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    • 3. 发明授权
    • Process for incorporation of a water-insoluble substance into a
hydrophilic layer
    • 将水不溶性物质并入亲水层的方法
    • US5376501A
    • 1994-12-27
    • US227387
    • 1994-04-14
    • August MarienRaf VoetsRafael SamijnMarc Stevens
    • August MarienRaf VoetsRafael SamijnMarc Stevens
    • B01F3/20B01J13/00C09D167/02G03C1/005G03C1/815G03C1/91G03C1/95G03C7/00G03C7/388G03F3/10G03C1/76
    • G03F3/10C09D167/02G03C1/005G03C1/815G03C7/3882Y10S430/134
    • Processes are disclosed for incorporating a water-insoluble substance in a diffusion resistant form into a hydrophilic colloidal layer of an element. In a first process A the water-insoluble substance is present during the polycondensation of diol(s) or polyol(s) and carboxylic acids, whereby at least 6 mole % of the reagents bear a water-solubilizing group, preferably a sulpho group in the salt form; the obtained mixture of polyester and water-insoluble substance is then dispersed in an aqueous medium. In an alternative process B the polyester is first prepared and then mixed homogeneously with the hydrophobe substance by melting in a reactor or extruder; the mixture is then similarly dispersed. The obtained latex is then incorporated in a hydrophilic colloidal layer which is coated on a support.The obtained element can serve as base for a reprographic image, e.g. a color proof image, or can form part of a complete photographic material.In a preferred embodiment the water-insoluble substance is a brightening agent.
    • 公开了将不溶于扩散的形式的水不溶性物质引入到元件的亲水性胶体层中的方法。 在第一方法A中,在二醇或多元醇和羧酸的缩聚期间存在水不溶性物质,由此至少6摩尔%的试剂具有水溶性基团,优选的是磺基 盐形式; 将得到的聚酯和水不溶性物质的混合物分散在水性介质中。 在替代方法B中,首先制备聚酯,然后通过在反应器或挤出机中熔融而与疏水物质均匀混合; 然后混合物类似地分散。 然后将所得胶乳掺入涂覆在载体上的亲水胶体层。 所获得的元件可以用作复制图像的基底,例如。 彩色图像,或可以形成完整的照相材料的一部分。 在优选的实施方案中,水不溶性物质是增白剂。