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1. 发明授权

US06617275B1 Process for preparing a catalyst for aromatic production 有权
标题翻译：制备芳香族生产催化剂的方法
公开(公告)号：US06617275B1
公开(公告)日：2003-09-09
申请号：US10022107
申请日：2001-12-13
申请人： Sanjay B. Sharma , John Kulach , Aaron James Imrie
发明人： Sanjay B. Sharma , John Kulach , Aaron James Imrie
IPC分类号： B01J2906
CPC分类号： B01J29/061 , B01J29/405 , B01J2229/20 , B01J2229/42
摘要： A novel process for converting C2 to C6 aliphatic hydrocarbons to aromatics and catalyst for use in this process are disclosed. The catalyst that contains a zeolite having a silica to alumina molar ratio greater than about 20 and a pore diameter from about 5 Å to about 6 Å, an essentially non-acidic binder, and a gallium component. The binder is selected from silica, zirconia, titania, and mixtures thereof and results in a catalyst formulation having both enhanced selectivity to desired C6-C9 aromatic products and improved stability compared to prior art compositions. Preferred zeolites that can be used include those of the MFI structure type, with ZSM-5 being a specific example.
摘要翻译：公开了一种用于将C2转化为C6脂族烃到用于该方法中的芳族化合物和催化剂的新方法。含有二氧化硅与氧化铝摩尔比大于约20，孔直径为约5至约6的沸石，基本上非酸性粘合剂和镓组分的沸石的催化剂。粘合剂选自二氧化硅，氧化锆，二氧化钛及其混合物，并且导致与现有技术组合物相比，具有对期望的C 6 -C 9芳香族产物的增强的选择性和改善的稳定性的催化剂制剂。可以使用的优选的沸石包括MFI结构类型的沸石，ZSM-5是具体实例。

2. 发明授权

US06512155B1 Process for the activation of an alkylaromatic isomerization catalyst by water 失效
标题翻译：用水活化烷基芳族异构化催化剂的方法
公开(公告)号：US06512155B1
公开(公告)日：2003-01-28
申请号：US09556811
申请日：2000-04-25
申请人： James A. Johnson , Benjamin D. Riley , Sanjay B. Sharma , Patrick J. Silady , Gail L. Gray
发明人： James A. Johnson , Benjamin D. Riley , Sanjay B. Sharma , Patrick J. Silady , Gail L. Gray
IPC分类号： C07C522
CPC分类号： C07C5/2724 , C07C2529/65 , C07C2529/70 , C07C2529/85 , C07C15/067
摘要： An improved process is disclosed for ethylbenzene and xylene isomerization in a non-equilibrium mixture of xylenes and ethylbenzene. By addition of trace quantities of water to the reaction zone, equivalent isomerization is effected at lower temperatures wherein benefits could be realized in reduced losses and improved catalyst life.
摘要翻译：公开了在二甲苯和乙苯的非平衡混合物中的乙苯和二甲苯异构化的改进方法。通过向反应区添加微量的水，相应的异构化在较低温度下进行，其中可以以减少的损失和改善的催化剂寿命实现有益效果。

3. 发明授权

US06486373B1 Shape selective zeolite catalyst and its use in aromatic compound conversion 有权
标题翻译：形状选择性沸石催化剂及其在芳香族化合物转化中的应用
公开(公告)号：US06486373B1
公开(公告)日：2002-11-26
申请号：US09011171
申请日：1998-11-04
申请人： Jeevan S. Abichandani , Daria N. Lissy , Mae K. Rubin , Sanjay B. Sharma , David S. Shihabi
发明人： Jeevan S. Abichandani , Daria N. Lissy , Mae K. Rubin , Sanjay B. Sharma , David S. Shihabi
IPC分类号： B01J2940
CPC分类号： C07C5/2708 , B01J29/04 , B01J29/40 , B01J37/0009 , B01J37/084 , B01J2229/123 , B01J2229/16 , B01J2229/32 , B01J2229/34 , C07C4/04 , C07C4/18 , C07C5/41 , C07C6/123 , C07C2529/40 , Y02P20/52 , C07C15/00 , C07C15/08
摘要： A shape-selective catalyst comprises a synthetic porous crystalline material having the structure of ZSM-5 and a composition involving the molar relationship: X2O3:(n)YO2, wherein X is a trivalent element, such as aluminum, boron, iron and/or gallium, preferably aluminum; Y is a tetravalent element such as silicon and/or germanium, preferably silicon; and n is greater than about 12, and wherein the crystals have a major dimension of at least about 0.5 micron and a surface YO2/X2O3 ratio which is no more than 20% less than the bulk YO2/X2O3 ratio of the crystal. The crystals have a diffusion-modifying surface coating of a refractory material such as silica or coke. The catalyst is useful in a wide variety of selective hydrocarbon conversion processes, particularly the selective disproportionation of toluene to para-xylene.
摘要翻译：形状选择性催化剂包括具有ZSM-5结构的合成多孔结晶材料和涉及摩尔关系的组成：X 2 O 3：（n）YO 2，其中X是三价元素，例如铝，硼，铁和/或镓，优选铝; Y是四价元素，例如硅和/或锗，优选硅; 并且n大于约12，并且其中所述晶体的主要尺寸为至少约0.5微米，并且表面YO 2 / X 2 O 3比率不超过所述晶体的体积YO 2 / X 2 O 3比率的20％以下。晶体具有耐火材料如二氧化硅或焦炭的扩散改性表面涂层。该催化剂可用于多种选择性烃转化方法，特别是甲苯对对二甲苯的选择性歧化。

