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    • 1. 发明专利
    • Production of tetracyanoanthraquinodimethane-type charge transfer complex
    • 四氯乙烯磺酸盐类型电荷转移复合物的生产
    • JPS61129158A
    • 1986-06-17
    • JP24877584
    • 1984-11-27
    • Toshio Mukai
    • MUKAI TOSHIOYAMASHITA TAKAOSUZUKI TAKANORI
    • H01B1/12C07C67/00C07C253/00C07C255/34
    • PURPOSE: To obtain a charge-transfer complex which is solid at normal temperature and useful as an organic electronic material, by reacting tetracyanoanthraquinodimethane with an electron-donative compound in a solvent, and removing the solvent from the reaction mixture.
      CONSTITUTION: The objective compound can be produced by dissolving tetracyanoanthraquinodimethane of formula (R is H, halogen, cyano, nitro, alkoxycarbonyl, alkyl or aryl) and excess electrondonative compound (e.g. benzene, naphthalene, tetrathiafluvalene, etc.) in a mixture of a good solvent of both compounds (e.g. carbon tetrachloride) or dissolving in the good solvent and adding the poor solvent thereto, and removing the solvents from the solution.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:为了获得在常温下为固体并可用作有机电子材料的电荷转移络合物,通过使四氰基蒽醌二甲烷与电子给体化合物在溶剂中反应,并从反应混合物中除去溶剂。 构成:目标化合物可以通过将式(R为H,卤素,氰基,硝基,烷氧基羰基,烷基或芳基)的四氰基蒽醌二甲烷和过量的电离化合物(例如苯,萘,四氢呋喃戊烯等)溶解在 两种化合物(例如四氯化碳)的溶剂良好或溶解在良溶剂中并加入不良溶剂,并从溶液中除去溶剂。
    • 2. 发明专利
    • Tsunami shelter
    • TSUNAMI SHELTER
    • JP2014104778A
    • 2014-06-09
    • JP2012257025
    • 2012-11-26
    • Toshio Mukai向井 敏雄
    • MUKAI TOSHIO
    • B63C9/06B63B13/00B63B19/12B63B21/04B63B21/22E04H9/14
    • Y02A50/14
    • PROBLEM TO BE SOLVED: To provide a tsunami shelter which is usable even airtightness is not so high.SOLUTION: A tsunami shelter S is a hollow structure which is an approximately spherical shape, oval shape, cube shape, or rectangular solid shape. The tsunami shelter S comprises: a tsunami shelter body 1 having a gate 10 at its apex; an opening/closing door 2 for opening and closing the gate 10; and plural concave stairs 11 disposed on an outside of the tsunami shelter body 1 and extending from a lower part of the tsunami shelter body 1 toward the opening/closing door 2. On the plural concave stairs 11, a rainwater passage 12 formed into a downward inclined form from an inlet 11a to a depth is provided respectively. A tip end of the downward inclined form is formed into a closing part 11b closed, and the rainwater passage 12 communicates to a bottom of the closing part 11b and the outside of the tsunami shelter body 1 and introduces rainwater stored in the bottom of the closing part 11b toward the outside of the tsunami shelter body 1.
    • 要解决的问题:提供可用于气密性的海啸避难所不是那么高。解决方案:海啸掩体S是中空结构,其是大致球形,椭圆形,立方体形或矩形实心形状。 海啸避难所S包括:海啸避难所主体1,其顶端具有门10; 用于打开和关闭门10的打开/关闭门2; 以及设置在海啸保护体1的外侧并且从海啸防护体1的下部向打开/关闭门2延伸的多个凹形楼梯11.在多个凹形楼梯11上形成有向下的雨水通道12 分别设置从入口11a到深度的倾斜形式。 向下倾斜形式的前端形成为封闭部分11b,并且雨水通道12与封闭部分11b的底部和海啸保护体1的外部连通并引入存储在封闭件底部的雨水 部分11b朝向海啸保护体1的外部。
    • 3. 发明专利
    • Tetracyanoanthraquinodimethane-type charge transfer complex
    • 四氯乙烯磺酸酯类型电荷转移复合物
    • JPS61129157A
    • 1986-06-17
    • JP24877484
    • 1984-11-27
    • Toshio Mukai
    • MUKAI TOSHIOYAMASHITA TAKAOSUZUKI TAKANORI
    • H01B1/12C07C67/00C07C253/00C07C255/34
    • NEW MATERIAL:The compound of formula (R is H, halogen, cyano, nitro, alkyl, aryl or alkoxycarbonyl).
