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1. 发明授权

US07179868B2 Polyglycolic acid-based resin composition and shaped product thereof 有权
标题翻译：聚乙醇酸系树脂组合物及其成型体
公开(公告)号：US07179868B2
公开(公告)日：2007-02-20
申请号：US10548646
申请日：2004-03-19
申请人： Kazuyuki Yamane , Hiroyuki Sato , Yukichika Kawakami
发明人： Kazuyuki Yamane , Hiroyuki Sato , Yukichika Kawakami
IPC分类号： C08L67/04 , C08F20/02
CPC分类号： B32B27/36 , C08L67/02 , C08L67/04 , C08L2666/18
摘要： A polyglycolic acid-based resin composition is formed by adding a relatively small amount of aromatic polyester resin to a polyglycolic acid resin. The thus-formed composition is provided with remarkably improved moisture resistance stability and hot-melt processability, and further improved stretchability, while retaining the excellent properties as represented by gas barrier property of the polyglycolic acid resin. As a result of stretching by utilizing the improved stretchability, a shaped product having an improved transparency can be obtained.
摘要翻译：通过将相对少量的芳族聚酯树脂加入到聚乙醇酸树脂中来形成聚乙醇酸类树脂组合物。提供如此形成的组合物具有显着改进的耐湿稳定性和热熔加工性，并且进一步提高拉伸性，同时保持由聚乙醇酸树脂的阻气性表示的优异性能。通过利用改进的拉伸性进行拉伸的结果，可以获得具有改善的透明度的成形制品。

2. 发明授权

US07067611B2 Polyhydroxycarboxylic acid and its production process 有权
标题翻译：聚羟基羧酸及其生产工艺
公开(公告)号：US07067611B2
公开(公告)日：2006-06-27
申请号：US10483039
申请日：2002-07-05
申请人： Kazuyuki Yamane , Yukichika Kawakami
发明人： Kazuyuki Yamane , Yukichika Kawakami
IPC分类号： C08G63/02
CPC分类号： C08G63/80 , C08G63/08
摘要： Polyhydroxycarhoxylic acids are provided, which are controlled in terms of the rate of biodegradability, and give molded or otherwise formed articles that are of uniform quality with neither premature strength drop nor premature deterioration of retention of outside shape, and their production process is provided as well. The poly-hydroxycarboxylic acids are obtained by ring-opening polymerization of cyclic esters. The polyhydroxy-carboxylic acids have a weight-average molecular weight (Mw) in the range of 10,000 to 1,000,000, a molecular weight distribution in the range of 1.0 to 2.5 as represented by the weight-average molecular weight-to-number-average molecular weight ratio (Mw/Mn) and a yellowness index (YI) of 40 or less, and have a precisely controlled rate of biodegradability.
摘要翻译：提供了多羟基甲氧基酸，其以生物降解性的速率进行控制，并且得到具有均匀质量的成型制品或其它成型制品，既不过早强度下降也不会使外部形状保持力过早劣化，并且还提供其制造方法。多羟基羧酸通过环状酯的开环聚合得到。多羟基羧酸的重均分子量（Mw）为10,000〜1,000,000，分子量分布范围为1.0〜2.5，以重均分子量与数均分子量重量比（Mw / Mn）和黄色指数（YI）为40以下，具有精确控制的生物降解率。

3. 发明授权

US06916939B2 Process for the preparation of cyclic esters and method for purification of the same 有权
标题翻译：环酯的制备方法及其纯化方法
公开(公告)号：US06916939B2
公开(公告)日：2005-07-12
申请号：US10344461
申请日：2001-08-08
申请人： Kazuyuki Yamane , Yukichika Kawakami , Hajime Hoshi , Kazuhiko Sunagawa
发明人： Kazuyuki Yamane , Yukichika Kawakami , Hajime Hoshi , Kazuhiko Sunagawa
IPC分类号： C07D319/12
CPC分类号： C08J3/28 , C07D319/12 , C08J11/24 , C08J2300/14 , C08J2367/04 , Y02W30/706
摘要： The present invention provides a process for production of a cyclic ester by depolymerization of an aliphatic polyester. In the process, a mixture containing the aliphatic polyester and a specific polyalkylene glycol ether, which has a boiling point of 230-450° C. and a molecular weight of 150-450, is heated under normal or reduced pressure to a temperature at which depolymerization of the aliphatic polyester takes place. Then, a substantially homogeneous solution phase, consisting of the melt phase of the aliphatic polyester and the liquid phase of the polyalkylene glycol ether, is formed. Heating of the solution phase is continued to form the cyclic ester by depolymerization and distil out the cyclic ester together with the polyalkylene glycol ether, and then the cyclic ester is recovered from the distillate. The present invention also provides a process for purification of a crude cyclic ester by use of the specific polyalkylene glycol ether described above.
摘要翻译：本发明提供了通过脂肪族聚酯的解聚制备环状酯的方法。在该方法中，将含有脂族聚酯和特定的聚亚烷基二醇醚的混合物在沸点为230-450℃，分子量为150-450的条件下，在正常或减压下加热至发生脂肪族聚酯的解聚。然后，形成由脂肪族聚酯的熔融相和聚亚烷基二醇醚的液相组成的基本均匀的溶液相。溶液相的加热继续通过解聚形成环酯，并与聚亚烷基二醇醚一起蒸馏出环状酯，然后从馏出物中回收环状酯。本发明还提供了通过使用上述特定的聚亚烷基二醇醚来纯化粗环酯的方法。

