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1. 发明申请

WO2011050204A3 NUCLEATION AND GROWTH OF TIN PARTICLES INTO THREE DIMENSIONAL COMPOSITE ACTIVE ANODE FOR LITHIUM HIGH CAPACITY ENERGY STORAGE DEVICE 审中-公开
标题翻译：用于锂高容量储能装置的三维复合活性阳极中的细颗粒的生成和生长
公开(公告)号：WO2011050204A3
公开(公告)日：2011-09-09
申请号：PCT/US2010053613
申请日：2010-10-21
申请人： APPLIED MATERIALS INC , LOPATIN SERGEY D , BREVNOV DMITRI A , WANG CONNIE P , BACHRACH ROBERT Z
发明人： LOPATIN SERGEY D , BREVNOV DMITRI A , WANG CONNIE P , BACHRACH ROBERT Z
IPC分类号： H01M4/04 , B82B3/00 , C23C2/00 , H01M4/38 , H01M10/0525
CPC分类号： H01M4/80 , C25D3/32 , C25D5/10 , C25D7/0614 , C25D17/28 , H01M4/13 , H01M4/139 , H01M4/364 , H01M4/661 , H01M4/666 , H01M4/667 , H01M4/70 , H01M10/0525 , H01M10/0566
摘要： Embodiments of the present invention generally relate to lithium-ion batteries, and more specifically, to a system and method for fabricating such batteries using thin-film processes that form three-dimensional structures. In one embodiment, an anodic structure used to form an energy storage device is provided. The anodic structure comprises a flexible conductive substrate, a plurality of conductive microstructures formed on the conductive substrate, comprising a plurality of columnar projections and dendritic structures formed over the plurality of columnar projections and a plurality of tin particles formed on the plurality of conductive microstructures. In another embodiment, the anodic structure further comprises a tin nucleation layer comprising tin particles formed on the flexible conductive substrate between the flexible conductive substrate and the plurality of conductive microstructures.
摘要翻译：本发明的实施方案一般涉及锂离子电池，更具体地，涉及使用形成三维结构的薄膜工艺制造这种电池的系统和方法。在一个实施例中，提供了用于形成能量存储装置的阳极结构。阳极结构包括柔性导电基板，形成在导电基板上的多个导电微结构，包括形成在多个柱状突起上的多个柱状突起和树枝状结构以及形成在多个导电微结构上的多个锡颗粒。在另一个实施方案中，阳极结构还包括锡成核层，其包含形成在柔性导电基底上的锡颗粒在柔性导电基底和多个导电微结构之间。

2. 发明申请

WO2010098977A3 THIN FILM ELECTROCHEMICAL ENERGY STORAGE DEVICE WITH THREE-DIMENSIONAL ANODIC STRUCTURE 审中-公开
标题翻译：具有三维阳极结构的薄膜电化学能量储存装置
公开(公告)号：WO2010098977A3
公开(公告)日：2011-01-20
申请号：PCT/US2010023640
申请日：2010-02-09
申请人： APPLIED MATERIALS INC , LOPATIN SERGEY D , BREVNOV DMITRI A , BACHRACH ROBERT Z
发明人： LOPATIN SERGEY D , BREVNOV DMITRI A , BACHRACH ROBERT Z
IPC分类号： H01M4/133 , H01M2/16 , H01M4/04 , H01M4/66 , H01M10/0525
CPC分类号： H01M10/0585 , C25D1/00 , C25D1/006 , H01M2/1653 , H01M2/1686 , H01M4/0428 , H01M4/133 , H01M4/1393 , H01M4/364 , H01M4/587 , H01M4/667 , H01M4/70 , H01M6/40 , H01M10/0525 , H01M10/0565 , H01M10/0566 , H01M10/058
摘要： A method for forming a battery from via thin-film deposition processes is disclosed. A mesoporous carbon material is deposited onto a surface of a conductive substrate that has high surface area, conductive micro-structures formed thereon. A porous, dielectric separator layer is then deposited on the layer of mesoporous carbon material to form a half cell of an energy storage device. The mesoporous carbon material is made up of CVD-deposited carbon fullerene "onions" and carbon nano-tubes, and has a high porosity capable of retaining lithium ions in concentrations useful for storing significant quantities of electrical energy. Embodiments of the invention further provide for the formation of an electrode having a high surface area conductive region that is useful in a battery structure. In one configuration the electrode has a high surface area conductive region comprising a porous dendritic structure that can be formed by electroplating, physical vapor deposition, chemical vapor deposition, thermal spraying, and/or electroless plating techniques.
摘要翻译：公开了一种通过薄膜沉积工艺形成电池的方法。在其上形成有高表面积的导电微结构的导电性基板的表面上沉积介孔碳材料。然后将多孔介电分离器层沉积在介孔碳材料层上以形成储能装置的半电池。中孔碳材料由CVD沉积的碳富勒烯“洋葱”和碳纳米管组成，并且具有能够将锂离子保留在用于储存大量电能的浓度的高孔隙率。本发明的实施例还提供了一种用于电池结构的具有高表面积导电区域的电极的形成。在一种配置中，电极具有高的表面积导电区域，其包括通过电镀，物理气相沉积，化学气相沉积，热喷涂和/或化学镀技术形成的多孔树枝状结构。

