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    • 5. 发明专利
    • Atomic layer deposition process for tungsten material
    • 原子层沉积过程的金属材料
    • JP2009024252A
    • 2009-02-05
    • JP2008128784
    • 2008-05-15
    • Applied Materials Incアプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated
    • KHANDELWAL AMITMOORTHY MADHUGELATOS AVGERINOS VWU KAI
    • C23C16/08H01L21/28H01L21/285H01L21/768H01L21/8242H01L27/108
    • PROBLEM TO BE SOLVED: To provide an improved process where, using an ALD process, a tungsten-containing material having satisfactory uniformity, hardly having contamination or having no contamination at all, and also having high electrical conductivity, i.e., low resistivity. SOLUTION: In one embodiment, the method for forming a tungsten-containing material on a substrate comprises: a step for positioning a substrate inside a process chamber, where the substrate comprises a base layer arranged thereon; and a step for successively exposing the substrate to a tungsten precursor and a reduction gas, so as to deposit a tungsten nucleation layer on the base layer upon an ALD process, where the reduction gas has a hydrogen/hydride flow ratio satisfying about 40:1, 100:1, 500:1, 800:1, 1,000:1 or more; and a step for depositing a tungsten bulk layer on the tungsten nucleation layer. The reduction gas comprises a hydride compound such as diborane, silane or a disilane. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种改进的方法,其中使用ALD工艺,具有令人满意的均匀性,几乎没有污染或完全没有污染的含钨材料,并且还具有高导电性,即低电阻率 。 解决方案:在一个实施例中,用于在衬底上形成含钨材料的方法包括:将衬底定位在处理室内的步骤,其中衬底包括布置在其上的基底层; 以及将基板依次暴露于钨前体和还原气体的步骤,以在ALD工艺中在基底层上沉积钨成核层,其中还原气体的氢/氢气流量比满足约40:1 ,100:1,500:1,800:1,1,000:1或更高; 以及在钨成核层上沉积钨体层的步骤。 还原气体包括氢化物化合物,例如乙硼烷,硅烷或乙硅烷。 版权所有(C)2009,JPO&INPIT