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1. 发明公开

EP1048344A2 Novel copper complexes for CO and olefin adsorption 审中-公开
标题翻译：新的铜配合物对CO和烯烃的吸附
公开(公告)号：EP1048344A2
公开(公告)日：2000-11-02
申请号：EP00109003.4
申请日：2000-04-26
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Strauss, Steven Howard , Polyakov, Oleg Gennadievich , Hammel, John Wesley , Ivanov, Svetlana Mechaelovna , Ivanov, Sergei Vladimirovich
IPC分类号： B01J20/02 , B01J20/18 , B01D53/02 , B01D53/62
CPC分类号： B01J20/22 , B01D53/02
摘要： A solid state composition is provided having the formula Cu(A) n Z, where A is CO or olefin, n > 1 and Z is a unitary or composite monovalent anion. Further provided are an apparatus adapted to adsorb and a method for adsorbing an adsorbate A from a fluid mixture. The apparatus and method employ an adsorbent having the formula Cu(A) n Z, where A is CO or olefin, n ≥ 0 and Z is a unitary or composite monovalent anion. Z can be selected from the group consisting of: a) X - where X - is BF 4 - , PF 6 - or SbF 6 - ; b) (Al x (OR) y ) - where R is fluoroalkyl or perfluoroalkyl, and x is 0 and y is 1, or x is 1 and y is 4; c) (RCO 2 ) - where R is alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl; d) (RSO 3 ) - where R is alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl; e) (H(RCO 2 ) 2 ) - where R is alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl; f) (H(RSO 3 ) 2 ) - where R is alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl; g) (N(SO 2 R) x R' y ) - where R is fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl, R' is alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl, x + y = 2 and x = 1 or 2; h) (C(SO 2 R) x R' y ) - where R is fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl, R' is hydrogen, alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl or perfluoroaryl, x + y = 3 and x = 1, 2 or 3; i) (CB 11 H 12-m X m ) - where m is from 0 to 12, and X is at least one member selected from the group consisting of halogen, alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl and perfluoroaryl; j) (CB 9 H 10-m X m ) - where m is from 0 to 10, and X is at least one member selected from the group consisting of halogen, alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl and perfluoroaryl; and k) (CB 11 F 11 R) - where R is alkyl, fluoroalkyl, perfluoroalkyl, aryl, fluoroaryl, perfluoroaryl or ammonium.

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