3. 发明申请

WO2010090956A3 POROUS THREE DIMENSIONAL COPPER, TIN, COPPER-TIN, COPPER-TIN-COBALT, AND COPPER-TIN-COBALT-TITANIUM ELECTRODES FOR BATTERIES AND ULTRA CAPACITORS 审中-公开
标题翻译：用于电池和超级电容器的多孔三维铜，锡，铜 - 锡，铜 - 锡 - 钴和铜 - 锡 - 钴 - 钛电极
公开(公告)号：WO2010090956A3
公开(公告)日：2010-11-11
申请号：PCT/US2010022597
申请日：2010-01-29
申请人： APPLIED MATERIALS INC , LOPATIN SERGEY D , BREVNOV DMITRI A , BACHRACH ROBERT Z
发明人： LOPATIN SERGEY D , BREVNOV DMITRI A , BACHRACH ROBERT Z
IPC分类号： H01M4/04 , H01G9/042 , H01G11/26 , H01G11/28 , H01G11/30 , H01G11/50 , H01G11/68 , H01G11/70 , H01G11/86 , H01M4/485 , H01M4/583 , H01M4/66 , H01M10/0525
CPC分类号： H01M4/02 , C25D3/30 , C25D3/38 , C25D3/58 , C25D3/60 , C25D17/00 , C25D17/10 , H01G11/26 , H01G11/28 , H01G11/30 , H01G11/50 , H01G11/68 , H01G11/70 , H01G11/86 , H01M4/134 , H01M4/139 , H01M4/38 , H01M4/387 , H01M4/661 , H01M4/662 , H01M4/70 , H01M10/0525 , H01M2004/025 , Y02E60/13
摘要： A method and apparatus for forming a reliable and cost efficient battery or electrochemical capacitor electrode structure that has an improved lifetime, lower production costs, and improved process performance are provided. In one embodiment a method for forming a three dimensional porous electrode for a battery or an electrochemical cell is provided. The method comprises depositing a columnar metal layer over a substrate at a first current density by a diffusion limited deposition process and depositing three dimensional metal porous dendritic structures over the columnar metal layer at a second current density greater than the first current density.
摘要翻译：提供了一种用于形成具有改善的使用寿命，较低的生产成本和改进的工艺性能的可靠且具有成本效益的电池或电化学电容器电极结构的方法和装置。在一个实施方案中，提供了用于形成电池或电化学电池的三维多孔电极的方法。该方法包括通过扩散限制沉积工艺以第一电流密度在衬底上沉积柱状金属层，并且以大于第一电流密度的第二电流密度在柱状金属层上沉积三维金属多孔树状结构。

