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1. 发明申请

WO2012153972A2 POLYANILINE CONDUCTOR DOPED WITH SULFONATED POLYPHENYLSILSESQUIOXANE AND DOPANT TO HAVE POSITIVE TEMPERATURE COEFFICIENT RESISTANCE, AND PREPARATION METHOD THEREOF 审中-公开
标题翻译：用磺化聚苯醚硅氧烷聚合的聚氨酯导体和具有正温度系数电阻的憎水剂及其制备方法
公开(公告)号：WO2012153972A2
公开(公告)日：2012-11-15
申请号：PCT/KR2012003599
申请日：2012-05-08
申请人： AJOU UNIV IND ACAD COOP FOUND , KOREA INST SCI & TECH , KWON O PIL , LEE SUCK HYUN , KIM TAE JA , HONG EUN YOUNG , HWANG SEUNG SANG , BEAK KYUNG YOUL , CHOI SEUNG SEOK , LEE DONG KI
发明人： KWON O PIL , LEE SUCK HYUN , KIM TAE JA , HONG EUN YOUNG , HWANG SEUNG SANG , BEAK KYUNG YOUL , CHOI SEUNG SEOK , LEE DONG KI
IPC分类号： C08G73/00 , C08G77/445 , C08L79/00 , C08L83/04 , H01B1/12
CPC分类号： C08G73/1071 , C08L83/04 , H01B1/128
摘要： The present invention relates to a polyaniline conductor doped with sulfonated polyphenylsilsesquioxane and a dopant to enable having a positive temperature coefficient resistance. When doped in a polyaniline, the sulfonated polyphenylsilsesquioxane allows the doped polyaniline to have high heat resistance and a negative temperature coefficient resistance. It is possible to control the temperature coefficient resistance of a doped polyaniline by simultaneously doping sulfonated polyphenylsilsesquioxane to have a negative temperature coefficient resistance and a dopant to have a positive temperature coefficient resistance.
摘要翻译：本发明涉及掺杂有磺化聚苯基倍半硅氧烷和掺杂剂以能够具有正温度系数电阻的聚苯胺导体。当掺杂在聚苯胺中时，磺化的聚苯基倍半硅氧烷允许掺杂的聚苯胺具有高的耐热性和耐温度系数的阻力。可以通过同时掺杂磺化聚苯基倍半硅氧烷以具有负温度系数电阻和掺杂剂来具有正温度系数电阻来控制掺杂聚苯胺的温度系数电阻。

2. 发明申请

WO2012148144A3 POLYVINYL COPOLYMER, DOPANT HAVING SAME, CONDUCTIVE POLYMER COMPOSITE HAVING THE DOPANT 审中-公开
标题翻译：聚乙烯共聚物，具有相同性的憎水剂，具有憎水性的导电聚合物复合物
公开(公告)号：WO2012148144A3
公开(公告)日：2013-01-17
申请号：PCT/KR2012003115
申请日：2012-04-23
申请人： AJOU UNIV IND ACAD COOP FOUND , LEE SUCK HYUN , KWON O PIL , KIM TAE JA
发明人： LEE SUCK HYUN , KWON O PIL , KIM TAE JA
IPC分类号： C08F216/06 , C08F16/30 , C08L29/04 , C08L101/12 , H01B1/12
CPC分类号： H01B1/128 , C08F8/36 , C08F216/06 , C08G2261/1452 , C08G2261/722 , C08L29/04 , C08L33/00 , C08L35/06 , C08L101/12 , C08L2203/20 , H01B1/127 , C08L79/02
摘要： The present invention relates to a polyvinyl copolymer having one or more lateral branch sulfonic acids attached on the hydroxy group of a polyvinyl alcohol or a polyvinyl phenol and a preparation method therefor, a dopant having same, and a conductive polymer composite having the dopant and a conductive polymer, and a preparation method therefor, wherein the electrical conductivity, dispersibility, solubility, heat resistance and environmental resistance of the conductive polymer composite is enhanced by using the dopant having the copolymer.
摘要翻译：本发明涉及在聚乙烯醇或聚乙烯基苯酚的羟基上具有一个或多个侧支磺酸的聚乙烯基共聚物及其制备方法，具有该聚合物的掺杂剂和具有该掺杂剂的导电聚合物复合物导电聚合物及其制备方法，其中通过使用具有共聚物的掺杂剂增强了导电聚合物复合材料的导电性，分散性，溶解性，耐热性和耐环境性。

