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1. 发明授权

US5922636A Catalyst for oligomerization of alpha-olefins 失效
标题翻译： α-烯烃低聚催化剂
公开(公告)号：US5922636A
公开(公告)日：1999-07-13
申请号：US972951
申请日：1997-11-19
申请人： Rakesh Sarin , Sabyasachi Sinha Ray , Deepak Kumar Tuli , Madan Mohan Rai , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
发明人： Rakesh Sarin , Sabyasachi Sinha Ray , Deepak Kumar Tuli , Madan Mohan Rai , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
IPC分类号： B01J27/125 , C07C2/26 , B01J31/02 , B01J31/12 , B01J31/26
CPC分类号： B01J31/0212 , B01J27/125 , C07C2/26 , B01J2231/20 , C07C2527/125 , C07C2527/126 , C07C2531/02 , C07C2531/26
摘要： A catalyst composition for use in oligomerization of olefins contained in refinery distillate streams including paraffins, naphthenes, and aromatics therein, the catalyst consisting of a first constituent which is at least one aluminum halide; and a second constituent which is at least one alkoxide of a transition metal of Group IVB of the Periodic Table and which has a general formula:M(OR).sub.4,where M is selected from the group consisting of metals of Group IVB of the Periodic Table and R is one of (a) an alkyl group having from 1-12 carbon atoms or (b) an alkylaryl group having an alkyl chain having from 1-12 carbon atoms.
摘要翻译：一种催化剂组合物，用于在包含石油馏出物流中的烯烃的低聚反应中，其中包括烷烃，环烷烃和芳烃，所述催化剂由至少一种卤化铝的第一组分组成; 和第二组分，其为元素周期表IVB族过渡金属的至少一种醇盐，其具有通式M（OR）4，其中M选自周期表IVB族的金属表和R是（a）具有1-12个碳原子的烷基或（b）具有1-12个碳原子的烷基链的烷基芳基之一。

2. 发明申请

US20050158237A1 Process for enhancing yield of sodium aluminosilicate molecular sieves during synthesis 审中-公开
标题翻译：在合成过程中提高硅铝酸钠分子筛的产率
公开(公告)号：US20050158237A1
公开(公告)日：2005-07-21
申请号：US10758898
申请日：2004-01-16
申请人： Ram Thakur , Mohan Kuvettu , Biswanath Sarkar , Venkatachalam Krishnan , Mitra Patel , Sanjay Ray , Gopal Ravichandran , Satish Makhija , Sobhan Ghosh
发明人： Ram Thakur , Mohan Kuvettu , Biswanath Sarkar , Venkatachalam Krishnan , Mitra Patel , Sanjay Ray , Gopal Ravichandran , Satish Makhija , Sobhan Ghosh
IPC分类号： C01B39/02 , C01B39/14 , C01B39/20 , C01B39/26
CPC分类号： C01B39/14 , C01B39/02 , C01B39/20 , C01B39/26
摘要： The present invention relates to a process for enhancing the yield of molecular sieve zeolite during the synthesis from a sodium aluminosilicate reaction mixture, said process comprising the step of adding at an intermediate stage of crystallization a source of aluminum to the sodium aluminosilicate reaction mixture and allowing the mixture to crystallize.
摘要翻译：本发明涉及一种在由铝硅酸钠反应混合物合成过程中提高分子筛沸石的产率的方法，所述方法包括在中间阶段将铝源加入到硅铝酸钠反应混合物中并允许混合物结晶。

3. 发明授权

US06613710B2 Process for preparation of bi-functional fluid catalytic cracking catalyst composition 失效
公开(公告)号：US06613710B2
公开(公告)日：2003-09-02
申请号：US09961384
申请日：2001-09-25
申请人： Sanjay Kumar Ray , Mohan Prabhu Kuvettu , Venkatchalam Krishnan , Gopal Ravichandran , Kamlesh Gupta , Sukumar Mandal , Satish Makhija , Sobhan Ghosh , Arumugam Velayutham Karthikeyani , Mitra Bhanu Patel
发明人： Sanjay Kumar Ray , Mohan Prabhu Kuvettu , Venkatchalam Krishnan , Gopal Ravichandran , Kamlesh Gupta , Sukumar Mandal , Satish Makhija , Sobhan Ghosh , Arumugam Velayutham Karthikeyani , Mitra Bhanu Patel
IPC分类号： B01J2116
CPC分类号： B01J37/0045 , B01J21/04 , B01J21/16 , B01J29/40 , B01J29/7007 , B01J35/002 , B01J2229/42 , C10G11/05
摘要： A process for preparing bi-functional catalyst for Fluid Catalytic Cracking (FCC), that comprises molecular sieves, modified clay and semi-basic alumina and the catalyst for highly effective cracking of high boiling petroleum feedstock to provide simultaneously, enhanced yields of Liquefied Petroleum Gas (LPG) and reduction of undesirable bottoms.