4. 发明申请

WO2011008539A2 PASSIVATION FILM FOR SOLID ELECTROLYTE INTERFACE OF THREE DIMENSIONAL COPPER CONTAINING ELECTRODE IN ENERGY STORAGE DEVICE 审中-公开
标题翻译：储能装置中三维含铜电极固体电解质界面钝化膜
公开(公告)号：WO2011008539A2
公开(公告)日：2011-01-20
申请号：PCT/US2010040385
申请日：2010-06-29
申请人： APPLIED MATERIALS INC , LOPATIN SERGEY D , BREVNOV DMITRI A , BABAYANTS RUBEN , BACHRACH ROBERT Z
发明人： LOPATIN SERGEY D , BREVNOV DMITRI A , BABAYANTS RUBEN , BACHRACH ROBERT Z
IPC分类号： H01M10/0525 , C23C14/00 , H01B1/02 , H01M2/14 , H01M4/04
CPC分类号： H01M4/66 , C25D3/38 , C25D7/0614 , C25D17/00 , H01M2/1653 , H01M2/1673 , H01M4/0438 , H01M4/0452 , H01M4/133 , H01M4/1393 , H01M4/62 , H01M4/661 , H01M4/664 , H01M4/667 , Y02E60/13 , Y02P20/133
摘要： A system and method for fabricating lithium-ion batteries using thin-film deposition processes that form three-dimensional structures is provided. In one embodiment, an anodic structure used to form an energy storage device is provided. The anodic structure comprises a conductive substrate, a plurality of conductive microstructures formed on the substrate, a passivation film formed over the conductive microstructures, and an insulative separator layer formed over the conductive microstructures, wherein the conductive microstructures comprise columnar projections.
摘要翻译：提供了一种使用形成三维结构的薄膜沉积工艺来制造锂离子电池的系统和方法。在一个实施例中，提供了用于形成能量存储装置的阳极结构。所述阳极结构包括导电基板，形成于所述基板上的多个导电微结构，形成于所述导电微结构上方的钝化膜以及形成于所述导电微结构上方的绝缘隔离层，其中所述导电微结构包括柱状突起。

5. 发明申请

WO2010091405A3 METROLOGY METHODS AND APPARATUS FOR NANOMATERIAL CHARACTERIZATION OF ENERGY STORAGE ELECTRODE STRUCTURES 审中-公开
标题翻译：能量储存电极结构的纳米材料特征的计量方法和装置
公开(公告)号：WO2010091405A3
公开(公告)日：2010-12-09
申请号：PCT/US2010023630
申请日：2010-02-09
申请人： APPLIED MATERIALS INC , LOPATIN SERGEY D , BREVNOV DMITRI A , CASAVANT ERIC , BACHRACH ROBERT Z
发明人： LOPATIN SERGEY D , BREVNOV DMITRI A , CASAVANT ERIC , BACHRACH ROBERT Z
IPC分类号： H01G4/005
CPC分类号： C25D5/18 , H01G11/26 , H01G11/30 , H01G11/50 , H01G11/86 , H01M4/0438 , H01M4/0452 , H01M4/1395 , Y02E60/13
摘要： Embodiments described herein generally relate to methods and apparatus for forming an electrode structure used in an energy storage device. More particularly, embodiments described herein relate to methods and apparatus for characterizing nanomaterials used in forming high capacity electrode structures for energy storage devices. In one embodiment a process for forming an electrode structure for an energy storage device is provided. The process comprises depositing a columnar metal structure over a substrate at a first current density by a diffusion limited deposition process, measuring a capacitance of the columnar metal structure to determine a surface area of the columnar metal structure, and depositing three dimensional porous metal structures over the columnar metal structure at a second current density greater than the first current density.
摘要翻译：本文描述的实施例一般涉及用于形成在能量存储装置中使用的电极结构的方法和装置。更具体地，本文描述的实施例涉及用于表征用于形成能量存储装置的高容量电极结构的纳米材料的方法和装置。在一个实施例中，提供了一种用于形成用于能量存储装置的电极结构的方法。该方法包括通过扩散限制沉积工艺在第一电流密度的衬底上沉积柱状金属结构，测量柱状金属结构的电容以确定柱状金属结构的表面积，并将三维多孔金属结构沉积在所述柱状金属结构的第二电流密度大于所述第一电流密度。