4. 发明授权

US06852827B2 Polyester production process and reactor apparatus 失效
标题翻译：聚酯生产工艺和反应器设备
公开(公告)号：US06852827B2
公开(公告)日：2005-02-08
申请号：US10476117
申请日：2002-07-05
申请人： Kazuyuki Yamane , Yukichika Kawakami , Hiroyuki Sato , Tomohiro Hoshi
发明人： Kazuyuki Yamane , Yukichika Kawakami , Hiroyuki Sato , Tomohiro Hoshi
IPC分类号： C08G63/89 , B01J19/02 , B01J19/24 , C08G63/08 , C08G63/78 , C08G63/02
CPC分类号： B01J19/24 , B01J19/02 , B01J19/2415 , B01J2219/0236 , B01J2219/1943 , B01J2219/1946 , C08G63/08 , C08G63/78 , C08G63/785 , C08G63/89
摘要： The invention provides a polyester production process by bulk polymerization in a reactor, wherein the volume of the resulting polyester is shrunk for a release from the inner surface of the reactor, so that the polyester can be recovered in the form of a bulky mass. The invention also provides a reactor for bulk polymerization for polyester, which comprises an inner surface that enabling the resulting polyester to be released therefrom upon its volume shrinkage.
摘要翻译：本发明提供了在反应器中本体聚合的聚酯制造方法，其中所得聚酯的体积收缩以从反应器的内表面释放，使得聚酯可以以体积质量的形式回收。本发明还提供了一种用于聚酯的本体聚合反应器，其包括使得所得聚酯在其体积收缩时能够从其中释放的内表面。

5. 发明授权

US6159416A Stretch blow molded container and production process thereof 有权
标题翻译：拉伸吹塑容器及其生产工艺
公开(公告)号：US6159416A
公开(公告)日：2000-12-12
申请号：US304353
申请日：1999-05-04
申请人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
发明人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
IPC分类号： B29C49/00 , B29C49/04 , B29C49/06 , B29C49/64 , B65D1/02 , C08L67/04 , B29C49/12 , B29C47/00
CPC分类号： B29C49/0005 , B65D1/0207 , C08L67/04 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/04 , B29C49/06 , B29C49/6472 , B29K2995/004 , Y10S220/30 , Y10T428/1352 , Y10T428/1397 , Y10T428/24975 , Y10T428/24992
摘要： The invention provides a stretch blow molded container formed from a thermoplastic resin material which comprises polyglycolic acid having(a) a repeating unit represented by the following formula (1): ##STR1## (b) a melt viscosity, .eta.* [as measured at a temperature of (the melting point, Tm of the polymer+20.degree. C.) and a shear rate of 100/sec] of 500-100,000 Pa.s;(c) a melting point, Tm of at least 180.degree. C.;(d) a melt enthalpy, .DELTA.Hm of at least 20 J/g; and(e) a density of at least 1.50 g/cm.sup.3 as measured in an unoriented, crystallized form,wherein the stretch blow molded container has tensile strength (in a circumferential direction) of at least 100 MPa and a carbon dioxide permeability (as measured at a temperature of 23.degree. C. and 80% relative humidity; in terms of the thickness of 50 .mu.m) of 300 cc/m.sup.2.day.atm or smaller at the body sidewall thereof, and a production process thereof.
摘要翻译：本发明提供一种由热塑性树脂材料形成的拉伸吹塑成型容器，该容器包含聚乙醇酸，该聚乙醇酸具有（a）由下式（1）表示的重复单元：（b）熔体粘度eta * [在（熔点，聚合物的Tm + 20℃）和100 /秒的剪切速率]为500-10000Pa.s; （c）熔点Tm为至少180℃。（d）熔体焓，至少20J / g的DELTA Hm; 和（e）以非取向的结晶形式测量的至少1.50g / cm 3的密度，其中拉伸吹塑成型容器的拉伸强度（在圆周方向）为至少100MPa，二氧化碳渗透性（测量在23℃和80％相对湿度的温度下，在其体侧壁为300cc / m2.day.atm或更小的厚度为50μm）及其制造方法。

