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1. 发明申请

WO2010098977A2 THIN FILM ELECTROCHEMICAL ENERGY STORAGE DEVICE WITH THREE-DIMENSIONAL ANODIC STRUCTURE 审中-公开
标题翻译：具有三维阳极结构的薄膜电化学能量储存装置
公开(公告)号：WO2010098977A2
公开(公告)日：2010-09-02
申请号：PCT/US2010/023640
申请日：2010-02-09
申请人： APPLIED MATERIALS, INC. , LOPATIN, Sergey D. , BREVNOV, Dmitri, A. , BACHRACH, Robert Z.
发明人： LOPATIN, Sergey D. , BREVNOV, Dmitri, A. , BACHRACH, Robert Z.
CPC分类号： H01M10/0585 , C25D1/00 , C25D1/006 , H01M2/1653 , H01M2/1686 , H01M4/0428 , H01M4/133 , H01M4/1393 , H01M4/364 , H01M4/587 , H01M4/667 , H01M4/70 , H01M6/40 , H01M10/0525 , H01M10/0565 , H01M10/0566 , H01M10/058
摘要： A method for forming a battery from via thin-film deposition processes is disclosed. A mesoporous carbon material is deposited onto a surface of a conductive substrate that has high surface area, conductive micro-structures formed thereon. A porous, dielectric separator layer is then deposited on the layer of mesoporous carbon material to form a half cell of an energy storage device. The mesoporous carbon material is made up of CVD-deposited carbon fullerene "onions" and carbon nano-tubes, and has a high porosity capable of retaining lithium ions in concentrations useful for storing significant quantities of electrical energy. Embodiments of the invention further provide for the formation of an electrode having a high surface area conductive region that is useful in a battery structure. In one configuration the electrode has a high surface area conductive region comprising a porous dendritic structure that can be formed by electroplating, physical vapor deposition, chemical vapor deposition, thermal spraying, and/or electroless plating techniques.
摘要翻译：公开了一种通过薄膜沉积工艺形成电池的方法。在其上形成有高表面积的导电微结构的导电性基板的表面上沉积介孔碳材料。然后将多孔介电分离器层沉积在介孔碳材料层上以形成储能装置的半电池。中孔碳材料由CVD沉积的碳富勒烯“洋葱”和碳纳米管组成，并且具有能够将锂离子保留在用于储存大量电能的浓度的高孔隙率。本发明的实施例还提供了一种用于电池结构的具有高表面积导电区域的电极的形成。在一种配置中，电极具有高的表面积导电区域，其包括通过电镀，物理气相沉积，化学气相沉积，热喷涂和/或化学镀技术形成的多孔树枝状结构。

2. 发明申请

WO2010091405A2 METROLOGY METHODS AND APPARATUS FOR NANOMATERIAL CHARACTERIZATION OF ENERGY STORAGE ELECTRODE STRUCTURES 审中-公开
标题翻译：计量储能电极结构的纳米表征的计量方法和装置
公开(公告)号：WO2010091405A2
公开(公告)日：2010-08-12
申请号：PCT/US2010/023630
申请日：2010-02-09
申请人： APPLIED MATERIALS, INC. , LOPATIN, Sergey D. , BREVNOV, Dmitri A. , CASAVANT, Eric , BACHRACH, Robert Z.
发明人： LOPATIN, Sergey D. , BREVNOV, Dmitri A. , CASAVANT, Eric , BACHRACH, Robert Z.
IPC分类号： H01G4/005
CPC分类号： C25D5/18 , H01G11/26 , H01G11/30 , H01G11/50 , H01G11/86 , H01M4/0438 , H01M4/0452 , H01M4/1395 , Y02E60/13
摘要： Embodiments described herein generally relate to methods and apparatus for forming an electrode structure used in an energy storage device. More particularly, embodiments described herein relate to methods and apparatus for characterizing nanomaterials used in forming high capacity electrode structures for energy storage devices. In one embodiment a process for forming an electrode structure for an energy storage device is provided. The process comprises depositing a columnar metal structure over a substrate at a first current density by a diffusion limited deposition process, measuring a capacitance of the columnar metal structure to determine a surface area of the columnar metal structure, and depositing three dimensional porous metal structures over the columnar metal structure at a second current density greater than the first current density.
摘要翻译：这里描述的实施例总体上涉及用于形成在能量存储装置中使用的电极结构的方法和设备。更具体地，本文描述的实施方式涉及用于表征用于形成用于能量存储装置的高容量电极结构的纳米材料的方法和设备。在一个实施例中，提供了一种用于形成能量存储装置的电极结构的过程。该方法包括通过扩散限制沉积工艺以第一电流密度在基板上沉积柱状金属结构，测量柱状金属结构的电容以确定柱状金属结构的表面积，并在基板上沉积三维多孔金属结构第二电流密度下的柱状金属结构大于第一电流密度。

