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1. 发明授权

US5734066A Supression of autoignition in maleic anhydride production 失效
标题翻译：抑制马来酸酐生产中的自燃
公开(公告)号：US5734066A
公开(公告)日：1998-03-31
申请号：US835152
申请日：1992-02-13
申请人： Robert A. Keppel , Scott F. Mitchell , Michael J. Mummey
发明人： Robert A. Keppel , Scott F. Mitchell , Michael J. Mummey
IPC分类号： B01J27/198 , C07C51/215 , C07C51/225 , C07C57/145 , C07D307/60
CPC分类号： C07C51/215
摘要： An improved process for the manufacture of maleic anhydride by catalytic oxidation of n-butane in which the feed flow channel to the catalytic reactor contains an autoignition suppression agent containing acid sites or trivalent phosphorus as an ignition inhibiting component. The autoignition suppression agent may also be used in other gas/liquid containment envelopes for flammable mixtures of hydrocarbons and oxygen. A novel apparatus and method are disclosed for assessing the influence of system conditions on autoignition of hydrocarbon/oxygen mixtures.
摘要翻译：通过正丁烷的催化氧化制备马来酸酐的改进方法，其中向催化反应器的进料流动通道含有含有酸性位点或三价磷作为点火抑制组分的自燃抑制剂。自燃抑制剂也可以用于其它气体/液体容纳包封，用于可燃的烃和氧混合物。公开了一种用于评估系统条件对烃/氧混合物的自燃的影响的新颖的装置和方法。

2. 发明授权

US5641722A High performance VPO catalyst and process of preparation thereof 失效
标题翻译：高性能VPO催化剂及其制备方法
公开(公告)号：US5641722A
公开(公告)日：1997-06-24
申请号：US306489
申请日：1994-09-15
申请人： Scott F. Mitchell , Robert A. Keppel , Michael J. Mummey
发明人： Scott F. Mitchell , Robert A. Keppel , Michael J. Mummey
IPC分类号： C07D307/60 , B01J27/198 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/08 , C07B61/00 , C07C51/21 , C07C51/215 , C07C51/25
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , B01J37/0018 , C07C51/215 , C07C51/25 , B01J2523/00 , B01J35/0026 , B01J35/1014 , B01J35/108 , B01J37/08
摘要： An activated porous phosphorus/vanadium oxide catalyst adapted for the catalytic oxidation of a hydrocarbon to produce a carboxylic acid anhydride. The catalyst comprises a shaped body having a volume of at least about 0.02 cc, a phosphorus content of between about 1.05 and about 1.20, a B.E.T. surface area of at least about 15 m.sup.2 /g, an average vanadium oxidation state of between about 4.06 and about 4.3, a total pore volume of at least about 0.15 cc/g, a normalized apparent shaped body density of between about 1.0 and about 2.0 g/cc, and a crush strength of at least about 4 pounds. At least about 20% of the pore volume of the catalyst is constituted of pores having a diameter between about 0.1 and about 3.3 .mu.M, and at least about 40% of the pore volume is constituted of pores having a diameter of less than about 0.1 .mu.M. The catalyst is prepared by mixing a particulate phosphorus/vanadium oxide precursor with a pore modification agent to produce a modified catalyst precursor composition, forming the modified precursor composition into a predetermined shape, and removing the pore modification agent substantially at a temperature below 300.degree. C., preferably using air as a stripping gas.
摘要翻译：一种活化的多孔磷/氧化钒催化剂，适于催化氧化烃以产生羧酸酐。催化剂包括具有至少约0.02cc的体积，约1.05至约1.20的磷含量的成形体，B.E.T. 表面积至少约15m 2 / g，平均钒氧化态在约4.06与约4.3之间，总孔体积至少约0.15cc / g，归一化表观体密度在约1.0至约2.0之间 g / cc，压碎强度至少约4磅。催化剂的孔体积的至少约20％由直径在约0.1至约3.3μm之间的孔构成，并且至少约40％的孔体积由直径小于约0.1的孔构成通过将颗粒状磷/钒氧化物前体与孔改性剂混合以制备改性催化剂前体组合物，将改性前体组合物形成预定形状并基本上在低于下述温度下除去孔改性剂来制备催化剂 300℃，优选使用空气作为汽提气体。

