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    • 1. 发明公开
    • 반도체산화물 섬유가 포함된 염료 감응형 태양전지 광전극 및 그 제조방법
    • 含有半导体氧化物纤维的透明型太阳能电池光电及其制造方法
    • KR1020130110372A
    • 2013-10-10
    • KR1020120032286
    • 2012-03-29
    • 재단법인 녹색에너지연구원
    • 박주영김은미구할본조흥관이재욱황경준최도영이석호
    • H01L31/042H01L31/0224H01L31/18
    • Y02E10/542Y02P70/521H01L31/042H01L31/0224H01L31/18
    • PURPOSE: A dye-sensitized solar cell photoelectrode containing semiconductor oxide fiber and a manufacturing method thereof increase the adsorption amount of dye by providing photoelectrodes in various forms. CONSTITUTION: A conductive thin film layer (111) is formed on the upper side of a transparent conductive substrate (110). The conductive thin film layer is composed of indium tin oxide (ITO) or fluoride doped tin oxide (FTO). A first photoelectrode layer (120) is formed on the upper side of the conductive thin film layer. The first photoelectrode layer is formed by coating the upper surface of the conductive thin film layer with paste and thermally treating the same. A second photoelectrode is formed on the upper side of the first photoelectrode layer. The second photoelectrode is formed by coating the upper surface of the first photoelectrode layer with metal-doped titanium oxide nanofiber paste and thermally treating the same. [Reference numerals] (120) TiO_2 + metal doping TiO_2 nano fiber
    • 目的:含有半导体氧化物纤维的染料敏化太阳能电池光电池及其制造方法通过提供各种形式的光电极来增加染料的吸附量。 构成:在透明导电性基板(110)的上侧形成有导电性薄膜层(111)。 导电薄膜层由氧化铟锡(ITO)或氟化物掺杂的氧化锡(FTO)组成。 第一光电极层(120)形成在导电薄膜层的上侧。 第一光电极层通过用糊涂覆导电薄膜层的上表面并对其进行热处理而形成。 第二光电极形成在第一光电极层的上侧。 第二光电极通过用金属掺杂的氧化钛纳米纤维糊涂覆第一光电极层的上表面并对其进行热处理而形成。 [参考数字](120)TiO_2 +金属掺杂TiO_2纳米纤维
    • 2. 发明授权
    • 전기방사와 수열반응을 이용한 반도체산화물 나노섬유 제조방법
    • 使用电解和热反应制备半导体氧化物纳米微粒的方法
    • KR101315917B1
    • 2013-10-08
    • KR1020120045152
    • 2012-04-30
    • 재단법인 녹색에너지연구원
    • 박주영최도영황철호이재욱이석호임철현오일홍이재혁김정훈김미진
    • D01F9/08D01D5/00B82Y40/00D01D1/06D01D10/02
    • D01F9/08B82Y40/00D01D1/065D01D5/0007D01D10/02D10B2101/00
    • PURPOSE: A semiconductor oxide nanofiber manufacture method using electrospinning and hydrothermal reaction is provided to relatively reduce a manufacture cost and time by producing organic and inorganic mixture nanofiber or organic and inorganic mixture nanofiber doped with metal and preparing a semiconductor oxide nanofiber by performing hydrothermal reaction on the mixture nanofiber. CONSTITUTION: A semiconductor oxide nanofiber manufacture method using electrospinning and hydrothermal reaction comprises following steps. An acetic acid and ethanol are added and stirred in a precursor material, and a polymer material is added thereto to prepare a homogenous synthetic solution (S10). A metal solution is mixed to the homogenous synthetic solution for metal doping at a molar ratio in a range of 0.5-2% (S20). The synthetic solution mixed with the metal solution is electrospun to produce organic and inorganic mixture nanofiber (S30). In a hydrothermal reaction process the organic and inorganic mixture nanofiber is added into a mixture solution of water and ethanol, and a polymer material is removed through hydrothermal reaction to manufacture a semiconductor oxide nanofiber (S40). [Reference numerals] (AA) Start; (BB) End; (S10) Stir precursor material + acetic acid + ethanol + polymer material; (S20) Mix metal solution in synthetic solution; (S30) Electrospin synthetic solution to produce metal doped nanofiber; (S40) Crystallize through hydrothermal reaction and remove polymer to produce semiconductor oxide nanofiber
    • 目的:提供一种使用静电纺丝和水热反应的半导体氧化物纳米纤维制造方法,通过生产有机和无机混合物纳米纤维或掺杂金属的有机和无机混合纳米纤维并通过进行水热反应制备半导体氧化物纳米纤维来相对降低制造成本和时间 混合纳米纤维。 构成:使用静电纺丝和水热反应的半导体氧化物纳米纤维制造方法包括以下步骤。 加入乙酸和乙醇并在前体材料中搅拌,并向其中加入聚合物材料以制备均匀的合成溶液(S10)。 将金属溶液与均匀的合成溶液混合,以0.5-2%的摩尔比进行金属掺杂(S20)。 将与金属溶液混合的合成溶液静电纺丝以产生有机和无机混合物纳米纤维(S30)。 在水热反应过程中,将有机和无机混合物纳米纤维加入到水和乙醇的混合溶液中,通过水热反应除去聚合物材料,制备半导体氧化物纳米纤维(S40)。 (附图标记)(AA)开始; (BB)结束; (S10)搅拌前体物质+乙酸+乙醇+聚合物材料; (S20)将合成溶液中的金属溶液混合; (S30)电纺丝合成溶液制备金属掺杂纳米纤维; (S40)通过水热反应结晶并除去聚合物,生成半导体氧化物纳米纤维