4. 发明授权

US06267873B1 Fluidized catalytic cracking process 有权
标题翻译：流化催化裂化工艺
公开(公告)号：US06267873B1
公开(公告)日：2001-07-31
申请号：US09201896
申请日：1998-11-30
申请人： Asit Kumar Das , Debasis Bhattacharyya , Sukumar Mandal , Vutukuru Lakshmi Narasimha Murthy , Sanjeev Singh , Marri Rama Rao , Sobhan Ghosh
发明人： Asit Kumar Das , Debasis Bhattacharyya , Sukumar Mandal , Vutukuru Lakshmi Narasimha Murthy , Sanjeev Singh , Marri Rama Rao , Sobhan Ghosh
IPC分类号： C10G1100
CPC分类号： C10G11/187 , C10G11/18 , Y10S585/91
摘要： A fluidized catalytic cracking process for catalytically cracking a feed to lighter products includes introducing a heated catalyst and the feed into a bottom riser of a fluidized catalytic cracking apparatus and allowing the heated catalyst and the feed to preaccelerate upwardly within the bottom riser as a mixture; flowing the mixture upwardly from the bottom riser through a plurality of microriser tubes disposed within a regenerator under conditions effective to cause a cracking reaction of the hydrocarbons and result in a mixture including coked catalyst and hydrocarbon vapors; passing the mixture from the microriser tubes through a catalyst separator for separating the coked catalyst from the hydrocarbon vapors; collecting coked catalyst in a stripper for stripping out hydrocarbon vapors carried along with the coked catalyst and introducing the coked catalyst collected into a regenerator; simultaneous with flowing the mixture, combusting the coked catalyst within the regenerator under conditions effective to cause regeneration of the catalyst so that hot regenerated catalyst is produced and heat transferred to the microriser tubes; introducing the hot regenerated catalyst from the regenerator into the bottom riser for facilitating continuous operation; and directing hydrocarbon vapors from the catalyst separator and from the stripper to a fractionator for separation of products.
摘要翻译：将进料催化裂化成较轻产物的流化催化裂化方法包括将加热的催化剂和进料引入流化催化裂化装置的底部提升管中，并允许加热的催化剂和进料作为混合物在底部提升管内向前预加速; 在有效引起烃的裂解反应并产生包括焦化催化剂和烃蒸汽的混合物的条件下，将混合物从底部提升管向上流过设置在再生器内的多个微型管; 将混合物从微循环管通过催化剂分离器，用于将焦化的催化剂与烃蒸气分离; 在汽提器中收集焦化的催化剂，用于汽提与焦炭催化剂一起携带的烃蒸气并将收集的焦化催化剂引入再生器中; 同时使混合物流动，在有效使催化剂再生的条件下在再生器内燃烧焦化催化剂，使得产生热再生催化剂并将热量传递至微型管; 将热再生催化剂从再生器引入底部提升管，以便于连续操作; 并将碳氢化合物蒸汽从催化剂分离器和汽提器引导至用于分离产物的分馏器。