3. 发明申请

WO2012148143A3 ORGANIC SULFONIC ACID COMPOUND, DOPANT HAVING SAME, AND CONDUCTIVE POLYMER COMPLEX HAVING THE DOPANT 审中-公开
标题翻译：有机硫酸化合物，具有相同性质的DOPANT和具有DOPANT的导电聚合物复合物
公开(公告)号：WO2012148143A3
公开(公告)日：2013-01-17
申请号：PCT/KR2012003114
申请日：2012-04-23
申请人： AJOU UNIV IND ACAD COOP FOUND , LEE SUCK HYUN , KWON O PIL , KIM TAE JA
发明人： LEE SUCK HYUN , KWON O PIL , KIM TAE JA
IPC分类号： C07C309/24 , C07C211/46 , C07C309/11 , C07F1/00 , C08K5/42 , C08L81/00 , H01B1/20
CPC分类号： H01B1/128 , C07C309/11 , C08G73/0266 , C08G2261/3221 , C08G2261/3222 , C08G2261/3223 , C08G2261/3422 , C08K5/42 , C08L77/00 , C08L79/02 , C08L79/08 , H01B1/127 , C08L65/00
摘要： The present invention relates to an organic sulfonic compound and a preparation method therefor, a dopant having the compound, and a conductive polymer complex having the dopant, and more specifically, to a dopant having a derivative compound having a sulfonic acid group connected to a benzene ring having a substituent by a flexible chain, thereby enhancing the solubility and the dispersibility in a general solvent, and the environmental resistance thereof, thus increasing the electric conductivity, and significantly improving not only the workability but also the mechanical feature.
摘要翻译：本发明涉及有机磺酸化合物及其制备方法，具有该化合物的掺杂剂和具有掺杂剂的导电聚合物复合物，更具体地说，涉及具有与苯连接的磺酸基的衍生化合物的掺杂剂通过柔性链具有取代基的环，从而提高了在一般溶剂中的溶解度和分散性及其耐环境性，从而增加了电导率，并且不仅显着地改善了可加工性，而且显着地改善了机械特征。

4. 发明授权

KR100946598B1 Solid dopants for conductive polymers, method and apparatus for preparing the same using plasma treatment, and solid doping method of conductive polymers 有权
标题翻译：用于导电聚合物的固体聚合物，使用等离子体处理制备其的方法和装置以及导电聚合物的固体掺杂方法
公开(公告)号：KR100946598B1
公开(公告)日：2010-03-09
申请号：KR20090035928
申请日：2009-04-24
申请人： ELPANI CO LTD , AJOU UNIV IND ACAD COOP FOUND
发明人： HONG YONG CHEOL , LEE SUCK HYUN , KWON O PIL , KIM TAE JA
IPC分类号： C08J3/28 , C08J7/18 , C08K3/12 , H01L21/265
CPC分类号： C08J3/212 , C08J2300/12 , H01L51/002
摘要： PURPOSE: A solid dopant is provided to enable doping of conductive polymer in a solvent while having high dispersibility using various plasma treatments and to stably manufacture a non-volatile conductive polymer. CONSTITUTION: A solid doping method of conductive polymer using plasma comprises: a step(S20) of synthesizing a dopant nanopowder for a solid dopant; a step(S100) of processing the dopant nanopowder using plasma; and a step(S60) of doping the conductive polymer by mixing the dopant nanopowder processed by the plasma with the conductive polymer dispersed in a solvent. The dopant nanopowder is selected from a group including titania, tungsten oxide, copper oxide, iron oxides, zinc oxidate, tin oxide, zirconium oxide, vanadium oxide, nickel oxide, cadmium oxide, selenium oxide, barium titanate, and the mixture or from a group including sulfate zinc, zinc iodide, barium iodide, sodium iodide, cesium iodine, lead iodide, zinc oxide, cesium bromide, barium bromide, ZnS, ZnCdS, Gd2O2S, Y2O2S, CaWO3, and ZnSiO4.
摘要翻译：目的：提供固体掺杂剂以使得能够在溶剂中掺杂导电聚合物，同时使用各种等离子体处理具有高分散性并稳定地制造非挥发性导电聚合物。构成：使用等离子体的导电聚合物的固体掺杂方法包括：合成固体掺杂剂的掺杂剂纳米粉末的步骤（S20）; 使用等离子体处理掺杂剂纳米粉末的步骤（S100）以及通过将由等离子体处理的掺杂剂纳米粉末与分散在溶剂中的导电聚合物混合来掺杂导电聚合物的步骤（S60）。掺杂剂纳米粉末选自二氧化钛，氧化钨，氧化铜，氧化铁，氧化锌，氧化锡，氧化锆，氧化钒，氧化镍，氧化镉，氧化硒，钛酸钡，包括硫酸锌，碘化锌，碘化钡，碘化钠，碘化铯，碘化铅，氧化锌，溴化铯，溴化钡，ZnS，ZnCdS，Gd2O2S，Y2O2S，CaWO3和ZnSiO4。

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