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1. 发明授权

US08827086B2 Ultrafiltration membrane 有权
标题翻译：超滤膜
公开(公告)号：US08827086B2
公开(公告)日：2014-09-09
申请号：US12299631
申请日：2007-05-03
申请人： Wolfgang Ansorge , Ernst Spindler , Richard Krüger , Martin Rütering , Oliver Schuster
发明人： Wolfgang Ansorge , Ernst Spindler , Richard Krüger , Martin Rütering , Oliver Schuster
IPC分类号： B01D69/08 , B01D71/68 , B01D61/14 , B01D67/00 , C02F1/44
CPC分类号： B01D61/145 , B01D67/0011 , B01D67/0016 , B01D69/081 , B01D69/087 , B01D71/68 , B01D2325/02 , B01D2325/022 , B01D2325/026 , B01D2325/04 , B01D2325/20 , B01D2325/24 , B01D2325/36
摘要： The invention relates to a hollow-fiber membrane for ultrafiltration made from a hydrophobic aromatic sulfone polymer and at least one hydrophilic polymer, the membrane having an open-pore separating layer on the lumen side, an adjoining supporting layer with asymmetric, sponge-like pore structure without finger pores and an outer layer adjoining the supporting layer towards the outer surface. The separating layer has a cutoff between 20 000 and 200 000 daltons, a thickness of max. 10% of the membrane thickness and an essentially isotropic pore structure. The size of the pores in the supporting layer initially increases up to a zone with maximum pore size, and then decreases towards the outer layer, and the outer layer exhibits a thickness of 10 to 30% of the wall thickness and an essentially isotropic pore structure. The mean size of the pores in the outer layer is larger than in the separating layer, but smaller than in the supporting layer. The wall thickness of the hollow-fiber membrane lies in the range from 100 to 450 μm. The invention relates furthermore to a method for the production of these hollow-fiber membranes.
摘要翻译：本发明涉及一种用于由疏水性芳香族砜聚合物和至少一种亲水性聚合物制成的超滤的中空纤维膜，所述膜在内腔侧具有开孔分离层，邻接的支撑层具有不对称的海绵状孔没有手指孔的结构和与支撑层相邻的外层朝向外表面。分离层的截留值在20 000至200 000道尔顿之间，厚度最大。 10％的膜厚度和基本上各向同性的孔结构。支撑层中的孔的尺寸最初增加到具有最大孔径的区域，然后向外层减小，并且外层的厚度为壁厚的10至30％，并且基本上具有各向同性的孔结构。外层的孔的平均尺寸大于分离层中的孔的平均尺寸，但小于支撑层中的孔的平均尺寸。中空纤维膜的壁厚在100〜450μm的范围内。本发明还涉及生产这些中空纤维膜的方法。

2. 发明授权

US08727136B2 Microfiltration membrane with improved filtration properties 有权
标题翻译：具有改善过滤性能的微滤膜
公开(公告)号：US08727136B2
公开(公告)日：2014-05-20
申请号：US12789593
申请日：2010-05-28
申请人： Wolfgang Ansorge , Oliver Schuster , Friedbert Wechs , Klaus Dombrowski
发明人： Wolfgang Ansorge , Oliver Schuster , Friedbert Wechs , Klaus Dombrowski
IPC分类号： B01D63/08 , B01D71/68 , C02F1/00 , B01D67/00
CPC分类号： B01D63/081 , B01D67/0011 , B01D67/0013 , B01D67/0016 , B01D67/0027 , B01D69/02 , B01D69/06 , B01D71/68 , B01D2325/022 , B01D2325/023 , B01D2325/24 , B01D2325/36 , B01D2325/38
摘要： Method for producing this membrane from a casting solution comprising the hydrophobic first sulfone polymer and the hydrophilic second polymer in a solvent system, the method comprising the steps of pouring the casting solution, conditioned to a molding temperature, onto a carrier to form a film, which carrier has a temperature that is higher in comparison to the molding temperature, conveying the film through a climate-controlled zone, initiating the coagulation in a coagulation bath for the formation of a membrane structure, withdrawing the membrane structure from the carrier with a speed that is increased in comparison to the carrier speed, stabilizing, extracting, and subsequently drying the membrane.
摘要翻译：在溶剂系统中由包含疏水性第一砜聚合物和亲水性第二聚合物的流延溶液制备该膜的方法，该方法包括以下步骤：将调节至模塑温度的浇铸溶液倒入载体上以形成膜，该载体的温度与成型温度相比较高，将膜输送通过气候控制区，在用于形成膜结构的凝固浴中引发凝结，以速度从载体中取出膜结构其与载体速度相比增加，稳定，提取和随后干燥膜。