5. 发明授权

US5846402A Process for catalytic cracking of petroleum based feed stocks 失效
标题翻译：石油基原料催化裂化工艺
公开(公告)号：US5846402A
公开(公告)日：1998-12-08
申请号：US855946
申请日：1997-05-14
申请人： Sukumar Mandal , Suresh Kumarshah , Debasis Bhattacharyya , Vutukuru Lakshmi Narasimha Murthy , Asit Kumar Das , Sanjeev Singh , Ram Mohan Thakur , Shankar Sharma , Jagdev Kumar Dixit , Sobhan Ghosh , Satyen Kumar Das , Manoranjan Santra , Latoor Lal Saroya , Marri Rama Rao , Ganga Shanker Mishra , Satish Makhija
发明人： Sukumar Mandal , Suresh Kumarshah , Debasis Bhattacharyya , Vutukuru Lakshmi Narasimha Murthy , Asit Kumar Das , Sanjeev Singh , Ram Mohan Thakur , Shankar Sharma , Jagdev Kumar Dixit , Sobhan Ghosh , Satyen Kumar Das , Manoranjan Santra , Latoor Lal Saroya , Marri Rama Rao , Ganga Shanker Mishra , Satish Makhija
IPC分类号： B01J29/80 , C10G11/05 , C10G11/18 , C10G11/00
CPC分类号： B01J29/80 , C10G2400/20 , C10G2400/28
摘要： A process for selective catalytic cracking of a petroleum-based feedstock to produce a product having a high yield of liquified petroleum gas (LPG) and light olefins having 3 to 4 carbons includes providing a fluidized bed reactor which is a high velocity riser, continuously circulating fluidized bed reactor; providing a solid acidic catalyst comprised of: from 1 to 6% by wt. of ultra stable Y-zeolite; from 8-25% by wt. of Pentasil zeolite which is shape selective; from 0-8% by wt. of an active material which is bottom selective; from 0-1% by wt. of rare earth constituents; and from 91 to 60% by wt. of nonacidic constituents and binder; charging the fluidized bed reactor with the solid acidic catalyst and the petroleum-based feedstock; and cracking the petroleum-based feedstock in the presence of the solid acidic catalyst in the fluidized bed reactor. The reactor is operated at a Weight Hourly Space Velocity (WHSV) ranging from 40 to 120 hr.sup.-1, a ratio of solid acidic catalyst to petroleum-based feedstock ranging from 15 to 25, a temperature at the top of the high velocity riser ranging from 530.degree. C. to 600.degree. C., recycled riser products ranging from 0 to 40%, a pressure in the fluidized bed reactor ranging from 1.0 to 4.0 kg/cm.sup.2 g, and an amount of steam for dilution and quenching of hydrocarbons ranging from 3 to 50 wt. % of the petroleum-based feedstock. The Pentasil zeolite has a pore size ranging from 5 to 6 .ANG. so that the catalyst is highly selective for LPG and C.sub.4 light olefins with minimum dry gas and coke make, and so that the vanadium tolerance of the catalyst is increased and ranges up to 21,000 PPM. The process produces a LPG yield ranging up to 40 to 65 wt. % of the fresh petroleum-based feedstock, a selectivity for the light olefins of at least 40 wt. %, and a selectivity for the LPG of at least 45 wt.
摘要翻译：选择性催化裂化石油基原料以生产具有高产率的液化石油气（LPG）和具有3至4个碳原子的轻质烯烃的产物的方法包括提供流化床反应器，其为高速提升管，连续循环流化床反应器; 提供固体酸性催化剂，其包含：1至6重量％的超稳定Y型沸石; 8-25重量％。具有形状选择性的pentasil沸石; 0-8重量％的底部选择性活性物质; 0-1重量％的稀土成分; 和91〜60重量％。的非酸成分和粘合剂; 用固体酸性催化剂和石油基原料装入流化床反应器; 并在流化床反应器中在固体酸性催化剂存在下裂化石油基原料。反应器以40至120小时-1的重量小时空间速度（WHSV）运行，固体酸性催化剂与石油基原料的比例为15至25，高速提升管顶部的温度范围从530℃至600℃，循环的提升产品的范围为0至40％，流化床反应器的压力范围为1.0至4.0kg / cm2g，以及用于稀释和猝灭烃的蒸汽量 3〜50重量％％的石油基原料。 Pentasil沸石的孔径范围为5至6安格姆，使得催化剂对于具有最少干燥气体和焦炭的LPG和C4轻质烯烃具有高选择性，并且使得催化剂的耐钒性增加并且范围高达21,000 PPM。该方法产生高达40至65重量％的LPG产率。％的新鲜石油基原料，轻质烯烃的选择性至少为40wt。％，并且LPG的选择性至少为45wt。