3. 发明申请

WO2011087588A3 GRADED ELECTRODE TECHNOLOGIES FOR HIGH ENERGY LITHIUM-ION BATTERIES 审中-公开
公开(公告)号：WO2011087588A3
公开(公告)日：2011-07-21
申请号：PCT/US2010/058215
申请日：2010-11-29
申请人： APPLIED MATERIALS, INC. , WANG, Connie P. , LOPATIN, Sergey D. , BACHRACH, Robert Z. , SIKHA, Godfrey
发明人： WANG, Connie P. , LOPATIN, Sergey D. , BACHRACH, Robert Z. , SIKHA, Godfrey
IPC分类号： H01M4/02 , H01M10/0525 , H01M4/48 , H01M4/64
摘要： Embodiments described herein provide methods and systems for manufacturing faster charging, higher capacity energy storage devices that are smaller, lighter, and can be more cost effectively manufactured at a higher production rate. In one embodiment, a graded cathode structure is provided. The graded cathode structure comprises a conductive substrate, a first porous layer comprising a first cathodically active material having a first porosity formed on the conductive substrate, and a second porous layer comprising a second cathodically active material having a second porosity formed on the first porous layer. In certain embodiments, the first porosity is greater than the second porosity. In certain embodiments, the first porosity is less than the second porosity.

4. 发明申请

WO2010120816A2 METALLIZED FIBERS FOR ELECTROCHEMICAL ENERGY STORAGE 审中-公开
标题翻译：用于电化学能量储存的金属化纤维
公开(公告)号：WO2010120816A2
公开(公告)日：2010-10-21
申请号：PCT/US2010/030936
申请日：2010-04-13
申请人： APPLIED MATERIALS, INC. , LOPATIN, Sergey D. , BACHRACH, Robert Z. , CHEN, Liang-Yuh
发明人： LOPATIN, Sergey D. , BACHRACH, Robert Z. , CHEN, Liang-Yuh
IPC分类号： H01M4/02 , H01M4/64 , H01G9/042 , H01M8/02 , H01M10/0525
CPC分类号： H01M4/66 , H01M4/133 , H01M4/366 , H01M4/587 , H01M4/626 , H01M4/661 , H01M4/667 , H01M10/0525 , Y10T29/49115
摘要： A cost effective method and apparatus are provided for forming metallized fibers and depositing multilayer films thereon to form thin film electrochemical energy storage devices. In one embodiment, a fibrous substrate is formed using a fiber spinning process and the fibrous substrate is plated with a copper layer using wet deposition. Multiple material layers are then deposited onto the copper layer to form a lithium-ion battery fiber.
摘要翻译：提供了一种成本有效的方法和装置，用于形成金属化纤维并在其上沉积多层膜以形成薄膜电化学能量存储装置。在一个实施例中，使用纤维纺丝工艺形成纤维基材，并且使用湿沉积将纤维基材镀铜层。然后将多个材料层沉积到铜层上以形成锂离子电池纤维。