3. 发明授权

US07811507B2 Dialysis membrane having improved ability for removal of middle molecules 有权
标题翻译：具有改善中间分子去除能力的透析膜
公开(公告)号：US07811507B2
公开(公告)日：2010-10-12
申请号：US10588696
申请日：2005-02-15
申请人： Friedbert Wechs , Arne Gehlen , Bodo Von Harten , Richard Kruger , Oliver Schuster
发明人： Friedbert Wechs , Arne Gehlen , Bodo Von Harten , Richard Kruger , Oliver Schuster
IPC分类号： B01D63/02 , B29C39/14
CPC分类号： B01D71/68 , B01D67/0011 , B01D67/0016 , B01D67/0088 , B01D67/0095 , B01D67/0097 , B01D69/02 , B01D69/08 , B01D2323/02 , B01D2323/12 , B01D2323/36 , B01D2325/14 , B01D2325/20 , Y10T428/2975
摘要： A hydrophilic semipermeable hollow-fibre membrane for blood treatment, with an integrally asymmetric structure based on a synthetic polymer. The hollow-fiber membrane possess on its inner surface a separating layer and an adjoining open-pored supporting layer, and has an ultrafiltration rate in albumin solution of 5 to ≦25 ml/(h·m2·mmHg). The hollow fiber membrane is free from pore-stabilizing additives and has a maximum sieving coefficient for albumin of 0.005 and a sieving coefficient of cytochrome c that satisfies the equation SCcc≧5·10−5·UFRAlb3−0.004·UFRAlb2+0.1081·UFRAlb−0.25.
摘要翻译：一种用于血液处理的亲水性半透性中空纤维膜，具有基于合成聚合物的整体不对称结构。中空纤维膜的内表面具有分离层和邻接的开孔支撑层，并且在白蛋白溶液中具有5至＆lt; llE; 25ml /（h·m 2·mmHg）的超滤速率。中空纤维膜不含孔稳定添加剂，白蛋白的最大筛分系数为0.005，细胞色素c的筛分系数满足公式SCcc≥5·10-5·UFRAlb3-0.004·UFRAlb2 + 0.1081·UFRAlb- 0.25。

4. 发明授权

US07547486B2 Direct methanol fuel cell 有权
标题翻译：直接甲醇燃料电池
公开(公告)号：US07547486B2
公开(公告)日：2009-06-16
申请号：US10974490
申请日：2004-10-27
申请人： Zhengming Zhang , Britta Zimmerer , Quan Huang , Oliver Schuster
发明人： Zhengming Zhang , Britta Zimmerer , Quan Huang , Oliver Schuster
IPC分类号： H01M4/94 , H01M8/10
CPC分类号： H01M8/1011 , H01M2300/0082 , H01M2300/0094 , Y02E60/523
摘要： A direct methanol fuel cell has a proton conducting membrane (PCM), a catalyst in contact with the PCM, a gas diffusion layer in contact with the catalyst, and a conducting plate in contact with the gas diffusion membrane. The gas diffusion layer comprises a microporous membrane. The microporous membrane may be a microporous membrane, a laminate of a microporous membrane, and a skinned microporous membrane.
摘要翻译：直接甲醇燃料电池具有质子传导膜（PCM），与PCM接触的催化剂，与催化剂接触的气体扩散层和与气体扩散膜接触的导电板。气体扩散层包括微孔膜。微多孔膜可以是微孔膜，微孔膜和表皮微孔膜的层压体。

