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1. 发明申请

US20050085559A1 Process for the reduction of the residual monomer content of water-absorbent foam 失效
标题翻译：减少吸水泡沫的残留单体含量的方法
公开(公告)号：US20050085559A1
公开(公告)日：2005-04-21
申请号：US10502135
申请日：2003-01-30
申请人： Hans-Joachim Hahnle , Rudiger Funk , Wolfgang Heider , Gunnar Schornick , Volker Frenz
发明人： Hans-Joachim Hahnle , Rudiger Funk , Wolfgang Heider , Gunnar Schornick , Volker Frenz
IPC分类号： A61F13/53 , A61F13/00 , A61F13/49 , A61L15/16 , A61L15/60 , C08F6/00 , C08J9/00 , C08J9/36
CPC分类号： C08J9/36 , C08F6/006 , C08J2207/12 , C08J2300/14 , Y10T156/1011 , Y10T156/1084 , C08L33/02
摘要： A process for the reduction of the residual monomer content and enhancement of the wet strength of articles formed from water absorbent crosslinked polymer foams containing units derived from monoethylenically unsaturated acids, which comprises treating the formed articles with at least 0.5 % by weight of a polymer containing primary and/or secondary amino groups and having a molar mass of at least 300, the formed foam articles thus obtainable and use of the wet strength enhanced formed foam articles in hygiene articles.
摘要翻译：一种降低残留单体含量并提高由含有衍生自单烯属不饱和酸的单元的吸水性交联聚合物泡沫形成的制品的湿强度的方法，该方法包括用至少0.5重量％的含有初级和/或仲氨基并且摩尔质量至少为300，所形成的泡沫制品如此可获得，并且在卫生制品中使用湿强度增强的成形泡沫制品。

2. 发明授权

US06472478B1 Process for crosslinking hydrogels with bis- and poly-2- oxazolidinones 有权
标题翻译：用双 - 和多 - 2-恶唑烷酮交联水凝胶的方法
公开(公告)号：US06472478B1
公开(公告)日：2002-10-29
申请号：US09601349
申请日：2000-08-18
申请人： Rüdiger Funk , Volker Frenz , Ulrich Riegel , Matthias Weismantel , Fritz Engelhardt , Thomas Daniel
发明人： Rüdiger Funk , Volker Frenz , Ulrich Riegel , Matthias Weismantel , Fritz Engelhardt , Thomas Daniel
IPC分类号： C08F830
CPC分类号： A61L15/60 , C08F8/30 , Y10S524/916 , Y10T442/699
摘要： The invention relates to a process for the gel or surface postcrosslinking of water-absorbing polymers in which the polymers are treated with a surface postcrosslinking solution and during or after the treatment are postcrosslinked and dried by means of an increase in temperature, the crosslinker being a compound of the formula in which R1 and R2 independently of one another are H, hydroxyl, phenyl or C1-C6-alkyl, R3 is hydrogen, C1-C12-alkyl, C1-C12-alkenyl or C6-C12-aryl and R4 and R5 independently of one another are C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl, hydroxyl, C1-C12-alkoxy or hydrogen, dissolved in an inert solvent, to water-absorbing polymers which can be obtained by said process, and to their use in hygiene articles, packaging materials and nonwovens.
摘要翻译：本发明涉及一种吸水聚合物的凝胶或表面后交联方法，其中聚合物用表面后交联溶液处理，并且在处理之间或之后，通过温度升高进行后交联和干燥，交联剂为 R 1和R 2彼此独立地是H，羟基，苯基或C 1 -C 6烷基的化合物，R 3是氢，C 1 -C 12 - 烷基，C 1 -C 12 - 烯基或C 6 -C 12 - 芳基，R 4和R 5 彼此独立地是溶解在惰性溶剂中的C 1 -C 12烷基，C 1 -C 12 - 烯基，C 6 -C 12 - 芳基，羟基，C 1 -C 12 - 烷氧基或氢，可以通过所述过程，以及它们在卫生用品，包装材料和无纺布中的应用。