5. 发明申请

WO2013025505A2 PARTICLE SYNTHESIS APPARATUS AND METHODS 审中-公开
标题翻译：颗粒综合装置和方法
公开(公告)号：WO2013025505A2
公开(公告)日：2013-02-21
申请号：PCT/US2012/050335
申请日：2012-08-10
申请人： APPLIED MATERIALS, INC. , YANG, Lu , HOOG, Joseph T. , WANG, Miaojun , ZENG, Dongli , BACHRACH, Robert Z. , BOLANDI, Hooman , LOPATIN, Sergey D.
发明人： YANG, Lu , HOOG, Joseph T. , WANG, Miaojun , ZENG, Dongli , BACHRACH, Robert Z. , BOLANDI, Hooman , LOPATIN, Sergey D.
IPC分类号： H01M4/1391
CPC分类号： H01M4/525 , B01J4/002 , B01J8/001 , B01J8/004 , B01J8/067 , B01J8/087 , B01J19/0006 , B01J19/0013 , B01J19/2415 , B01J19/242 , B01J2208/00044 , B01J2208/0007 , B01J2208/00212 , B01J2208/00415 , B01J2208/0053 , B01J2219/00094 , B01J2219/00135 , B01J2219/00159 , B01J2219/00186 , B01J2219/00198 , B01J2219/002 , B01J2219/00202 , B01J2219/00211 , B01J2219/00238 , B22F9/16 , B22F9/30 , C01G45/1235 , C01G51/42 , C01G53/42 , C01G53/50 , C01P2002/72 , H01M4/366 , H01M4/505 , Y02E60/122
摘要： Apparatus and methods of forming a battery-active material are described. An apparatus includes a first processing section that raises the temperature of a precursor material to a reaction threshold temperature, a second processing section that converts the precursor material to a battery-active material, and a third processing section that cools the resulting battery-active material. Each of the processing sections may be a continuous flow tubular component. The first and third processing sections may be metal, and the second processing section may be a refractory material for high temperature service. The battery-active material is collected using a solids collector.
摘要翻译：描述了形成电池活性材料的设备和方法。一种设备包括：第一处理部分，其将前体材料的温度升高至反应阈值温度;第二处理部分，其将前体材料转化为电池活性材料;以及第三处理部分，其将所得到的电池活性材料。每个处理部分可以是连续流动管状部件。第一和第三处理部分可以是金属，并且第二处理部分可以是用于高温服务的耐火材料。使用固体收集器收集电池活性材料。

6. 发明申请

WO2012118840A3 MANUFACTURING OF HIGH CAPACITY PRISMATIC LITHIUM-ION ALLOY ANODES 审中-公开
公开(公告)号：WO2012118840A3
公开(公告)日：2012-09-07
申请号：PCT/US2012/026991
申请日：2012-02-28
申请人： APPLIED MATERIALS, INC. , LOPATIN, Sergey D. , BREVNOV, Dimitri , LIU, Eric H. , BACHRACH, Robert Z. , WANG, Connie P.
发明人： LOPATIN, Sergey D. , BREVNOV, Dimitri , LIU, Eric H. , BACHRACH, Robert Z. , WANG, Connie P.
IPC分类号： H01M4/13 , H01M4/64 , H01M10/052 , H01M4/139
摘要： High capacity energy storage devices and energy storage device components, and more specifically, to a system and method for fabricating such high capacity energy storage devices and storage device components using processes that form three-dimensional porous structures are provided. In one embodiment, an anode structure for use in a high capacity energy storage device, comprising a conductive collector substrate, a three-dimensional copper-tin-iron porous conductive matrix formed on one or more surfaces of the conductive collector substrate, comprising a plurality of meso-porous structures formed over the conductive current collector, and an anodically active material deposited over the three-dimensional copper-tin-iron porous conductive matrix is provided. In certain embodiments, the three-dimensional copper-tin-iron porous conductive matrix further comprises a plurality of columnar projections formed on the conductive current collector with the plurality of meso-porous structure formed on the plurality of columnar projections.