5. 发明申请

US20050202307A1 Direct methanol fuel cell 有权
标题翻译：直接甲醇燃料电池
公开(公告)号：US20050202307A1
公开(公告)日：2005-09-15
申请号：US10974490
申请日：2004-10-27
申请人： Zhengming Zhang , Britta Zimmerer , Quan Huang , Oliver Schuster
发明人： Zhengming Zhang , Britta Zimmerer , Quan Huang , Oliver Schuster
IPC分类号： H01M4/94 , H01M8/02 , H01M8/10
CPC分类号： H01M8/1011 , H01M2300/0082 , H01M2300/0094 , Y02E60/523
摘要： A direct methanol fuel cell has a proton conducting membrane (PCM), a catalyst in contact with the PCM, a gas diffusion layer in contact with the catalyst, and a conducting plate in contact with the gas diffusion membrane. The gas diffusion layer comprises a microporous membrane. The microporous membrane may be a microporous membrane, a laminate of a microporous membrane, and a skinned microporous membrane.
摘要翻译：直接甲醇燃料电池具有质子传导膜（PCM），与PCM接触的催化剂，与催化剂接触的气体扩散层和与气体扩散膜接触的导电板。气体扩散层包括微孔膜。微多孔膜可以是微孔膜，微孔膜和表皮微孔膜的层压体。

6. 发明申请

US20100230843A1 MICROFILTRATION MEMBRANE WITH IMPROVED FILTRATION PROPERTIES 有权
标题翻译：具有改进过滤特性的微滤膜
公开(公告)号：US20100230843A1
公开(公告)日：2010-09-16
申请号：US12789593
申请日：2010-05-28
申请人： Wolfgang Ansorge , Oliver Schuster , Friedbert Wechs , Klaus Dombrowski
发明人： Wolfgang Ansorge , Oliver Schuster , Friedbert Wechs , Klaus Dombrowski
IPC分类号： B01D67/00 , C08J3/00
CPC分类号： B01D63/081 , B01D67/0011 , B01D67/0013 , B01D67/0016 , B01D67/0027 , B01D69/02 , B01D69/06 , B01D71/68 , B01D2325/022 , B01D2325/023 , B01D2325/24 , B01D2325/36 , B01D2325/38
摘要： Method for producing this membrane from a casting solution comprising the hydrophobic first sulfone polymer and the hydrophilic second polymer in a solvent system, the method comprising the steps of pouring the casting solution, conditioned to a molding temperature, onto a carrier to form a film, which carrier has a temperature that is higher in comparison to the molding temperature, conveying the film through a climate-controlled zone, initiating the coagulation in a coagulation bath for the formation of a membrane structure, withdrawing the membrane structure from the carrier with a speed that is increased in comparison to the carrier speed, stabilizing, extracting, and subsequently drying the membrane.
摘要翻译：在溶剂系统中由包含疏水性第一砜聚合物和亲水性第二聚合物的流延溶液制备该膜的方法，该方法包括以下步骤：将调节至模塑温度的浇铸溶液倒入载体上以形成膜，该载体的温度与成型温度相比较高，将膜输送通过气候控制区，在用于形成膜结构的凝固浴中引发凝结，以速度从载体中取出膜结构其与载体速度相比增加，稳定，提取和随后干燥膜。

7. 发明授权

US5551839A Pump housing for rotary pumps 失效
标题翻译：旋转泵泵壳
公开(公告)号：US5551839A
公开(公告)日：1996-09-03
申请号：US331526
申请日：1994-10-28
申请人： Oliver Schuster , Axel Riel , Kurt Seitz
发明人： Oliver Schuster , Axel Riel , Kurt Seitz
IPC分类号： F04D29/42 , F04D29/62 , F04D29/44
CPC分类号： F04D29/628 , F04D29/426 , F04D29/4266 , F04D29/428
摘要： A standard pump housing is provided for rotary pumps having impellers with various delivery heads and flow rates. The pump housing can be manufactured by a simple sheet metal shaping technique, is very stiff even at the joint of the pressure pipe and achieves the best possible efficiency. The pump housing has a flattened part at its circumference which narrows the flow room arranged downstream of the impeller and delimited by the pump housing, in the direction of the pump axis. An opening for connecting with a pipe having a standard connection cross-section is arranged in the flattened part of the housing.
摘要翻译： PCT No.PCT / EP93 / 00992 Sec。 371日期：1994年10月28日 102（e）日期1994年10月28日PCT提交1993年4月24日PCT公布。公开号WO93 / 22564 日期1993年11月11日为具有各种输送头和流量的叶轮的旋转泵提供标准泵壳体。泵壳可以通过简单的钣金成型技术制造，即使在压力管的接头处也非常坚硬，达到最佳的效率。泵壳体在其圆周处具有扁平部分，其沿着泵轴线的方向使布置在叶轮下游并由泵壳体限定的流动室变窄。用于与具有标准连接横截面的管连接的开口布置在壳体的扁平部分中。

