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    • 4. 发明授权
    • Copolymers, compositions, and articles, and methods for making same
    • 共聚物,组合物和制品及其制备方法
    • US4280979A
    • 1981-07-28
    • US76624
    • 1979-09-18
    • Raymond A. DunleavyWilliam A. Gill
    • Raymond A. DunleavyWilliam A. Gill
    • C08G18/68C08G18/62C08G18/14C08G18/82
    • C08G18/68Y10T156/1052Y10T428/31554Y10T428/31587
    • Novel polyester diols are described containing aliphatically saturated divalent diacyl moieties and olefinically unsaturated divalent diacyl moieties in a mole ratio of 0.25:1 to 3:1; and divalent dioxy moieties which are linear and/or branched, preferably divalent branched dioxy moieties and divalent linear dioxy moieties in a mole ratio of 0.3:1 to 3:1, the diacyl moieties being bonded through ester linkage to the dioxy moieties in a mole ratio of at least 1.75 dioxy moieties per diacyl moiety, wherein the polyester diol is end-blocked essentially only by alcoholic hydroxyl groups and has an acid number of less than 3. The novel polyester diols are highly useful in the production of polyurethane/vinyl polymer copolymers by reaction with polyisocyanates and polymerizable ethylenically unsaturated monomers. The polyester diols can be used for this purpose by mixing same with the polymerizable ethylenically unsaturated monomer, a catalyst capable of catalyzing polyurethane-forming reactions of polyisocyanates and polyhydroxyl compounds and the resulting compositions can be used in batch or automated molding operations. The novel tough polyurethane/vinyl polymer copolymers, reinforced or unreinforced, are useful as substitutes for metals in the manufacture of structural and other parts, such as, automotive fenders for the purpose of providing energy-saving light-weight parts, and appliance and business machine housings.
    • 描述了新的聚酯二醇,其摩尔比为0.25:1至3:1,含有脂族饱和二价二酰基部分和烯属不饱和二价二酰基部分; 和二价二氧基部分,其摩尔比为0.3:1至3:1的线性和/或支链,优选二价支链二氧基部分和二价线性二氧基部分,二酰基部分通过酯键连接到二氧基部分 每个二酰基部分具有至少1.75个二氧基部分的比例,其中聚酯二醇基本上仅被醇羟基封端并且具有小于3的酸值。该新型聚酯二醇在生产聚氨酯/乙烯基聚合物中是非常有用的 通过与多异氰酸酯和可聚合的烯属不饱和单体反应的共聚物。 可以通过将聚酯二醇与可聚合的烯属不饱和单体,能够催化多异氰酸酯和多羟基化合物的聚氨酯形成反应的催化剂混合而用于此目的,并且所得组合物可用于分批或自动模塑操作。 新型硬质聚氨酯/乙烯基聚合物共聚物,增强或非增强,可用作制造结构和其他部件的金属替代品,例如汽车挡泥板,用于提供节能轻质零件,以及家电和商业 机壳。
    • 8. 发明授权
    • Novel polyester diols
    • 新型聚酯二醇
    • US4241199A
    • 1980-12-23
    • US76625
    • 1979-09-18
    • Raymond A. Dunleavy
    • Raymond A. Dunleavy
    • C08G63/676C08L67/06C08G63/76
    • C08G63/676C08K3/0008
    • Novel polyester diols are described containing aliphatically saturated divalent diacyl moieties and olefinially unsaturated divalent diacyl moieties in a mole ratio of 0.25:1 to 3:1; and divalent dioxy moieties which are linear and/or branched, preferably divalent branched dioxy moieties and divalent linear dioxy moieties in a mole ratio of 0.3:1 to 3:1, the diacyl moieties being bonded through ester linkage to the dioxy moieties in a mole ratio of at least 1.75 dioxy moieties per diacyl moiety, wherein the polyester diol is end-blocked essentially only by alcoholic hydroxyl groups and has an acid number of less than 3. The novel polyester diols are highly useful in the production of polyurethane/vinyl polymer copolymers by reaction with polyisocyanates and polymerizable ethylenically unsaturated monomers. The polyester diols can be used for this purpose by mixing same with the polymerizable ethylenically unsaturated monomer, a catalyst capable of catalyzing polyurethane-forming reactions of polyisocyanates and polyhydroxyl compounds and the resulting compositions can be used in batch or automated molding operations. The novel tough polyurethane/vinyl polymer copolymers, reinforced or unreinforced, are useful as substitutes for metals in the manufacture of structural and other parts, such as, automotive fenders for the purpose of providing energy-saving light-weight parts, and appliance and business machine housings.
    • 描述了新的聚酯二醇,其摩尔比为0.25:1至3:1,含有脂族饱和二价二酰基部分和烯属不饱和二价二酰基部分; 和二价二氧基部分,其摩尔比为0.3:1至3:1的线性和/或支链,优选二价支链二氧基部分和二价线性二氧基部分,二酰基部分通过酯键连接到二氧基部分 每个二酰基部分具有至少1.75个二氧基部分的比例,其中聚酯二醇基本上仅被醇羟基封端并且具有小于3的酸值。该新型聚酯二醇在生产聚氨酯/乙烯基聚合物中是非常有用的 通过与多异氰酸酯和可聚合的烯属不饱和单体反应的共聚物。 可以通过将聚酯二醇与可聚合的烯属不饱和单体,能够催化多异氰酸酯和多羟基化合物的聚氨酯形成反应的催化剂混合而用于此目的,并且所得组合物可用于分批或自动模塑操作。 新型硬质聚氨酯/乙烯基聚合物共聚物,增强或非增强,可用作制造结构和其他部件的金属替代品,例如汽车挡泥板,用于提供节能轻质零件,以及家电和商业 机壳。