3. 发明授权

US4632915A Iron/lithium--promoted catalysts for the production of maleic anhydride 失效
标题翻译：用于生产马来酐的铁/锂促进催化剂
公开(公告)号：US4632915A
公开(公告)日：1986-12-30
申请号：US791655
申请日：1985-10-28
申请人： Robert A. Keppel , Victoria M. Franchetti
发明人： Robert A. Keppel , Victoria M. Franchetti
IPC分类号： B01J27/198 , C07B61/00 , C07C51/215 , C07C51/25 , B01J27/185 , C07D307/34
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： Catalysts useful for the partial oxidation of nonaromatic hydrocarbons, particularly n-butane, with molecular oxygen or an oxygen-containing gas in the vapor phase to produce maleic anhydride are provided which comprise phosphorus, vanadium, and oxygen and a promoter component containing each of iron and lithium.
摘要翻译：提供了用于在气相中分子氧或含氧气体部分氧化非芳族烃，特别是正丁烷以产生马来酸酐的催化剂，其包含磷，钒和氧，以及含有各自的铁的促进剂组分和锂。

4. 发明授权

US4567158A Process for preparing phosphorus-vanadium mixed oxide oxidation catalysts 失效
标题翻译：制备磷钒混合氧化物氧化催化剂的方法
公开(公告)号：US4567158A
公开(公告)日：1986-01-28
申请号：US566361
申请日：1983-12-28
申请人： James T. Wrobleski , James W. Edwards , Charles R. Graham , Robert A. Keppel , Harold Raffelson
发明人： James T. Wrobleski , James W. Edwards , Charles R. Graham , Robert A. Keppel , Harold Raffelson
IPC分类号： B01J27/198 , C07C51/215 , C07C51/25 , C07C51/31 , B01J27/14 , C07D307/34
CPC分类号： B01J23/002 , B01J27/198 , C07C51/215 , C07C51/25 , C07C51/252 , C07C51/313 , B01J2523/00
摘要： Phosphorus-vanadium mixed oxide oxidation catalysts are prepared by introducing a substantially pentavalent vanadium-containing compound and a pentavalent phosphorus-containing compound into an alcohol medium capable of reducing the vanadium to a valence state less than +5 in the presence of an alcohol-modifying agent to form a phosphorus-vanadium mixed oxide catalyst precursor. The catalyst precursor is recovered, dried, formed into desired structures, and calcined at temperatures from about 250.degree. C. to about 600.degree. C. The catalysts are highly effective in that they exhibit a weight/weight productivity of at least 70 grams of maleic anhydride per kilogram of catalyst per hour.
摘要翻译：磷钒混合氧化物氧化催化剂是通过将基本上五价含钒的化合物和五价含磷化合物引入到能够在醇改性的存在下将钒还原成低于+5的价态的醇介质中来制备的以形成磷钒混合氧化物催化剂前体。将催化剂前体回收，干燥，形成所需的结构，并在约250℃至约600℃的温度下煅烧。催化剂非常有效，因为它们表现出至少70克马来酸的重量/重量产率酸酐每小时每千克催化剂。

