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    • 6. 发明授权
    • 폴리염화비페닐의 처리시스템
    • 폴리염화비페닐의처리시스템
    • KR100675106B1
    • 2007-01-29
    • KR1020060044519
    • 2006-05-18
    • 김경심송병주
    • 송병주김경심
    • B01D53/26B01D53/34
    • A treatment system of polychlorinated biphenyls which can prevent generation and discharge of dioxin and the like by pyrolyzing and oxidation-decomposing polychlorinated biphenyls simply, thereby fully detoxifying the polychlorinated biphenyls, and can maximize treatment efficiency by continuously performing pyrolysis and oxidation decomposition is provided. The treatment system of polychlorinated biphenyls comprises: a supercritical pyrolysis tank(10) into which a waste solution of polychlorinated biphenyls dissolved into methanol, and an alkaline solution are supplied to dechlorinate the polychlorinated biphenyls; and a supercritical oxidation reactor(30) into which a reaction product produced through reaction in the pyrolysis tank and an oxidizer are supplied to oxidize the reaction product, wherein the waste solution of polychlorinated biphenyls dissolved into methanol, and the alkaline solution are respectively supplied into the pyrolysis tank using high pressure pumps(114,134), the oxidizer is supplied into the oxidation reactor through a high pressure pump(314), a high pressure control valve(630) is installed on a pipe(40) for discharging a product reacted and produced in the oxidation reactor to control the pyrolysis tank and the reactor to a pressure range of 25 to 35 MPa.
    • 本发明提供一种多氯联苯处理系统,其能够通过简单地热解和氧化分解多氯联苯来防止二恶英等的产生和排出,从而充分地解毒多氯联苯,并且通过连续进行热解和氧化分解可以使处理效率最大化。 多氯联苯的处理系统包括:超临界热解罐(10),其中将多氯联苯的废溶液溶解在甲醇中,并供应碱溶液以对多氯联苯进行脱氯; 和超临界氧化反应器(30),其中通过热解罐中的反应产生的反应产物和氧化剂被供应以氧化反应产物,其中将多氯联苯的废溶液溶解到甲醇中,并将碱溶液分别供入 使用高压泵(114,134)的热解罐,通过高压泵(314)将氧化剂供应到氧化反应器中,将高压控制阀(630)安装在用于排出反应产物的管(40)上, 在氧化反应器中产生以控制热解罐和反应器至25至35MPa的压力范围。