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1. 发明授权

US10680193B2 Photoelectric cells incorporating wrinkles and folds to enhance efficiency and bendability and method of making 有权
公开(公告)号：US10680193B2
公开(公告)日：2020-06-09
申请号：US14214564
申请日：2014-03-14
申请人： Yueh-Lin Loo , Jongbok Kim , Pilnam Kim , Howard Stone , Nicolas Pegard , Jason Fleischer
发明人： Yueh-Lin Loo , Jongbok Kim , Pilnam Kim , Howard Stone , Nicolas Pegard , Jason Fleischer
IPC分类号： H01L51/44 , H01L51/00 , H01L51/42
摘要： A photovoltaic cell and method of making are disclosed. The photovoltaic cell includes a substrate having a surface at least partially covered in wrinkles and folds, the folds dividing the surface into a plurality of domains. A photoactive layer is formed on the substrate. At least one transparent electrode is coupled to the photoactive layer and configured to allow transmission of light into the photoactive layer. The domains may have a wrinkle periodicity of less than 2 μm. The folds may have a fold density of less than 0.25. The transport layer may comprise PEDOT:PSS. The photoactive layer may comprise P3HT:PCBM. The photoactive layer may comprise a bulk heterojunction.

2. 发明申请

US20140261675A1 PHOTOELECTRIC CELLS INCORPORATING WRINKLES AND FOLDS TO ENHANCE EFFICIENCY AND BENDABILITY AND METHOD OF MAKING 审中-公开
标题翻译：光电池加入皱纹和加强效率和弯曲性及其制作方法
公开(公告)号：US20140261675A1
公开(公告)日：2014-09-18
申请号：US14214564
申请日：2014-03-14
申请人： Yueh-Lin Loo , Jongbok Kim , Pilnam Kim , Howard Stone , Nicolas Pegard , Jason Fleischer
发明人： Yueh-Lin Loo , Jongbok Kim , Pilnam Kim , Howard Stone , Nicolas Pegard , Jason Fleischer
IPC分类号： H01L31/0236 , H01L51/44
CPC分类号： H01L51/447 , H01L51/0037 , H01L51/0097 , H01L51/4253 , Y02E10/549
摘要： A photovoltaic cell and method of making are disclosed. The photovoltaic cell includes a substrate having a surface at least partially covered in wrinkles and folds, the folds dividing the surface into a plurality of domains. A photoactive layer is formed on the substrate. At least one transparent electrode is coupled to the photoactive layer and configured to allow transmission of light into the photoactive layer. The domains may have a wrinkle periodicity of less than 2 μm. The folds may have a fold density of less than 0.25. The transport layer may comprise PEDOT:PSS. The photoactive layer may comprise P3HT:PCBM. The photoactive layer may comprise a bulk heterojunction.
摘要翻译：公开了一种光伏电池及其制造方法。光伏电池包括具有至少部分地被折皱和折叠的表面的基底，该折叠将表面分成多个畴。在基板上形成光敏层。至少一个透明电极耦合到光敏层并且被配置为允许光透射到光活性层中。这些区域的皱纹周期可能小于2μm。折叠可以具有小于0.25的折叠密度。传输层可以包括PEDOT：PSS。光敏层可以包括P3HT：PCBM。光活性层可以包括体异质结。

3. 发明授权

US08248681B2 Water-dispersible polyaniline films capable of undergoing stable and reversible polyelectrochromic transitions 有权
标题翻译：能够经历稳定和可逆的多电解色素转换的水分散性聚苯胺薄膜
公开(公告)号：US08248681B2
公开(公告)日：2012-08-21
申请号：US12984166
申请日：2011-01-04
申请人： Yueh-Lin Loo , Joung Eun Yoo , Jacob Tarver
发明人： Yueh-Lin Loo , Joung Eun Yoo , Jacob Tarver
IPC分类号： G02F1/15
CPC分类号： G02F1/15 , G02F2001/1515
摘要： The present disclosure relates generally to polyaniline (PANI) materials capable of undergoing stable and reversible polyelectrochromic transitions between multiple oxidation states. More specifically, the embodiments described herein include novel PANI-PAAMPSA structures that are capable of undergoing stable and reversible transitions between the ES, LB and PB oxidation states. In some embodiments, the structures described are capable of undergoing stable transitions over a broad pH range. Also described herein are methods of preparing certain electrochromic structures.
摘要翻译：本公开通常涉及能够在多种氧化态之间经历稳定和可逆的多电致变色转变的聚苯胺（PANI）材料。更具体地，本文描述的实施方案包括能够在ES，LB和PB氧化态之间经历稳定和可逆转变的新型PANI-PAAMPSA结构。在一些实施方案中，所描述的结构能够在宽的pH范围内经历稳定的转变。本文还描述了制备某些电致变色结构的方法。