3. 发明授权

US06277900B1 Well cementing aids 有权
标题翻译：固井助剂
公开(公告)号：US06277900B1
公开(公告)日：2001-08-21
申请号：US09196668
申请日：1998-11-19
申请人： Reinhard Oswald , Volker Frenz , Juergen Tonhauser , Aranka Tardi , Pierre Maroy , Florence L'Alloret
发明人： Reinhard Oswald , Volker Frenz , Juergen Tonhauser , Aranka Tardi , Pierre Maroy , Florence L'Alloret
IPC分类号： C09K700
CPC分类号： C09K8/46 , C04B24/163 , C04B28/02 , C08F220/54 , C08F220/58 , C04B22/0026
摘要： The present invention relates to copolymers consisting of (a) 1-99% by weight of structural units of the formula (1) where R1 is hydrogen or methyl, R4 is C1-C22-alkylene, R5 is C1-C22-alkyl or hydrogen, and X is ammonium, lithium, sodium, potassium, an amine or a mixture of these substances, and (b) 99-1% by weight of structural units of the formula (2) where R1 is hydrogen or methyl, R2 and R3, independently of one another, are hydrogen, or C2-C22-alkyl, wherein component b) is not hydrolysed and the copolymers have been prepared by a solution precipitation polymerization in a nonaqueous solvent or a water-miscible, organic solvent having a low water content which is a precipitant for the copolymer. The invention furthermore relates to a process for cementing subterranean wells using a cement slurry comprising the following components: a) water of various salinity cement a novel copolymer in a concentration of 0.01-5% bwoc, preferably from 0.05 to 0.9% bwoc.
摘要翻译：本发明涉及由（a）1-99重量％的式（1）结构单元，其中R 1是氢或甲基，R 4是C 1 -C 22 - 亚烷基，R 5是C 1 -C 22 - 烷基或氢，和X是铵，锂，钠，钾，胺或这些物质的混合物，和（b）99-1重量％的式（2）的结构单元，其中R 1是氢或甲基，R 2和R 3 彼此独立地为氢或C 2 -C 22 - 烷基，其中组分b）未水解，并且该共聚物通过在非水溶剂或具有低水的水混溶性有机溶剂中的溶液沉淀聚合制备作为共聚物的沉淀剂的含量。本发明还涉及一种使用包含以下组分的水泥浆料固井地下井的方法：a）浓度为0.01-5％bwoc，优选0.05-0.9％bwoc的各种盐酸盐型新型共聚物的水。

4. 发明申请

US20070066947A1 Hydrogel capable of absorbing blood and/or body fluids 失效
标题翻译：能够吸收血液和/或体液的水凝胶
公开(公告)号：US20070066947A1
公开(公告)日：2007-03-22
申请号：US10576049
申请日：2004-10-28
申请人： Martin Beck , Volker Frenz , Anna Kowalski , Elisabeth Selzer , Ernst Bauer , Harald Keller , Bernhard Steinmetz
发明人： Martin Beck , Volker Frenz , Anna Kowalski , Elisabeth Selzer , Ernst Bauer , Harald Keller , Bernhard Steinmetz
IPC分类号： A61F13/15 , C09K3/00
CPC分类号： A61L15/60 , A61L15/48 , Y10S516/905 , Y10S516/906 , Y10S524/904 , Y10S524/917 , Y10S524/922 , Y10S525/934 , Y10S526/91 , Y10S526/932 , Y10T428/12181 , Y10T428/1438 , Y10T428/1443 , Y10T428/1462 , Y10T428/24802 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/31855 , Y10T428/31931
摘要： A hydrogel having a floatability where from 40% to 90% of a solution and/or suspension to be thickened are thickened starting from the surface of the liquid and the rest of the solution and/or suspension to be thickened is thickened starting from the bottom of the container, a process for preparing the hydrogel and also its use for absorbing blood and/or body fluids, especially in hygiene articles, or for thickening aqueous solutions and/or suspensions, especially for thickening medical wastes.
摘要翻译：具有浮选性的水凝胶，其中40％至90％的待加厚的溶液和/或悬浮液从液体的表面开始增稠，并且待加厚的溶液和/或悬浮液的其余部分从底部开始变厚容器的制备方法，以及其用于吸收血液和/或体液，特别是卫生制品的用途，或用于增稠水溶液和/或悬浮液，特别是用于增加医疗废物的用途。

