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1. 发明授权

US06884876B2 Disperse-reactive dyes containing acetoxyethylsulfone or vinylsulfone and their process 失效
标题翻译：含有乙酰氧基乙基砜或乙烯基砜的分散反应性染料及其工艺
公开(公告)号：US06884876B2
公开(公告)日：2005-04-26
申请号：US10466356
申请日：2002-01-16
申请人： Sea Wha Oh , Seung Rim Shin , Tae Kyung Kim , Sun Il Kim , Jong Il Shin
发明人： Sea Wha Oh , Seung Rim Shin , Tae Kyung Kim , Sun Il Kim , Jong Il Shin
IPC分类号： C07D277/82 , C07D213/85 , C09B62/51
CPC分类号： C09B62/51
摘要： The present invention relates to water insoluble disperse-reactive dyes expressed by the formula (3) and (4) and to their preparation, (3) (4) wherein each of Ar1 and Ar2 represents aryl or benzothiazole group, and each of R, R1, R2, and R3 independently represents hydrogen, alkyl, alkoxy, cyanoalkyl or aminoacetyl group.
摘要翻译：本发明涉及由式（3）和（4）表示的水不溶性分散反应性染料及其制备，（3）（4），其中Ar 1和 R 2表示芳基或苯并噻唑基，R 1，R 2，R 2和R 3 3各自独立地表示氢，烷基，烷氧基，氰基烷基或氨基乙酰基。

2. 发明授权

US07897735B2 Compound having thiol anchoring group, method of synthesizing the same, and molecular electronic device having molecular active layer formed using the compound 失效
标题翻译：具有硫醇锚定基团的化合物，其合成方法和使用该化合物形成分子活性层的分子电子器件
公开(公告)号：US07897735B2
公开(公告)日：2011-03-01
申请号：US12431651
申请日：2009-04-28
申请人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
发明人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
IPC分类号： C07C245/02
CPC分类号： C07D417/12 , C07D333/42
摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.
摘要翻译：提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。该化合物在分子电子器件中形成分子活性层。使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件。

3. 发明申请

US20090294762A1 COMPOUND HAVING THIOL ANCHORING GROUP, METHOD OF SYNTHESIZING THE SAME, AND MOLECULAR ELECTRONIC DEVICE HAVING MOLECULAR ACTIVE LAYER FORMED USING THE COMPOUND 失效
标题翻译：具有THIOL锚固组的化合物，其合成方法和具有使用化合物形成的分子活性层的分子电子装置
公开(公告)号：US20090294762A1
公开(公告)日：2009-12-03
申请号：US12431651
申请日：2009-04-28
申请人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
发明人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
IPC分类号： H01L51/30 , C09B41/00
CPC分类号： C07D417/12 , C07D333/42
摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.
摘要翻译：提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。该化合物在分子电子器件中形成分子活性层。使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件。

4. 发明授权

US07538199B2 Compound having thiol anchoring group, method of synthesizing the same, and molecular electronic device having molecular active layer formed using the compound 失效
标题翻译：具有硫醇锚定基团的化合物，其合成方法和使用该化合物形成分子活性层的分子电子器件
公开(公告)号：US07538199B2
公开(公告)日：2009-05-26
申请号：US11398188
申请日：2006-04-04
申请人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
发明人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
IPC分类号： C07C245/02
CPC分类号： C07D417/12 , C07D333/42
摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.
摘要翻译：提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。该化合物在分子电子器件中形成分子活性层。使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件。

5. 发明授权

US06326474B1 Reactive black dyes containing acetoxyethyl sulfone moiety 失效
标题翻译：含有乙酰氧基乙基砜部分的活性黑色染料
公开(公告)号：US06326474B1
公开(公告)日：2001-12-04
申请号：US09646938
申请日：2000-11-20
申请人： Sea Wha Oh , Myeong Nyeo Kang , Seung Rim Shin , Tae Kyung Kim , Sung Nyung Yun
发明人： Sea Wha Oh , Myeong Nyeo Kang , Seung Rim Shin , Tae Kyung Kim , Sung Nyung Yun
IPC分类号： C09B62513
CPC分类号： C09B62/513
摘要： This invention relates to a reactive black dye containing acetoxyethyl sulfone compound and more particularly, to the reactive black dye containing acetoxyethyl sulfone compound of formula (1), which is characterized by lessening the loss of dyes in filtering process owing to the low solubility by introducing the aminophenyl-beta-acetoxyethyl sulfone moiety, saving the cost for waste water treatment by using a small amount of salt in salting-out process and furthermore obtaining bright color with high dyeing yield and good substantivity wherein M is an alkali metal atom, and wherein the compound of formula (1) is chosen from
摘要翻译：本发明涉及含有乙酰氧基乙基砜化合物的反应性黑色染料，更具体地说，涉及含有式（1）的乙酰氧基乙基砜化合物的反应性黑色染料，其特征在于减少过滤过程中染料的损失，因为通过引入氨基苯基-β-乙酰氧基乙基砜部分，通过在盐析过程中使用少量的盐来节省废水处理的成本，并且进一步获得具有高染色产率和良好亲和性的亮色，其中M是碱金属原子，其中式（1）的化合物选自

