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1. 发明授权

US4379872A Amphoteric amino sulfonate derivatives of epoxy resins 失效
标题翻译：环氧树脂的两性氨基磺酸酯衍生物
公开(公告)号：US4379872A
公开(公告)日：1983-04-12
申请号：US293077
申请日：1981-08-17
申请人： Shin-Ichi Ishikura , Kazunori Kanda , Ryuzo Mizuguchi
发明人： Shin-Ichi Ishikura , Kazunori Kanda , Ryuzo Mizuguchi
IPC分类号： C08G59/14 , C08G59/40 , C09D151/08 , C08L63/00
CPC分类号： C09D151/08 , C08G59/1483 , C08G59/4064
摘要： Amphoteric amino sulfonate derivatives of epoxy resins having at least one terminal group of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen or methyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.20 alkyl or substituted alkyl, and R.sub.4 is C.sub.1 -C.sub.6 alkylene or substituted alkylene, which are reaction products of an epoxy resin having a plurality of terminal groups of the formula: ##STR2## wherein R.sub.1 and R.sub.2 are as defined, with an amino sulfonate of the formula:R.sub.3 --NH--R.sub.4 --SO.sub.3 Mwherein R.sub.3 and R.sub.4 are as defined, and M is a cation.
摘要翻译：具有至少一个下式的末端基团的环氧树脂的两性氨基磺酸酯衍生物：其中R 1和R 2是氢或甲基，R 3是氢或C 1 -C 20烷基或取代的烷基，R 4是C 1 -C 6亚烷基或取代的亚烷基，其是具有下列式的多个端基的环氧树脂的反应产物：其中R 1和R 2如上所定义，与下式的氨基磺酸盐：R3-NH-R4-SO3M，其中R3和R4 如上所定义，M为阳离子。

2. 发明授权

US4205152A Thermosetting resin and its production 失效
标题翻译：热固性树脂及其生产
公开(公告)号：US4205152A
公开(公告)日：1980-05-27
申请号：US859102
申请日：1977-12-09
申请人： Ryuzo Mizuguchi , Atsushi Takahashi , Shin-ichi Ishikura , Akimitsu Uenaka
发明人： Ryuzo Mizuguchi , Atsushi Takahashi , Shin-ichi Ishikura , Akimitsu Uenaka
IPC分类号： C08F220/58 , C08F246/00 , C09D133/24 , C08F20/06 , C08F220/06 , C08F28/00
CPC分类号： C08F220/58 , C08F246/00 , C09D133/24 , Y10S526/923
摘要： A thermosetting resin which is a linear copolymer having a molecular weight of 10,000 to 1,000,000 and a glass transition point of -30.degree. to +80.degree. C., obtained by polymerizing in an aqueous medium a monomer mixture comprising (1) 0.1 to 50% by weight of at least one polymerizable monomer having an ampho-ionic structure, selected from the group consisting of (i) compounds representable by the formula: ##STR1## wherein R.sub.1 is a hydrogen atom or a methyl group, R.sub.2 and R.sub.3 are each, the same or different, a C.sub.1 -C.sub.6 alkyl group, A is O or NH, m.sub.1 and n.sub.1 are each, the same or different, an integer of 1 to 12 and X.sup..crclbar. is SO.sub.3.sup..crclbar., SO.sub.4.sup..crclbar. or CO.sub.2.sup..crclbar. and (ii) compounds representable by either one of the formulae: ##STR2## wherein R.sub.4 is a hydrogen atom or a methyl group, R.sub.5 is a hydrogen atom or a C.sub.1 -C.sub.3 alkyl group, m.sub.2 is an integer of 0 to 6 and n.sub.2 is an integer of 1 to 6, and A and X.sup.- are as defined above, (2) 0.5 to 70% by weight of at least one polymerizable monomer containing a reactive amide group, representable by the formula: ##STR3## wherein R.sub.6 is a hydrogen atom or a methyl group and R.sub.7 is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group and (3) 1 to 99.4% by weight of at least one of other polymerizable monomers.
摘要翻译：一种热固性树脂，它是一种线性共聚物，其分子量为10,000至1,000,000，玻璃化转变温度为-30℃至+ 80℃。通过在水性介质中聚合单体混合物获得，该单体混合物包含（1）0.1至50％的至少一种具有两性离子结构的可聚合单体，其选自（i）由下式表示的化合物：其中R 1是氢原子或甲基，R 2和R 3 各自相同或不同，C1-C6烷基，A为O或NH，m1和n1各自相同或不同，为1〜12的整数，X（ - ）为SO 3（ - ），SO 4 （ - ）或CO 2（ - ）和（ii）可以由下式之一表示的化合物：其中R 4是氢原子或甲基，R 5是氢原子或C1-C3烷基，m2为0〜6的整数，n2为1〜6的整数，A和X定义如上，（2）0.5〜70重量％的至少一种可聚合单体含量其中R6是氢原子或甲基，R7是氢原子或C1-C4烷基，和（3）1到99.4重量％的下式表示的反应性酰胺基团：的至少一种其它可聚合单体。

