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    • 2. 发明申请
    • METHODS FOR ETCH OF METAL AND METAL-OXIDE FILMS
    • 金属和金属氧化物膜的蚀刻方法
    • WO2012125654A2
    • 2012-09-20
    • PCT/US2012/028952
    • 2012-03-13
    • APPLIED MATERIALS, INC.ZHANG, JingchunWANG, AnchuanINGLE, Nitin
    • ZHANG, JingchunWANG, AnchuanINGLE, Nitin
    • H01L21/3065
    • H01L21/31116H01J37/32422H01L21/31122H01L21/32136
    • A method of selectively etching a metal-containing film from a substrate comprising a metal-containing layer and a silicon oxide layer includes flowing a fluorine-containing gas into a plasma generation region of a substrate processing chamber, and applying energy to the fluorine-containing gas to generate a plasma in the plasma generation region. The plasma comprises fluorine radicals and fluorine ions. The method also includes filtering the plasma to provide a reactive gas having a higher concentration of fluorine radicals than fluorine ions, and flowing the reactive gas into a gas reaction region of the substrate processing chamber. The method also includes exposing the substrate to the reactive gas in the gas reaction region of the substrate processing chamber. The reactive gas etches the metal-containing layer at a higher etch rate than the reactive gas etches the silicon oxide layer.
    • 从包含含金属层和氧化硅层的基板选择性地蚀刻含金属膜的方法包括将含氟气体流入基板处理室的等离子体产生区域,并将能量施加到含氟 气体在等离子体产生区域中产生等离子体。 等离子体包含氟自由基和氟离子。 该方法还包括过滤等离子体以提供具有比氟离子更高浓度​​的氟自由基的反应气体,并使反应气体流入基板处理室的气体反应区域。 该方法还包括将衬底暴露于衬底处理室的气体反应区域中的反应气体。 反应气体以比反应气体更高的蚀刻速率蚀刻含金属层蚀刻氧化硅层。
    • 3. 发明申请
    • UNIFORM DRY ETCH IN TWO STAGES
    • 两阶段均匀干燥
    • WO2012106033A2
    • 2012-08-09
    • PCT/US2011/064724
    • 2011-12-13
    • APPLIED MATERIALS, INC.YANG, DongqingTANG, JingINGLE, Nitin
    • YANG, DongqingTANG, JingINGLE, Nitin
    • H01L21/31116
    • A method of etching silicon oxide from a multiple trenches is described which allows more homogeneous etch rates among trenches. The surfaces of the etched silicon oxide within the trench following the etch may also be smoother. The method includes two dry etch stages followed by a sublimation step. The first dry etch stage removes silicon oxide quickly and produces large solid residue granules. The second dry etch stage remove silicon oxide slowly and produces small solid residue granules in amongst the large solid residue granules. Both the small and large solid residue are removed in the ensuing sublimation step. There is no sublimation step between the two dry etch stages.
    • 描述了从多个沟槽蚀刻氧化硅的方法,其允许沟槽之间更均匀的蚀刻速率。 蚀刻后的沟槽内的蚀刻氧化硅的表面也可以更平滑。 该方法包括两个干蚀刻阶段,接着是升华步骤。 第一次干蚀刻阶段快速去除氧化硅并产生大的固体残渣颗粒。 第二干蚀刻步骤缓慢除去氧化硅,并在大的固体残渣颗粒中产生小的固体残渣颗粒。 在随后的升华步骤中,小和大的固体残余物都被去除。 两个干蚀刻阶段之间没有升华步骤。
    • 9. 发明申请
    • SMOOTH SICONI ETCH FOR SILICON-CONTAINING FILMS
    • 用于含硅片的SMOOTH SICONI蚀刻
    • WO2011087580A1
    • 2011-07-21
    • PCT/US2010/057676
    • 2010-11-22
    • APPLIED MATERIALS, INC.TANG, JingINGLE, NitinYANG, Dongqing
    • TANG, JingINGLE, NitinYANG, Dongqing
    • H01L21/3065
    • H01L21/31116H01J37/32357H01J2237/3341
    • A method of etching silicon-containing material is described and includes a SiConi™ etch having a greater or lesser flow ratio of hydrogen compared to fluorine than that found in the prior art. Modifying the flow rate ratios in this way has been found to reduce roughness of the post-etch surface and to reduce the difference in etch-rate between densely and sparsely patterned areas. Alternative means of reducing post-etch surface roughness include pulsing the flows of the precursors and/or the plasma power, maintaining a relatively high substrate temperature and performing the SiConi™ in multiple steps. Each of these approaches, either alone or in combination, serve to reduce the roughness of the etched surface by limiting solid residue grain size.
    • 描述了蚀刻含硅材料的方法,并且包括与现有技术中发现的氢相比具有更大或更小的氢流量比的SiConiTM蚀刻。 已经发现以这种方式修改流速比降低了蚀刻后表面的粗糙度并且减少了密集和稀疏图案化区域之间的蚀刻速率的差异。 降低蚀刻后表面粗糙度的替代方法包括脉冲前体和/或等离子体功率的流动,维持相对高的衬底温度并以多个步骤执行SiConiTM。 单独或组合的这些方法中的每一种用于通过限制固体残余物颗粒尺寸来减少蚀刻表面的粗糙度。