4. 发明申请

US20100112750A1 Post-Processing Treatment of Conductive Polymers to Enhance Electrical Conductivity 有权
标题翻译：导电聚合物的后处理加强电导率
公开(公告)号：US20100112750A1
公开(公告)日：2010-05-06
申请号：US12574677
申请日：2009-10-06
申请人： Yueh-Lin Loo , Joung Eun Yoo , Kwang Seok Lee
发明人： Yueh-Lin Loo , Joung Eun Yoo , Kwang Seok Lee
IPC分类号： H01L51/40
CPC分类号： H01L51/0035 , H01L51/0021 , H01L51/102 , H01L51/5203
摘要： A method for enhancing electrical conductivity of a film which includes at least one conductive polymer. The method includes providing the film comprising the at least one conductive polymer and at least one polymer acid, agitating the film in at least one reagent; and, placing the film on a heated surface. The at least one reagent includes a reagent acid that is stronger than the polymer acid. The conductivity of the treated film is significantly greater than the conductivity of the untreated film.
摘要翻译：一种用于增强包括至少一种导电聚合物的膜的导电性的方法。该方法包括提供包含至少一种导电聚合物和至少一种聚合物酸的膜，在至少一种试剂中搅拌该膜; 并将膜放置在加热的表面上。所述至少一种试剂包括比聚合物酸更强的试剂酸。经处理的膜的电导率显着大于未处理膜的电导率。

5. 发明申请

US20110205613A1 WATER-DISPERSIBLE POLYANILINE FILMS CAPABLE OF UNDERGOING STABLE AND REVERSIBLE POLYELECTROCHROMIC TRANSITIONS 有权
标题翻译：水溶性聚苯胺薄膜可承受稳定和可逆的聚电解质转换
公开(公告)号：US20110205613A1
公开(公告)日：2011-08-25
申请号：US12984166
申请日：2011-01-04
申请人： Yueh-Lin Loo , Joung Eun Yoo , Jacob Tarver
发明人： Yueh-Lin Loo , Joung Eun Yoo , Jacob Tarver
IPC分类号： G02F1/15 , B05D5/06 , B05D5/12 , B05D3/00 , B05D3/10
CPC分类号： G02F1/15 , G02F2001/1515
摘要： The present disclosure relates generally to polyaniline (PANI) materials capable of undergoing stable and reversible polyelectrochromic transitions between multiple oxidation states. More specifically, the embodiments described herein include novel PANI-PAAMPSA structures that are capable of undergoing stable and reversible transitions between the ES, LB and PB oxidation states. In some embodiments, the structures described are capable of undergoing stable transitions over a broad pH range. Also described herein are methods of preparing certain electrochromic structures.
摘要翻译：本公开通常涉及能够在多种氧化态之间经历稳定和可逆的多电致变色转变的聚苯胺（PANI）材料。更具体地，本文描述的实施方案包括能够在ES，LB和PB氧化态之间经历稳定和可逆转变的新型PANI-PAAMPSA结构。在一些实施方案中，所描述的结构能够在宽的pH范围内经历稳定的转变。本文还描述了制备某些电致变色结构的方法。

6. 发明申请

US20090321277A1 ELECTRON-CONDUCTING CROSSLINKED POLYANILINE-BASED REDOX HYDROGEL, AND METHOD OF MAKING 有权
标题翻译：基于交联聚氨酯的REDOX HYDROGEL的电子导电及其制造方法
公开(公告)号：US20090321277A1
公开(公告)日：2009-12-31
申请号：US12114359
申请日：2008-05-02
申请人： Adam Heller , Benjamin J. Feldman , Nicolas Mano , Yueh-Lin Loo
发明人： Adam Heller , Benjamin J. Feldman , Nicolas Mano , Yueh-Lin Loo
IPC分类号： C12Q1/54 , C12N9/96 , G01N27/30
CPC分类号： G01N27/3271 , C12Q1/001 , C12Q1/005 , C12Q1/006 , C12Q1/26 , G01N27/327
摘要： A polymer matrix that may coated on an electrode is created by co-crosslinking (1) an adduct of a polyaniline formed by templated oxidative polymerization on a polymer acid; (2) a water-soluble crosslinker; and (3) a redox enzyme. The polymer matrix may be hydrated, and the absorbed water may make it permeable to, for example, glucose. The polyaniline may be polyaniline itself or a substituted polyaniline; the water-soluble crosslinker may be poly(ethylene glycol) diglycidyl ether, and the redox enzyme may be glucose oxidase. The polymer matrix may be produced by co-crosslinking (1) an adduct of an electrically conductive polymer and a polymer acid; (2) a water-soluble crosslinker; and (3) a redox enzyme in a single step at an about neutral pH, curing by drying. After hydration, the crosslinked polymer matrix may form a 3-dimensional glucose-permeable bioelectrocatalyst, catalyzing the electrooxidation of glucose.
摘要翻译：可以通过共聚交联（1）通过模板化氧化聚合形成的聚苯胺在聚合物酸上的加合物来产生可涂覆在电极上的聚合物基质; （2）水溶性交联剂; 和（3）氧化还原酶。聚合物基质可以是水合的，并且所吸收的水可以使其可以例如葡萄糖渗透。聚苯胺可以是聚苯胺本身或取代的聚苯胺; 水溶性交联剂可以是聚（乙二醇）二缩水甘油醚，氧化还原酶可以是葡萄糖氧化酶。聚合物基质可以通过共交联（1）导电聚合物的加合物和聚合物酸来制备; （2）水溶性交联剂; 和（3）在大约中性pH下在一个步骤中的氧化还原酶，通过干燥固化。水合后，交联聚合物基质可形成3维葡萄糖可渗透的生物电催化剂，催化葡萄糖的电氧化。