6. 发明申请

WO2012036908A2 SPRAY DEPOSITION MODULE FOR AN IN-LINE PROCESSING SYSTEM 审中-公开
标题翻译：用于在线处理系统的喷涂沉积模块
公开(公告)号：WO2012036908A2
公开(公告)日：2012-03-22
申请号：PCT/US2011049984
申请日：2011-08-31
申请人： APPLIED MATERIALS INC , BACHRACH ROBERT Z , WANG CONNIE P , LOPATIN SERGEY D , BOLANDI HOOMAN , BABAYANTS RUBEN , BROWN KARL M , KUTNEY MICHAEL C , OLGADO DONALD J K
发明人： BACHRACH ROBERT Z , WANG CONNIE P , LOPATIN SERGEY D , BOLANDI HOOMAN , BABAYANTS RUBEN , BROWN KARL M , KUTNEY MICHAEL C , OLGADO DONALD J K
IPC分类号： H01M4/04 , B05C5/02 , B05D1/26 , H01M10/04 , H01M10/052
CPC分类号： H01M4/0419 , H01M10/0404
摘要： In one embodiment, an apparatus for simultaneously depositing an anodically or cathodically active material on opposing sides of a flexible conductive substrate is provided. The apparatus comprises a chamber body defining one or more processing regions in which a flexible conductive substrate is exposed to a dual sided spray deposition process, wherein each of the one or more processing regions are further divided into a first spray deposition region and a second spray deposition region for simultaneously spraying an anodically active or cathodically active material onto opposing sides of a portion of the flexible conductive substrate, wherein each of the first and second spray deposition regions comprise a spray dispenser cartridge for delivering the activated material toward the flexible conductive substrate and a movable collection shutter.
摘要翻译：在一个实施例中，提供了一种用于在柔性导电衬底的相对侧上同时沉积阳极或阴极活性材料的装置。该设备包括限定一个或多个处理区域的腔室主体，其中柔性导电基板暴露于双面喷射沉积工艺，其中一个或多个处理区域中的每一个进一步分成第一喷射沉积区域和第二喷射用于将阳极活性材料或阴极活性材料同时喷射到柔性导电基底的一部分的相对侧上，其中第一和第二喷射沉积区中的每一个包括用于将活化材料输送到柔性导电基底的喷射分配器盒，以及可移动的收集快门。

7. 发明申请

WO2012118840A2 MANUFACTURING OF HIGH CAPACITY PRISMATIC LITHIUM-ION ALLOY ANODES 审中-公开
标题翻译：高容量棱柱状锂离子合金阳极的制造
公开(公告)号：WO2012118840A2
公开(公告)日：2012-09-07
申请号：PCT/US2012026991
申请日：2012-02-28
申请人： APPLIED MATERIALS INC , LOPATIN SERGEY D , BREVNOV DIMITRI , LIU ERIC H , BACHRACH ROBERT Z , WANG CONNIE P
发明人： LOPATIN SERGEY D , BREVNOV DIMITRI , LIU ERIC H , BACHRACH ROBERT Z , WANG CONNIE P
IPC分类号： H01M4/13 , H01M4/139 , H01M4/64 , H01M10/052
CPC分类号： H01M4/626 , H01M4/02 , H01M4/0404 , H01M4/0419 , H01M4/0452 , H01M4/134 , H01M4/1395 , H01M4/364 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/587 , H01M4/625 , H01M4/64 , H01M4/661 , H01M10/0525 , H01M2004/021 , H01M2004/027 , Y02E60/122 , Y02P70/54
摘要： High capacity energy storage devices and energy storage device components, and more specifically, to a system and method for fabricating such high capacity energy storage devices and storage device components using processes that form three-dimensional porous structures are provided. In one embodiment, an anode structure for use in a high capacity energy storage device, comprising a conductive collector substrate, a three-dimensional copper-tin-iron porous conductive matrix formed on one or more surfaces of the conductive collector substrate, comprising a plurality of meso-porous structures formed over the conductive current collector, and an anodically active material deposited over the three-dimensional copper-tin-iron porous conductive matrix is provided. In certain embodiments, the three-dimensional copper-tin-iron porous conductive matrix further comprises a plurality of columnar projections formed on the conductive current collector with the plurality of meso-porous structure formed on the plurality of columnar projections.
摘要翻译：高容量能量存储装置和能量存储装置部件，并且更具体地涉及用于使用形成三维多孔结构的工艺来制造这种高容量能量存储装置和存储装置部件的系统和方法。在一个实施例中，用于高容量能量存储装置的阳极结构包括导电集电极衬底，在导电集电极衬底的一个或多个表面上形成的三维铜 - 锡 - 铁多孔导电基体，其包括多个在导电集电器上形成的介孔结构，以及沉积在三维铜 - 锡 - 铁多孔导电基体上的阳极活性材料。在某些实施方式中，所述三维铜 - 锡 - 铁多孔导电基体还包括在所述导电集流体上形成的多个柱状突起，所述多个柱状突起上形成有多个中孔结构。

