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    • 3. 发明专利
    • Detergent compositions
    • GB599542A
    • 1948-03-15
    • GB2933145
    • 1945-12-05
    • WILLIAM BAIRDGERALD PATRICK CROWLEYICI LTD
    • C11D1/52C11D1/72
    • A detergent composition, suitable for use in the cleaning of soiled textile materials, comprises (i) a condensation product of ethylene oxide with an alkylated phenol and (ii) up to 400 per cent. based on the weight of ingredient (i) of a b -monohydroxyethylamide of a fatty acid. Ingredient (i) must be derived from an alkylated phenol bearing an alkyl substituent or substituents totalling between 6 and 20 carbon atoms, one molecular proportion of the alkylated phenol being condensed with between 6 and 30 molecular proportions of ethylene oxide while ingredient (ii) must be derived from a fatty acid of from 9 to 19 carbon atoms. The detergent composition may be used in aqueous solution with the addition of alkali, for example soda ash. Alkylated phenols which may be used in preparing ingredient (i) include a , a , g , g -tetramethylbutylphenol, dodecylphenol, di-tertiary butylphenol, octylphenols, octylcresols and 4-methyl-2-tertiary octylphenol. Suitable examples of ingredient (ii) are stearo-b -hydroxyethylamide, lauro-b -hydroxyethylamide, oleo-b -hydroxyethylamide, ricinoleo-b -hydroxyethylamide and the b -hydroxyethylamides of mixtures of fatty acids, for example those derived from coconut oil, tallow or castor oil. In examples the alkylated phenol of ingredient (i) is p-(a , a , g , g -tetramethylbutyl) phenol, 4 methyl-2-(a , a , g , g -tetramethylbutyl) phenol or 4-methyl-2-tertiary-octyl-phenol while the fatty acid of ingredient (ii) is coconut oil fatty acids, stearic acid and stearic acid respectively. In each case an aqueous solution of the detergent composition together with soda ash is compared with a similar solution not containing ingredient (ii). Specification 470,181 is referred to.
    • 5. 发明专利
    • Construction of chairs, davenports, and like furniture
    • GB219572A
    • 1924-07-31
    • GB3047623
    • 1923-12-04
    • CECIL PATRICK CROWLEY
    • A47C7/54
    • 219,572. Vidal, A. E., (Crowley, C. P.). Dec. 4, 1923. Cushions and the like, attaching to other articles.-Relates to a chair constructed to receive a detachable covering in such a manner that the securing means are hidden from view. The side members 2 are movably connected to the back 1 and are locked in place by catches 16 carried by a front bar 11. The seat 3 is removable and has a separate cover 35, 36 the fastening edges 37 of which are concealed by the back, sides and front bar when in place. One. cover is used for the back and arms, the arm covers 43 being formed as lateral extensions of the main cover 40 the front extension 41 of which is secured in a recess 5 below the back. The rear fastening edges 47 of the back and arm covers are hidden in the arm joints when the arms are returned to the normal position, and the front edges of the arm covers by detachable panels 27 on the front faces of the arms. The edges may be fastened by pins 53 projecting from the chair structure.