8. 发明授权

US08302781B2 High-flux dialysis membrane with an improved separation behaviour 有权
标题翻译：高通量透析膜具有改善的分离行为
公开(公告)号：US08302781B2
公开(公告)日：2012-11-06
申请号：US10588695
申请日：2005-02-15
申请人： Friedbert Wechs , Arne Gehlen , Bodo Von Harten , Richard Kruger , Oliver Schuster
发明人： Friedbert Wechs , Arne Gehlen , Bodo Von Harten , Richard Kruger , Oliver Schuster
IPC分类号： B01D63/02 , B01D67/00 , B01D69/00 , B01D69/08 , B01D39/14
CPC分类号： B01D69/08 , B01D67/0013 , B01D67/0088 , B01D67/0095 , B01D67/0097 , B01D69/02 , B01D71/64 , B01D71/68 , B01D2323/02 , B01D2323/12 , B01D2323/36 , B01D2325/14 , B01D2325/20
摘要： A hydrophilic, semipermeable hollow-fiber membrane for blood treatment, with an integrally asymmetric structure based on a synthetic polymer. The hollow-fiber membrane possesses on its inner surface a porous separating layer and an open-pored supporting layer adjoining the separating layer, and has an ultrafiltration rate in albumin solution of 25 to 60 ml/(h·m2·mmHg). The hollow-fiber membrane is free from pore-stabilizing additives, and has a minimum sieving coefficient for cytochrome c of 0.8 and maximum sieving coefficient for albumin of 0.005. Method for the preparation of such membranes based on coagulation induced by a non-solvent, whereby a spinning solution of a synthetic first polymer and possibly a hydrophilic second polymer is extruded into a hollow fiber through the annular slit of a hollow-fiber die with simultaneous extrusion of a coagulation medium as the interior filler through the central opening of the hollow-fiber die, the interior filler initiating coagulation in the interior of the hollow fiber as a result of which a separating layer on the inner surface of the hollow-fiber membrane is formed as well as the membrane structure, the method being characterized in that the interior filler contains a polyelectrolyte with negative fixed charges.
摘要翻译：用于血液处理的亲水性半透性中空纤维膜，具有基于合成聚合物的整体不对称结构。中空纤维膜在其内表面具有邻接分离层的多孔分离层和开孔支撑层，并且在白蛋白溶液中的超滤速率为25至60ml /（h·m 2·mmHg）。中空纤维膜不含孔稳定添加剂，细胞色素c的筛分系数最小为0.8，白蛋白筛分系数为0.005。基于由非溶剂引起的凝结制备这种膜的方法，由此将合成的第一聚合物和可能的亲水性第二聚合物的纺丝溶液通过中空纤维模具的环形狭缝挤出成中空纤维，同时通过中空纤维模头的中心开口挤出凝固介质作为内部填料，内部填料在中空纤维内部引发凝结，由此在中空纤维膜的内表面上形成分离层形成膜结构，该方法的特征在于内部填充物含有具有负固定电荷的聚电解质。