5. 发明申请

US20050233072A1 Method for producing coatings sticking discrete patterns on a substrate 审中-公开
标题翻译：用于在基材上粘附离散图案的涂层的制造方法
公开(公告)号：US20050233072A1
公开(公告)日：2005-10-20
申请号：US10520021
申请日：2003-07-03
申请人： Oskar Stephan , Christian Weidl , Volker Frenz , Felix Gorth , Martin Beck
发明人： Oskar Stephan , Christian Weidl , Volker Frenz , Felix Gorth , Martin Beck
IPC分类号： A61F13/82 , C09J7/02 , C09J5/00
CPC分类号： A61F13/82 , C09J7/38 , C09J2201/28
摘要： The invention relates to a method of producing discrete patterns of an adhesive coating on a substrate, comprising the following steps: (a) the substrate is moved continuously or discontinuously in a conveying direction, (b) in an application zone a low-viscosity polymerizable and/or crosslinkable precursor material of an adhesive material is applied two-dimensionally to the substrate through at least one opening of substantially slotlike configuration of at least one movable applicator, a pattern being produced by movement of the applicator relative to the substrate, (c) downstream of the application zone the applied precursor material is polymerized and/or crosslinked.
摘要翻译：本发明涉及一种在基材上制备粘合剂涂层的分散图案的方法，包括以下步骤：（a）基材在输送方向上连续或不连续地移动，（b）在涂布区域中具有低粘度可聚合和/或可交联的粘合剂材料的前体材料通过至少一个可移动施加器的至少一个基本上为槽状构造的开口二维地施加到衬底，所述至少一个开口通过施加器相对于衬底的移动而产生，（c ）施加的前体材料聚合和/或交联。

6. 发明授权

US06849665B2 Absorbent compositions 有权
标题翻译：吸收剂组合物
公开(公告)号：US06849665B2
公开(公告)日：2005-02-01
申请号：US10028908
申请日：2001-12-28
申请人： Volker Frenz , Norbert Herfert , Ulrich Riegel , William E. Volz , Thomas H. Majette , James Hill
发明人： Volker Frenz , Norbert Herfert , Ulrich Riegel , William E. Volz , Thomas H. Majette , James Hill
IPC分类号： A61F13/53 , A61F13/00 , A61F13/15 , A61F13/49 , A61L15/60 , B01J20/26 , C08L101/14 , C08J9/28
CPC分类号： A61L15/60 , B01J20/26 , Y10T428/249953 , Y10T428/2991 , Y10T428/2998 , Y10T428/31971 , Y10T428/31975 , Y10T428/31978
摘要： Described is a water-absorbent composition containing from 30 to 100% by weight, based on the water-absorbent composition, of water-insoluble water-swellable hydrogels characterized by the following features: Centrifuge Retention Capacity (CRC) of at least 24 g/g, Saline Flow Conductivity (SFC) of at least 80×10−7 cm3 s/g and Free Swell Rate (FSR) of at least 0.15 g/g s and/or Vortex Time of not more than 160 s.
摘要翻译：描述了基于吸水性组合物含有30-100重量％的水不溶性水溶胀性水凝胶的吸水性组合物，其特征在于以下特征：离心保留容量（CRC）为至少24g / g，至少80×10 -7 cm 3 / s的盐水流动电导率（SFC）和至少0.15g / gs和/或不超过160s的涡旋时间的无膨胀速率（FSR）。