    • 8. 发明申请
    • Fungicides
    • US20060240988A1
    • 2006-10-26
    • US10536516
    • 2003-11-10
    • Roger SalmonPatrick CrowleyDavid Bacon
    • Roger SalmonPatrick CrowleyDavid Bacon
    • A01N37/18
    • C07D249/08A01N39/04C07C235/20C07C255/30C07C317/28C07C323/41
    • Fungicidal compounds of the general formula (1): wherein X, Y and Z are independently H, halogen, C1-4 alkyl, halo(C1-4)alkyl, C2-4alkenyl, halo(C2-4)alkenyl, C24 alkynyl, halo(C2-4)alkynyl, C1-4 alkoxy, halo(C1-4)alkoxy, —S(O)n(C1-4)alkyl where n is 0, 1 or 2 and the alkyl group is optionally substituted with fluoro, —OS02(C1-4)alkyl where the alkyl group is optionally substituted with fluoro, cyano, nitro, C1-4 alkoxycarbonyl, —CONR′R″, —COR′, —NR′COR″ or —NR′COOR′″ where R′ and R″ are independently H or C1-4, alkyl and R′″ is C1-4 alkyl, provided that at least one of X and Z is other than H; R1 is C1-4alkyl, C2-4 alkenyl or C2-4 alkynyl in which the alkyl, alkenyl and alkynyl groups are optionally substituted on their terminal carbon atom with one, two or three halogen atoms, with a cyano group, with a C1-4 alkylcarbonyl group, with a C1-4 alkoxycarbonyl group or with a hydroxy group; R2 is H, C1-4 alkyl, C1-4 alkoxymethyl or benzyloxymethyl in which the phenyl ring of the benzyl moiety is optionally substituted with C1-4alkoxy; R3 and R4 are independently H, C1-3 alkyl, C2-3 alkenyl or C2-3 alkynyl provided that both are not H and that when both are other than H their combined total of carbon atoms does not exceed 4, or R3 and R4 join with the carbon atom to which they are attached to form a 3 or 4 membered carbocyclic ring optionally containing one 0, S or N atom and optionally substituted with halo or C1-4alkyl; and R5 is unsubstituted C3-4 alkyl, unsubstituted C3-6 cycloalkyl or C1-4 alkyl or C3-6 cycloalkyl in which the alkyl and cycloalkyl groups are substituted with halo, hydroxy, C1-6 alkoxy, cyano, C1-4 alkylcarbonyloxy, aminocarbonyloxy, mono- or di(C1-4)alkylaminocarbonyloxy, —S(O)″(C1-6)alkyl where n is 0, 1 or 2, triazolyl, tri(C1-4)alkylsilyloxy, optionally substituted phenoxy, optionally substituted thienyloxy, optionally substituted benzyloxy or optionally substituted thienyl-methoxy, in which the optionally substituted phenyl and thienyl rings of phenoxy, thienyloxy, benzyloxy and thienylmethoxy are optionally substituted with one, two or three substituents selected from halo, hydroxy, mercapto, C1-4 alkyl, C2-4 alkenyl, C2-4 alkynyl, C1-4alkoxy, C2-4 alkenyloxy, C2-4 alkynyloxy, halo(C1-4)alkyl, halo(C1-4)alkoxy, C1-4 alkylthio; halo(C1-4)alkylthio, hydroxy(C1-4)alkyl, C1-4 alkoxy(C1-4)alkyl, C3-6 cycloalkyl, C3-6 cycloalkyl(C1-4)alkyl, phenoxy, benzyloxy, benzoyloxy, cyano, isocyano, thiocyanato, isothiocyanato, nitro, —NR—R′, —NHCORm, —NHCONRmR″, —CONRmR″, —S02Rm, —OS02Rm, —CORM, —CR′═NR″ or —N═CRmR″, in which R′″ and R″ are independently hydrogen, CI-4 alkyl, halo(C1-4)alkyl, C1-4 alkoxy, halo(C1-4)alkoxy, C1-4alkylthio, C3-6 cycloalkyl, C3-6 cycloalkyl(C1-4)alkyl, phenyl or benzyl, the phenyl and benzyl groups being optionally substituted with halogen, C1-4alkyl or C1-4 alkoxy.