8. 发明申请

WO2011068685A3 COMPRESSED POWDER 3D BATTERY ELECTRODE MANUFACTURING 审中-公开
标题翻译：压缩粉末3D电池电极制造
公开(公告)号：WO2011068685A3
公开(公告)日：2011-11-24
申请号：PCT/US2010057063
申请日：2010-11-17
申请人： APPLIED MATERIALS INC , BACHRACH ROBERT Z , LOPATIN SERGEY D , WANG CONNIE P , OLGADO DONALD J K
发明人： BACHRACH ROBERT Z , LOPATIN SERGEY D , WANG CONNIE P , OLGADO DONALD J K
IPC分类号： H01M4/02 , H01G9/04 , H01M4/04 , H01M4/64 , H01M10/0525
CPC分类号： H01M4/70 , H01M4/134 , H01M4/139 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/587 , H01M4/661
摘要： Embodiments of the invention contemplate forming an electrochemical device and device components, such as a battery cell or supercapacitor, using thin-film or layer deposition processes and other related methods for forming the same. In one embodiment, a battery bi-layer cell is provided. The battery bi-layer cell comprises an anode structure comprising a conductive collector substrate, a plurality of pockets formed on the conductive collector substrate by conductive microstructures comprising a plurality of columnar projections, and an anodically active powder deposited in and over the plurality of pockets, an insulative separator layer formed over the plurality of pockets, and a cathode structure joined over the insulative separator.
摘要翻译：本发明的实施例考虑使用薄膜或层沉积工艺和用于形成其的相关方法形成电化学装置和装置部件，例如电池单元或超级电容器。在一个实施例中，提供了一种电池双层电池。该电池双层电池包括阳极结构和阳极结构，阳极结构包括导电集电极衬底，通过导电微结构形成在导电集电极衬底上的多个凹穴，所述导电微结构包括多个柱状突起以及沉积在多个凹穴中和上方的阳极活性粉末，形成在所述多个凹穴上方的绝缘分隔层以及接合在所述绝缘分隔物上的阴极结构。