5. 发明授权

US4409127A Attrition resistant metal/oxygen compositions and a process for their preparation 失效
标题翻译：耐磨损金属/氧组合物及其制备方法
公开(公告)号：US4409127A
公开(公告)日：1983-10-11
申请号：US335785
申请日：1981-12-30
申请人： Robert A. Keppel , Samuel J. Tremont , Emerson H. Lee , George D. Davis
发明人： Robert A. Keppel , Samuel J. Tremont , Emerson H. Lee , George D. Davis
IPC分类号： C04B35/00 , B01J21/04 , B01J23/00 , B01J23/02 , B01J23/14 , B01J23/18 , B01J23/76 , B01J23/84 , B01J29/00 , B01J35/10 , B01J37/04 , B01J37/08 , C07C1/00 , C07C2/76 , C07C2/84 , C07C15/52 , C07C67/00
CPC分类号： B01J37/08 , B01J21/04 , B01J23/18 , B01J35/10 , C07C2/76 , B01J35/1009 , B01J35/1019 , B01J35/1061
摘要： Attrition resistant metal/oxygen compositions comprising the infusion and reaction product of alumina and at least one metal oxide, or compound convertible by heat to such metal oxide, which metal oxide is susceptible of undergoing infusion and reaction with the alumina, are useful in a wide variety of metal oxide-catalyzed reactions. The compositions are especially useful in reactions which involve reaction conditions of high stress, for example, vapor phase oxidations under fluidized bed conditions.
摘要翻译：包含氧化铝和至少一种金属氧化物的输注和反应产物的耐磨金属/氧组合物，或通过加热转化为这种金属氧化物的化合物，该金属氧化物易于经历输入并与氧化铝反应，可用于宽各种金属氧化物催化反应。该组合物在涉及高应力的反应条件的反应中是特别有用的，例如在流化床条件下的气相氧化。

6. 发明授权

US5773382A High performance VPO catalyst and process of preparation thereof 失效
标题翻译：高性能VPO催化剂及其制备方法
公开(公告)号：US5773382A
公开(公告)日：1998-06-30
申请号：US775938
申请日：1997-01-03
申请人： Scott F. Mitchell , Robert A. Keppel , Michael J. Mummey
发明人： Scott F. Mitchell , Robert A. Keppel , Michael J. Mummey
IPC分类号： C07D307/60 , B01J27/198 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/08 , C07B61/00 , C07C51/21 , C07C51/215 , C07C51/25
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , B01J37/0018 , C07C51/215 , C07C51/25 , B01J2523/00 , B01J35/0026 , B01J35/1014 , B01J35/108 , B01J37/08
摘要： An activated porous phosphorus/vanadium oxide catalyst adapted for the catalytic oxidation of a hydrocarbon to produce a carboxylic acid anhydride. The catalyst comprises a shaped body having a volume of at least about 0.02 cc, a phosphorus content of between about 1.05 and about 1.20, a B.E.T. surface area of at least about 15 m.sup.2 /g, an average vanadium oxidation state of between about 4.06 and about 4.3, a total pore volume of at least about 0.15 cc/g, a normalized apparent shaped body density of between about 1.0 and about 2.0 g/cc, and a crush strength of at least about 4 pounds. At least about 20% of the pore volume of the catalyst is constituted of pores having a diameter between about 0.1 and about 3.3 .mu.M, and at least about 40% of the pore volume is constituted of pores having a diameter of less than about 0.1 .mu.M. The catalyst is prepared by mixing a particulate phosphorus/vanadium oxide precursor with a pore modification agent to produce a modified catalyst precursor composition, forming the modified precursor composition into a predetermined shape, and removing the pore modification agent substantially at a temperature below 300.degree. C., preferably using air as a stripping gas.
摘要翻译：一种活化的多孔磷/氧化钒催化剂，适于催化氧化烃以产生羧酸酐。催化剂包括具有至少约0.02cc的体积，约1.05至约1.20的磷含量的成形体，B.E.T. 表面积至少约15m 2 / g，平均钒氧化态在约4.06与约4.3之间，总孔体积至少约0.15cc / g，归一化表观体密度在约1.0至约2.0之间 g / cc，压碎强度至少约4磅。催化剂的孔体积的至少约20％由直径在约0.1至约3.3μm之间的孔构成，并且至少约40％的孔体积由直径小于约0.1的孔构成通过将颗粒状磷/钒氧化物前体与孔改性剂混合以制备改性催化剂前体组合物，将改性前体组合物形成预定形状并基本上在低于下述温度下除去孔改性剂来制备催化剂 300℃，优选使用空气作为汽提气体。