4. 发明授权

US06222086B1 Aromatics isomerization using a dual-catalyst system 失效
标题翻译：使用双催化剂体系进行芳烃异构化
公开(公告)号：US06222086B1
公开(公告)日：2001-04-24
申请号：US09348119
申请日：1999-07-02
申请人： Sanjay B. Sharma , Aaron J. Imrie
发明人： Sanjay B. Sharma , Aaron J. Imrie
IPC分类号： C07C522
CPC分类号： C07C5/2724 , B01J29/005 , B01J29/12 , B01J29/22 , B01J29/44 , B01J29/67 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7469 , B01J29/7484 , B01J29/84 , B01J29/85 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C07C2523/40 , C07C2529/04 , C07C2529/068 , C07C15/067
摘要： This invention is drawn to a catalyst system comprising two or more molecular sieves, including at least one non-zeolitlc molecular sieve and one zeolitic aluminosilicate, having specified contrasting pore structures and to a process for isomerizing a non-equilibrium mixture of xylenes and ethylbenzene using the subject catalyst system to obtain an improved yield of para-xylene from the mixture relative to prior-art processes.
摘要翻译：本发明涉及包含两种或更多种分子筛的催化剂体系，所述分子筛包括具有特定对比孔结构的至少一种非沸石分子筛和一种沸石硅铝酸盐，以及使用二甲苯和乙苯的非平衡混合物异构化的方法，使用本发明的催化剂体系相对于现有技术的方法从混合物中获得提高的对二甲苯的产率。

5. 发明授权

US06143941A Selective xylenes isomerization and ethylbenzene conversion 有权
标题翻译：选择性二甲苯异构化和乙苯转化
公开(公告)号：US06143941A
公开(公告)日：2000-11-07
申请号：US261249
申请日：1999-03-03
申请人： Sanjay B. Sharma , Sergey V. Gurevich , Benjamin D. Riley , Greg A. Rosinski
发明人： Sanjay B. Sharma , Sergey V. Gurevich , Benjamin D. Riley , Greg A. Rosinski
IPC分类号： C07C5/27 , C07C15/08 , C07C5/22
CPC分类号： C07C15/08 , C07C5/2724 , C07C2523/40 , C07C2523/42 , C07C2527/167 , C07C2529/40
摘要： This invention is drawn to a process for isomerizing a non-equilibrium mixture of xylenes and ethylbenzene using an oil-dropped catalyst comprising a zeolite, a platinum-group metal and an aluminophosphate binder, resulting in a greater yield of para-xylene at favorable conditions compared to processes of the known art.
摘要翻译：本发明涉及使用包含沸石，铂族金属和磷酸铝粘合剂的油滴催化剂使二甲苯和乙苯的非平衡混合物异构化的方法，导致在有利条件下更高的对二甲苯产率与已知技术的方法相比。