7. 发明申请

US20070142619A1 FORMING ELECTRICAL CONTACTS TO A MOLECULAR LAYER 审中-公开
标题翻译：形成与分子层的电气联系
公开(公告)号：US20070142619A1
公开(公告)日：2007-06-21
申请号：US11677403
申请日：2007-02-21
申请人： Julia Hsu , Yueh-Lin Loo , John Rogers
发明人： Julia Hsu , Yueh-Lin Loo , John Rogers
IPC分类号： C08G79/00
CPC分类号： H01L51/0595 , B82Y10/00 , B82Y40/00 , G03F7/0002 , H01L21/2007 , H01L21/76251 , H01L27/283 , H01L51/0001 , H01L51/0004 , H01L51/0013 , H01L51/0021 , H01L51/0024 , H01L51/0036 , H01L51/0052 , H01L51/0053 , H01L51/0078 , H01L51/0512 , H01L51/0516 , H01L51/0541 , H01L51/0545 , H01L51/105
摘要： The present invention provides a process for forming electrical contacts to a molecular layer in a nanoscale device, the nanoscale device, and a method of manufacturing an integrated circuit comprise such devices. The process includes coating a surface of a stamp with a metal layer and forming an attached layer of anchored molecules by coupling first ends of the anchored molecules to a conductive or semiconductive substrate. The process also includes placing the metal layer in contact with the attached layer of anchored molecules such that the metal layer chemically bonds to free ends of the anchored molecules. The resulting devices produced have superior reliability as compared to conventional prepared devices.
摘要翻译：本发明提供了一种用于在纳米级器件中形成与分子层的电接触的方法，纳米级器件，以及制造集成电路的方法包括这样的器件。该方法包括用金属层涂覆印模的表面并通过将锚定分子的第一端耦合到导电或半导电基底而形成附着的锚定分子层。该方法还包括使金属层与附着的锚定分子层接触，使得金属层化学键合到锚定分子的自由端。所制造的装置与传统的制备装置相比具有优异的可靠性。

8. 发明授权

US06946332B2 Forming nanoscale patterned thin film metal layers 有权
标题翻译：形成纳米级图案薄膜金属层
公开(公告)号：US06946332B2
公开(公告)日：2005-09-20
申请号：US10098202
申请日：2002-03-15
申请人： Yueh-Lin Loo , John A. Rogers
发明人： Yueh-Lin Loo , John A. Rogers
IPC分类号： G03F7/00 , H01L21/00 , H01L27/12 , H01L51/05 , H01L51/40 , H01L21/84
CPC分类号： G03F7/0002 , B82Y10/00 , B82Y40/00 , H01L27/1203 , H01L51/0001 , H01L51/0004 , H01L51/0024 , H01L51/0516 , H01L51/0541 , H01L51/0545
摘要： The specification describes a contact printing technique for forming patterns of thin films with nanometer resolution over large areas. The procedure, termed here “nanotransfer printing (nTP)”, relies on tailored surface chemistries for transferring thin films, typically metal films, from the raised regions of a stamp to a substrate when these two elements are brought into intimate physical contact. This technique is purely additive, it is fast (
摘要翻译：本说明书描述了一种用于在大面积上形成具有纳米分辨率的薄膜图案的接触印刷技术。在这里称为“纳米转印（nTP）”的方法依赖于定制的表面化学成分，以将薄膜（通常为金属薄膜）从印模的凸起区域转移到基底，当这两个元素进行紧密的物理接触时。这种技术纯粹是添加剂，它是快速的（<15秒的接触时间），并且在室温下在单独的加工步骤中进行印刷。 nTP能够产生具有大小至100nm的大范围特征的图案，并且边缘分辨率优于25nm。已经为高性能有机薄膜晶体管（TFT）和互补逆变器电路制造了电触点和互连，以证明nTP的许多潜在应用之一。