9. 发明申请

WO2011087588A2 GRADED ELECTRODE TECHNOLOGIES FOR HIGH ENERGY LITHIUM-ION BATTERIES 审中-公开
标题翻译：用于高能锂离子电池的梯度电极技术
公开(公告)号：WO2011087588A2
公开(公告)日：2011-07-21
申请号：PCT/US2010058215
申请日：2010-11-29
申请人： APPLIED MATERIALS INC , WANG CONNIE P , LOPATIN SERGEY D , BACHRACH ROBERT Z , SIKHA GODFREY
发明人： WANG CONNIE P , LOPATIN SERGEY D , BACHRACH ROBERT Z , SIKHA GODFREY
CPC分类号： H01M4/70 , H01M4/0404 , H01M4/0419 , H01M4/043 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/139 , H01M4/1391 , H01M4/1397 , H01M4/366 , H01M4/505 , H01M4/525 , H01M4/581 , H01M4/5815 , H01M4/582 , H01M4/5825 , H01M4/621 , H01M4/623 , H01M4/742 , H01M4/745 , H01M10/0525 , H01M2004/021 , H01M2004/028 , Y02P20/133
摘要： Embodiments described herein provide methods and systems for manufacturing faster charging, higher capacity energy storage devices that are smaller, lighter, and can be more cost effectively manufactured at a higher production rate. In one embodiment, a graded cathode structure is provided. The graded cathode structure comprises a conductive substrate, a first porous layer comprising a first cathodically active material having a first porosity formed on the conductive substrate, and a second porous layer comprising a second cathodically active material having a second porosity formed on the first porous layer. In certain embodiments, the first porosity is greater than the second porosity. In certain embodiments, the first porosity is less than the second porosity.
摘要翻译：本文描述的实施例提供用于制造更快，更高容量的能量储存装置的方法和系统，所述更快，更高容量的能量储存装置更小，在一个实施例中，提供渐变阴极结构。梯度阴极结构包括导电基底，第一多孔层和第二多孔层，第一多孔层包括在导电基底上形成的具有第一孔隙率的第一阴极活性材料，第二多孔层包括具有第二孔隙率的第二阴极活性材料，。在某些实施例中，第一孔隙度大于第二孔隙率。在某些实施例中，第一孔隙度小于第二孔隙度。

10. 发明申请

WO2010120813A3 COMPOSITE MATERIALS CONTAINING METALLIZED CARBON NANOTUBES AND NANOFIBERS 审中-公开
标题翻译：包含金属化碳纳米管和纳米纤维的复合材料
公开(公告)号：WO2010120813A3
公开(公告)日：2011-01-13
申请号：PCT/US2010030933
申请日：2010-04-13
申请人： APPLIED MATERIALS INC , LOPATIN SERGEY D , BACHRACH ROBERT Z , CHEN LIANG-YUH
发明人： LOPATIN SERGEY D , BACHRACH ROBERT Z , CHEN LIANG-YUH
IPC分类号： H01M4/02 , B82B3/00 , H01G9/042 , H01M4/64 , H01M10/0525
CPC分类号： H01M4/66 , H01M4/133 , H01M4/366 , H01M4/587 , H01M4/626 , H01M4/661 , H01M4/667 , H01M10/0525 , Y10T29/49115
摘要： A method and apparatus are provided for the cost effective formation of a composite material which includes metallized carbon nanotubes and/or nanofibers that can be used to form portions of an energy storage device, such as a lithium ion battery. In one embodiment, carbon nanotubes are formed on a host substrate using a catalytic chemical vapor deposition process. An initiation-adhesion layer is formed over the carbon nanotubes and a metallic layer is then deposited on the initiation-adhesion layer and each layer is formed using a wet deposition process. In one embodiment, portions of the host substrate are used to form an electrochemical storage device that may be integrated with other formed electrochemical storage devices to create an interconnected battery array. The battery array may be formed as a woven sheet, panel, or other flexible structure depending upon the type of host substrate material. In one case, the host substrate material may be a flexible fibrous material that has multiple layers formed thereon to form a fiber battery, such as a lithium ion battery.
摘要翻译：提供了一种用于成本有效地形成复合材料的方法和装置，所述复合材料包括可用于形成诸如锂离子电池的能量存储装置的部分的金属化碳纳米管和/或纳米纤维。在一个实施方案中，使用催化化学气相沉积工艺在主体衬底上形成碳纳米管。在碳纳米管上形成起始粘合层，然后在起始粘合层上沉积金属层，并且使用湿沉积工艺形成每个层。在一个实施例中，主机衬底的部分用于形成电化学存储器件，其可以与其它形成的电化学存储器件集成以产生互连的电池阵列。取决于主机基板材料的类型，电池阵列可以形成为编织片，面板或其它柔性结构。在一种情况下，主体衬底材料可以是其上形成有多层以形成诸如锂离子电池的纤维电池的柔性纤维材料。

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