7. 发明申请

WO2011109043A1 INTEGRATED COMPOSITE SEPARATOR FOR LITHIUM-ION BATTERIES 审中-公开
标题翻译：用于锂离子电池的集成复合分离器
公开(公告)号：WO2011109043A1
公开(公告)日：2011-09-09
申请号：PCT/US2010/051328
申请日：2010-10-04
申请人： APPLIED MATERIALS, INC. , WANG, Connie P. , BACHRACH, Robert Z. , LOPATIN, Sergey D. , OLGADO, Donald J.K. , KUTNEY, Michael , WANG, Zheng
发明人： WANG, Connie P. , BACHRACH, Robert Z. , LOPATIN, Sergey D. , OLGADO, Donald J.K. , KUTNEY, Michael , WANG, Zheng
IPC分类号： H01M10/0525 , H01M2/16 , C04B35/01 , B32B37/00 , H01M4/48
CPC分类号： B32B37/02 , B32B38/0008 , B32B38/145 , B32B38/164 , B32B39/00 , B32B2037/243 , B32B2309/10 , B32B2310/14 , B32B2457/10 , C04B35/44 , C04B2235/3203 , C04B2235/3262 , C04B2235/3279 , H01M2/145 , H01M2/162 , H01M2/1673 , H01M2/1686 , H01M2/348 , H01M10/052 , H01M10/0565 , H01M2300/0094
摘要： Embodiments of the present invention relate generally to lithium-ion batteries, and more specifically, to batteries having integrated separators and methods of fabricating such batteries. In one embodiment, a lithium-ion battery having an electrode structure is provided. The lithium-ion battery comprises an anode stack, a cathode stack, and an integrated separator formed between the anode stack and the cathode stack. The anode stack comprises an anodic current collector and an anode structure formed over a first surface of the anodic current collector. The cathode stack comprises a cathodic current collector and a cathode structure formed over a first surface of the cathodic current collector. The integrated separator comprises a first ceramic layer, a second ceramic layer, and a polymer material layer deposited between the first ceramic layer and the second ceramic layer.
摘要翻译：本发明的实施方案一般涉及锂离子电池，更具体地，涉及具有集成分离器的电池和制造这种电池的方法。在一个实施例中，提供具有电极结构的锂离子电池。锂离子电池包括阳极堆叠，阴极堆叠和形成在阳极堆叠和阴极堆叠之间的集成隔板。阳极堆叠包括阳极集电器和形成在阳极集电器的第一表面上的阳极结构。阴极堆叠包括在阴极集电器的第一表面上形成的阴极集电器和阴极结构。集成分离器包括第一陶瓷层，第二陶瓷层和沉积在第一陶瓷层和第二陶瓷层之间的聚合物材料层。

8. 发明申请

WO2011068685A2 COMPRESSED POWDER 3D BATTERY ELECTRODE MANUFACTURING 审中-公开
标题翻译：压缩粉末3D电池电极制造
公开(公告)号：WO2011068685A2
公开(公告)日：2011-06-09
申请号：PCT/US2010/057063
申请日：2010-11-17
申请人： APPLIED MATERIALS, INC. , BACHRACH, Robert Z. , LOPATIN, Sergey D. , WANG, Connie P. , OLGADO, Donald J.K.
发明人： BACHRACH, Robert Z. , LOPATIN, Sergey D. , WANG, Connie P. , OLGADO, Donald J.K.
IPC分类号： H01M4/02 , H01M4/64 , H01M4/04 , H01G9/04 , H01M10/0525
CPC分类号： H01M4/70 , H01M4/134 , H01M4/139 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/587 , H01M4/661
摘要： Embodiments of the invention contemplate forming an electrochemical device and device components, such as a battery cell or supercapacitor, using thin-film or layer deposition processes and other related methods for forming the same. In one embodiment, a battery bi-layer cell is provided. The battery bi-layer cell comprises an anode structure comprising a conductive collector substrate, a plurality of pockets formed on the conductive collector substrate by conductive microstructures comprising a plurality of columnar projections, and an anodically active powder deposited in and over the plurality of pockets, an insulative separator layer formed over the plurality of pockets, and a cathode structure joined over the insulative separator.
摘要翻译：本发明的实施例考虑使用薄膜或层沉积工艺以及其它相关方法来形成电化学装置和器件部件，例如电池单元或超级电容器。在一个实施例中，提供了电池双层电池。电池双层电池包括阳极结构，其包括导电收集器基板，通过包括多个柱状突起的导电微结构形成在导电收集器基板上的多个凹穴以及沉积在多个凹穴中和之上的阳极活性粉末，形成在所述多个凹穴上的绝缘隔离层，以及连接在所述绝缘隔板上的阴极结构。

