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1. 发明授权

US5367050A Polyether polyol production of a flexible urethane foam and shaped article therefrom 失效
标题翻译：聚醚多元醇生产柔性聚氨酯泡沫及其成型制品
公开(公告)号：US5367050A
公开(公告)日：1994-11-22
申请号：US197321
申请日：1994-02-16
申请人： Yoshihiko Tairaka , Mitsuhiro Nishimura , Katsuhisa Kodama
发明人： Yoshihiko Tairaka , Mitsuhiro Nishimura , Katsuhisa Kodama
IPC分类号： C08G18/50 , C08G18/63
CPC分类号： C08G18/506 , C08G18/632 , C08G2101/0008 , C08G2101/0083
摘要： A polyether polyol produced by using an N-amino-ethylpiperazine-ethylene oxide aduct as an initiator and addition-polymerizing an alkylene oxide thereto and having a molecular weight of about 2000 to 7000; a process for producing a flexible urethane foam starting with the above polyether polyol; a process suited for the production of a hot-cure urethane foam which comprises using the above polyether polyol with a hydroxyl value of 40 to 80 mg KOH/g and, as a blowing agent, 4.6 to 6.0 weight parts of water based on 100 weight parts of the polyol; and a process suited for the production of a cold-cure urethane foam which comprises using the above polyether polyol with a hydroxyl value of 23 to 50 mg KOH/g and, as a blowing agent, 2.5 to 5.0 weight parts of water on the same basis.The use of the polyether polyol enables the production of a low-density, low-hardness flexible urethane foam using a small amount of water, without requiring any environment-unfriendly chlorofluorocarbon and without being accompanied by deterioration of humid age compression set and other characteristics.
摘要翻译：通过使用N-氨基 - 乙基哌嗪 - 环氧乙烷加成物作为引发剂并加成聚合烯化氧并分子量为约2000〜7000的聚醚多元醇; 从上述聚醚多元醇开始制造柔性聚氨酯泡沫塑料的方法; 一种适用于生产热固化聚氨酯泡沫的方法，其包括使用上述羟值为40-80mg KOH / g的聚醚多元醇，作为发泡剂，基于100重量份为4.6至6.0重量份的水部分多元醇; 以及适用于生产冷固化聚氨酯泡沫的方法，该方法包括使用上述羟值为23至50mg KOH / g的聚醚多元醇，作为发泡剂，使用2.5至5.0重量份的水基础。使用聚醚多元醇能够使用少量的水生产低密度，低硬度的柔性聚氨酯泡沫，而不需要任何环境不友好的氯氟烃，并且不伴随潮湿压缩永久变形和其它特性的恶化。

2. 发明授权

US5519068A Method of producing open cell rigid polyurethane foam 失效
标题翻译：开孔硬质聚氨酯泡沫的生产方法
公开(公告)号：US5519068A
公开(公告)日：1996-05-21
申请号：US233445
申请日：1994-04-26
申请人： Kazuo Okada , Yoshihiko Tairaka
发明人： Kazuo Okada , Yoshihiko Tairaka
IPC分类号： C08G18/28 , C08G18/48 , C08G18/66
CPC分类号： C08G18/2815 , C08G18/482 , C08G18/6688 , C08G2101/0025 , C08G2101/0083
摘要： There is provided a method of producing an open cell rigid polyurethane foam which comprises reacting a specified polyol mixture by use of water as the substantially sole blowing agent without the use of a volatile hlorofluorocarbon as a blowing agent. There is provided a further method of producing an open cell rigid polyurethane foam particularly suitable for use as a shock absorbing material which comprises reacting a specified polyol/monool mixture. Water is used in an amount of 0.5-5.5 parts by weight in relation to 100 parts by weight of the polyol mixture or polyol/monool mixture used.
摘要翻译：提供一种生产开孔硬质聚氨酯泡沫的方法，其包括使用水作为基本上唯一的发泡剂使特定的多元醇混合物反应，而不使用挥发性的四氟碳氟化合物作为发泡剂。提供了另外一种生产特别适合用作冲击吸收材料的开孔硬质聚氨酯泡沫的方法，该材料包括使指定的多元醇/一元醇混合物反应。相对于所使用的多元醇混合物或多元醇/一元醇混合物100重量份，水的使用量为0.5-5.5重量份。