9. 发明授权

US09040318B2 Lamination as a modular approach for building organic photosensitive devices 有权
标题翻译：层压作为构建有机光敏器件的模块化方法
公开(公告)号：US09040318B2
公开(公告)日：2015-05-26
申请号：US13083220
申请日：2011-04-08
申请人： Yueh-Lin Loo , Jong Bok Kim
发明人： Yueh-Lin Loo , Jong Bok Kim
IPC分类号： H01L21/00 , H01L51/00 , B82Y10/00 , H01L51/42
CPC分类号： H01L51/0024 , B82Y10/00 , H01L51/0023 , H01L51/0036 , H01L51/0047 , H01L51/4246 , H01L51/4253 , Y02E10/549
摘要： There is disclosed a modular lamination approach for processing organic photosensitive devices that allows the individual processing of device components, that once processed are brought together in a final step to make electrical contact. The disclosed method of preparing a laminated photosensitive device having at least one donor-acceptor heterojunction comprises: preparing a top electrode by depositing a functional material on a flexible substrate, such as an elastomer; optionally processing the functional material to obtain desired properties prior to lamination; preparing a bottom portion by depositing a second functional material over a substrate; optionally processing the second functional material to obtain desired properties prior to lamination; and coupling the top electrode to said bottom portion to form a laminated photosensitive device.
摘要翻译：公开了一种用于处理有机光敏器件的模块化层压方法，其允许在最终步骤中将一次处理的装置部件的各个处理结合在一起以进行电接触。所公开的制备具有至少一个供体 - 受体异质结的层压感光装置的方法包括：通过将功能材料沉积在诸如弹性体的柔性基底上来制备顶部电极; 任选地处理功能材料以在层压之前获得期望的性能; 通过在衬底上沉积第二功能材料来制备底部部分; 任选地处理第二功能材料以在层压之前获得期望的性能; 并且将顶部电极耦合到所述底部部分以形成层叠的感光装置。

10. 发明申请

US20120152762A1 Crosslinked Adduct of Polyaniline and Polymer Acid Containing Redox Enzyme for Electrochemical Sensor 有权
标题翻译：聚苯胺和含有氧化还原酶的聚合物酸的电化学传感器的交联加合物
公开(公告)号：US20120152762A1
公开(公告)日：2012-06-21
申请号：US13326071
申请日：2011-12-14
申请人： Adam Heller , Benjamin J. Feldman , Nicolas Mano , Yueh-Lin Loo
发明人： Adam Heller , Benjamin J. Feldman , Nicolas Mano , Yueh-Lin Loo
IPC分类号： G01N33/66 , G01N27/26
CPC分类号： G01N27/3271 , C12Q1/001 , C12Q1/005 , C12Q1/006 , C12Q1/26 , G01N27/327
摘要： A polymer matrix that may coated on an electrode is created by co-crosslinking (1) an adduct of a polyaniline formed by templated oxidative polymerization on a polymer acid; (2) a water-soluble crosslinker; and (3) a redox enzyme. The polymer matrix may be hydrated, and the absorbed water may make it permeable to, for example, glucose. The polyaniline may be polyaniline itself or a substituted polyaniline; the water-soluble crosslinker may be poly(ethylene glycol)diglycidyl ether, and the redox enzyme may be glucose oxidase. The polymer matrix may be produced by co-crosslinking (1) an adduct of an electrically conductive polymer and a polymer acid; (2) a water-soluble crosslinker; and (3) a redox enzyme in a single step at an about neutral pH, curing by drying. After hydration, the crosslinked polymer matrix may form a 3-dimensional glucose-permeable bioelectrocatalyst, catalyzing the electrooxidation of glucose.
摘要翻译：可以通过共聚交联（1）通过模板化氧化聚合形成的聚苯胺在聚合物酸上的加合物来产生可涂覆在电极上的聚合物基质; （2）水溶性交联剂; 和（3）氧化还原酶。聚合物基质可以是水合的，并且所吸收的水可以使其可以例如葡萄糖渗透。聚苯胺可以是聚苯胺本身或取代的聚苯胺; 水溶性交联剂可以是聚（乙二醇）二缩水甘油醚，氧化还原酶可以是葡萄糖氧化酶。聚合物基质可以通过共交联（1）导电聚合物的加合物和聚合物酸来制备; （2）水溶性交联剂; 和（3）在大约中性pH下在一个步骤中的氧化还原酶，通过干燥固化。水合后，交联聚合物基质可形成3维葡萄糖可渗透的生物电催化剂，催化葡萄糖的电氧化。

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