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    • 1. 发明申请
    • INKJET PRINTING FLUID
    • INKJET印刷油
    • WO2012030546A1
    • 2012-03-08
    • PCT/US2011/048212
    • 2011-08-18
    • EASTMAN KODAK COMPANYFALKNER, Catherine, AnnBRUST, Thomas, B.WANG, YongcaiYAU, Hwei-LingROBELLO, Douglas, Robert
    • FALKNER, Catherine, AnnBRUST, Thomas, B.WANG, YongcaiYAU, Hwei-LingROBELLO, Douglas, Robert
    • C09D11/00
    • C09D11/322C09D11/102C09D11/326
    • An inkjet printing fluid composition including water and dispersible polyurethane additive of the general formula of (I): wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; Χ 1 -Υ 1 -Χ 1 represents one or more soft segments wherein Y 1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X 2 -Y 2 -X 2 represents one or more hard segments wherein Y 2 represents the central portion of a unit that is the polymerization product of a C 2 -C 8 diol or diamine having a molecular weight of less than 250 Daltons; and X 1 , V and X 2 can be the same or different and are an -O- or -N- atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X 2 -Y 2 -X 2 hard segments are present at from 1 wt% to less than 13 wt% of the polyurethane additive. Also disclosed is a method for printing an inkjet image including I) providing an inkjet printing fluid according to the invention; and II) jetting the inkjet printing fluid in the form of ink drops onto a recording element to form a printed image.
    • 一种包含水和通式(I)的分散性聚氨酯添加剂的喷墨印刷液组合物:其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; α1-β1-β1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。 还公开了一种用于印刷喷墨图像的方法,包括:I)提供根据本发明的喷墨印刷液; 和II)将墨滴形式的喷墨打印流体喷射到记录元件上以形成打印图像。
    • 5. 发明申请
    • RECIRCULATING FLUID PRINTING SYSTEM AND METHOD
    • 循环流体印刷系统和方法
    • WO2012030553A3
    • 2012-05-03
    • PCT/US2011048365
    • 2011-08-19
    • MIS MARK RFALKNER CATHERINE ANNWANG YONGCAIYAU HWEI-LINGROBELLO DOUGLAS ROBERTEASTMAN KODAK CO
    • MIS MARK RFALKNER CATHERINE ANNWANG YONGCAIYAU HWEI-LINGROBELLO DOUGLAS ROBERT
    • C09D11/00
    • C09D11/326C09D11/102C09D11/322
    • A printing system for applying a printing fluid to a substrate, comprising a printing fluid applicator and a recirculating printing fluid supply supplying printing fluid to the applicator, wherein the printing fluid comprising water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; ?1-?1-?1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2-Y2-X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an -O- or -N- atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2-Y2-X2 hard segments are present at from 1 wt% to less than 13 wt% of the polyurethane additive.
    • 一种印刷系统,用于将印刷液体施加到基材上,包括印刷液体涂抹器和将印刷液体供应给涂布器的再循环印刷液体供给装置,其中包含水的印刷液和(I)通式的水分散性聚氨酯添加剂, 其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; α1-β1-β1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。
    • 9. 发明申请
    • RECIRCULATING FLUID PRINTING SYSTEM AND METHOD
    • 再循环流体印刷系统和方法
    • WO2012030553A2
    • 2012-03-08
    • PCT/US2011/048365
    • 2011-08-19
    • MIS, Mark, R.FALKNER, Catherine, AnnWANG, YongcaiYAU, Hwei-lingROBELLO, Douglas, RobertEASTMAN KODAK COMPANY
    • MIS, Mark, R.FALKNER, Catherine, AnnWANG, YongcaiYAU, Hwei-lingROBELLO, Douglas, Robert
    • C09D11/00
    • C09D11/326C09D11/102C09D11/322
    • A printing system for applying a printing fluid to a substrate, comprising a printing fluid applicator and a recirculating printing fluid supply supplying printing fluid to the applicator, wherein the printing fluid comprising water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; Χ 1 -Υ 1 -Χ 1 represents one or more soft segments wherein Y 1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X 2 -Y 2 -X 2 represents one or more hard segments wherein Y 2 represents the central portion of a unit that is the polymerization product of a C 2 -C 8 diol or diamine having a molecular weight of less than 250 Daltons; and X 1 , V and X 2 can be the same or different and are an -O- or -N- atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X 2 -Y 2 -X 2 hard segments are present at from 1 wt% to less than 13 wt% of the polyurethane additive.
    • 一种用于将印刷流体施加到基底上的印刷系统,包括印刷流体施加器和将印刷流体供应到施加器的再循环印刷流体供应器,其中所述印刷流体包括水和水分散性聚氨酯添加剂 (I)的通式中Z是作为二异氰酸酯聚合产物的单体单元的中心部分; X 1 -Y 1 -X 1代表一个或多个软链段,其中Y 1代表 作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元; W是一个或多个含有酸基的单元的中心部分; X 2 -Y 2 -X 2代表一个或多个硬链段,其中Y 2代表 作为C 2 -C 8二醇或分子量小于250道尔顿的二胺的聚合产物的单元; 和X 1,V和X 2可以相同或不同,并且是-O-或-N-原子; 并且进一步地其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足以提供大于35的酸值的酸基团数量,并且所述一种或多种X 2 -Y- 2 -X 2硬段的含量为聚氨酯添加剂的1重量%至小于13重量%。