6. 发明授权

US07462275B2 Process for conversion of hydrocarbons to saturated LPG and high octane gasoline 有权
标题翻译：将碳氢化合物转化为饱和LPG和高辛烷值汽油的方法
公开(公告)号：US07462275B2
公开(公告)日：2008-12-09
申请号：US10894341
申请日：2004-07-20
申请人： Asit Kumar Das , Debasis Bhattacharyya , Gadari Saidulu , Satayen Kumar Das , Bandaru Venkata Hari P. Gupta , Ramakrishnan Ramanarayanan , Latoor Lal Saroya , Konduri Lakshminarayana , Marri Rama Rao , Vinod Ramchandra Upadhyay , Sukumar Mandal , Deepa Meghavathu , Arumugam Velayutham Karthikeyani , Wadharwa Ram Kalsi , Arvind Pratap Singh , Veena Bansal , Ashok Kumar Tiwari , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raghunath Raje
发明人： Asit Kumar Das , Debasis Bhattacharyya , Gadari Saidulu , Satayen Kumar Das , Bandaru Venkata Hari P. Gupta , Ramakrishnan Ramanarayanan , Latoor Lal Saroya , Konduri Lakshminarayana , Marri Rama Rao , Vinod Ramchandra Upadhyay , Sukumar Mandal , Deepa Meghavathu , Arumugam Velayutham Karthikeyani , Wadharwa Ram Kalsi , Arvind Pratap Singh , Veena Bansal , Ashok Kumar Tiwari , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raghunath Raje
IPC分类号： C10G67/00
CPC分类号： C10G11/05 , C10G2400/28
摘要： The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2 (g) and weight hourly space velocity in range of 0.1 to 20 hour−1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.
摘要翻译：本发明涉及一种将95％真实沸点低于400℃的烃流转化成非常高产率的进料和高辛烷值汽油的45-65重量％的液化石油气的方法，所述方法包括使用固体可流化催化剂催化裂化烃，所述固体可流化催化剂包含具有或不具有Y-沸石的中孔结晶铝硅酸盐，非结晶酸性物质或其组合，其在400至550℃的温度范围内操作的流化密床反应器 ℃，压力范围为2至20kg / cm2（g）和0.1至20小时-1范围内的重时空速，其中所述致密床反应器与用于连续的催化剂汽提塔和再生器流动连通在存在空气和/或含氧气体的情况下再生焦化的催化剂，催化剂在反应器 - 再生器系统之间连续循环。

7. 发明申请

US20060096890A1 Resid cracking apparatus with catalyst and adsorbent regenerators and a process thereof 有权
公开(公告)号：US20060096890A1
公开(公告)日：2006-05-11
申请号：US11266233
申请日：2005-11-04
申请人： Kawliwal Pankaj , Rama Marri , Dixit Kumar , Saroya Lal , Sukumar Mandal , Satish Makhija , Sobhan Ghosh
发明人： Kawliwal Pankaj , Rama Marri , Dixit Kumar , Saroya Lal , Sukumar Mandal , Satish Makhija , Sobhan Ghosh
IPC分类号： C10G11/00
CPC分类号： C10G55/06 , C10G11/18 , C10G25/05 , C10G25/08
摘要： This invention provides a resid cracking apparatus comprising a riser, reactor, stripper cum separator with adjustable outlets in flow communication with adsorbent and catalyst regenerators for converting hydrocarbon residues containing higher concentration of conradson carbon content, poisonous metals such as nickel & vanadium and basic nitrogen etc., into lighter and valuable products and a process thereof.

8. 发明授权

US06540904B1 Process for the upgradation of petroleum residue 有权
标题翻译：石油残渣升级过程
公开(公告)号：US06540904B1
公开(公告)日：2003-04-01
申请号：US09518413
申请日：2000-03-03
申请人： Suhas Ranjan Gun , Priya Bandhu Chowdhury , Kashi Nath Bhattacharya , Achinta Kumar Roy , Umanand Sharma , Swapan Kumar Ghosh , Awadhesh Kumar Sinha , Santosh Kumar Chanda , Sukumar Mandal , Sanjay Kumar Ray , Asit Kumar Das , Satish Makhija , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
发明人： Suhas Ranjan Gun , Priya Bandhu Chowdhury , Kashi Nath Bhattacharya , Achinta Kumar Roy , Umanand Sharma , Swapan Kumar Ghosh , Awadhesh Kumar Sinha , Santosh Kumar Chanda , Sukumar Mandal , Sanjay Kumar Ray , Asit Kumar Das , Satish Makhija , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
IPC分类号： C10G1102
CPC分类号： C10G11/02 , C10G2300/107
摘要： The present invention provides a process for the upgradation of petroleum residue into useful fractions by subjecting petroleum residue in the presence of a solvent and ferrous sulphate catalyst to a pressure in the range of 10 atm. to 120 atm., temperature in the range of 380-420° C., for a period in the range of 0-120 minutes, in a reactor vessel, in an inert atmosphere. The charge is then cooled to room temperature and the product gas released through scrubbers. The residue is re-heated, if required, for free flow of liquid product. The resulting liquid product is distilled to obtain useful fractions.
摘要翻译：本发明提供了一种通过在溶剂和硫酸亚铁催化剂存在下将石油残余物在10atm范围内的压力下将石油残渣升级为有用级分的方法。温度在380-420℃的范围内，在0-120分钟的时间内，在反应器容器中，在惰性气氛中。然后将电荷冷却至室温，并通过洗涤器释放产物气体。如果需要，残余物被重新加热，用于液体产品的自由流动。将所得液体产物蒸馏以获得有用的级分。