      EXAMPLE: 2-CN-tetracyanoanthraquinodimethane-anthracene complex (2:1).
      USE: An organic electronic material. Useful as an organic semiconductor, charge- transfer or charge-generation material for electrophotography, electrically conductive material, resistor, or thermistor material.
      PREPARATION: The complex of formula can be prepared by reacting a tetracyanoanthraquinodimethane derivative with excess electron-donative compound (e.g. benzene, naphthalene, anthracene, etc.) in a mixture of a good solvent (e.g. methylene chloride, dichloroethane, etc.) and a poor solvent (e.g. CCl
      4 ), and removing the solvents.
      COPYRIGHT: (C)1986,JPO&Japio
    • 新材料:式(R为H,卤素,氰基,硝基,烷基,芳基或烷氧基羰基)的化合物。 实施例:2-CN-四氰基蒽醌二甲烷 - 蒽配合物(2:1)。 使用:有机电子材料。 用作电子照相,电导材料,电阻或热敏电阻材料的有机半导体,电荷转移或电荷产生材料。 制备:配方的络合物可以通过使四氰基蒽醌二甲烷衍生物与过量的给电子化合物(例如苯,萘,蒽等)在良溶剂(例如二氯甲烷,二氯乙烷等)和 不良溶剂(如CCl4),并除去溶剂。
    • 9. 发明授权
    • Rare-earth antisotropic powders and magnets and their manufacturing
processes
    • 稀土防腐粉末和磁铁及其制造工艺
    • US5009706A
    • 1991-04-23
    • US554109
    • 1990-07-18
    • Hiroaki SakamotoMasahiro FujikuraToshio Mukai
    • Hiroaki SakamotoMasahiro FujikuraToshio Mukai
    • H01F1/06B22F1/00H01F1/057
    • H01F1/0571H01F1/0576
    • Rare-earth alloy anisotropic powders consist of, in atomic percent, over 12 percent and not more than 20 percent of R (R is at least one on neodymium and praseodymium or at least one of them and or more rare-earth elements), not less than 4 percent and not more than 10 percent of boron, not less than 0.05 percent and not more than 5 percent of copper and the rest that consists of iron and unavoidable impurities. Up to 20 percent of the iron contained is replaceable with cobalt. The alloy powders are made up of flat crystal grains having mean thickness h (the shortest measure), d not smaller than 0.01 .mu.m and not larger than 0.5 .mu.m and ratio d/h not smaller than 2, where d is the means measure of the grains taken at right angles to the widthwide direction thereof, and the alloy powders are magnetically anisotropic. Each rare-earth alloy anisotropic powder is prepared by melting an R-Fe-B-Cu alloy, putting thin ribbons prepared by quenching the melt or a powder prepared by grinding the thin ribbons in a metal container, hermetically sealing the metal container after replacing its inner atmosphere with a vacuum or an inert gas atmosphere, and rolling the thin ribbons or powder, together with the metal container, at a temperature not lower than 500.degree. C. and not higher than 900.degree. C. Rare-earth alloy anisotropic magnets are made by kneading and forming the rare-earth alloy anisotropic powders with not less than 10 percent and not more than 50 percent by volume of resin or by hot-compressing the rare-earth alloy anisotropic powders.
    • 稀土合金各向异性粉末以原子百分比超过12%且不超过20%的R(R是钕和镨上的至少一种或至少其中一种和/或更多的稀土元素),而不是 小于4%且不超过10%的硼,不少于0.05%且不超过5%的铜,其余由铁和不可避免的杂质组成。 含铁量高达20%可替代钴。 合金粉末由具有平均厚度h(最短测量)的平均晶粒构成,d不小于0.01μm且不大于0.5μm,d / h不小于2,其中d是平均值 的晶粒与其宽度方向成直角,并且合金粉末是磁各向异性的。 通过熔化R-Fe-B-Cu合金制备每种稀土合金各向异性粉末,将通过将熔体淬火制成的薄带或通过在金属容器中研磨薄带而制备的粉末,在更换之后气密地密封金属容器 其内部气氛具有真空或惰性气体气氛,并在不低于500℃且不高于900℃的温度下将薄带或粉末与金属容器一起滚动。稀土合金各向异性磁体 通过捏合和形成不少于10%且不大于50体积%的树脂的稀土合金各向异性粉末或通过热压缩稀土合金各向异性粉末来制备。