7. 发明授权

US5168090A Shaped oxidation catalyst structures for the production of maleic anhydride 失效
标题翻译：用于生产马来酸酐的形状氧化催化剂结构
公开(公告)号：US5168090A
公开(公告)日：1992-12-01
申请号：US812252
申请日：1991-12-20
申请人： Jerry R. Ebner , Robert A. Keppel
发明人： Jerry R. Ebner , Robert A. Keppel
IPC分类号： B01J19/30 , B01J27/198 , B01J35/00 , B01J35/02 , C07C51/215 , C07C51/25 , C07C51/31
CPC分类号： B01J19/30 , B01J23/002 , B01J27/198 , B01J35/026 , B01J35/1004 , C07C51/215 , C07C51/25 , C07C51/252 , C07C51/313 , B01J2219/30242 , B01J2219/30296 , B01J2219/30475 , B01J2523/00 , B01J35/0026
摘要： Shaped oxidation catalyst structures containing catalytic material comprised of mixed oxides of vanadium and phosphorus which are useful for the production of maleic anhydride via the partial oxidation of nonaromatic hydrocarbons, particularly n-butane, in the vapor phase with molecular oxygen or a molecular oxygen-containing gas are provided. Such structures are characterized by exhibiting (a) a geometric volume of from about 30 percent to about 67 percent of that exhibited by the void space-free solid geometric form, (b) an external geometric surface area/geometric volume ratio of at least about 20 cm.sup.-1, (c) a bulk density of from about 0.4 g/cm.sup.3 to about 1.4 g/cm.sup.3, and (d) a mechanical resistance sufficient to maintain substantially the structural integrity of the shaped structure under handling and use conditions.
摘要翻译：包含由钒和磷的混合氧化物组成的催化材料的成形氧化催化剂结构，其可用于通过在分子氧或含分子氧的气相中部分氧化非芳族烃，特别是正丁烷来生产马来酸酐提供气体。这种结构的特征在于显示（a）无空隙空间固体几何形状所显示的几何体积的几何体积约为30％至约67％，（b）外部几何表面积/几何体积比为至少约 20cm-1，（c）约0.4g / cm 3至约1.4g / cm 3的堆积密度，和（d）足以在处理和使用条件下基本上保持成形结构的结构完整性的机械阻力。

8. 发明授权

US4670415A Process for the preparation of iron/lithium -promoted catalysts for the production of maleic anhydride 失效
标题翻译：用于制备用于生产马来酸酐的铁/锂 - 催化剂的方法
公开(公告)号：US4670415A
公开(公告)日：1987-06-02
申请号：US791977
申请日：1985-10-28
申请人： Robert A. Keppel , Victoria M. Franchetti
发明人： Robert A. Keppel , Victoria M. Franchetti
IPC分类号： B01J27/198 , C07C51/215 , C07C51/25 , B01J27/185 , C07D307/34
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： Iron/lithium promoted phosphorus-vanadium-oxygen catalysts for the production of maleic anhydride are prepared by contacting a substantially tetravalent vanadium-containing compound and a phosphorus-containing compound and a promoter component containing each of iron and lithium in a substantially anhydrous alcohol medium in the presence of anhydrous hydrogen chloride to form an iron/lithium promoted phosphorus-vanadium-oxygen catalyst precursor. The catalyst precursor is recovered, dried, roasted, formed into structures if structures are desired, and calcined.
摘要翻译：通过使基本上四价的含钒化合物和含磷化合物和含有铁和锂的助催化剂组分在基本上无水的醇介质中接触来制备用于生产马来酐的铁/锂促进的磷 - 钒 - 氧催化剂存在无水氯化氢以形成铁/锂促进的磷 - 钒 - 氧催化剂前体。将催化剂前体回收，干燥，焙烧，如果需要结构，则形成结构并煅烧。