6. 发明授权

US06143261A Catalytic reduction of nitrogen oxide emissions with MCM-49 and MCM-56 失效
标题翻译：用MCM-49和MCM-56催化还原氮氧化物排放
公开(公告)号：US06143261A
公开(公告)日：2000-11-07
申请号：US990459
申请日：1997-12-15
申请人： Daria N. Lissy , David O. Marler , John P. McWilliams , David S. Shihabi , Sanjay B. Sharma
发明人： Daria N. Lissy , David O. Marler , John P. McWilliams , David S. Shihabi , Sanjay B. Sharma
IPC分类号： B01D53/86 , B01D53/94 , B01J29/03 , B01J29/04 , C01B21/00
CPC分类号： B01J29/042 , B01D53/8628 , B01D53/9418 , B01J29/0308 , B01J29/041 , B01J29/045 , B01D2251/2067 , B01D2255/202 , B01D2255/204 , B01D2255/20761 , Y02T10/24
摘要： MCM-56 and MCM-49 have been demonstrated to be effective catalysts for the reduction of nitrogen oxide (NO.sub.x) emissions in a net oxidizing environment such as Selective Catalytic Reduction or lean burn engine exhaust applications. MCM-56 and MCM-49 can be utilized as a component of a spherical or cylindrical catalyst particle or as a wash coat on a ceramic or metallic monolith. Optionally, a transition metal such as copper, can be added to the catalyst for improved activity.
摘要翻译： MCM-56和MCM-49已经被证明是在净氧化环境（如选择性催化还原或贫燃发动机排气应用）中减少氮氧化物（NOx）排放的有效催化剂。 MCM-56和MCM-49可用作球形或圆柱形催化剂颗粒的组分或作为陶瓷或金属整料上的洗涤涂层。任选地，可以将诸如铜的过渡金属加入到催化剂中以改善活性。

7. 发明授权

US5589147A Catalytic system for the reducton of nitrogen oxides 失效
标题翻译：用于氮氧化物还原的催化体系
公开(公告)号：US5589147A
公开(公告)日：1996-12-31
申请号：US271685
申请日：1994-07-07
申请人： Maria D. Farnos , John P. McWilliams , Sanjay B. Sharma , David S. Shihabi
发明人： Maria D. Farnos , John P. McWilliams , Sanjay B. Sharma , David S. Shihabi
IPC分类号： B01D53/86 , B01D53/94 , B01J29/072 , B01J37/02 , C01B21/00
CPC分类号： B01J37/0203 , B01D53/8621 , B01D53/865 , B01D53/9418 , B01J29/072 , B01D2251/2062 , B01D2255/20738 , B01D2255/504
摘要： There is presented a process for the treatment of exhaust gas, which process uses a specially prepared catalyst composition, for the selective catalytic reduction of NO.sub.x contained in the exhaust gas. An embodiment of the process of this invention comprises a catalytic stage to selectively catalytically reduce NO.sub.x over a catalyst composition comprising a molecular sieve that has been treated with a metal in a way effective to maximize metal dispersion. The catalyst of this invention typically comprises a silica, titania, or zirconia binder, e.g. a binder including a high molecular weight, hydroxyl functional silicone resin. The catalyst of this invention may be formed into a desired shape, e.g., by extrusion, and finished in a humidified atmosphere after forming.
摘要翻译：提出了一种处理废气的方法，该方法使用特别制备的催化剂组合物来选择性催化还原废气中所含的NOx。本发明方法的一个实施方案包括催化阶段，以选择性地催化还原NOx，所述催化剂组合物包含用有效使金属分散最大化的金属处理的分子筛。本发明的催化剂通常包括二氧化硅，二氧化钛或氧化锆粘合剂，例如，包含高分子量羟基官能的有机硅树脂的粘合剂。本发明的催化剂可以例如通过挤出形成所需的形状，并在成型后的加湿气氛中成型。

8. 发明授权

US06576581B1 Aromatics isomerization using a dual-catalyst system 失效
标题翻译：使用双催化剂体系进行芳烃异构化
公开(公告)号：US06576581B1
公开(公告)日：2003-06-10
申请号：US09746584
申请日：2000-12-21
申请人： Sanjay B. Sharma , Aaron J. Imrie
发明人： Sanjay B. Sharma , Aaron J. Imrie
IPC分类号： B01J29068
CPC分类号： C07C5/2724 , B01J29/005 , B01J29/12 , B01J29/22 , B01J29/44 , B01J29/67 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7469 , B01J29/7484 , B01J29/84 , B01J29/85 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C07C2523/40 , C07C2529/04 , C07C2529/068 , C07C15/067
摘要： This invention is drawn to a catalyst system comprising two or more molecular sieves, including at least one non-zeolitic molecular sieve and one zeolitic aluminosilicate, having specified contrasting pore structures and to a process for isomerizing a non-equilibrium mixture of xylenes and ethylbenzene using the subject catalyst system to obtain an improved yield of para-xylene from the mixture relative to prior-art processes.
摘要翻译：本发明涉及包含两种或多种分子筛的催化剂体系，所述分子筛包括具有特定对比孔结构的至少一种非沸石分子筛和一种沸石硅铝酸盐，以及使用二甲苯和乙苯的非平衡混合物异构化的方法，使用本发明的催化剂体系相对于现有技术的方法从混合物中获得提高的对二甲苯的产率。