6. 发明授权

US6001439A Stretch blow molded container and production process thereof 失效
标题翻译：拉伸吹塑容器及其生产工艺
公开(公告)号：US6001439A
公开(公告)日：1999-12-14
申请号：US846137
申请日：1997-04-25
申请人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
发明人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
IPC分类号： B29C49/00 , B29C49/04 , B29C49/06 , B29C49/64 , B65D1/02 , C08L67/04 , C08K5/10 , B29D22/00
CPC分类号： B29C49/0005 , B65D1/0207 , C08L67/04 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/04 , B29C49/06 , B29C49/6472 , B29K2995/004 , Y10S220/30 , Y10T428/1352 , Y10T428/1397 , Y10T428/24975 , Y10T428/24992
摘要： The invention provides a stretch blow molded container formed from a thermoplastic resin material which comprises polyglycolic acid having(a) a repeating unit represented by the following formula (1): ##STR1## (b) a melt viscosity, .eta.* [as measured at a temperature of (the melting point, Tm of the polymer+20.degree. C.) and a shear rate of 100/sec] of 500-100,000 Pa.multidot.s;(c) a melting point, Tm of at least 180.degree. C.;(d) a melt enthalpy, .DELTA.Hm of at least 20 J/g; and(e) a density of at least 1.50 g/cm.sup.3 as measured in an unoriented, crystallized form,wherein the stretch blow molded container has tensile strength (in a circumferential direction) of at least 100 MPa and a carbon dioxide permeability (as measured at a temperature of 23.degree. C. and 80% relative humidity; in terms of the thickness of 50 .mu.m) of 300 cc/m.sup.2 .multidot.day.multidot.atm or smaller at the body sidewall thereof, and a production process thereof.
摘要翻译：本发明提供一种由热塑性树脂材料形成的拉伸吹塑成型容器，该容器包含聚乙醇酸，该聚乙醇酸具有（a）由下式（1）表示的重复单元：（b）熔体粘度eta * [在（熔点，聚合物的Tm + 20℃）和100 /秒的剪切速率]为500-10000Pax; （c）熔点Tm为至少180℃。（d）熔体焓，至少20J / g的DELTA Hm; 和（e）以非取向的结晶形式测量的至少1.50g / cm 3的密度，其中拉伸吹塑成型容器的拉伸强度（在圆周方向）为至少100MPa，二氧化碳渗透性（测量在23℃和80％相对湿度的温度下，在其体侧壁为300cc / m 2×day×atm以下的厚度为50μm），及其制造方法。

7. 发明授权

US4495332A Process for producing aromatic sulfide polymers 失效
标题翻译：生产芳香族硫化物聚合物的方法
公开(公告)号：US4495332A
公开(公告)日：1985-01-22
申请号：US517837
申请日：1983-07-27
申请人： Zenya Shiiki , Yo Iizuka , Yukichika Kawakami
发明人： Zenya Shiiki , Yo Iizuka , Yukichika Kawakami
IPC分类号： C08F2/16 , C08G75/02
CPC分类号： C08G75/0254
摘要： A process for obtaining aromatic sulfide polymer which has a markedly high molecular weight and can be readily formed into films, fibers, and other structures. The process comprises heating, in an aprotic solvent to a temperature of 100.degree. to 250.degree. C., (i) a dihaloaromatic compound and (ii) substantially anhydrous fine powder of the sulfide of an alkali or alkaline earth metal in the presence of (iii) substantially anhydrous fine powder of the carbonate of an alkali or alkaline earth metal, or of a mixture thereof with a hygroscopic inorganic salt and (iv) a strictly controlled very small amount of water dissolved in or solvated with the solvent.
摘要翻译：一种获得具有显着高分子量并可容易地形成薄膜，纤维和其它结构的芳香族硫化物聚合物的方法。该方法包括在非质子溶剂中加热至100-250℃的温度，（i）二卤代芳族化合物和（ii）碱金属或碱土金属的硫化物的基本上无水的细粉末，在（ iii）碱性或碱土金属碳酸盐或其吸湿性无机盐的混合物的基本上无水的细粉末和（iv）严格控制的非常少量的溶于溶剂或溶剂化的水。