9. 发明授权

US5945368A Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride 失效
标题翻译：用于生产马来酸酐的钼改性钒 - 磷氧化物催化剂
公开(公告)号：US5945368A
公开(公告)日：1999-08-31
申请号：US538005
申请日：1995-10-02
申请人： Timothy R. Felthouse , Robert A. Keppel , Carl J. Schaefer
发明人： Timothy R. Felthouse , Robert A. Keppel , Carl J. Schaefer
IPC分类号： B01J19/00 , B01J27/198 , B01J27/199 , C07C51/215 , C07C51/42 , B01J27/19
CPC分类号： C07C51/42 , B01J19/0093 , B01J23/002 , B01J27/198 , B01J27/199 , C07C51/215 , B01J2219/00835 , B01J2523/00
摘要： An active catalyst having a crystal structure corresponding to that of a catalyst that has been prepared and activated by the following process. A substantially pentavalent vanadium-containing compound is reacted with a pentavalent phosphorus-containing compound in an alcohol medium capable of reducing the vanadium to an oxidation state of less than +5. Molybdenum is incorporated into the product of the reaction, thereby forming a solid molybdenum-modified precursor composition. The alcohol is removed to produce a dried solid molybdenum-modified precursor composition. Shaped bodies comprising said dried solid molybdenum-modified precursor composition are formed. The dried formed molybdenum-modified catalyst precursor composition is activated to transform it into the active catalyst.
摘要翻译：具有与通过以下方法制备和活化的催化剂相当的晶体结构的活性催化剂。使含五价钒的化合物与能够将钒还原成小于+5的氧化态的醇介质中的五价含磷化合物反应。将钼掺入反应产物中，从而形成固体钼改性的前体组合物。除去醇以产生干燥的固体钼改性的前体组合物。形成包含所述干固体钼改性前体组合物的成形体。干燥的形成的钼改性催化剂前体组合物被活化以将其转化成活性催化剂。

10. 发明授权

US5929256A Production of maleic anhydride using molybdenum-modified vanadium-phosphorus oxide catalysts 失效
标题翻译：使用钼改性钒 - 磷氧化物催化剂生产马来酸酐
公开(公告)号：US5929256A
公开(公告)日：1999-07-27
申请号：US909638
申请日：1997-08-12
申请人： Timothy R. Felthouse , Robert A. Keppel , Carl J. Schaefer
发明人： Timothy R. Felthouse , Robert A. Keppel , Carl J. Schaefer
IPC分类号： B01J19/00 , B01J27/198 , B01J27/199 , C07C51/215 , C07C51/42 , C07D307/60
CPC分类号： C07C51/42 , B01J19/0093 , B01J23/002 , B01J27/198 , B01J27/199 , C07C51/215 , B01J2219/00835 , B01J2523/00
摘要： An active catalyst having a crystal structure corresponding to that of a catalyst that has been prepared and activated by the following process. A substantially pentavalent vanadium-containing compound is reacted with a pentavalent phosphorus-containing compound in an alcohol medium capable of reducing the vanadium to an oxidation state of less than +5. Molybdenum is incorporated into the product of the reaction, thereby forming a solid molybdenum-modified precursor composition. The alcohol is removed to produce a dried solid molybdenum-modified precursor composition. Shaped bodies comprising said dried solid molybdenum-modified precursor composition are formed. The dried formed molybdenum-modified catalyst precursor composition is activated to transform it into the active catalyst.
摘要翻译：具有与通过以下方法制备和活化的催化剂相当的晶体结构的活性催化剂。使含五价钒的化合物与能够将钒还原成小于+5的氧化态的醇介质中的五价含磷化合物反应。将钼掺入反应产物中，从而形成固体钼改性的前体组合物。除去醇以产生干燥的固体钼改性的前体组合物。形成包含所述干固体钼改性前体组合物的成形体。干燥的形成的钼改性催化剂前体组合物被活化以将其转化成活性催化剂。

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