3. 发明授权

US5112876A Polyether polyol and rigid polyurethane foam 失效
标题翻译：聚醚多元醇和硬质聚氨酯泡沫
公开(公告)号：US5112876A
公开(公告)日：1992-05-12
申请号：US426226
申请日：1989-10-25
申请人： Yoshihiko Tairaka , Katsumi Inaoka
发明人： Yoshihiko Tairaka , Katsumi Inaoka
IPC分类号： C08G18/48 , C08G18/50
CPC分类号： C08G18/4845 , C08G18/5033 , C08G2101/0025 , C08G2101/005
摘要： The present invention relates to a polyether polyol which is prepared by(i) reacting 3.0 to 4.0 molecular equivalents of ethylene oxide with one molecular equivalent of 2,3- or 3,4-tolylenediamine, or a mixture thereof in the absense of catalyst, and thereafter,(ii) reacting 2.8 to 4.8 molecular equivalents of propylene oxide with one molecular equivalent of the reaction product in the presence of an alkali metal hydroxide in an amount of not more than 0.8% by weight based on the 2,3- or 3,4-tolylenediamine, or the mixture thereof.The present invention also relates to a rigid polyurethane foam which is prepared by reacting a polyol mixture containing not less than 50 wt % of the above-mentioned polyether polyol with an isocyanate. The rigid polyurethane foam is obtained with reduced fron requirements.
摘要翻译：本发明涉及一种聚醚多元醇，其通过以下步骤制备：（i）使3.0至4.0分子当量的环氧乙烷与一种分子当量的2,3-或3,4-甲苯二胺或其混合物在催化剂的缺失中反应，然后，（ii）在碱金属氢氧化物存在下使2.8至4.8分子当量的环氧丙烷与一种分子当量的反应产物反应，其量为不超过0.8重量％，基于2,3-或 3,4-甲苯二胺或其混合物。本发明还涉及一种刚性聚氨酯泡沫，其通过使含有不少于50重量％的上述聚醚多元醇的多元醇混合物与异氰酸酯反应而制备。刚性聚氨酯泡沫塑料获得了较少的fron要求。

4. 发明授权

US5332764A Polyether polyol production of a flexible urethane foam and shaped article therefrom 失效
标题翻译：聚醚多元醇生产柔性聚氨酯泡沫及其成型制品
公开(公告)号：US5332764A
公开(公告)日：1994-07-26
申请号：US141942
申请日：1993-10-28
申请人： Yoshihiko Tairaka , Mitsuhiro Nishimura , Katsuhisa Kodama
发明人： Yoshihiko Tairaka , Mitsuhiro Nishimura , Katsuhisa Kodama
IPC分类号： C08G18/50 , C08G18/63 , C08G18/00
CPC分类号： C08G18/506 , C08G18/632 , C08G2101/0008 , C08G2101/0083
摘要： A polyether polyol produced by using an N-aminoethylpiperazine-ethylene oxide aduct as an initiator and addition-polymerizing an alkylene oxide thereto and having a molecular weight of about 2000 to 7000; a process for producing a flexible urethane foam starting with the above polyether polyol; a process suited for the production of a hot-cure urethane foam which comprises using the above polyether polyol with a hydroxyl value of 40 to 80 mg KOH/g and, as a blowing agent, 4.6 to 6.0 weight parts of water based on 100 weight parts of the polyol; and a process suited for the production of a cold-cure urethane foam which comprises using the above polyether polyol with a hydroxyl value of 23 to 50 mg KOH/g and, as a blowing agent, 2.5 to 5.0 weight parts of water on the same basis.The use of the polyether polyol enables the production of a low-density, low-hardness flexible urethane foam using a small amount of water, without requiring any environment-unfriendly chlorofluorocarbon and without being accompanied by deterioration of humid age compression set and other characteristics.
摘要翻译：通过使用N-氨基乙基哌嗪 - 环氧乙烷加成物作为引发剂，加成聚合烯化氧并分子量为约2000〜7000的聚醚多元醇; 从上述聚醚多元醇开始制造柔性聚氨酯泡沫塑料的方法; 一种适用于生产热固化聚氨酯泡沫的方法，其包括使用上述羟值为40-80mg KOH / g的聚醚多元醇，作为发泡剂，基于100重量份为4.6至6.0重量份的水部分多元醇; 以及适用于生产冷固化聚氨酯泡沫的方法，该方法包括使用上述羟值为23至50mg KOH / g的聚醚多元醇，作为发泡剂，使用2.5至5.0重量份的水基础。使用聚醚多元醇能够使用少量的水生产低密度，低硬度的柔性聚氨酯泡沫，而不需要任何环境不友好的氯氟烃，并且不伴随潮湿压缩永久变形和其它特性的恶化。