9. 发明申请

WO2010120813A2 COMPOSITE MATERIALS CONTAINING METALLIZED CARBON NANOTUBES AND NANOFIBERS 审中-公开
标题翻译：包含金属化碳纳米管和纳米纤维的复合材料
公开(公告)号：WO2010120813A2
公开(公告)日：2010-10-21
申请号：PCT/US2010/030933
申请日：2010-04-13
申请人： APPLIED MATERIALS, INC. , LOPATIN, Sergey D. , BACHRACH, Robert Z. , CHEN, Liang-Yuh
发明人： LOPATIN, Sergey D. , BACHRACH, Robert Z. , CHEN, Liang-Yuh
IPC分类号： H01M4/02 , H01M4/64 , H01M10/0525 , H01G9/042 , B82B3/00
CPC分类号： H01M4/66 , H01M4/133 , H01M4/366 , H01M4/587 , H01M4/626 , H01M4/661 , H01M4/667 , H01M10/0525 , Y10T29/49115
摘要： A method and apparatus are provided for the cost effective formation of a composite material which includes metallized carbon nanotubes and/or nanofibers that can be used to form portions of an energy storage device, such as a lithium ion battery. In one embodiment, carbon nanotubes are formed on a host substrate using a catalytic chemical vapor deposition process. An initiation-adhesion layer is formed over the carbon nanotubes and a metallic layer is then deposited on the initiation-adhesion layer and each layer is formed using a wet deposition process. In one embodiment, portions of the host substrate are used to form an electrochemical storage device that may be integrated with other formed electrochemical storage devices to create an interconnected battery array. The battery array may be formed as a woven sheet, panel, or other flexible structure depending upon the type of host substrate material. In one case, the host substrate material may be a flexible fibrous material that has multiple layers formed thereon to form a fiber battery, such as a lithium ion battery.
摘要翻译：提供了一种用于成本有效地形成复合材料的方法和装置，所述复合材料包括可用于形成诸如锂离子电池的能量存储装置的部分的金属化碳纳米管和/或纳米纤维。在一个实施方案中，使用催化化学气相沉积工艺在主体衬底上形成碳纳米管。在碳纳米管上形成起始粘合层，然后在起始粘合层上沉积金属层，并且使用湿沉积工艺形成每个层。在一个实施例中，主机衬底的部分用于形成电化学存储器件，其可以与其它形成的电化学存储器件集成以产生互连的电池阵列。取决于主机基板材料的类型，电池阵列可以形成为编织片，面板或其它柔性结构。在一种情况下，主体衬底材料可以是其上形成有多层以形成诸如锂离子电池的纤维电池的柔性纤维材料。

10. 发明申请

WO2017123443A1 ANODE STRUCTURE WITH BINDERS FOR SILICON AND STABILIZED LITHIUM METAL POWDER 审中-公开
标题翻译：阳极结构与粘结剂用于硅和稳定的锂金属粉末
公开(公告)号：WO2017123443A1
公开(公告)日：2017-07-20
申请号：PCT/US2017/012192
申请日：2017-01-04
申请人： APPLIED MATERIALS, INC.
发明人： LIU, Gao , LOPATIN, Sergey D. , LIU, Eric H. , JOSHI, Ajey M. , AI, Guo , WANG, Zhihui , ZHAO, Hui , WANG, Donghai
IPC分类号： H01M4/04 , H01M4/62 , H01M4/36 , H01M4/02
CPC分类号： H01M10/052 , H01M4/0402 , H01M4/134 , H01M4/1395 , H01M4/366 , H01M4/382 , H01M4/622 , H01M2004/027
摘要： A simple solution processing method is developed to achieve uniform and scalable stabilized lithium metal powder coating on Li-ion negative electrode. A solvent and binder system for stabilized lithium metal powder coating is developed, including the selection of solvent, polymer binder and enhancement of polymer concentration. The enhanced binder solution is 1% concentration of polymer binder in xylene, and the polymer binder is chosen as the mixture of poly(styrene-co-butadiene) rubber (SBR) and polystyrene (PS). Long-sustained, uniformly dispersed stabilized lithium metal powder suspension can be achieved with the enhanced binder solution. A uniform stabilized lithium metal powder coating can be achieved with simple doctor blade coating method and the resulting stabilized lithium metal powder coating can firmly glued on the anode surface. With the prelithiation of negative electrode by stabilized lithium metal powder, improvements in electrochemical performances are demonstrated in both graphite/NMC and SiO/NMC full-cell.
摘要翻译：开发了一种简单的溶液处理方法，以在锂离子负极上实现均匀且可放大的稳定的锂金属粉末涂层。开发了用于稳定锂金属粉末涂料的溶剂和粘合剂体系，包括溶剂，聚合物粘合剂的选择和聚合物浓度的提高。增强的粘合剂溶液是在二甲苯中1％浓度的聚合物粘合剂，聚合物粘合剂选作聚（苯乙烯 - 丁二烯共聚物）橡胶（SBR）和聚苯乙烯（PS）的混合物。增强的粘合剂溶液可以实现持久的，均匀分散的稳定化锂金属粉末悬浮液。用简单的刮刀涂布方法可以获得均匀稳定的锂金属粉末涂层，并且所得稳定的锂金属粉末涂层可牢固地粘合在阳极表面上。通过稳定的锂金属粉末对负极进行预锂化，在石墨/ NMC和SiO / NMC全电池中都证明了电化学性能的改进。

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