9. 发明授权

US06184429B2 Oligomerization of alpha-olefins 失效
标题翻译： α-烯烃的低聚
公开(公告)号：US06184429B2
公开(公告)日：2001-02-06
申请号：US09354844
申请日：1999-07-16
申请人： Rakesh Sarin , Sabyasachi Sinha Ray , Deepak Kumar Tuli , Madan Mohan Rai , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
发明人： Rakesh Sarin , Sabyasachi Sinha Ray , Deepak Kumar Tuli , Madan Mohan Rai , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
IPC分类号： C07C202
CPC分类号： B01J31/0212 , B01J27/125 , B01J2231/20 , C07C2/26 , C07C2527/125 , C07C2527/126 , C07C2531/02 , C07C2531/26
摘要： This invention relates to a catalyst composition capable of effecting selective oligomerisation of olefins contained in cracked refinery distillate streams, comprising of olefins, aromatics, paraffins and cycloparaffins. The catalyst composition gives very high conversion of olefins to poly olefins, which after distillation and stabilization by hydrogenation affords lubricating oil base stocks. The catalyst composition comprises of an aluminum halide and a transition metal alkoxide belonging to group IVB.
摘要翻译：本发明涉及一种催化剂组合物，其能够对包含在烯烃，芳族化合物，链烷烃和环烷烃的裂化炼油馏出物流中的烯烃进行选择性低聚。催化剂组合物提供非常高的烯烃转化为聚烯烃，其在蒸馏和通过氢化稳定化后提供润滑油基础油。催化剂组合物包含属于IVB族的卤化铝和过渡金属醇盐。

10. 发明授权

US6114267A Process for the preparation of fluidized catalytic cracking (FCC) catalyst 失效
标题翻译：流化催化裂化（FCC）催化剂的制备方法
公开(公告)号：US6114267A
公开(公告)日：2000-09-05
申请号：US80201
申请日：1998-05-18
申请人： Sobhan Ghosh , Satish Makhija , Mohan Prabhu Kuvettu , Ventachalam Krishnan , Sanjay Kumar Ray , Manoranjan Santra , Ram Mohan Thakur , Jagdev Kumar Dixit
发明人： Sobhan Ghosh , Satish Makhija , Mohan Prabhu Kuvettu , Ventachalam Krishnan , Sanjay Kumar Ray , Manoranjan Santra , Ram Mohan Thakur , Jagdev Kumar Dixit
IPC分类号： B01J29/08 , C10G11/05 , B01J29/06
CPC分类号： C10G11/05 , B01J29/084
摘要： A process for preparation of fluidized catalytic cracking (FCC) catalyst, comprising silicon stabilized large crystallite sized synthetic faujasite zeolite, aluminum depleted and normal kaolin clay, alumina and silica. The cracking catalyst is highly active and selective for bottom upgradation, it produces less coke and higher gasoline and total cycle oil (TCO) and possesses improved metal tolerance properties when evaluated and compared with a commercial catalyst under conditions of a typical FCC unit in a petroleum refinery.
摘要翻译：一种制备流化催化裂化（FCC）催化剂的方法，包括硅稳定的大晶粒大小的合成八面沸石沸石，贫铝和正常的高岭土，氧化铝和二氧化硅。裂解催化剂对于底部升级具有高度活性和选择性，它在较低的焦炭和更高的汽油和全周期循环油（TCO）时产生较少的金属耐受性，并且在石油中典型的FCC装置条件下与商业催化剂进行比较炼油厂

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