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1. 发明授权

US4438086A Method for preparation of graphite fluoride by contact reaction between carbon and fluorine gas 失效
标题翻译：通过碳氟与氟气接触反应制备氟化石墨的方法
公开(公告)号：US4438086A
公开(公告)日：1984-03-20
申请号：US413889
申请日：1982-09-01
申请人： Minoru Aramaki , Yasushi Kita , Hishagi Nakano , Shiro Moroi
发明人： Minoru Aramaki , Yasushi Kita , Hishagi Nakano , Shiro Moroi
IPC分类号： C01B31/04 , B01J8/02 , C01B31/00 , C01B9/08 , C01B31/30
CPC分类号： B01J8/02 , C01B31/005 , B01J2208/00194 , B01J2208/00407 , B01J2208/0053 , B01J2208/00548 , B01J2219/182
摘要： A method and apparatus for preparation of a graphite fluoride such as (CF).sub.n or (C.sub.2 F).sub.n by heterogeneous contact reaction between a carbon material such as graphite or petroleum coke and fluorine gas at about 200.degree.-550.degree. C. The carbon material in the form of small pieces such as granules or powder particles is kept in a holder having a number of openings so as to form a carbon material layer in the holder, which is placed in a reactor so as to leave gas passages around the holder. With heating, fluorine gas is forcibly passed through the gas passages without agitating the carbon material in the holder. The openings of the holder are shaped and arranged such that the fluorine gas permeates through the carbon material layer in the holder. For example, the holder is an open-type box made of either a wire screen or a perforated metal plate, or a conveyor belt made of a wire screen. This method is effective for prevention of spontaneous decomposition of the formed graphite fluoride attributed to accumulation of the heat of reaction within the reacting carbon material layer and/or mechanical shocks or vibrations to the fluorinated carbon.
摘要翻译：一种用于在约200-550℃之间的诸如石墨或石油焦炭等碳材料与氟气之间的非均相接触反应来制备（CF）n或（C2F）n等氟化石墨的方法和装置。将小颗粒或粉末颗粒的形式保持在具有多个开口的保持器中，以便在保持器中形成碳材料层，该碳材料层放置在反应器中，以使得气体通道围绕保持器。通过加热，氟气被强制地通过气体通道，而不会搅动保持器中的碳材料。保持器的开口被成形和布置成使得氟气渗透通过保持器中的碳材料层。例如，保持器是由丝网或穿孔金属板或由丝网制成的输送带制成的开放式箱体。该方法对于防止由于反应碳材料层内的反应热的积累和/或对氟化碳的机械冲击或振动而导致的形成的氟化石墨的自发分解是有效的。

2. 发明授权

US4593132A Process for producing a graphite fluoride 失效
标题翻译：石墨氟化物的制造方法
公开(公告)号：US4593132A
公开(公告)日：1986-06-03
申请号：US659049
申请日：1984-12-10
申请人： Yasushi Kita , Hishaji Nakano , Shiro Moroi , Akira Sakanoue
发明人： Yasushi Kita , Hishaji Nakano , Shiro Moroi , Akira Sakanoue
IPC分类号： C01B31/04 , C01B31/00 , D01F11/12 , C07C17/00
CPC分类号： D01F11/129 , C01B31/005
摘要： A graphite fluoride can be produced safely and in high yield on a commercial production scale by a process comprising reacting a carbon material having an average size of 100.mu. to 10 mm with fluorine. Further, when the fluorination reaction is stopped before completion thereof and the graphite fluoride product is subjected to sifting with a sieve to separate a desired graphite fluoride from the raw carbon material remaining unreacted.
摘要翻译：可以通过包括使平均粒度为100〜10mm的碳材料与氟反应的方法以商业生产规模安全地和高收率地生产氟化石墨。此外，当氟化反应在其完成之前停止并且氟化石墨产物用筛子进行筛分以从未还原的原料碳分离所需的氟化石墨。