8. 发明申请

US20050214368A1 Controlled release formulations using intelligent polymers 审中-公开
标题翻译：使用智能聚合物的控制释放配方
公开(公告)号：US20050214368A1
公开(公告)日：2005-09-29
申请号：US11109067
申请日：2005-04-19
申请人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
发明人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
IPC分类号： A61K9/14 , A61K9/20 , A61K9/22 , A61K9/28 , A61K31/716
CPC分类号： A61K9/2846 , A61K9/2054 , A61K9/2077 , A61K31/716
摘要： A controlled release pharmaceutical composition comprises (a) at least one pharmaceutically active substance having a water contact angle (θ) such that cos θ is between +0.9848 and −0.9848, (b) a first intelligent polymer component; and (c) a second intelligent polymer component having opposite wettability characteristics to the first intelligent polymer component, the first and second polymer components being present in a ratio in the range of about 1:100 to about 100:1 by weight. The polymer components are effective for controlled release of the pharmaceutically active substance from the composition.
摘要翻译：控释药物组合物包含（a）至少一种具有水接触角（θ）的药物活性物质，使得cosθ在+ 0.9848和-0.9848之间，（b）第一智能聚合物组分; 和（c）具有与第一智能聚合物组分相反润湿特性的第二智能聚合物组分，第一和第二聚合物组分以约1:100至约100:1重量比的比例存在。聚合物组分对于从组合物中控制释放药物活性物质是有效的。

9. 发明授权

US06183679B2 Production process for injection-molded product of polyglycolic acid 有权
标题翻译：聚乙醇酸注射成型产品的生产工艺
公开(公告)号：US06183679B2
公开(公告)日：2001-02-06
申请号：US09504604
申请日：2000-02-15
申请人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
发明人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
IPC分类号： B29C4500
CPC分类号： C08G63/08 , B29C45/0001 , C08L67/04
摘要： The invention provides an injection-molded product of polyglycolic acid obtainable by molding a thermoplastic resin material at an injection temperature ranging from the melting point, Tm of the polymer to 255° C., wherein the thermoplastic resin material comprises polyglycolic acid having a repeating unit represented by the following formula (1): and the following physical properties: (a) the melt viscosity, &eegr;* [as measured at a temperature of (the melting point, Tm of the polymer+20° C.) and a shear rate of 1,000/sec] being 30-10,000 Pa·s; (b) the melting point, Tm being at least 150° C.; (c) the melt enthalpy, &Dgr;Hm being at least 20 J/g; and (d) the density being at least 1.50 g/cm3 as measured in an unoriented, crystallized form, and a production process thereof.
摘要翻译：本发明提供一种聚乙醇酸的注射成型品，其通过在从聚合物的熔点Tm至255℃的注射温度下模制热塑性树脂材料而得到，其中热塑性树脂材料包含具有重复单元的聚乙醇酸由下式（1）表示：和（a）熔体粘度eta * [在（熔点，聚合物的Tm + 20℃）的温度和剪切速率 1,000 /秒]为30-10,000Pa.s;（b）熔点Tm为至少150℃;（c）熔体焓DELTAHm为至少20J / g; 和（d）以非取向的结晶形式测量的密度为至少1.50g / cm 3，及其制造方法。

10. 发明授权

US5853639A Oriented polyglycolic acid film and production process thereof 失效
标题翻译：取向聚乙醇酸薄膜及其制备方法
公开(公告)号：US5853639A
公开(公告)日：1998-12-29
申请号：US844408
申请日：1997-04-18
申请人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
发明人： Yukichika Kawakami , Nobuo Sato , Mitsuru Hoshino , Toshitaka Kouyama , Zenya Shiiki
IPC分类号： B29C47/00 , B29C55/02 , B29C61/06 , B29K67/00 , B29L7/00 , C08G63/06 , C08G63/08 , C08J5/18 , C08L101/16 , B29C47/12
CPC分类号： B29C55/06 , B29C55/143 , C08G63/08 , C08J5/18 , B29C55/28 , B29K2067/043 , B29K2067/046 , B29K2995/006 , C08J2367/04 , Y10S264/73 , Y10T428/249921 , Y10T428/25
摘要： The invention provides an oriented polyglycolic acid film formed from a thermoplastic resin material which comprises polyglycolic acid having a repeating unit represented by the following formula (1): ##STR1## and the following physical properties: (a) the melt viscosity, .rho.* �as measured at a temperature of (the melting point, Tm of the polymer+20.degree. C.) and a shear rate of 100/sec! being 500-100,000 Pa.s; (b) the melting point, Tm being at least 150.degree. C.; (c) the melt enthalpy, .DELTA.Hm being at least 20 J/g; and (d) the density being at least 1.50 g/cm.sup.3 as measured in an unoriented, crystallized form, wherein the film has tensile strength of at least 150 MPa, and production processes thereof.
摘要翻译：本发明提供一种由热塑性树脂材料形成的定向聚乙醇酸膜，其包含具有由下式（1）表示的重复单元的聚乙醇酸：rties：（a）熔体粘度rho * [在（熔点，聚合物的Tm + 20℃）和剪切速率为100 /秒]为500-100,000Pa.s; （b）熔点Tm为至少150℃。（c）熔体焓DELTA Hm为至少20J / g; 和（d）以未取向的结晶形式测量的密度为至少1.50g / cm 3，其中所述膜具有至少150MPa的拉伸强度及其制备方法。

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