3. 发明授权

US4322324A Ampho-ionic group-containing alkyd resins 失效
标题翻译：含两性离子基团的醇酸树脂
公开(公告)号：US4322324A
公开(公告)日：1982-03-30
申请号：US208641
申请日：1980-11-20
申请人： Ryuzo Mizuguchi , Shin-ichi Ishikura , Keizo Ishii
发明人： Ryuzo Mizuguchi , Shin-ichi Ishikura , Keizo Ishii
IPC分类号： C08G63/00 , B01F17/52 , C08G63/49 , C08G63/68 , C08G63/685 , C08G63/688 , C09D167/00
CPC分类号： C08G63/6884
摘要： An alkyd resin containing ampho-ionic groups of the formula: ##STR1## wherein A is a C.sub.1 -C.sub.6 alkylene or a phenylene group, is disclosed. Said resin is prepared by reacting a polyol, a polybasic acid and an ampho-ionic compound of the formula: ##STR2## wherein A is as defined above, R.sub.1 is a hydroxyalkyl, R.sub.2 and R.sub.3 are H or alkyl optionally containing sulfo and/or hydroxyl group.
摘要翻译：公开了含有下式的两性离子基团的醇酸树脂：其中A是C1-C6亚烷基或亚苯基。所述树脂通过使多元醇，多元酸和下式的两性离子化合物反应制备：其中A如上所定义，R 1是羟烷基，R 2和R 3是H或任选地含有磺基和/或羟基。

4. 发明授权

US4140664A Thermosetting resin composition 失效
标题翻译：热固性树脂组合物
公开(公告)号：US4140664A
公开(公告)日：1979-02-20
申请号：US830792
申请日：1977-09-06
申请人： Ryuzo Mizuguchi , Atushi Takahashi , Shin-ichi Ishikura , Akimitsu Uenaka
发明人： Ryuzo Mizuguchi , Atushi Takahashi , Shin-ichi Ishikura , Akimitsu Uenaka
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F20/00 , C08F20/34 , C08F20/38 , C08F20/52 , C08F26/00 , C08F26/06 , C08F220/34 , C08F220/60 , C08F226/06 , C09D133/00 , C09D133/04 , C08L33/02 , C08L35/00 , C08L61/24 , C08L61/28
CPC分类号： C08F226/06 , C08F220/34 , C08F220/60 , C09D133/00
摘要： An aqueous solution or dispersion of thermosetting resin comprising a resin, dissolved or dispersed in water in an amount of 5 to 85% by weight, said resin being obtained by solution polymerization of a mixture comprising (1) at least one polymerizable monomer having an amphoteric ion structure, (2) at least one polymerizable monomer containing a carboxyl group and (3) at least one of other polymerizable monomers in a hydrophilic organic solvent and has a number average molecular weight of 1,000 to 30,000 and a glass transition point of -30 to +80.degree. C.
摘要翻译：一种热固性树脂的水溶液或分散体，其包含溶解或分散在水中的树脂，其量为5至85重量％，所述树脂通过溶液聚合获得，所述混合物包含（1）至少一种具有两性的可聚合单体离子结构，（2）含有羧基的至少一种可聚合单体和（3）亲水性有机溶剂中的至少一种其它可聚合单体，数均分子量为1,000至30,000，玻璃化转变温度为-30 至+80℃

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