3. 发明授权

US4590316A Method of safely preparing graphite fluoride 失效
标题翻译：安全地制备氟化石墨的方法
公开(公告)号：US4590316A
公开(公告)日：1986-05-20
申请号：US650986
申请日：1984-09-14
申请人： Yasushi Kita , Hisaji Nakano , Shiro Moroi , Akira Sakanoue
发明人： Yasushi Kita , Hisaji Nakano , Shiro Moroi , Akira Sakanoue
IPC分类号： C01B31/00 , C01B31/04 , C07C17/00
CPC分类号： C01B31/005
摘要： A method of preparing graphite fluoride such as (CF).sub.n or (C.sub.2 F).sub.n by heterogeneous contact reaction between a carbon material such as graphite or petroleum coke and fluorine gas at about 200.degree.-550.degree. C. In the gas phase of the reaction system, the total concentration of higher fluorocarbons having more than four carbon atoms formed by side reactions is controlled so as not to become above 3% by volume by, for example, condensation or catalytic decomposition of at least a portion of the higher fluorocarbons in the gas flowed out of the reaction chamber for recirculation. Such control is highly effective for prevention of rapid and violent decomposition of the graphite fluoride existing in the solid phase of the reaction system induced by sudden decomposition of the higher fluorocarbons in the reaction system to lower fluorocarbons.
摘要翻译：一种在约200〜-550℃之间的碳材料如石墨或石油焦炭与氟气之间的非均相接触反应制备（CF）n或（C 2 F）n的氟化石墨的方法。在反应的气相通过副反应形成的具有多于四个碳原子的高级碳氟化合物的总浓度被控制为通过例如至少一部分较高碳氟化合物的冷凝或催化分解而不会变成高于3体积％气体从反应室流出，用于再循环。这种控制对于防止由反应体系中的较高碳氟化合物突然分解成低碳氟化合物引起的反应体系固相中存在的氟化石墨的快速和剧烈分解是非常有效的。

4. 发明授权

US4710335A Method of producing electric cell anode using powdery active material 失效
标题翻译：使用粉末状活性物质制造电池阳极的方法
公开(公告)号：US4710335A
公开(公告)日：1987-12-01
申请号：US743931
申请日：1985-06-12
申请人： Yasushi Kita , Shiro Moroi
发明人： Yasushi Kita , Shiro Moroi
IPC分类号： H01M4/06 , H01M4/04 , H01M4/08 , H01M4/62 , H01M4/26
CPC分类号： H01M4/0404 , H01M4/04 , H01M4/0416 , H01M4/043 , H01M4/08 , H01M4/621
摘要： Using a positive active material in powder form such as a metal salt or graphite fluoride, an anode for use in an electric cell, and particularly suitable for use in an organic electrolyte cell, is produced by the steps of dispersing the active material, and a conductive material such as carbon powder where necessary, in a solution of an organic polymer used as binder in a suitable liquid, mixing the dispersion with another liquid in which the polymer is substantially insoluble so as to cause precipitation of the polymer in a state intimately mixed with the active material and the conductive material, separating the solid phase mixture from the liquid phase and drying it, and press-shaping the dried mixture into an anode body of a desired shape. By mixing the binder with the active material in this manner, it is possible to obtain an anode body sufficient in mechanical strength and high in electrochemical activity by using only a very small amount of binder.
摘要翻译：使用粉末形式的正极活性物质，例如金属盐或氟化石墨，用于电池的阳极，特别适合用于有机电解质电池的阳极通过以下步骤制备：分散活性物质，和导电材料如碳粉，必要时在用作粘合剂的合适液体中的有机聚合物的溶液中，将该分散体与其中聚合物基本上不溶的另一种液体混合，以使聚合物在紧密混合的状态下沉淀与活性材料和导电材料，将固相混合物与液相分离并干燥，并将干燥的混合物压成型为所需形状的阳极体。通过以这种方式将粘合剂与活性物质混合，可以通过仅使用非常少量的粘合剂获得足够的机械强度和高的电化学活性的阳极体。

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