9. 发明申请

US20110239865A1 HYDROPHOBIC OZONE-STABLE MEMBRANE MADE OF POLYVINYLIDENE FLUORIDE 有权
标题翻译：聚偏二氟乙烯的疏水性臭氧稳定膜
公开(公告)号：US20110239865A1
公开(公告)日：2011-10-06
申请号：US13132941
申请日：2009-12-07
申请人： Quan Huang , Karl Bauer , Phung Duong , Oliver Schuster
发明人： Quan Huang , Karl Bauer , Phung Duong , Oliver Schuster
IPC分类号： B01D19/00 , D01D5/247
CPC分类号： B01D69/087 , B01D69/08 , B01D71/34 , B01D71/76 , B01D2325/02 , B01D2325/24
摘要： The invention relates to a hydrophobic, integrally asymmetrical hollow-fiber membrane made of a vinylidene fluoride homopolymer or copolymer, wherein the wall of said membrane has a microporous supporting layer having a sponge-like, open-pored, essentially isotropic pore structure without finger pores, said supporting layer extending across at least 90% of the wall thickness and having pores with an average diameter of less than 0.5 μm. The hollow-fiber membrane is characterized in that it has a separating layer adjacent to the supporting layer on its outer surface and that it has an outer surface with a homogeneous, uniform structure without pores, a porosity in the range from 40 to 80 vol. %, a wall thickness from 25 to 100 μm, a diameter of the lumen of the hollow-fiber membrane from 100 to 500 μm, a permeability for nitrogen of at least 25 ml/(cm2·min·bar), and an elongation at break of at least 250%. The invention further relates to a method for producing hollow-fiber membranes of this type.
摘要翻译：本发明涉及由偏二氟乙烯均聚物或共聚物制成的疏水，整体不对称的中空纤维膜，其中所述膜的壁具有微孔支撑层，其具有海绵状，开孔，基本上各向同性的孔结构，无指孔所述支撑层延伸穿过至少90％的壁厚并且具有平均直径小于0.5μm的孔。中空纤维膜的特征在于，在其外表面上具有与支撑层相邻的分离层，并且其具有不具有孔的均匀，均匀结构的外表面，孔隙率在40至80体积％范围内。％，壁厚为25〜100μm，中空纤维膜的内径为100〜500μm，氮的渗透性为25ml /（cm 2·分钟·bar）以上，至少打破250％。本发明还涉及这种类型的中空纤维膜的制造方法。

10. 发明申请

US20080000828A1 High-Flux Dialysis Membrane With an Improved Separation Behaviour 有权
标题翻译：高通量透析膜具有改进的分离行为
公开(公告)号：US20080000828A1
公开(公告)日：2008-01-03
申请号：US10588695
申请日：2005-02-15
申请人： Friedbert Wechs , Arne Gehlen , Bodo Harten , Richard Kruger , Oliver Schuster
发明人： Friedbert Wechs , Arne Gehlen , Bodo Harten , Richard Kruger , Oliver Schuster
IPC分类号： B01D63/02 , B01D39/14 , B01D67/00 , B01D69/00 , B01D69/02 , B01D69/08 , B29C47/00 , B29C47/02
CPC分类号： B01D69/08 , B01D67/0013 , B01D67/0088 , B01D67/0095 , B01D67/0097 , B01D69/02 , B01D71/64 , B01D71/68 , B01D2323/02 , B01D2323/12 , B01D2323/36 , B01D2325/14 , B01D2325/20
摘要： A hydrophilic, semipermeable hollow-fibre membrane for blood treatment, with an integrally asymmetric structure based on a synthetic polymer. The hollow-fibre membrane possesses on its inner surface a porous separating layer and an open-pored supporting layer adjoining the separating layer, and has an ultrafiltration rate in albumin solution of 25 to 60 ml/(h·m2·mmHg). The hollow-fibre membrane is free from pore-stabilising additives, and has a minimum sieving coefficient for cytochrome c of 0.8 and maximum sieving coefficient for albumin of 0.005. Method for the preparation of such membranes based on coagulation induced by a non-solvent, whereby a spinning solution of a synthetic first polymer and possibly a hydrophilic second polymer is extruded into a hollow fibre through the annular slit of a hollow-fibre die with simultaneous extrusion of a coagulation medium as the interior filler through the central opening of the hollow-fibre die, the interior filler initiating coagulation in the interior of the hollow fibre as a result of which a separating layer on the inner surface of the hollow-fibre membrane is formed as well as the membrane structure, the method being characterised in that the interior filler contains a polyelectrolyte with negative fixed charges.
摘要翻译：用于血液处理的亲水性半透性中空纤维膜，具有基于合成聚合物的整体不对称结构。中空纤维膜在其内表面具有邻接分离层的多孔分离层和开孔支撑层，并且在白蛋白溶液中的超滤速率为25至60ml /（hm 2 / .mmHg）。中空纤维膜不含孔稳定添加剂，细胞色素c的筛分系数最小为0.8，白蛋白筛分系数为0.005。基于由非溶剂引起的凝结制备这种膜的方法，由此将合成的第一聚合物和可能的亲水性第二聚合物的纺丝溶液通过中空纤维模具的环形狭缝挤出成中空纤维，同时通过中空纤维模头的中心开口挤出凝固介质作为内部填料，内部填料在中空纤维内部引发凝结，由此在中空纤维膜的内表面上形成分离层形成膜结构，该方法的特征在于内部填充物含有具有负固定电荷的聚电解质。

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