7. 发明授权

US06559239B1 Method for the secondary cross-linking of hydrogels with N-acyl-2-oxazolidinones 失效
标题翻译：水凝胶与N-酰基-2-恶唑烷酮二次交联的方法
公开(公告)号：US06559239B1
公开(公告)日：2003-05-06
申请号：US09831920
申请日：2001-05-29
申请人： Ulrich Riegel , Matthias Weismantel , Volker Frenz , Thomas Daniel , Fritz Engelhardt
发明人： Ulrich Riegel , Matthias Weismantel , Volker Frenz , Thomas Daniel , Fritz Engelhardt
IPC分类号： C08F830
CPC分类号： C08F8/30 , C08J3/245 , C08J2300/14 , C08J2333/02 , C08F220/06
摘要： Liquid-absorbent polymers are prepared by a process for the gel and/or surface postcrosslinking of water-absorbent polymers by the polymer being treated with a surface postcrosslinking solution and being postcrosslinked and dried during and after the treatment by raising the temperature, wherein the surface postcrosslinking solution comprises as crosslinker a compound of the formula I where R1, R2, R3 and R4 are independently hydrogen, C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl or C1-C12-alkoxy, R5 is C1-C16-alkyl, C1-C4-hydroxyalkyl, C6-C12-aryl, C1-C16-alkenyl or a group of the formula —(CH2)n—COOH or —(CH2)n—SO3H in the form of the acid or a respective metal salt, ammonium salt or triethanolammonium salt thereof or —(CH2—CH2—O—)m—R6, R6 is hydrogen or C1-C16-alkyl, n is from 1 to 10, m is from 1 to 20 dissolved in an inert solvent, and are used in hygiene articles, packaging materials and nonwovens.
摘要翻译：通过用表面后交联溶液处理的聚合物进行凝胶和/或表面后吸附吸水性聚合物的方法制备液体吸收聚合物，并且在处理之间和之后通过升高温度进行后交联和干燥，其中表面后交联溶液包含作为交联剂的式I化合物，其中R 1，R 2，R 3和R 4独立地是氢，C 1 -C 12 - 烷基，C 1 -C 12 - 烯基，C 6 -C 12 - 芳基或C 1 -C 12 - 烷氧基，R 5是C 1 -C 16 - 烷基，C 1 -C 4 - 羟基烷基，C 6 -C 12 - 芳基，C 1 -C 16 - 烯基或式 - （CH 2）n -COOH或 - （CH 2）n -SO 3 H的基团，其形式为酸或相应的金属盐，铵盐或三乙醇铵盐或 - （CH 2 -CH 2 -O-）m -R 6，R 6是氢或C 1 -C 16 - 烷基，n为1至10，m为1至20，溶于惰性溶剂，用于卫生用品，包装材料和无纺布。

8. 发明授权

US08623945B2 Use of oligomeric carbodiimides as stabilizers 失效
标题翻译：使用低聚碳二亚胺作为稳定剂
公开(公告)号：US08623945B2
公开(公告)日：2014-01-07
申请号：US13421363
申请日：2012-03-15
申请人： Theo Smit , Laurence Pottie , Simone Schillo , Volker Frenz , Roelof van der Meer
发明人： Theo Smit , Laurence Pottie , Simone Schillo , Volker Frenz , Roelof van der Meer
IPC分类号： C08K5/3412 , C07D413/12 , C08K5/3415 , C08K5/353
CPC分类号： C07D403/12 , C07D413/12 , C08K5/29 , C08K5/3412
摘要： This invention relates to a process for stabilizing polymers with oligomeric carbodiimides containing at least one heterocyclic end group and stabilizers. The oligomeric carbodiimides may be compounds of the general formula (I): where A1, A2 are each independently, identically or differently, hydrocarbon groups having 2 to 20 carbon atoms, B1, B2 are each independently, identically or differently, heterocycles, C1-C30-alcohols, polyetherols, polyesterols, amines, polyether amines, polyester amines, thioalcohols, polyether thiols, polyester thiols; R1, R2 are each independently, identically or differently: n is an integer from 2 to 100, and A1, A2, B1 and B2 may each be substituted at any desired position by C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkynyl, C1-C20-alkoxy, carbonyl oxygen (═O) or halogen, with the proviso that at least one B1 or B2 substituent is a heterocyclic end group. The invention also relates to compositions of the oligomeric carbodiimides and mixtures.
摘要翻译：本发明涉及一种使含有至少一个杂环端基和稳定剂的低聚碳二亚胺稳定聚合物的方法。低聚碳二亚胺可以是通式（I）的化合物：其中A1，A2各自独立地，相同地或不同地是具有2-20个碳原子的烃基，B1，B2各自独立地，相同地或不同地是杂环，C1- C30醇，聚醚醚，聚酯醇，胺，聚醚胺，聚酯胺，硫代醇，聚醚硫醇，聚酯硫醇; R 1，R 2各自独立地，相同地或不同地表示：n是2至100的整数，并且A1，A2，B1和B2各自可以在任何所需位置被C 1 -C 20 - 烷基，C 2 -C 20 - 链烯基，C 2 -C 20炔基，C 1 -C 20 - 烷氧基，羰基氧（= O）或卤素，条件是至少一个B1或B2取代基是杂环端基。本发明还涉及低聚碳二亚胺及其混合物的组合物。