6. 发明授权

US06310187B1 Reactive red dyes containing monochlorotriazine and acetoxyethyl sulfone groups 失效
标题翻译：含有一氯三嗪和乙酰氧基乙基砜基团的活性红色染料
公开(公告)号：US06310187B1
公开(公告)日：2001-10-30
申请号：US09646868
申请日：2001-04-09
申请人： Sea Wha Oh , Myeong Nyeo Kang , Seung Rim Shin , Tae Kyung Kim , Mi Kyoung Song
发明人： Sea Wha Oh , Myeong Nyeo Kang , Seung Rim Shin , Tae Kyung Kim , Mi Kyoung Song
IPC分类号： C09B6251
CPC分类号： C09B62/4413
摘要： The present invention relates to a bifunctional red reactive dye and more particularly, to the bifunctional red reactive dye with monochlorotriazine and acetoxyethylsulfone as reactive groups expressed by formula (I), wherein, M is alkaline metal atom, which provides excellent combination of properties in that 1) the introduction of aminophenyl-&bgr;-acetoxyethylsulfone group to the dye may minimize the loss of dye, since its low solubility to water lessens the amount of the remaining solution during filtration, 2) an easier salting-out process requires a smaller amount of salt during the process so that the costs for the treatment of waste water may be significantly reduced, and 3) a better dyeing yield with enhanced substantivity and better brightness in color
摘要翻译：本发明涉及双功能红色反应性染料，更具体地说，涉及由式（I）表示的作为反应性基团的单氯三嗪和乙酰氧基乙基砜的双功能红色活性染料，其中M为碱金属原子，其中提供优异的性能组合 1）将氨基苯基-β-乙酰氧基乙基砜基团引入到染料中可以使染料的损失最小化，因为其对水的低溶解度可以减少过滤期间剩余溶液的量，2）更容易的盐析过程需要较少量的在处理过程中可以显着降低处理废水的成本，并且3）更好的染色产量，增强的亲和性和更好的颜色亮度

7. 发明申请

US20100090210A1 COMPOUND HAVING THIOL ANCHORING GROUP, METHOD OF SYNTHESIZING THE SAME, AND MOLECULAR ELECTRONIC DEVICE HAVING MOLECULAR ACTIVE LAYER FORMED USING THE COMPOUND 审中-公开
标题翻译：具有THIOL锚固组的化合物，其合成方法和具有使用化合物形成的分子活性层的分子电子装置
公开(公告)号：US20100090210A1
公开(公告)日：2010-04-15
申请号：US12638839
申请日：2009-12-15
申请人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
发明人： Hyoyoung Lee , Junghyun Lee , Heeyoel Baek , Gyeong Sook Bang , Jonghyurk Park , Nak-Jin Choi , Kun Jun , Seung Rim Shin
IPC分类号： H01L51/30
CPC分类号： C07D417/12 , C07D333/42
摘要： Provided are an electron donor-azo-electron acceptor compound having a thiol-based anchoring group, a method of synthesizing the compound, and a molecular electronic device having a molecular active layer formed of the compound. The compound for forming a molecular electronic device includes an azo compound that has a dinitrothiophene group and an aminobenzene group having thiol derivatives. The compound forms a molecular active layer in the molecular electronic devices. The molecular active layer is self-assembled on an electrode using the thiol derivative in the azo compound as an anchoring group. The molecular active layer in the molecular electronic device forms a switching device switching between an on-state and an off-state in response to a voltage applied to electrodes or a memory device storing a predetermined electric signal in response to a voltage applied to the electrodes.
摘要翻译：提供具有硫醇基锚定基团的电子给体 - 偶氮电子受体化合物，合成该化合物的方法和具有由该化合物形成的分子活性层的分子电子器件。用于形成分子电子器件的化合物包括具有二硝基噻吩基团和具有硫醇衍生物的氨基苯基团的偶氮化合物。化合物在分子电子器件中形成分子活性层。使用偶氮化合物中的硫醇衍生物作为锚定基团，在电极上自组装分子活性层。分子电子器件中的分子活性层响应于施加到电极的电压或存储预定电信号的存储器件响应于施加到电极的电压而形成在导通状态和截止状态之间切换的开关器件。

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