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    • 7. 发明授权
    • Electroluminescent polymers and use thereof in light-emitting devices
    • 电致发光聚合物及其在发光器件中的应用
    • US07098297B2
    • 2006-08-29
    • US10932685
    • 2004-09-01
    • Qibing Pei
    • Qibing Pei
    • C08G73/00C08G73/06
    • C08G61/10C08G61/122C08G73/0627C08G73/0633C08G73/0638C09K11/06C09K2211/1003C09K2211/1007C09K2211/1014C09K2211/1408C09K2211/1416C09K2211/1425C09K2211/1458H01G11/48Y02E60/13Y10S428/917
    • The invention provides conjugated polymers that have good solubility and semiconductivity, and that display high photoluminescent and electroluminescent efficiency. Representative polymers containing monomer units having the general structure of formula (I) wherein: Ar1 and Ar2 are independently selected from the group consisting of monocyclic, bicyclic and polycyclic arylene, heteroarylene, substituted arylene and substituted heteroarylene groups; L is alkylene, alkenylene, substituted alkylene, substituted alkenylene, heteroalkylene, heteroalkenylene, substituted heteroalkylene, substituted heteroalkenylene, arylene, heteroarylene, substituted arylene, substituted heteroarylene, or a combination thereof; Q is a heteroatom; m is zero or 1; p is zero or 1, and q is zero or 1, with the proviso that when p is zero, then q is zero; x is zero or 1; Q1 and Q2 are independently selected from the group consisting of H, aryl, heteroaryl, substituted aryl, substituted heteroaryl, alkyl, substituted alkyl, heteroalkyl, and substituted heteroalkyl, and Q3 is selected from the group consisting of alkyl, substituted alkyl, heteroalkyl, and substituted heteroalkyl, with the proviso that when m is 1, Q1 and Q2 are other than H; and A− is a negatively charged counterion. Electroluminescent and other devices containing a polymer of the invention are also provided.
    • 本发明提供具有良好的溶解度和半导电性并且显示出高的光致发光和电致发光效率的共轭聚合物。 含有具有通式(I)的通式结构的单体单元的代表性聚合物其中:Ar 1和Ar 2独立地选自单环,双环和多环亚芳基, 亚杂芳基,取代的亚芳基和取代的亚杂芳基; L是亚烷基,亚烯基,取代的亚烷基,取代的亚烯基,杂亚烷基,杂亚烯基,取代的杂亚烷基,取代的亚杂烯基,亚芳基,亚杂芳基,取代的亚芳基,取代的亚杂芳基或它们的组合; Q是杂原子; m为零或1; p为零或1,q为零或1,条件是当p为零时,q为零; x为零或1; Q 1和Q 2独立地选自H,芳基,杂芳基,取代的芳基,取代的杂芳基,烷基,取代的烷基,杂烷基和取代的杂烷基, 并且Q 3选自烷基,取代的烷基,杂烷基和取代的杂烷基,条件是当m为1时,Q 1和Q 2 > 2 不是H; 而A - 是负电荷的抗衡离子。 还提供含有本发明聚合物的电致发光和其它装置。
    • 9. 发明授权
    • Arylamine-substituted poly (arylene vinylenes) and associated methods of preparation and use
    • 芳胺取代的聚(亚芳基亚乙烯基)和相关的制备和使用方法
    • US06414104B1
    • 2002-07-02
    • US09619372
    • 2000-07-19
    • Qibing Pei
    • Qibing Pei
    • C08G7300
    • H01L51/5012C07C211/56C08G61/02H01L51/0036H01L51/0038H01L51/0059Y02E10/549Y10S428/917
    • The invention provides novel conjugated polymers comprised of arylamine-substituted poly(arylene vinylenes). The polymers have the general structure (I) wherein: Ar is arylene, heteroarylene, substituted arylene or substituted heteroarylene containing one to three aromatic rings; R1 is an arylamine substituent having the formula —Ar1—N(R4R5) wherein Ar1 is as defined for Ar and R4 and R5 are independently hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, or substituted heteroatom-containing hydrocarbyl, or together form a cyclic group; and R2 and R3 are independently selected from the group consisting of hydrido, halo and cyano, or may be as defined for R4 and R5, or may together form a triple bond. Monomeric precursors and methods of synthesizing the precursors are also provided, as are electroluminescence and other devices containing a polymer of the invention.
    • 本发明提供由芳基胺取代的聚(亚芳基乙烯基)构成的新型共轭聚合物。 聚合物具有通式(I),其中:Ar是亚芳基,亚杂芳基,取代的亚芳基或含1至3个芳环的取代的亚杂芳基; R1是具有式-Ar1-N(R4R5)的芳基胺取代基,其中Ar1如对Ar和R4所定义,R5独立地是烃基,取代的烃基,含杂原子的烃基或取代的含杂原子的烃基,或一起形成环状 组; 并且R 2和R 3独立地选自氢,卤素和氰基,或可以如R4和R5所定义,或者可以一起形成三键。 还提供单体前体和合成前体的方法,电致发光和含有本发明聚合物的其它装置也是如此。