9. 发明授权

US07727586B2 Production of water-absorbing polymeric particles by dropletization polymerization in the gas phase 有权
标题翻译：在气相中通过液滴聚合制备吸水聚合物颗粒
公开(公告)号：US07727586B2
公开(公告)日：2010-06-01
申请号：US11814021
申请日：2006-01-24
申请人： Stefan Bruhns , Volker Frenz , Dennis Lösch , Volker Seidl , Uwe Stueven , Carolin Nadine Dücker , Matthias Weismantel , Wilfried Heide , Stefan Blei
发明人： Stefan Bruhns , Volker Frenz , Dennis Lösch , Volker Seidl , Uwe Stueven , Carolin Nadine Dücker , Matthias Weismantel , Wilfried Heide , Stefan Blei
IPC分类号： C08F2/10 , C08F2/00 , C08F2/01 , C08F2/04
CPC分类号： B01J8/388 , A61L15/60 , B01J8/0055 , B01J8/36 , B01J2208/00433 , B01J2208/0046 , B01J2208/00681 , C08F2/01 , C08F2/34 , C08F6/008 , F26B3/08 , Y10T428/2982
摘要： A process for producing water-absorbing polymeric particles by dropletization polymerization in the gas phase, which comprises drying the polymeric particles after the polymerization in a fluidized bed, the water-absorbing polymeric particles themselves, hygiene articles comprising these water-absorbing polymeric particles and also apparatus for implementing the process.
摘要翻译：在气相中通过液滴聚合制备吸水性聚合物颗粒的方法，其包括在流化床中聚合后干燥聚合物颗粒，吸水聚合物颗粒本身，包含这些吸水性聚合物颗粒的卫生制品，以及用于实施该过程的装置。

10. 发明申请

US20080188586A1 Production of Water-Absorbing Polymeric Particles by Dropletization Polymerization in the Gas Phase 有权
标题翻译：通过在气相中的液滴聚合制备吸水聚合物颗粒
公开(公告)号：US20080188586A1
公开(公告)日：2008-08-07
申请号：US11814021
申请日：2006-01-24
申请人： Stefan Bruhns , Volker Frenz , Dennis Losch , Volker Seidl , Uwe Stueven , Carolin Nadine Ducker , Matthias Weismantel , Wilfried Heide , Stefan Blei
发明人： Stefan Bruhns , Volker Frenz , Dennis Losch , Volker Seidl , Uwe Stueven , Carolin Nadine Ducker , Matthias Weismantel , Wilfried Heide , Stefan Blei
IPC分类号： C08F2/48 , C08F6/00
CPC分类号： B01J8/388 , A61L15/60 , B01J8/0055 , B01J8/36 , B01J2208/00433 , B01J2208/0046 , B01J2208/00681 , C08F2/01 , C08F2/34 , C08F6/008 , F26B3/08 , Y10T428/2982
摘要： A process for producing water-absorbing polymeric particles by dropletization polymerization in the gas phase, which comprises drying the polymeric particles after the polymerization in a fluidized bed, the water-absorbing polymeric particles themselves, hygiene articles comprising these water-absorbing polymeric particles and also apparatus for implementing the process.
摘要翻译：在气相中通过液滴聚合制备吸水性聚合物颗粒的方法，其包括在流化床中聚合后干燥聚合物颗粒，吸水聚合物颗粒本身，包含这些吸水性聚合物颗粒的卫生制品，以及用于实施该过程的装置。

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