9. 发明授权

US5520895A Method for the reduction of nitrogen oxides using iron impregnated zeolites 失效
标题翻译：使用铁浸渍沸石还原氮氧化物的方法
公开(公告)号：US5520895A
公开(公告)日：1996-05-28
申请号：US271693
申请日：1994-07-07
申请人： Sanjay B. Sharma , David S. Shihabi
发明人： Sanjay B. Sharma , David S. Shihabi
IPC分类号： B01D53/86 , B01D53/94 , B01J29/072 , B01J37/02 , C01B21/00
CPC分类号： B01J37/0203 , B01D53/8621 , B01D53/865 , B01D53/9418 , B01J29/072 , B01D2251/2062 , B01D2255/20738 , B01D2255/50
摘要： There is provided a process for the treatment of exhaust gas, which process uses a specially prepared catalyst composition, for the selective catalytic reduction of NO.sub.x contained in the exhaust gas. An embodiment of the process of this invention comprises a catalytic stage to selectively catalytically reduce NO.sub.x over a catalyst composition comprising an intermediate pore size zeolite catalyst that has been treated with a water soluble iron salt or salt precursor in a way effective to maximize iron dispersion. The intermediate pore size zeolite of this invention preferably has a silica:alumina molar ratio of between about 20 and about 1000. The catalyst of this invention typically comprises a silica, titania, or zirconia binder, preferably a binder including a high molecular weight, hydroxyl functional silicone resin. The catalyst of this invention is preferably formed, e.g., extruded, and then simultaneously calcined and hydrothermally treated.
摘要翻译：提供了一种处理废气的方法，该方法使用特别制备的催化剂组合物来选择性催化还原废气中所含的NOx。本发明方法的一个实施方案包括催化阶段，以催化还原催化剂还原催化剂组合物，该催化剂组合物包含中和孔径的沸石催化剂，该催化剂已经以有效使铁分散最大化的方式用水溶性铁盐或盐前体处理。本发明的中等孔径沸石优选具有约20至约1000的二氧化硅：氧化铝摩尔比。本发明的催化剂通常包含二氧化硅，二氧化钛或氧化锆粘合剂，优选包含高分子量羟基的粘合剂功能硅树脂。本发明的催化剂优选形成例如挤出，然后同时进行煅烧和水热处理。

10. 发明授权

US5451387A Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst 失效
标题翻译：使用铁浸渍的沸石催化剂选择性还原氮氧化物
公开(公告)号：US5451387A
公开(公告)日：1995-09-19
申请号：US271692
申请日：1994-07-07
申请人： Maria D. Farnos , John P. McWilliams , Sanjay B. Sharma , David S. Shihabi , Scott A. Stevenson , James C. Vartuli
发明人： Maria D. Farnos , John P. McWilliams , Sanjay B. Sharma , David S. Shihabi , Scott A. Stevenson , James C. Vartuli
IPC分类号： B01D53/86 , B01D53/94 , B01J29/072 , B01J29/46 , B01J37/02 , C01B21/20
CPC分类号： B01J37/0203 , B01D53/8621 , B01D53/8628 , B01D53/865 , B01D53/9418 , B01J29/072 , B01J29/46 , B01D2251/2062 , B01D2255/20738 , B01D2255/50
摘要： An exhaust gas treatment process useful for the removal of nitrogen oxides using an iron containing zeolite as the catalyst and ammonia as a reducing agent. It is desired to extend the effective temperature range for the selective catalytic reduction (SCR) of nitrogen oxides below about 400.degree. C. This is accomplished in the instant invention through the use of an intermediate pore size zeolite, such as ZSM-5, based catalyst which has been treated to incorporate iron into its pores.
摘要翻译：用于使用含铁沸石作为催化剂除去氮氧化物的废气处理方法和氨作为还原剂。期望将氮氧化物的选择性催化还原（SCR）的有效温度范围延伸到低于约400℃。这在本发明中通过使用中等孔径的沸石，例如ZSM-5，基于已经处理以将铁掺入其孔中的催化剂。

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