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    • 9. 发明申请
    • ANODE STRUCTURE WITH BINDERS FOR SILICON AND STABILIZED LITHIUM METAL POWDER
    • 阳极结构与粘结剂用于硅和稳定的锂金属粉末
    • WO2017123443A1
    • 2017-07-20
    • PCT/US2017/012192
    • 2017-01-04
    • APPLIED MATERIALS, INC.
    • LIU, GaoLOPATIN, Sergey D.LIU, Eric H.JOSHI, Ajey M.AI, GuoWANG, ZhihuiZHAO, HuiWANG, Donghai
    • H01M4/04H01M4/62H01M4/36H01M4/02
    • H01M10/052H01M4/0402H01M4/134H01M4/1395H01M4/366H01M4/382H01M4/622H01M2004/027
    • A simple solution processing method is developed to achieve uniform and scalable stabilized lithium metal powder coating on Li-ion negative electrode. A solvent and binder system for stabilized lithium metal powder coating is developed, including the selection of solvent, polymer binder and enhancement of polymer concentration. The enhanced binder solution is 1% concentration of polymer binder in xylene, and the polymer binder is chosen as the mixture of poly(styrene-co-butadiene) rubber (SBR) and polystyrene (PS). Long-sustained, uniformly dispersed stabilized lithium metal powder suspension can be achieved with the enhanced binder solution. A uniform stabilized lithium metal powder coating can be achieved with simple doctor blade coating method and the resulting stabilized lithium metal powder coating can firmly glued on the anode surface. With the prelithiation of negative electrode by stabilized lithium metal powder, improvements in electrochemical performances are demonstrated in both graphite/NMC and SiO/NMC full-cell.
    • 开发了一种简单的溶液处理方法,以在锂离子负极上实现均匀且可放大的稳定的锂金属粉末涂层。 开发了用于稳定锂金属粉末涂料的溶剂和粘合剂体系,包括溶剂,聚合物粘合剂的选择和聚合物浓度的提高。 增强的粘合剂溶液是在二甲苯中1%浓度的聚合物粘合剂,聚合物粘合剂选作聚(苯乙烯 - 丁二烯共聚物)橡胶(SBR)和聚苯乙烯(PS)的混合物。 增强的粘合剂溶液可以实现持久的,均匀分散的稳定化锂金属粉末悬浮液。 用简单的刮刀涂布方法可以获得均匀稳定的锂金属粉末涂层,并且所得稳定的锂金属粉末涂层可牢固地粘合在阳极表面上。 通过稳定的锂金属粉末对负极进行预锂化,在石墨/ NMC和SiO / NMC全电池中都证明了电化学性能的改进。