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    • 2. 发明授权
    • Combination pH electrode with stable standard potential
    • 组合pH电极具有稳定的标准电位
    • US07276142B2
    • 2007-10-02
    • US10074219
    • 2002-02-12
    • Steven J. WestMoshe Hirshberg
    • Steven J. WestMoshe Hirshberg
    • G01N27/36G01N27/403
    • G01N27/36
    • Disclosed are combination glass pH electrodes, the standard potential of which is stabilized by means one or more of the following structural modifications: (a) incorporating a noble metal internal element in the pH half-cell; (b) incorporating a noble metal internal element in the reference half-cell; (c) incorporating an internal pH bulb electrolyte with stable pH and oxidation-reduction potential; (d) incorporating an homogenous reference electrolyte with stable oxidation-reduction potential and equitransferent salt; (e) incorporating a liquid junction composed of a porous, inert material; (f) incorporating a reference electrolyte compartment vent; (g) incorporating a storage sleeve, with or without an absorbent medium located therein.
    • 公开了组合玻璃pH电极,其标准电位通过以下一种或多种以下结构修饰来稳定:(a)在pH半电池中掺入贵金属内部元素; (b)在参考半电池中掺入贵金属内部元素; (c)结合具有稳定的pH和氧化还原电位的内部pH球形电解质; (d)掺入具有稳定的氧化还原电位的均质参比电解质和等价盐; (e)加入由多孔惰性材料构成的液体接头; (f)加入参考电解液隔室通风口; (g)结合存储套筒,有或没有位于其中的吸收介质。
    • 4. 发明申请
    • ROBUST POTENTIOMETRIC SENSOR
    • 稳定的电位传感器
    • US20110048971A1
    • 2011-03-03
    • US12869252
    • 2010-08-26
    • Michael M. BowerDavid G. FournierZhisheng SunStephen B. TalutisDaniel G. TowerSteven J. West
    • Michael M. BowerDavid G. FournierZhisheng SunStephen B. TalutisDaniel G. TowerSteven J. West
    • G01N27/30G01N27/333G01N27/26B23P11/00
    • G01N27/4035Y10T29/49826
    • A modular potentiometric sensor includes a housing having measuring and reference half-cells, a temperature sensor, and solution ground combination assembly. An electrical conductor of the combination assembly extends through the housing, while remaining electrically isolated from the housing and half-cells, terminating at an electrically and thermally conductive end cap. Seals at opposite ends of the housing permit portions of the half-cells and the combination assembly to extend therethrough. The seals, measuring half-cell, and the combination assembly define an electrolyte compartment for the reference half-cell. The end cap provides close thermal coupling to the test fluid while also serving as a test fluid ground that is electrically isolated from the electrolyte compartment. The housing, measuring half-cell, reference half-cell, and combination assembly are modular, with the measurement sensor configurable in a plurality of lengths by altering the length of the housing independently of the half-cells and combination assembly.
    • 模块化电位传感器包括具有测量和参考半电池的壳体,温度传感器和溶液接地组合组件。 组合组件的电导体延伸穿过壳体,同时保持与壳体和半电池电隔离,终止于导电和导热端盖。 在壳体的相对端处的密封件允许半电池和组合组件的部分延伸穿过其中。 测量半电池的密封件和组合组件限定了用于参考半电池的电解质隔室。 端盖提供与测试流体的紧密热耦合,同时还用作与电解质隔室电隔离的测试流体地面。 壳体,测量半电池,参考半电池和组合组件是模块化的,测量传感器可以通过独立于半电池和组合组件改变壳体的长度而以多个长度配置。
    • 7. 发明授权
    • Calibration method using a stable and safe redox standard solution
    • 校准方法使用稳定和安全的氧化还原标准溶液
    • US06350367B1
    • 2002-02-26
    • US09178011
    • 1998-10-23
    • Steven J. West
    • Steven J. West
    • G01N2726
    • G01N27/4165Y10T436/10
    • The present invention is directed to a stable, non-hazardous solution for calibrating oxidation-reduction potential (ORP) measurement cells. The redox standard calibration solution of the present invention consists essentially of an aqueous solution containing the triiodide/iodide redox couple. In a preferred embodiment, the solution of the present invention consists essentially of an aqueous solution containing up to about 0.01 moles per liter of iodine (I2) and at least about 1 mole per liter of potassium iodide. In a most preferred embodiment, the solution of the present invention consists of an aqueous solution of 4 molar potassium iodide (KI) and 0.0067 molar iodine (I2).
    • 本发明涉及用于校准氧化还原电位(ORP)测量单元的稳定的,非危险的解决方案。 本发明的氧化还原标准校准溶液基本上由含有三碘化物/碘化物氧化还原对的水溶液组成。 在优选的实施方案中,本发明的溶液基本上由每升碘(I 2)至多约0.01摩尔和每升碘化钾至少约1摩尔的水溶液组成。 在最优选的实施方案中,本发明的溶液由4摩尔碘化钾(KI)和0.0067摩尔碘(I2)的水溶液组成。
    • 10. 发明申请
    • pH Electrode and Electrolyte
    • pH电极和电解质
    • US20120318684A1
    • 2012-12-20
    • US13595410
    • 2012-08-27
    • Steven J. WestZhisheng Sun
    • Steven J. WestZhisheng Sun
    • G01F1/64
    • G01N27/4035
    • A pH half-cell method and apparatus includes an electrode, a pH sensitive glass membrane and an electrolyte in electrolytic contact with the electrode and membrane. The membrane includes at least about 15 mole percent lithium, and the electrolyte includes a lithium salt as the predominant monovalent cation. The pH half-cell is used with a reference half-cell and meter to provide an electrochemical potential measurement sensor, optionally with both half-cells disposed within a single housing. The lithium salt electrolyte is also used in a method for storing, conditioning, preserving and/or rehabilitating a pH half-cell.
    • pH半电池方法和装置包括电极,pH敏感玻璃膜和与电极和膜电解接触的电解质。 该膜包括至少约15摩尔%的锂,并且电解质包括作为主要一价阳离子的锂盐。 pH半电池与参考半电池和电表一起使用以提供电化学电位测量传感器,任选地两个半电池都设置在单个外壳内。 锂盐电解质也用于储存,调理,保存和/或修复pH半电池的方法。