5. 发明授权

US5318997A Method for production of open cell rigid polyurethane foam 失效
标题翻译：开孔硬质聚氨酯泡沫的生产方法
公开(公告)号：US5318997A
公开(公告)日：1994-06-07
申请号：US48513
申请日：1993-04-20
申请人： Kazuo Okada , Yoshihiko Tairaka
发明人： Kazuo Okada , Yoshihiko Tairaka
IPC分类号： C08G18/48 , C08G18/66 , C08G18/00
CPC分类号： C08G18/6688 , C08G18/4816 , C08G18/482 , C08G18/6674 , C08G2101/0025 , C08G2101/005 , C08G2101/0083
摘要： A method of producing an open cell rigid polyurethane foam which comprises reacting a mixture of polyols having a hydroxyl value of 160-360 mg KOH/g with a polyisocyanate in the presence of water as a blowing agent in an amount of 6-12 parts by weight in relation to 100 parts by weight of the mixture of polyols at an isocyanate index of 70-120, the mixture of polyols comprising:(a) 30-60% by weight of a first polyoxyalkylene polyol having a functionality of 2-3.5, a hydroxyl value of 28-90 mg KOH/g, a polyoxyethylene unit content of not more than 5% by weight, and a primary hydroxyl group content of not more than 15% based on the total of the hydroxyl groups of the first polyoxyalkylene polyol;(b) 30-60% by weight of a second polyoxyalkylene polyol having a functionality of 3-6, a hydroxyl value of 150-500 mg KOH/g, and a primary hydroxyl group content of not more than 5% based on the total of the hydroxyl groups of the second polyoxyalkylene polyol; and(c) 0-25% by weight of a third polyol having a functionality of 2-3, a hydroxyl value of 450-840 mg KOH/g, and a primary hydroxyl group content of not more than 5% based on the total of the hydroxyl groups of the third polyol.
摘要翻译：一种开孔硬质聚氨酯泡沫塑料的制造方法，其特征在于，在作为发泡剂的水作为发泡剂存在下，使羟值为160〜360mg KOH / g的多羟基化合物与多异氰酸酯的混合物以6-12份的量重量相对于100重量份异氰酸酯指数为70-120的多元醇混合物，多元醇混合物包含：（a）30-60重量％的官能度为2-3.5的第一聚氧化烯多元醇，基于第一聚氧化烯多元醇的总数，羟基值为28〜90mg KOH / g，聚氧乙烯单元含量为5重量％以下，伯羟基含量为15％以下 ; （b）30-60重量％的官能度为3-6的第二聚氧化烯多元醇，羟值为150-500mg KOH / g，伯羟基含量不超过5％，基于总量的第二聚氧化烯多元醇的羟基; 和（c）0-25重量％的官能度为2-3的第三多元醇，羟值为450-840mg KOH / g，伯羟基含量不超过5％的第三多元醇的羟基。

6. 发明授权

US5091438A Method of producing rigid urethane foam 失效
标题翻译：生产刚性尿素泡沫的方法
公开(公告)号：US5091438A
公开(公告)日：1992-02-25
申请号：US550367
申请日：1990-07-10
申请人： Yoshihiko Tairaka , Masayoshi Idomoto
发明人： Yoshihiko Tairaka , Masayoshi Idomoto
IPC分类号： C08G18/48 , C08G18/50 , C08G18/72 , C08G101/00 , C08J9/02 , C08J9/14
CPC分类号： C08J9/142 , C08G18/4816 , C08G18/4829 , C08G18/5033 , C08G18/727 , C08J9/02 , C08G2101/0025 , C08G2101/005 , C08G2101/0083 , C08J2375/04
摘要： A method of producing a rigid urethane foam, which comprises reacting a blend polyol consisting of a polyol having a hydroxyl value of 300 to 450 mg KOH/g as prepared by using an acyclic sugar alcohol of 5 to 6 carbon atoms as an initiator and one or more other polyols, said blend polyol having a sugar alcohol content of 3 to 14 weight % and an average hydroxyl value of 300 to 430 mg KOH/g, with a polyisocyanate using 4.0 to 7.0 weight parts of water based on 100 weight parts of said polyol composition as a blowing agent, can reduce the CFC requirements by 50 to 100 percent as compared with the known production technology for rigid urethane foams and, moreover, the adhesive property of the resulting foam is not inferior to that of the conventional urethane foam.

