is 1 or 2 and t is 0 or 1, R and R′ are identical or different and represent a group comprising 1-20 carbon atoms. The also relates to plastic bodies which have coating which can be obtained by means of the coating agents.
    • 本发明涉及具有防刮涂作用的包衣剂。 所述包衣剂可以根据通式(I)的有机硅化合物缩合的方法获得:R 1,N 2,S 4,N 4, 其中R 1表示包含1-20个碳原子的基团,X表示具有1-20个碳原子的烷氧基或卤素,n表示0-3之间的偶数。 不同的基团X或R 1可以相同或不同,和/或可以从所述组分获得预缩合物。 至少50wt。 相对于所使用的硅化合物的总重量,硅化合物的百分比由式R 1 SiX 3 N表示,其中R 1, SUP>和X具有上述含义,为了形成聚硅氧烷,直到信号R 1 SiO(OH)和信号R 1 SiO 2的比例 ,通过NMR光谱测量的5 范围为0.6-4,并且通过加入式(II)(R“)的化合物(R”)Si(R') (OR)(4-tu))与所述聚硅氧烷混合物,其中R表示含有至少3个氟原子的1-20个碳原子的基团。 U为1或2,t为0或1,R和R'相同或不同,表示1-20个碳原子的基团。 也涉及具有可以通过涂布剂获得的涂层的塑料体。
    • 6. 发明申请
    • Coating Agents for Producing Formable, Scratch and Soiling-Resistant Coatings, Scratch-Resistant, Formable and Soiling-Resistant Shaped Bodies and a Method for the Production Thereof
    • 用于生产可成型,耐划伤和耐污染的涂层,耐划伤,耐成型和耐腐蚀的成形体的涂层剂及其生产方法
    • US20080139690A1
    • 2008-06-12
    • US11814082
    • 2005-12-10
    • Patrick BeckerRolf NeebGhirmay Seyoum
    • Patrick BeckerRolf NeebGhirmay Seyoum
    • C08K5/101C08F2/46
    • C09D133/14
    • The present invention relates to coating compositions for producing formable scratchproof coatings with dirt repellency effect, comprising A) from 1% by weight to 30% by weight of a prepolymer obtainable by free-radically polymerizing a mixture comprising A1) from 1 to 10 parts by weight of at least one sulphur compound containing at least 3 thiol groups and A2) from 90 to 99 parts by weight of alkyl (meth)acrylates, B) from 0.2% by weight to 10% by weight of at least one fluoroalkyl (meth)acrylate having 6 to 60 carbon atoms in the alcohol residue and including 13 to 121 fluorine atoms, C) from 20% by weight to 80% by weight of polyfunctional (meth)acrylates, D) from 0.01% by weight to 10% by weight of at least one initiator E) from 2% by weight to 75% by weight of at least one diluent and F) from 0% by weight to 40% by weight of customary additives G) from 0.01% by weight to 10% by weight of 2,2,3,3-tetrafluoropropyl methacrylate. Additionally disclosed are scratchproof/formable and dirt-repellent mouldings comprising a polymeric substrate and a scratchproof coating.
    • 本发明涉及用于生产具有防污效果的可成形防刮涂层的涂料组合物,其包含A)1重量%至30重量%的预聚物,所述预聚物可通过将包含A1)1至10份的混合物自由基聚合 至少一种含至少3个硫醇基的硫化合物的重量,和A2)90-99重量份的(甲基)丙烯酸烷基酯,B)0.2重量%-10重量%的至少一种(甲基) 丙烯酸酯在醇残基中含有6〜60个碳原子,含有13〜121个氟原子,C)20重量%〜80重量%的多官能(甲基)丙烯酸酯,D)0.01重量%〜10重量% 的至少一种引发剂E)2重量%至75重量%的至少一种稀释剂和F)0重量%至40重量%的常规添加剂G),0.01重量%至10重量% 的2,2,3,3-四氟丙基甲基丙烯酸酯。 另外公开了包括聚合物基材和防刮涂层的防刮/可成形和防污模制品。
    • 8. 发明授权
    • Method for the production of anti-statically coated moulded body
    • 抗静电涂层成型体的制造方法
    • US07608306B2
    • 2009-10-27
    • US10548878
    • 2004-03-02
    • Thomas HasskerlStipan KatusicPatrick BeckerRolf NeebGhirmay Seyoum
    • Thomas HasskerlStipan KatusicPatrick BeckerRolf NeebGhirmay Seyoum
    • C08F2/46C09D4/00
    • C09D5/24Y10T428/31511
    • A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and optionally a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated [sic] in a manner known per se and the lacquer cured.