    • 10. 发明申请
    • Fungicides based on nitrogen-containing heterocycles
    • US20060100203A1
    • 2006-05-11
    • US10540039
    • 2003-12-03
    • Patrick CrowleyMarkus DoblerUrs MuellerJohn Williams
    • Patrick CrowleyMarkus DoblerUrs MuellerJohn Williams
    • A01N43/90A01N43/42
    • C07D471/04
    • Fungicidal compounds having the general formula (1): formula (1) wherein W, Z and one of X and Y are N and the other one of X and Y is CR8; R8 is H, halo, C1-4alkyl, C1-4alkoxy, C1-4alkylthio or halo(C1-4)alkyl; R and R2 are independently H, halo, C1-8 alkyl, C1-8 alkoxy, C1-8 alkylthio, C2-8alkenyl, C2-8 alkynyl, cyano or NR3R4, provided that at least one of R and R2 is NR3R4; R1 is halo, C1-8 alkyl, C2-8 alkenyl, C2-8alkynyl, C3-8 cycloalkyl, C3-8 cycloalkyl(C1-6)-alkyl, C1-8 alkoxy, C1-8 alkylthio, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio, aryl(C1-4)alkyl, aryl(C1-4)alkoxy, heteroaryl(C1-4)alkyl, heteroaryl(C1-4)alkoxy, aryl(C1-4)alkylthio, heteroaryl(C1-4)alkylthio, morpholino, piperidino or pyrrolidino; R3 and R4 are independently H, C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, aryl, aryl(C1-8)-alkyl, C3-8cycloalkyl, C3-8 cycloalkyl(C1-6)alkyl, heteroaryl, heteroaryl(C1-8)alkyl, NR5R6, provided that not both R3 and R4 are H or NR5R6, or R3 and R4 together form a C3-7 alkylene or C3-7 alkenylene chain optionally substituted with one or more C1-4 alkyl or C1-4 alkoxy groups, or, together with the nitrogen atom to which they are attached, R3 and R4 form a morpholine, thiomorpholine, thiomorpholine S-oxide or thiomorpholine S-dioxide ring or a piperazine or piperazine N-(C1-4)alkyl (especially N-methyl) ring; and R5 and R6 are independently H, C1-8 alkyl, C2-8 alkenyl, C2-8-alkynyl, aryl, aryl(C1-8)alkyl, C3-8 cycloalkyl, C3-8 cycloalkyl(C1-6)alkyl, heteroaryl or heteroaryl(C1-8)alkyl; any of the foregoing alkyl, alkenyl, alkynyl or cycloalkyl groups or moieties (other than for R8) being optionally substituted with halogen, cyano, C1-6 alkoxy, C1-6alkylcarbonyl, C1-6 alkoxycarbonyl, C1-6 haloalkoxy, C1-6 alkylthio, tri(C1-4)alkylsilyl, C1-6 alkylamino or C1-6 dialkylamino, any of the foregoing morpholine, thiomopholine, piperidine, piperazine and pyrrolidine rings being optionally substituted with C1-4 alkyl (especially methyl), and any of the foregoing aryl or heteroaryl groups or moieties being optionally substituted with one or more substituents selected from halo, hydroxy, mercapto, C1-6alkyl, C2-6 alkenyl, C2-6 alkynyl, C1-6 alkoxy, C2-6 alkenyloxy, C2-6 alkynyloxy, halo(C1-6)alkyl, halo(C1-6)alkoxy, C1-6 alkylthio, halo(C1-6)alkylthio, hydroxy(C1-6)alkyl, C1-4 alkoxy(C1-6)alkyl, C3-6 cycloalkyl, C3-6cycloalkyl(C1-4)alkyl, phenoxy, benzyloxy, benzoyloxy, cyano, isocyano, thiocyanato, isothiocyanato, nitro, —NR″′R″″, NHCOR″′, —NHCONR″′R″″, —CONR″′R″″, —SO2R″′, —OSO2R″′, —COR″′, —CR″′═NR″″ or —N═CR ″′R″″, in which R″′ and R″″ are independently hydrogen, C1-4 alkyl, halo(C1-4)alkyl, C1-4 alkoxy, halo(C1-4)alkoxy, C1-4 alkylthio, C3-6 cycloalkyl, C3-6 cycloalkyl(C1-4)alkyl, phenyl or benzyl, the phenyl and benzyl groups being optionally substituted with halogen, C1-4 alkyl or C1-4 alkoxy.