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    • 4. 发明专利
    • Method for producing synthesis gas by partial oxidation of heavy charge, such as heavy crude oil, distillation residue and the like
    • 通过部分氧化重金属(如重油,石油渣等)生产合成气的方法
    • JP2005002306A
    • 2005-01-06
    • JP2003202524
    • 2003-07-28
    • Snamprogetti Spaスナムプロゲッティ、ソシエタ、ペル、アチオニSnamprogetti S.P.A.
    • SANFILIPPO DOMENICOMIRACCA IVANO
    • B01J3/00B01J19/00C01B3/24C01B3/36C10K1/02C10K1/06
    • B01J19/0013B01J2219/00123B01J2219/00243C01B3/36C10K1/06
    • PROBLEM TO BE SOLVED: To provide a method for producing a synthetic gas from a heavy charge with stable function of the system, almost no problem in foaming and no difficulty in adjusting a water level, in a cooling separation process of a method for producing a synthesis gas by partially oxidizing the heavy charge such as heavy crude oil, distillation residue or the like.
      SOLUTION: The method for producing the synthesis gas includes a process in which the heavy charge is partially oxidized at ≥1,000°C and ≥20 atm. in the presence of steam using oxygen or a highly oxygen-containing air, the obtained synthetic gas 1 is cooled by directly pouring water 2 to the synthesis gas 1, subsequently cooled gas 4 and water 3 are separated through a ring formed between an adduction tube TA and a concentric tube TC installed around the adduction tube and having both open ends. The distance (L) between the lower end of the adduction tube and the lower end of the open concentric tube is equal to or larger than x [x is expressed by x=0.026F+0.15 and varies depending on a gas flow ratio (F)(expressed by kg/h/cm
      2 )] times of the diameter (D) of the lower end of the adduction pipe.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题:为了提供一种由系统功能稳定的重负荷生产合成气的方法,在方法的冷却分离过程中几乎没有发泡问题和调节水位难度 用于通过部分氧化重质原油,蒸馏残余物等重质装料来生产合成气。 解决方案:合成气的制备方法包括重荷在≥1000℃和≥20atm下部分氧化的方法。 在使用氧气或高含氧空气的蒸汽的存在下,通过将合成气1直接倒入合成气1中来冷却所得的合成气体1,随后将冷却气体4和水3分离通过形成在内装管 TA和同心管TC安装在内收管周围并且具有两个开口端。 内接管的下端与开放的同心管的下端之间的距离(L)等于或大于x [x由x = 0.026F + 0.15表示,并且根据气体流量比(F )(以kg / h / cm 2表示)SP吸收管内壁直径(D)。 版权所有(C)2005,JPO&NCIPI
    • 5. 发明申请
    • Catalytic system and process for the production of hydrogen
    • 催化系统和生产氢气的方法
    • US20040152790A1
    • 2004-08-05
    • US10768103
    • 2004-02-02
    • ENI S.p.A.SNAMPROGETTI S.p.A.
    • Ugo CornaroDomenico Sanfilippo
    • C07C027/06
    • B01J23/83B01J23/005B01J23/745B01J23/78B01J23/80B01J35/08C01B3/063Y02E60/36
    • Catalytic system for the production of hydrogen consisting of an active component based on iron and a micro-spheroidal carrier based on alumina and represented by the following formula nullFex1Mx2Qx3Dx4Alx5nullOy wherein xi with inull1.5 represent the atomic percentages assuming values which satisfy the equation nullxinull100. y is the value required by the oxidation number with which the components are present in the formulate, x1 is the atomic percentage with which Fe is present in the formulate and ranges from 5 to 80, preferably from 20 to 50, M is Cr and/or Mn, x2 ranges from 0 to 30, preferably from 0 to 10, Q is La, Lanthanides (with Ce particularly preferred), Zr or a combination thereof, x3 ranges from 0 to 30, preferably from 0 to 10, D is Mg, Ca, Ba, Co, Ni, Cu, Zn or combinations thereof, x4 ranges from 0 to 35, preferably from 5 to 25, x5 is the atomic percentage with which Al is present in the formulate and ranges from 20 to 95, preferably from 50 to 80.
    • 用于生产基于铁的活性组分和基于氧化铝的微球形载体的氢的催化体系,由下式[Fex1Mx2Qx3Dx4Alx5] Oy表示,其中i = 1.5的xi表示原子百分比,假定满足式 Sigmaxi = 100。 y是组分存在于配方中的氧化数所需的值,x1是配制物中Fe存在的原子百分数,范围为5至80,优选为20至50,M为Cr和/ 或Mn,x2为0〜30,优选为0〜10,Q为La,镧系元素(特别优选Ce),Zr或其组合,x3为0〜30,优选为0〜10,D为Mg ,Ca,Ba,Co,Ni,Cu,Zn或其组合,x4的范围为0至35,优选5至25,x5是配位体中Al存在的原子百分比,范围为20至95,优选 从50到80。