    • 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法,该漆系统由粘合剂或粘合剂混合物,任选的溶剂或溶剂混合物,任选的其它通常在漆系统中的添加剂 并且任选地是增稠剂,并且这里可以使用0-20%含量的聚合物增稠剂和0至40%含量的低聚增稠剂,在每种情况下基于干膜(组分a,c,d,e), 5至500重量份,基于a),中值一次粒径为1至80nm,百分比聚集度为0.01至99%的导电金属氧化物粉末为5至500个 基于a),以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。
    • 9. 发明申请
    • Method for producing an antistatically coated molded body
    • 抗静电涂层成型体的制造方法
    • US20070098884A1
    • 2007-05-03
    • US10578568
    • 2004-08-06
    • Thomas HasskerlPatrick BeckerRolf NeebGhirmay Seyoum
    • Thomas HasskerlPatrick BeckerRolf NeebGhirmay Seyoum
    • B05D3/02B05D1/12
    • C08J7/047C09D5/24
    • A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated in a manner known per se and the lacquer cured.
    • 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法,该漆系统由粘合剂或粘合剂混合物,任选的溶剂或溶剂混合物,任选的其它通常在漆系统中的添加剂 和增稠剂,并且这里可以使用0-20%含量的聚合物增稠剂和0至40%含量的低聚增稠剂,在每种情况下基于干膜(组分a,c,d,e),来自 5至500重量份,基于a),中值一次粒径为1至80nm,百分比聚集度为0.01至99%的导电金属氧化物粉末为5至500份, 重量,基于a),以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。
    • 10. 发明申请
    • Anti-statically coated moulded body and method for the production thereof
    • 抗静电涂层成型体及其制造方法
    • US20060157675A1
    • 2006-07-20
    • US10548878
    • 2004-03-02
    • Thomas HasskerlStipan KatusicPatrick BeckerRolf NeebGhirmay Seyoum
    • Thomas HasskerlStipan KatusicPatrick BeckerRolf NeebGhirmay Seyoum
    • H01B1/12
    • C09D5/24Y10T428/31511
    • A process is described for producing mouldings from plastics by coating a moulding on one or more sides with a lacquer system, the lacquer system being composed of a binder or a binder mixture, optionally a solvent or solvent mixture, optionally other additives usual in lacquer systems and optionally a thickener, and use can be made here of polymeric thickeners at from 0 to 20% content and oligomeric thickeners at from 0 to 40% content, in each case based on dry film (components a, c, d, e), from 5 to 500 parts by weight, based on a), of an electrically conductive metal oxide powder with a median primary particle size of from 1 to 80 nm and a percentage degree of aggregation of from 0.01 to 99%, from 5 to 500 parts by weight, based on a), of inert nanoparticles coated [sic] in a manner known per se and the lacquer cured.
    • 描述了一种用于通过在一个或多个侧面上用漆系统涂覆模制品来从塑料制造模制品的方法,该漆系统由粘合剂或粘合剂混合物,任选的溶剂或溶剂混合物,任选的其它通常在漆系统中的添加剂 并且任选地是增稠剂,并且这里可以使用0-20%含量的聚合物增稠剂和0至40%含量的低聚增稠剂,在每种情况下基于干膜(组分a,c,d,e), 5至500重量份,基于a),中值一次粒径为1至80nm,百分比聚集度为0.01至99%的导电金属氧化物粉末为5至500个 基于a),以本身已知的方式涂覆的惰性纳米颗粒和固化的漆。