7. 发明授权

US4649163A Flame-retardant polyurethane foam and polyol composition therefor 失效
标题翻译：阻燃聚氨酯泡沫及其多元醇组合物
公开(公告)号：US4649163A
公开(公告)日：1987-03-10
申请号：US804254
申请日：1985-12-03
申请人： Yoshihiko Tairaka
发明人： Yoshihiko Tairaka
IPC分类号： C08G18/00 , C08G18/28 , C08G18/48 , C08G18/65 , C08G18/66 , C08G101/00 , C08J9/02 , C08K5/05 , C08K5/521 , C08L71/00 , C08L71/02 , C08L71/12 , C08L75/00 , C08L75/08 , C08G18/14
CPC分类号： C08G18/4887 , C08G18/284 , C08G18/4804 , C08G18/4891 , C08G18/6674 , C08G2101/0008 , C08G2101/0083
摘要： A polyol composition comprising(a) a polyether polyol with an average molecular weight of 2,000 to 10,000,(b) an adduct of a carboxylic acid having not less than 8 carbon atoms with ethylene oxide or both ethylene oxide and propylene oxide and(c) a diol with an average molecular weight of 62 to 400, having one or more primary hydroxyl groups;in a ratio of (88 to 98):(2 to 8):(0 to 4) by weight is suitable for the production of flame-retardant flexible polyurethane foam and a flame-retardant flexible polyurethane foam produced by reacting(i) the above polyol composition with(ii) a polyisocyanatein the presence of(iii) water,(iv) both a foam-setting agent for slab foam and a foam-setting agent for HR foam(v) both a metal-containing catalyst and a tertiary amine catalyst and(vi) a flame retardant comprising a triarylphosphatenot only has an excellent flame retardant effect but also causes no discoloration of the foam-covering material.
摘要翻译：一种多元醇组合物，其包含（a）平均分子量为2,000至10,000的聚醚多元醇，（b）具有不少于8个碳原子的羧酸与环氧乙烷或环氧乙烷和环氧丙烷两者的加合物，和（c）平均分子量为62〜400的二醇，具有一个或多个伯羟基; 以（88〜98）：（2〜8）：（0〜4）的比例适合于生产阻燃软质聚氨酯泡沫塑料和阻燃软质聚氨酯泡沫体，其通过使（i）（ii）多异氰酸酯在（iii）水的存在下，（iv）均匀泡沫塑料的泡沫固化剂和HR泡沫的泡沫固化剂（v），含金属的催化剂和叔胺催化剂和（vi）包含磷酸三芳基酯的阻燃剂不仅具有优异的阻燃效果，而且也不会使泡沫覆盖材料变色。

8. 发明授权

US4032574A Production of polyetherpolyols useful in preparing rigid polyurethane foams 失效
标题翻译：用于制备刚性聚氨酯泡沫塑料的聚乙烯醇的生产
公开(公告)号：US4032574A
公开(公告)日：1977-06-28
申请号：US616898
申请日：1975-09-25
申请人： Akizo Keshi , Katsuhisa Kodama , Ichiro Takemura , Yoshihiko Tairaka , Kunio Yoshinaga
发明人： Akizo Keshi , Katsuhisa Kodama , Ichiro Takemura , Yoshihiko Tairaka , Kunio Yoshinaga
IPC分类号： C08G18/00 , C08G18/18 , C08G18/48 , C08G65/00 , C08G65/26 , C08G65/28 , C07C93/04 , C07C93/06 , C07C93/08 , C07C93/12
CPC分类号： C08G18/1808 , C08G18/48 , C08G65/2618
摘要： Polyetherpolyols useful in preparing rigid polyurethane foam excellent in dimensional stability and inflammability. These polyetherpolyols are obtained by reacting alkylene oxide with compounds containing active hydrogen atoms, part or all of which comprise the reaction product obtained by heating the distillation residue secured as a byproduct in the distillation process of a crude polyisocyanate in the presence of (1) water, alcohols and/or amines and (2) hydroxides or oxides of alkali metals or alkaline earth metals and/or monoalkanolamines.

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